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(9e) c01 Basic Concepts of Chemistry

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1: The mass of 1 mole of electrons is :

(a)
(b) 1.008 mg
(c) 0.55 mg
(d)

2: Which one of the following is ambiguous ?


(a) A mole of electron
(b) A mole of sodium atoms
(c) A mole of potassium ions
(d) A mole of hydrogen

3: If 30 mL of H2 and 20 mL of O2 reacts to form water, what is left at the end of the reaction ?
(a) 10 mL of H2
(b) 5 mL of H2
(c) 10 mL of O2
(d) 5 mL of O2

4: The number of atoms present in 0.1 mole of P 4 (atomic mass = 31) are
(a) atoms
(b) same as in 0.05 mole of S8
(c) same as in 3.2 g of sulphur
(d) None

5: Find the equivalent mass of zinc if 1.98 g of zinc displaced 1.92 g of copper from CuSO 4 solution. (equivalent mass of Cu =
31.8)
(a) 32.79
(b) 32.3
(c) 65.5
(d) 63.5

6: 1.520 g of a certain metal hydroxide on ignition gave 0.995 g of metal oxide. The equivalent mass of the metal is
(a) 3
(b) 18
(c) 12
(d) 9

7: Which has maximum number of atoms ?


(a) 24g of C (12)
(b) 56g of Fe (56)
(c) 27g of Al (27)
(d) 108g of Ag (108)

8: Which of the following is a metalloid ?


(a) Bromine
(b) Bismuth
(c) Graphic
(d) Francium

9: How many seconds are three in 2 days ?


(a)

(b)
(c) 172800
(d) 232800

10: 1 mile = ______


(a) 1.2 km
(b) 1.4 km
(c) 1.52 km
(d) 1.6 km

11: The average mass of an Indian male is 150 pounds, the mass in kg is
(a) 58 kg
(b) 68 kg
(c) 67.5 kg
(d) 68.25 kg

12: How many moles are present in 4.68 mg of Si (at mass of Si = 28 amu)
(a)

(b)
(c) 167
(d) 16.7

13: The number of atoms in 4.25 g of NH3 is approximately


(a)

(b)

(c)

(d)

14: 4.4 g of an unknown gas occupies 2.24 L of volume under N.T.P. conditions. The gas may be
(a) CO2
(b) CO
(c) O2
(d) SO2

15: The equivalent mass of phosphoric acid in the reaction :


is
(a) 49
(b) 98
(c) 32.66
(d) None of these

16: Among the following pairs of compounds, the one that illustrates the law of multiple proportion is
(a) NH3 and NF3
(b) CO2 and CS2
(c) CS2 and FeSO4
(d) SnCl2, SnCl4

17: The number of atoms in 52 u of He are


(a) 13
(b)
(c) 52
(d)

18: One requires 0.01 mole of . Mass of to be taken is :


(a) 0.322 g
(b) 32.2 g
(c) 31.8 g
(d) 3.22 g

19: B1g of an element gives B2g of its chloride, the equivalent mass of the element is :

(a)

(b)

(c)

(d)

20: Dulong and Petit's law is valid only for


(a) Solids
(b) Liquids
(c) Gases
(d) Plasma state

21: 0.5 mol of potassium ferrocyanide contains carbon equal to


(a) 1.5 mol
(b) 36 g
(c) 18 g
(d) 3.6 g

22: Law of multiple proportion was given by


(a) Landolt
(b) Dalton
(c) Richter
(d) Proust
23: How many gram atoms of oxygen are contained in 0.25 mole of (Hypo) ?
(a) 0.5
(b) 0.75
(c) 2.0
(d) 1.20

24: The charge in coulombs on ion is :

(a)

(b)

(c)

(d)

25: If 0.24 g of a volatile liquid upon vaporization gives 45 mL of vapours at NTP. What will be the vapour density of the
substance ? (Density of )

(a) 95.39
(b) 5.993
(c) 95.93
(d) 56.0

26: The mass of 90% H2SO4 that would be required for notarization of 60 g NaOH is
(a) 0.8167 g
(b) 81.67 g
(c) 0.735 g
(d) 73.5 g

27: The no. of electrons present in 18 mL of water is


(a)

(b)

(c)
(d) None

16
28: Oxygen contains 90% O and 10% 8O. Its atomic mass is
(a) 16.2
(b) 17.4
(c) 17
(d) 16.5

29: 19.7 kg of gold was recovered from a smuggler. How many atoms of gold were recovered ? (Au = 197)< /P >
(a) 100
(b)

(c)

(d)

30: The weight of 2.8 L of a gas at NTP is 3.50 g. Its vapour density is
(a) 14
(b) 28
(c) 32
(d) 20

31: Phosphine gas (PH3) on strong heating decomposes into phosphorus [P 4(s)] and H2(g). When 100 mL of PH3(g) at STP is
completely decomposed, the change in volume is
(a) 50 mL
(b)
(c) 200 mL
(d)

