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for the
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Designation: A976 − 13

Standard Classification of
Insulating Coatings for Electrical Steels by Composition,
Relative Insulating Ability and Application1
This standard is issued under the fixed designation A976; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.

1. Scope 2. Referenced Documents

1.1 This document classifies insulating coatings for electri- 2.1 ASTM Standards:2
cal steels according to their composition, relative insulating A340 Terminology of Symbols and Definitions Relating to
ability, and functionality. The purpose of this classification is to Magnetic Testing
assist users of insulating coatings by providing general infor- A345 Specification for Flat-Rolled Electrical Steels for
mation about the chemical nature and use of the coatings, as Magnetic Applications
well as to provide important data concerning limits to their use, A677 Specification for Nonoriented Electrical Steel Fully
that is, relative insulating ability, punchability, temperature Processed Types
stability, weldability, and fabricability. Specific surface insula- A683 Specification for Nonoriented Electrical Steel, Semi-
tion resistivity values for each coating are not included in this processed Types
classification. The user is referred to the flat-rolled electrical A717/A717M Test Method for Surface Insulation Resistivity
steel specifications noted in 1.2 should more detailed informa- of Single-Strip Specimens
tion concerning surface insulation resistivity values be re- A726 Specification for Cold-Rolled Magnetic Lamination
quired. Quality Steel, Semiprocessed Types
1.2 This classification is to be used in conjunction with the A840 Specification for Fully Processed Magnetic Lamina-
various specifications for flat-rolled electrical steels under the tion Steel (Withdrawn 2011)3
jurisdiction of Committee A06, including Specifications A345, A876 Specification for Flat-Rolled, Grain-Oriented, Silicon-
A677, A683, A726, A840, and A876. However, in those Iron, Electrical Steel, Fully Processed Types
instances in which the coating descriptions and characteristics A937/A937M Test Method for Determining Interlaminar
differ between this classification and any of the specifications, Resistance of Insulating Coatings Using Two Adjacent
this classification shall supersede the specification. Test Surfaces
1.3 The values stated in customary (cgs-emu and inch- 3. Terminology
pound) units are to be regarded as standard. The values given 3.1 Definitions of Terms Specific to This Standard:
in parentheses are mathematical conversions to SI units which 3.1.1 interlaminar resistance, n—the average resistance of
are provided for information only and are not considered two adjacent insulating surfaces in contact with each other, in
standard. accordance with Test Method A937/A937M.
1.4 This standard does not purport to address all of the 3.1.2 stress-relief anneal, n—heat treatment that improves
safety concerns, if any, associated with its use. It is the the magnetic properties of electrical steel by relieving internal
responsibility of the user of this standard to establish appro- stresses which are introduced during fabrication of magnetic
priate safety and health practices and determine the applica- cores.
bility of regulatory limitations prior to use.

1 2
This classification is under the jurisdiction of ASTM CommitteeA06 on For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Magnetic Properties and is the direct responsibility of SubcommitteeA06.02 on contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Material Specifications. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved Nov. 1, 2013. Published November 2013. Originally the ASTM website.
3
published in 1997. Last previous edition approved in 2008 as A976 – 03 (2008). The last approved version of this historical standard is referenced on
DOI: 10.1520/A0976-13. www.astm.org.