32: The volumetric composition of heavy water D2O is D2 : O2 [Atomic mass D = 2, O = 16]
(a) 2 : 1
(b) 1 : 2
(c) 3 : 2
(d) 2 : 3

33: In Haber process, 30 litres of dihydrogen and 30 litres of dinitrogen were taken for reaction which yielded only 50% of the
expected product. What will be the composition of the gaseous mixture under the aforesaid condition in the end ?
(a) 20 litres NH3, 25 litres N2, 20 litres H2
(b) 10 litres NH3, 25 litres N2, 15 litres H2
(c) 20 litres NH3, 10 litres N2, 30 litres H2
(d) 20 litres NH3, 25 litres N2, 15 litres H2

34: Caffeine has a molecular mass of 194. If it contains 28.9% by mass of nitrogen, number of atoms nitrogen in one molecule of
it is
(a) 1
(b) 2
(c) 3
(d) 4

35: 1.615 g of anhydrous ZnSO4 was placed in moist air. After few days its weight was found to be 2.875 g. What is the
molecular formula of hydrated salt ?
(a)
(b)
(c)
(d)

36: The prefix 1018 is


(a) giga
(b) exa
(c) nano
(d) mega
(e) kilo

37: The submultiple has the prefix


(a) peta
(b) pico
(c) nano
(d) tetra

38: Which of the following is not an element ?


(a) Diamond
(b) Silica
(c) Tungsten
(d) Graphite

39: What amount of quick lime (CaO) is given on complete decomposition of 1g CaCO3 ?
(a) 56g
(b) 5.6g
(c) 0.56g
(d) 56g

40: The empirical formula of a compound is CH2. One mole of this compound has mass of 42 grams. Its molecular formula is :
(a) C3H6
(b) C3H8
(c) CH2
(d) C2H2

41: Assuming fully decomposed, the volume of CO2 released at N.T.P. on heating 9.85 g of BaCO3 (Atomic mass of Ba = 137)
will be
(a) 0.84 L
(b) 2.24 L
(c) 4.06 L
(d) 1.12 L

42: The mass of CaCO3 produced when carbon dioxide is bubbled through 500 mL of 0.5 M Ca(OH) 2 solution will be
(a) 25 g
(b) 50 g
(c) 20 g
(d) 10 g

43: Determine of volume of the product gas when 30 mL of O 2 and 30 mL CO are sparkled
(a) 45 mL
(b) 30 mL
(c) 15 mL
(d) 60 mL

44: The volume in litres of CO2 liberated at STP when 10 gram of 90% pure limestone is heated completely is
(a) 22.4
(b) 2.24
(c) 20.16
(d) 2.016

45: Equivalent weight of an acid :


(a) depends on the reaction involved
(b) depends upon the number of oxygen atoms present
(c) is always constant
(d) none of the above

46: How many moles of Al2(SO4)3 would be present in 50g of the substance ?
(a) 0.083 mole
(b) 0.952 mole
(c) 0.481 mole
(d) 0.140 mole

47: One mole of CO2 contains :


(a) 3g atoms of CO2
(b) molecules of CO2

(c) atoms of O

(d) atoms of C.

48: 0.56 g of gas occupies 280 cm3 at NTP, then its molecular mass is ______
(a) 4.8
(b) 44.8
(c) 2
(d) 22.4

49: Chemical equations convey quantitative information on the


(a) type of atoms/molecules taking part in the reaction
(b) number of atoms/molecules of the reactants and products involved in the reaction
(c) relative number of moles of reactants and products in the reaction
(d) quantity of reactant consumed and quantity of product involved.

50: How much K2Cr2O7 (M.W. = 294.19) is required to prepare one litre of 0.1 N solution ?
(a) 9.8063g
(b) 7.3548g
(c) 3.6774g
(d) 4.903g

51: A heavy element has atomic number X and mass number Y. Correct relation between X and Y is
(a) X > Y
(b) X < Y
(c) X = Y
(d)

52: The number of molecules in 16g of methane is


(a)

(b)

(c)

(d)

53: Hundred grams of each of the following are present in different flasks. Which of these contains maximum number of moles ?
(a) Silver
(b) Carbon
(c) Sulphur
(d) Magnesium

54: The percentage of oxygen in NaOH is


(a) 40
(b) 60
(c) 8
(d) 10

55: The maximum amount of BaSO4 precipitated on mixing BaCl2 (0.5 M) with H2SO4 (1 M) will correspond to
(a) 0.05 M
(b) 0.5 M
(c) 1.0 M
(d) 2.0 M

56: One mole of calcium phosphide on reaction with excess of water gives
(a) one mole of phosphine
(b) two moles of phosphoric acid
(c) two moles of phosphine
(d) one mole of phosphorus pentoxide

57: The hydrated salt on heating loses 55.9% weight and becomes anhydrous. The value of x is :
(a) 3
(b) 6
(c) 7
(d) 10

58: If an iodized salt contains 1% KI and a person takes 1 g of the salt everyday, the iodide ions going into his body everyday
would be approximately
(a)

(b)

(c)

(d)

59: In the reaction, equivalent weight of As2S3 (having


molecular mass M) is
(a) M/16
(b) M/8
(c) M/24
(d) M/28

60: An alloy of iron (54%), nickel (45%) and manganese (1%) has a density of . How many iron atoms are there in
a block of alloy measuring ?

(a)
(b)

(c)

(d)

61: 1g of green algae absorbs moles of CO2 per hour by photosynthesis 6n

. If all the carbon of CO2 is converted into starch, how long will it take for
the algae to increase its mass by 20%.
(a) 15.74 min
(b) 1.574 min
(c) 15.74 hours
(d) 1.574 hours

62: 0.7160 g of a hydrated metallic sulphate of formula precipitated 0.7002 g of BaSO4. When mixed with
K2SO4 and crystallized, the metallic sulphate yielded an alum isomorphous with potash alum. What is the atomic mass of the
metal ?
(a) 28.06
(b) 102.77
(c) 51.38
(d) None

63: A mixture of FeO and Fe3O4 when heated in air to a constant weight gains 5% in it's weight. The initial percentage of FeO in
the mixture is
(a) 91.29
(b) 20.25
(c) 91.92
(d) 92.19

64: A drug marijuana has its activity due to tetrahydrocannabinol, which has 70% as many carbon atoms as hydrogen atoms and
15 times as many hydrogen atoms as oxygen atoms. The number of moles in a gram of tetrahydro-cannabinol is 0.00318. What is
its molecular formula.
(a) C16H34O2
(b) C22H32O3
(c) C21H30O2
(d) None

65: Cortisone is a molecular substance which contains 21 carbon atoms per molecule. If carbon content is 69.98% by weight,
what is the molecular weight of cortisone ?
(a) 360.1
(b) 176.8
(c) 575.2
(d) 143.8

66: 100 ml of 0.1 N hypo decolourised iodine by the addition of x g of crystalline copper sulphate to excess of KI. The value of x
is :
(a) 5.0g
(b) 2.5g
(c) 10g
(d) 1.25g
67: A drop (0.05ml) of 12.0 M HCl is spread over a sheet of thin aluminium foil. Assuming that all the acid dissolves through the
foil, what will be the area of the hope produced ? (Density of ; thickness of the foil = 0.20 mm)

(a) 0.0001 cm
(b) 0.01 cm
(c) 0.02 cm
(d) 0.002 cm

68: A given sample of xenon fluoride contains molecules of a single type XeFn where n is a whole number. If
molecules has a mass of 0.311g then what is the value of n. (Atomic mass of Xe = 131 and F = 19)
(a) 3
(b) 4
(c) 5
(d) 6

69: A weightlifter after competition, drinks 500 ml of 9% glucose (mol. wt. = 180) solution. The numbers of glucose molecules
taken by him are
(a)

(b)

(c)

(d)

70: The equivalent mass of an element is 4. Its chloride has a vapour density 59.25. The valency of the element is
(a) 4
(b) 3
(c) 2
(d) 1

71: If the atomic weight of carbon were set at 100 u, what would be the value of Avogadro's number ?
(a)

(b)

(c)
(d) None

72: The significant figures in 0.0360 are :


(a) 2
(b) 3
(c) 4
(d) 5

73: The number of significant figures in is :


(a) one
(b) two
(c) three
(d) eight

74: Which of the following number has three significant figures ?


(a) 0.009
(b) 628.00
(c) 1038
(d) 0.0400

75: Eight thousand with three significant figures is written as :


(a) 8000
(b)

(c)

(d)

76: How many time is a kg heavier than a mg ?


(a) 106
(b) 103
(c) 104
(d) 105

77: To differentiate between carbon-12, carbon-13 and carbon-14, the instrument that you would use is :
(a) Infra-red spectrometer
(b) Atomic absorption spectrometer
(c) Mass spectrometer
(d) Ultra violet spectrometer

78: What volume is occupied by 16g of oxygen at 273 K and 1 bar pressure ?
(a) 22.4 L
(b) 11.2 L
(c) 22.7 L
(d) 11.35 L

79: The percentage of nitrogen in urea is


(a) 59
(b) 54
(c) 46
(d) 25

80: The mass of 112 cm3 of O2 gas at STP is


(a) 0.16 g
(b) 0.8 g
(c) 0.08 g
(d) 1.6 g

81: The flask A and B of equal size contain 2g of H2 and 2g of N2 respectively at the same temperature. The number of
molecules in flask A is
(a) Same as those in flask B
(b) Less than those in flask B
(c) Greater than those in flask B
(d) Exactly half than those in flask B
82: Law of constant composition does not hold good for
(a) Exothermic compounds
(b) Endothermic compounds
(c) Non stoichimetric compounds
(d) Stoichimetric compounds

83: If molecules are removed from 98 mg of H2SO4, then the numbers of moles of H2SO4 left are

(a)

(b)

(c)

(d)

84: A 500 mg iron capsule contains 100 mg of ferrous fumarate [(CHCOO) 2Fe]. The percentage of iron present in the capsule is
approx.
(a) 6.58
(b) 26.32
(c) 6.43
(d) 13.16

85: If mercury has density of , volume occupied by one atom of mercury (At. Wt. = 200) is

(a)

(b)

(c)

(d)

86: 0.59 g of silver salt of an organic acid (molar mass 210) on ignition gave 0.36 g of pure silver. The basicity of the acid is
(a) 3
(b) 2
(c) 1
(d) 4

87: Which among the following is the heaviest ?