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 A976 − 13
3.1.3 surface insulation resistivity, n— the effective resistiv- fied applied voltage. This current value often is referred to as
ity of a single insulating layer tested between applied bare the “Franklin Current” and may be used directly as an indicator
metal contacts and the base metal of the insulated test of the quality of the insulation. Specifically, a Franklin Current
specimen, in accordance with Test Method A717/A717M. of zero corresponds to a perfect insulator. A Franklin Current of
3.2 Definitions for other terms and symbols used in this 1 ampere corresponds to a perfect conductor. If desired, an
specification are defined in Terminology A340. apparent surface insulation resistivity value for the insulating
layer may be calculated as follows:
4. Significance and Use R i 5 6.45 $ ~ 1 / I ! 2 1 % in Ω·cm2 /lamination (1)
4.1 This classification establishes categories of insulating
or
coatings based on their chemical nature, relative insulating
ability, and typical applications. These categories describe R i 5 645 $ ~ 1 / I ! 2 1 % in Ω·mm2 /lamination (2)
general physical and chemical characteristics of the coatings where:
that are useful in making broad estimates of their insulating
Ri = surface insulation resistivity of test sample (two sur-
ability and suitability for various applications.
faces in series) in Ω·cm2/lamination or Ω·mm2/
5. Basis of Classification lamination and
I = ammeter reading in A (also known as Franklin Current).
5.1 The insulating coatings are categorized according to
general composition, relative insulating ability, and function- Note that this test method often is referred to as the Franklin
ality (Table 1). The purpose of this classification is to create a test. The Franklin test is a widely used method for evaluating
nomenclature for the various coating types. It is not the intent the effectiveness of surface insulation on electrical steels.
of this classification to specify coating requirements. Specific 6.2 The average resistance of two adjacent insulating sur-
properties required by coating users should be negotiated with faces in contact with each other, interlaminar resistance, may
the steel producer. be measured using Test Method A937/A937M. Because the
5.2 To reduce confusion regarding the various categories of interlaminar resistance is influenced by coating-to-coating
coatings, this classification follows the “C” type of designation contact, this test method is particularly useful for providing an
initially used by the American Iron and Steel Institute for estimate of the interlaminar resistance in a stacked or wound
describing insulating coatings.4 The “C” is included in the core in which coated surfaces are in contact with each other.
coating designation because insulating coatings for electrical Furthermore, this test method is particularly useful for electri-
steels have been historically referred to as “coreplate” coatings. cal steels coated with insulating coatings having surface
This classification includes new coatings and test methods not insulation resistivities in excess of 300 Ω·cm2 (30 kΩ·mm2)
included in the most recent edition of the AISI classification. (that is, less than 0.02 A when measured according to Test
Note that the electrical steel committee of the AISI is no longer Method A717/A717M). In this Two-Surface test method,
active, and the 1983 edition of the coating classification intimate physical contact of these surfaces is achieved by
document was the last edition of the coating classification to be means of test heads that force a defined surface area into
published.5 contact under a specified pressure. For the interlaminar resis-
tance measurement, electrical contact is established between
6. Test Methods the test specimen and a constant direct current source using
6.1 The surface insulation resistivity of an insulating layer metallic contacts. The tester uses two sets of metallic contacts,
may be measured using Test Methods A717/A717M. In this which penetrate the exposed test surfaces into the base metal,
test method, ten metallic contacts of fixed area are applied to to form a four–probe configuration (Fig. 3). A continuous
one of the surfaces of the test specimen, and electrical contact electrical path is formed between the contacts and the constant
is made with the base metal by two drills (Fig. 1 and Fig. 2). current source when the metallic contacts penetrate through the
The effectiveness of the coating (surface insulation) then is coating on the exposed test surfaces to the underlying base
indicated by a measurement of the average electrical current metal. When current flows in the circuit, the dc voltage
flowing between the contacts and the base metal under speci- developed in the circuit is measured with a voltmeter. The
resistance of the insulation is then determined by Ohm’s law.
4
Steel Products Manual on Flat–Rolled Electrical Steel, American Iron and
Steel Institute, 1101 17th St., N.W., Washington, DC 20036–4700, January 1983. 7. Keywords
5
Loudermilk, D. S. and Murphy, R. A., “Overview of Technology of Insulating
7.1 coatings; coreplate; Franklin test; insulation; insulating
Coatings for Grain–Oriented and Nonoriented Electrical Steels,” Fifteenth Annual
Conference on Properties and Applications of Magnetic Materials, Illinois Institute coatings; interlaminar resistance; steels; surface insulation
of Technology, Chicago, IL, May 1996. resistivity ; Two–Surface test; varnishes

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 A976 − 13
TABLE 1 Classification of Insulating Coatings for Electrical Steels
Coating
Coating Description/Characteristics
NameA
C-0 Oxide that is formed naturally on the steel surface during mill processing. This oxide layer is thin, tightly adherent, and provides sufficient insulating quality
for most small cores. The oxide layer will withstand normal stress-relief annealing temperatures. The insulation quality is affected by the oxidizing
potential of the user’s anneal, that is, the oxidized surface condition may be enhanced by controlling the atmosphere to be more or less oxidizing to the
surface. It is not appropriate to assert a maximum acceptable Franklin test current for this coating.

C-1 User-formed oxide that is created on the steel surface by contact with an oxidizing furnace atmosphere at the end of the heat-treating cycle. This coating
usually is bluish to gray in color and used for various electrical steel applications. It is not appropriate to assert a maximum acceptable Franklin
test current for this coating.

C-2 Inorganic insulating coating predominantly comprised of magnesium silicate and used on grain-oriented electrical steel. The coating is formed from the
reaction of the annealing separator with the steel surface during high-temperature annealing. The resulting coating often is referred to as “mill glass”
or “glass film”even though the coating is not technically a glass. The coating is very abrasive, and hence, is not typically used for stamped laminations.
The primary application of this coating is air-cooled or oil-immersed wound distribution transformers. This coating will withstand normal
stress-relief annealing temperatures. It is not appropriate to assert a maximum acceptable Franklin test current for this coating.