(a) One mole of oxygen
(b) One molecules of sulphur trioxide
(c) 100 amu of uranium
(d) 44 g of carbon dioxide

88: One gram of a metallic oxide on reduction gives 0.68 g of the metal. The equivalent mass of the metal is
(a) 68
(b) 34
(c) 51
(d) 17

89: A metal oxide was found to contain 60% of the metal. What is the equivalent weight of the metal ?
(a) 8
(b) 12
(c) 24
(d) 36

90: In a compound C, H and N are present in the ratio 9 : 1 : 3.5 by weight. Molecular mass of the compound is 108. Molecular
formula of the compound is :
(a) C2H6N2
(b) C3H4N
(c) C6H8N2
(d) C9H12N3

91: Number of atoms is 560 g of Fe (atomic mass )

(a) is twice that of 70g N


(b) is half that of 20g H
(c) both are correct
(d) none is correct

92: What volume of hydrogen gas at 273 K and 1 atm pressure will be consumed in obtaining 21.6 g elemental boron (atomic
mass = 10.8) from the reduction of boron trichloride by hydrogen ?
(a) 67.2 L
(b) 44.8 L
(c) 22.4 L
(d) 89.6 L

93: One mole of magnesium nitride on reaction with an excess of water gives
(a) one mole of ammonia
(b) two moles of nitric acid
(c) two moles of ammonia
(d) one moles of nitric acid

94: How many moles of magnesium phosphate Mg 3(PO4)2 will contain 0.25 mole of oxygen atoms ?
(a)

(b)

(c)
(d) 0.02

95: In the reaction,

(a) 33.6 L H2(g) is produced regardless of temperature and pressure for every mole Al that reacts
(b) 67.2 L H2(g) at STP is produced for every mole of Al that reacts
(c) 11.2 L H2 (g) at STP is produced for every mole HCl (aq) consumed
(d) 6 L HCl (aq) is consumed for every 3 L H2(g) is produced.

96: The total number of valence electron in 4.2 g on nitride ion are

(a) 2.4 NA
(b) 4.2 NA
(c) 3.2 NA
(d) 1.6 NA

97: How many moles of electrons weigh one kilogram ? (Mass of electron , Avogadro number
)

(a)

(b)

(c)

(d)

98: How many grams of CaO are required to neutralize 852 g of P 4O10 ?
(a) 958 g
(b) 1008 g
(c) 1032 g
(d) 993.9 g

99: 0.083 mole of carbohydrate of empirical formula CH 2O contain 1 g of hydrogen the molecular formula of the carbohydrate is
:
(a) C5H10O5
(b) C3H4O3
(c) C12H22O11
(d) C6H12O6

100: How many H-atoms are present in 0.046 g of ethanol ?


(a)

(b)

(c)

(d)

101: Which element exist as a solid at 25oC and 1 atmospheric pressure among the following ?
(a) Br
(b) Cl
(c) Hg
(d) P

102: For the reaction Equivalent weight of Na2CO3 is :


(a) M/2
(b) M
(c) 2M
(d) M/4

103: The mass of 112 cm3 of CH4 gas at STP is :


(a) 0.16 g
(b) 0.8 g
(c) 0.08 g
(d) 1.6 g

104: A hydrocarbon contains 10.5 g carbon and 1g hydrogen. Its 0.36 g has 1 L volume at 1 atm and 127oC, hydrocarbon is :
(a) C6H7
(b) C7H8
(c) C5H6
(d) none of these

105: The mass of BaCO3 produced when excess CO2 is bubbled through a solution of 0.205 mole Ba(OH) 2 is (mol. mass of
BaCO3 = 197.3)
(a) 81 g
(b) 40.5 g
(c) 20.25 g
(d) 162 g

106: A compound contains 54.55% carbon, 9.09% hydrogen, 36.36% oxygen. The empirical formula of this compound is :
(a) C3H5O
(b) C4H8O2
(c) C2H4O2
(d) C2H4O

107: Given the numbers : 281 cm, 0.281 cm and 0.0281 cm. The no. of significant figures for the three numbers are
(a) 3, 4, 5
(b) 3, 3, 3
(c) 3, 3, 4
(d) 3, 4, 4

108: The second most abundant element in the earth crust is :


(a) oxygen
(b) aluminium
(c) hydrogen
(d) silicon

109: The term molecule was introduced by


(a) Dalton
(b) Avogadro
(c) Richter
(d) Aston

110: A wooden stick of a magician is 30 inch long. The length in cm is :


(a) 76.2 cm
(b) 75.0 cm
(c) 85.2 cm
(d) 79.5 cm

111: The amount of CO2 formed by burning 1 mole of carbon in 6 g of dioxygen is


(a) 44g
(b) 22g
(c) 11g
(d) 66g

112: How many molecules are present in three moles of ethane ?


(a)
(b) 3
(c)

(d)

113: Which is larger quantity ?


(a) Mega
(b) Femto
(c) Milli
(d) Giga

114: The specific notation of 0.0000000540 is


(a)

(b)

(c)

(d)

115: When 300 atoms of A reacts with 200 molecules of B 2 according to the equation , the limiting reagent is
(a) A
(b) B
(c) B2
(d) None

116: How many significant figures are present in ?


(a) 2
(b) 3
(c) 2
(d) 4

117: 1 kg mole of oxygen (O2) has _____ electrons


(a)

(b)

(c)

(d)

118: 3 g of a hydrocarbon on combustion with 11.2 g of oxygen produces 8.8 g CO 2 and 5.4 g H2O. The data illustrates the law
of
(a) conservation of mass
(b) multiple proportions
(c) definite proportions
(d) reciprocal proportions
119: The percentage of Se in peroxide anhydrous enzyme is 0.5% by weight (atomic weight = 78.4). Then minimum molecular
weight of peroxidase anhydrous enzyme is
(a)

(b)
(c) 15.68
(d)

120: The element whose atom has a mass of is

(a) Silver
(b) Zinc
(c) Calcium
(d) Boron

121: The weight of molecules of is ______


(a) 42.42 g
(b) 41.42 g
(c) 44.44 g
(d) 48.94 g

122: The number of gram molecules of oxygen in CO molecules is


(a) 10 g molecules
(b) 5 g molecules
(c) 1 g molecules
(d) 0.5 g molecules

123: Rearrange the following (I to IV) in the order of increasing masses and choose the correct answer from (1). (2), (3), (4).
(Atomic masses : N = 14, O = 16, Cu = 63)
I. 1 molecule of oxygen
II. 1 atom of nitrogen
III. molecular weight of oxygen
IV. atomic weight of copper

(a) II < I < IV < III


(b) IV < III< II < I
(c) II < III < I < IV
(d) III < IV < I < II

124: If 1021 molecules are removed from 200 mg of CO2, then the no. of moles of CO2 left will be
(a)

(b)

(c)

(d)

125: Under similar conditions, oxygen and nitrogen are taken in the same mass. The ratio of their volumes will be
(a) 7 : 8
(b) 3 : 5
(c) 6 : 5
(d) 9 : 2

126: The number of molecules present in the drop of water (Volume = 0.0018 mL) at room temperature is
(a)

(b)

(c)

(d)

127: Which has the maximum number of atoms ?


(a) molecules of CO2
(b) 22.4 L of CO2 at N.T.P.
(c) 0.44 g of CO2
(d) 1 molecule of ozone

128: The weight of one molecule of compound C60H122 is

(a)

(b)

(c)

(d)

129: Number of atoms in 635.5 g Cu (atomic mass of ) is

(a) twice that in 60 g carbon


(b)
(c) half that of 8 g He
(d)

130: The maximum number of molecules are present in


(a) 5 L of N2 gas at STP
(b) 0.5 g of H2 gas
(c) 10 g of O2 gas
(d) 15 L of H2 gas at STP

131: Mass of one mole of protons is


(a) 0.20 mg
(b) 0.02 mg
(c) 0.55 mg
(d) 1.00 mg

132: In a vessel 2 g O2, 2 g H2 and 2 g N2 are present which has the largest number of atoms ?
(a) O2
(b) H2
(c) N2
(d) All have equal number of atoms
133: Assuming that the human body is to be 80% water, calculate the no. of molecules that are present in the body of a person
who has a mass of 65 kg.
(a)

(b)

(c)

(d)

134: The number of water molecules present in a drop of water weighing 0.018 g is
(a)

(b)

(c)

(d)

135: Which property of an element is always a whole number ?


(a) Atomic weight
(b) Atomic number
(c) Valency
(d) Both (2) and (3)

136: How many moles of CO2 are present in 1 m3 of volume at STP (0oC, 1 bar pressure)
(a) 44.05
(b) 44.64
(c) 40.48
(d) 10

137: How many gram atoms are present in 1.4 g of nitrogen ?


(a) 1
(b) 0.1
(c) 0.01
(d) 0.5

138: One gram mole of a gas at N.T.P. occupies 22.4 L. This fact was derived from
(a) Law of gaseous volumes
(b) Avogadro's hypothesis
(c) Berzelius hypothesis
(d) Dalton's atomic theory

139: One fermi is :

(a)

(b)

(c)

(d)

140: One of the following combinations which illustrates the law of reciprocal proportions is ?
(a) NO2, N2O4, N2O
(b) NaCl, NaBr, NaI
(c) CS2, CO2, SO2
(d) PH3, PF3, PCl3

141: Irrespective of the source, pure sample of water always yield 88.89% mass of oxygen and 11.11% mass of hydrogen. This is
explained by the law of
(a) conservation of mass
(b) constant composition
(c) multiple proportion
(d) constant volume
(e) Gay-Lussac's

142: Which of the following contains maximum number of molecules ?