C-3 Organic varnish/enamel coating that is applied to the steel surface and cured by heating. Used for fully processed nonoriented and other electrical steels. It
is appropriate to designate a maximum Franklin test current for this type of coating. The required Franklin test current is subject to agreement between
the producer and user. This coating generally improves the punchability of the steel, and hence, is quite suitable for stamped laminations. This coating
will not withstand typical stress-relief annealing temperatures. The coating normally is suitable for operating temperatures up to about 350°F (180°C).

C-4 Coating formed by chemical treating or phosphating of the steel surface followed by an elevated temperature curing treatment. This type of coating is used
in applications requiring moderate levels of insulation resistance. This coating will withstand normal stress-relief annealing temperatures, but some
reduction of surface insulation resistivity may occur during the anneal. It is appropriate to specify a maximum acceptable Franklin test current with a value
agreed to by the producer and user.

C-4-A Thin film of C-4-type coating used primarily for preventing sticking of semiprocessed nonoriented electrical steel or cold-rolled motor lamination steel during
quality anneals. This coating often is referred to as “anti-stick.” It is not appropriate to specify a maximum acceptable Franklin test current
for this coating.
Note: This coating was known as C-4-AS in previous versions of this classification. Existing references to C-4-AS in manufacturing, procurement, and other
documents may be directly substituted by coating C-4-A.

C-5 Inorganic or mostly inorganic coating similar to C-4, to which ceramic fillers or film-forming inorganic components have been added to increase the
insulating ability of the coating. The coating typically is a phosphate, chromate, or silicate coating, or combination thereof. Such coatings are applied
to the steel surface and cured by heating. The coatings can be applied to grain-oriented electrical steels, nonoriented electrical steels, and cold-
rolled motor lamination steels. A C-5 coating may be applied over top of a C-2 coating for applications in which extra surface insulation is required, for
example, sheared laminations of grain-oriented electrical steel for cores of power transformers.

C-5 coatings are used for applications requiring a high-surface resistivity. It is appropriate to designate a maximum Franklin test current for this type of
coating before stress-relief annealing. The required Franklin test current is subject to agreement between the producer and user. The coating will
withstand stress-relief annealing up to 1550°F (840°C) in neutral or slightly reducing furnace atmospheres, but some reduction in surface insulation
resistivity may occur during the anneal. The coating will withstand burn-off treatments at 600-1000°F (320-540°C) used to remove stator
winding insulation during rebuilding of motors. The coating can be used in air-cooled or oil-immersed cores.

In some cases, organic components may be added to C-5 coatings to enhance punchability. The applications, use, and properties of such coatings are
similar to those of inorganic C-5 coatings. The user should consult the producer if there are particular concerns with coating off-gassing
during welding or elevated temperature exposure of the coated steel.

C-5-A Thin film of C-5-type coating used primarily for preventing sticking of semiprocessed nonoriented electrical steel and cold-rolled motor lamination steel
during quality anneals. This coating often is referred to as “anti-stick.” It is not appropriate to assert a maximum acceptable Franklin test current
for this coating.
Note: This coating was known as C-5-AS in previous versions of this classification. Existing references to C-5-AS in manufacturing, procurement, and other
documents may be directly substituted by coating C-5-A.

C-6 Organic-based coating to which inorganic fillers have been added to increase the insulating ability of the coating. The coating is applied to the steel surface
and cured by heating. C-6 coatings typically are used for fully processed nonoriented electrical steels. It is appropriate to designate a maximum Franklin
test current for this type of coating. The required Franklin test current is subject to agreement between the producer and user. The coating will withstand
burn-off treatments used to remove stator winding insulation during rebuilding of motors, done at 600-1000°F (320-540°C), but is not considered to
be a coating that will withstand normal stress-relief annealing. The coating generally improves the punchability of the steel, and hence, is suitable
for stamped laminations.
A
The coating names and coating descriptions and characteristics in this table conform to the requirements of this classification. As other coating types may be commercially
available bearing product names such as C-5A that are similar to the coating names in this classification, the user is cautioned to confirm with the producer that a particular
coating is in conformance with this classification or is being offered independent of this classification. If a coating is offered independently, the user should confirm the
coating characteristics with the producer prior to ordering.

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 A976 − 13

FIG. 1 Apparatus of Surface Insulation Resistivity Measurement

for Franklin Test

FIG. 2 Diagram of Connections for Contacts and Resistors for

Franklin Test

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 A976 − 13

NOTE 1—Contacts pierce insulating coating and contact substrate.

FIG. 3 Schematic Illustration of Four-Probe Configuration for Two-Surface Test

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