(a) 100 cc of CO2 at STP
(b) 150 cc of N2 at STP
(c) 50 cc of SO2 at STP
(d) 150 cc of O2 at STP
(e) 200 cc of NH3 at STP

143: The numerical value of (where N is the number of molecules in a given sample of gas and n is the number of moles of
the gas) is
(a) 8.314
(b)
(c) 0.0821
(d)

(e)

144: The mass of 11.2 L of ammonia gas at STP is


(a) 8.5 g
(b) 85 g
(c) 17 g
(d) 1.7 g
(e) 4.25 g

145: 116 mg of a compound on vapourisation in Victor Meyer's apparatus displaces 44.8 mL of air measured at STP. The
molecular mass of the compound is
(a) 46.4
(b) 44.8
(c) 58
(d) 116
(e) 232

146: 100 g CaCO3 is treated with 1 litre of 1 N HCl. What would be the weight of CO 2 liberated after the completion of the
reaction ?
(a) 5.5 g
(b) 11 g
(c) 22 g
(d) 33 g
(e) 44 g

147: Mass of the one atom of the element X is . Number of atoms in 1 g of the element is :

(a)

(b)

(c)

(d)

148: What is the equivalent weight of H3PO4 in the reaction

(a) 98
(b) 49
(c) 3.66
(d) 24.5

149: The equivalent weight of MnSO4 is half of its molecular mass when it is converted into
(a) Mn2O3
(b) KMnO4
(c) MnO2
(d) K2MnO4

150: If molecular mass of KMnO4 is M, then its equivalent mass in acidic medium will be
(a) M
(b) M/2
(c) M/5
(d) M/4

151: The specific heat of a metal is 0.16. Its approximate atomic mass would be
(a) 32
(b) 16
(c) 40
(d) 64

152: If m1g of a metal A displaces m2g of another metal B from its salt solution and if their equivalent masses are E 1 and E2
respectively, then the equivalents mass of A can be expressed as

(a)

(b)

(c)

(d)

153: The atomic masses of the elements are usually fractional because :
(a) elements consist of impurities
(b) these are mixtures of allotropes
(c) these are mixtures of isobars
(d) these are mixtures of isotopes

154: Molecular mass of a volatile substance may be obtained by


(a) Titration method
(b) Duma's method
(c) Victor-Meyer's method
(d) None

155: Which one of the following is the standard for atomic mass ?
(a)

(b)

(c)

(d)

156: Taxol is a/an


(a) acid
(b) explosive
(c) anticancer drug
(d) antiviral medicine

157: The equivalent mass of Fe in FeO is ______


(a) 56
(b) 28
(c) 36
(d) 18.66

158: Nickel ammonium sulphate is isomorphous with :


(a) Mohr's salt
(b) Glauber's salt
(c) Blue vitriol
(d) Green vitriol

159: Formula of bicarbonate of a metal is M(HCO3)3. The formula of its pyrophosphate is :


(a) M3(P2O7)4
(b) M(P2O7)2
(c) M3(P2O7)3
(d) M4(P2O7)3

160: The percentage of carbon and oxygen in samples of CO 2 obtained by different methods were found to be the same. This
illustrates the law of :
(a) conservation of mass
(b) constant proportions
(c) multiple proportions
(d) reciprocal proportions
161: Vapour density of a gas is 40. Its specific heats at constant pressure and volume are 0.115 and 0.082 respectively. The
atomic mass of the gas is
(a) 40
(b) 20
(c) 80
(d) None

10 11 10 11
162: Boron has two isotopes B and B. If the atomic mass of boron is 10.81, then the ratio of B and B in nature is
(a) 19/81
(b) 15/16
(c) 10/11
(d) 100/110

163: In Victor-Meyer's method 0.2 g of an organic compound displaced 56 mL of air at STP. The molecular weight of the
compound is
(a) 56
(b) 112
(c) 80
(d) 28

164: Element X (Atomic mass = 75) and element Y (Atomic mass = 16) combine to give a compound having 75.8% X. The
formula of the compound is :
(a) XY
(b) X2Y
(c) X2Y2
(d) X2Y3

165: The number of moles of oxygen in 1L of air which contains 21% oxygen by volume under standard conditions is :
(a) 0.186 mol
(b) 0.21 mol
(c) 2.10 mol
(d) 0.0093 mol

166: How many times an atom of sulphur is heavier than an atom of carbon ?
(a) 32 times
(b) 12 times
(c) 8/3 times
(d) 12/32 times

167: The no. of oxygen atoms in 4.4 g of CO2 is approx.


(a)

(b)

(c)

(d)

168: A sample of CaCO3 contains ions of and . The mass of the sample is :

(a) 100g
(b) 50 g
(c) 200g
(d) 5g

169: The empirical formula of a substance which has H, C, O and N in the mass ratio of 1 : 3 : 4 : 7 is
(a) H4C2O2N2
(b) H2CON2
(c) H4CON2
(d) H4CON

170: What mass of NH3(g) will be formed when 50 kg of N2(g) and 10.0 kg of H2(g) are mixed ?
(a) 50.23 kg
(b) 56.66 kg
(c) 60.7 kg
(d) 85.0 kg

171: How many moles of carbon atoms and hydrogen atoms respectively are present in 3 moles of ethane ?
(a) 6, 18
(b) 6, 12
(c) 2, 18
(d) 2, 6

172: Which of the following has largest number of atoms ?


(a) 1g Au
(b) 1g Na
(c) 1g K
(d) 1g Cl2

173: Population of a country is approx. 100 million. If one mole of rupees is distributed equally among all the peoples, one
person will get rupees approximately ______
(a) 1015
(b)

(c)
(d) 10 million

174: A quantity of sulphur has mass 3.2 g. What is the mass of calcium having same number of atoms ?
(a) 0.4 g
(b) 4 g
(c) 40 g
(d) 8 g

175: What mass of carbon monoxide has the same number of oxygen as are present in 22 g CO 2 ?
(a) 14 g
(b) 280 g
(c) 28 g
(d) 56 g

176: Number of atoms of oxygen present in 10.6 g of Na 2CO3 will be


(a)

(b)

(c)

(d)

177: For the formation of 36.5 g of hydrogen chloride gas, what volumes of hydrogen and chlorine gas are required at N.T.P.
conditions ?
(a) 1 L, 1 L
(b) 1.12 L, 1.12 L
(c) 1.12 L, 2.24 L
(d) 3.65 L, 1.83 L

178: An alkaloid contains 17.28% of nitrogen and its molecular mass is 162. The number of nitrogen atoms present in one
molecule of alkaloid is
(a) five
(b) four
(c) three
(d) two

179: 'x' grams of calcium carbonate was completely burnt in air. The weight of the solid residue formed is 28 g. What is the
value of 'x' in grams ?
(a) 44
(b) 200
(c) 150
(d) 50

180: 20 mL of 0.1 N BaCl2 is mixed with 30 mL of 0.2 N Al 2(SO4)3. The mass of BaSo4 formed is
(a) 233 g
(b) 23.3 g
(c) 2.33 g
(d) 0.233 g

181: 0.224 g of a metal when dissolved in dilute acid liberates 275.3 cc of hydrogen at 0 oC and 1 atmosphere pressure. The
equivalent mass of the metal is
(a) 9.216
(b) 0.998
(c) 92.16
(d) 99.8

182: 0.585 g of the chloride of a metal dissolved in water and excess of AgNO 3 was added. The mass of precipitated silver
chloride after washing and drying was found to be 1.435 g. The eq. mass of other metal is
(a) 2.3
(b) 23
(c) 5.85
(d) 3.16

183: Same quantity of electricity deposits 0.654 g of Zn and 1.0 g of another metal. If equivalent mass of Zn is 32.7, then eq.
mass of other metal is
(a) 40
(b) 55
(c) 50
(d) 60

184: A compound of Se and Cl has 52.1% Se. The empirical formula is (Ar. Mass of Se = 79.ou)
(a) SeCl
(b) SeCl2
(c) SeCl3
(d) SeCl4

185: atoms of X and atoms of Y are present in a compound. The empirical formula is
(a) XY
(b) XY2
(c) XY3
(d) X2Y3

186: Calculate molecular mass of glucose (C6H12O6) molecule; Given atomic masses of C, H and O are 12.011 amu, 1.008 amu
and 16.00 amu respectively.
(a) 180 amu
(b) 180.162 amu
(c) 184.32 amu
(d) 180.262 amu

187: atoms of iron weigh as much as 1 cm3 of H2 at STP. What is the atomic mass of iron ?
(a) 26
(b) 55.7
(c) 56.0
(d) 58.6

188: The number of water molecules in 1 litre of water is (N A represents Avogadro number)
(a) 18
(b)
(c) NA
(d) 55.5 NA

189: An element X has the following isotopic composition200X : 90%,199X : 8.0%,202X : 2.0%. The weighed average atomic mass
of the naturally occurring element X is closest to
(a) 200 amu
(b) 199 amu
(c) 201 amu
(d) 202 amu

190: Hydrogen and nitrogen react to produce ammonia according to the equation :
What amount of ammonia would be produced if 200 g hydrogen react ?
(a) 34 g
(b) 1.132 g
(c) 11.32 g
(d) 113.2 g
191: The mass of carbon anode consumed (giving only CO2) in the production of 270 kg of aluminium metal from bauxite by the
Hall's process is
(a) 90 kg
(b) 180 kg
(c) 270 kg
(d) 540 kg

192: The amount of the zinc needed to produce 112 mL of H 2 at STP on reaction with dil H2SO4 will be
(a) 0.65 g
(b) 0.325 g
(c) 6.5 g
(d) 3.25 g

193: molecules of sucrose are present in 100 mL of its solution. The number of moles per litre of solution is
(a) 0.02
(b) 0.01
(c) 0.001
(d) 0.1

194: The following question contains two statements. Choose one of the options below:
Statement 1: Law of conservation of mass holds good for nuclear reactions.
Statement 2: In a nuclear reaction, the mass lost is converted into energy.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1.
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1.
(c) Statement-1 is True, Statement-2 is False.
(d) Statement-1 is False, Statement-2 is True

195: The following question contains two statements. Choose one of the options below:
Statement-1: 1 amu is equal to

Statement-2: 1 amu is of mass of a C - 12 atom.

(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1.
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1.
(c) Statement-1 is True, Statement-2 is False.
(d) Statement-1 is False, Statement-2 is True

196: The following question contains two statements. Choose one of the options below:
Statement-1: and are isotones.
Statement-2: Isotones have the same number of protons.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1.
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1.
(c) Statement-1 is True, Statement-2 is False.
(d) Statement-1 is False, Statement-2 is True

197: The following question contains two statements. Choose one of the options below:
Statement-1: 22 carat gold is a mixture:
Statement-2: A compound has fixed composition of the elements present in it.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True

198: The following question contains two statements. Choose one of the options below:
Statement-1 : The standard unit of expressing mass of atoms is called 'u'.
Statement-2 : 'u' represents unit mass.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True

199: The following question contains two statements. Choose one of the options below:
Statement 1: In a gaseous reaction, the ratio of the volumes of gaseous reactants and products is in agreement with their molar
ratio.
Statement 2: This is according to Avogadro's hypothesis.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True

200: The following question contains two statements. Choose one of the options below:
Statement- 1: Both 32 g f SO2 and 8 g of CH4 have same number of molecules.
Statement-2: Equal moles of substances have equal number of molecules.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True

201: The following question contains two statements. Choose one of the options below:
Statement-1: Atomic mass of calcium is 40 u.
Statement-2: An atoms of calcium is 40 times heavier than an atom of carbon with mass 12 u.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True

202: The following question contains two statements. Choose one of the options below:
Statement-1: 1 mole of N and 1 mole of N 2 contain equal number of particles.
Statement-2: 1 mole of molecules is always double than 1 mole of atoms in all the diatomic molecules.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1
(b) Statement -1 is True, Statement -2 is true. Statement-2 is not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True

203: The following question contains two statements. Choose one of the options below:
Statement-1: 2 moles of BaCl2 react with 3 moles of Na3PO4 to form 0.66 mole of Ba3(PO4)2.
Statement-2: BaCl2 is the limiting reactant and some of Na3PO4 remains unreacted.
(a) Statement-1 is True, Statement -2 is true, Statement - 2 is a correct explanation for Statement -1
(b) Statement -1 is True, Statement -2 is true, Statement-2 is not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True
204: 5 mL of 1 N, HCl, 20 mL of N/2 H2SO4 and 30 mL of N/3 HNO3 are mixed together and the volume made to one litre. The
normally of the resulting solution is
(a) N/5
(b) N/10
(c) N/28
(d) N/40

205: A gas mixture contains 50% helium and 50% methane by volume. The mass percentage of CH 4 in the mixture is
(a) 19.97%
(b) 20.05%
(c) 45%
(d) 80%

206: During the titration of KMnO4 with oxalic acid in acid medium, the oxidation number of Mn 7+ changes to
(a) +2
(b) +3
(c) +5
(d) 0

207: 2 g of aluminium is treated separately with excess of dilute H 2SO4 and excess of NaOH. The ratio of the volumes of
hydrogen evolved is
(a) 1 : 2
(b) 2 : 1
(c) 1 : 1
(d) 2 : 3

208: An aqueous solution containing 100 grams of dissolved MgSO4 is fed to a crystallizer where 80% of the dissolved salt
crystallises out as crystals. How many grams of the hexahydrate slat crystals are obtained from the crystallizer ?
(Given atomic masses of Mg = 24, S = 32, O = 16 and H = 1)
(a) 80
(b) 152
(c) 120
(d) 100

209: What is the volume of 0.1 N HCl required to react completely with 1.0 g of pure calcium carbonate ? (Ca = 40, C = 12 and
C = 16)
(a) 250 cm3
(b) 150 cm3
(c) 100 cm3
(d) 200 cm3

210: If a mixture containing 3 moles of hydrogen and 1 mole of nitrogen is converted completely into ammonia, the ratio of
initial and final volumes at the same temperature and pressure would be
(a) 1 : 2
(b) 2 : 1
(c) 1 : 3
(d) 3 : 1

211: The molarity of a solution containing 5.6 g of KOH in 250 cm3 solution is
(a) 0.4
(b) 0.1
(c) 2
(d) 1

212: The hydrogen phosphate of certain metal has formula MHPO4. The formula of metal vapour would be
(a) MCl
(b) MCl2
(c) M2Cl2
(d) MCl3

213: The density of air is . Its vapour density is

(a) 143
(b) 14.3
(c) 1.43
(d) 0.143

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