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IIT – JEE: 2023 TW TEST (ADV) DATE: 20/06/21

TIME: 1 Hr. TOPIC: ATOMIC STRUCTURE MARKS: 100

SINGLE CORRECT ANSWER TYPE

This section contains 25 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

26. The mass of a photon having wavelength 1 nm is :-

(A) 2.21 1035 kg
(B) 2.211033 g
(C) 2.21 1033 kg
(D) 2.21 1026 kg

27. If the kinetic energy of an electron is increased 4 times, the wavelength of the de Broglie wave
associated with it would become :-
(A) 4 times
(B) 2 times
1
(C) times
2
1
(D) times
4

28. According to Bohr theory, the angular momentum of electron in 5th orbit is
25 h
(A)

1h
(B)

10 h
(C)

2.5h
(D)


29. Calculate the wavelength (in nm) associated with a proton moving at 1103 msec1 .
(Mass of proton  1.67 1027 kg, h  6.63 1034 J sec )
(A) 0.032 nm
(B) 0.40 nm
(C) 2.5 nm

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 (D) 14 nm

30. Consider that azimuthal quantum number (l) is having (n + 1) values i.e. whole number from o to n
instead of 0 to (n – 1) value for any value of principle quantum number n. If all the current laws of
electronic configuration are applicable then what will be the spin only magnetic moment of Fe2+ ion
(A) 2.82 BM
(B) 4.89 BM
(C) 3.87 BM
(D) 1.73 BM

31. If the radius of 3rd orbit of hydrogen atom is ‘x’ then the radius of 4th orbit of Li2+ ion would be :-
27x
(A)
16
16x
(B)
27
9x
(C)
16
16x
(D)
9

32. Which of the following graphs between radial probability distribution and radius of an atom
correspond to 4s-orbital (n = 4,   0 ) is correct?

(A)

(B)

(C)

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 (D)

33. A compound of vanadium has a magnetic moment of 1.73 B.M. The electronic configuration of
vanadium ion in the compound is
(A) [Ar] 3d2
(B) [Ar] 3d1 4s0
(C) [Ar] 3d3
(D) [Ar] 3d0 4s1

34. The orbital angular momentum of an electron in p-orbital is :-

(A) Zero
h
(B)
2
h
(C)
2
1 h
(D) 
2 2

35. In hydrogen spectrum, the third line from red and corresponds to which one of the following inter-
orbit jumps of the electrons from Bohr orbit of hydrogen?
(A) 4  1
(B) 2  5
(C) 3  2
(D) 5  2

36. What is the most probable distance of 1s electron in a He  ion. If wave function for 1s orbital is given
Z 3  zr / a0
by  
 a03
.e  a0  52.9 Pm 
(A) 52.9 pm
(B) 105.8 pm
(C) 26.45 pm
(D) 13.225 pm

37. The ratio of kinetic energy and potential energy of an electron in a Bohr orbit of a hydrogen like species
is
(A) –1
(B) +1
1
(C) 
2

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 1
(D) 
2

38. The radius of the second Bohr orbit for hydrogen atom is
(A) 1.65 Å
(B) 4.76 Å
(C) 0.529 Å
(D) 2.12 Å
(Planck’s constant h  6.626 1034 Js , mass of electron  9.11031 kg , charge of electron,
e  1.6 1019 C , Permittivity of vacuum  0  8.8 1012 kg 1m 3 Å )

39. No. of visible lines when a electrons de-excite from 5th orbit to ground state in H spectrum
(A) 5
(B) 4
(C) 3
(D) 10

40. The correct set of four quantum number for the valence electrons of rubidium atom (Z = 37) is
1
(A) 5, 1, 1, 
2
1
(B) 5, 0, 1, 
2
1
(C) 5, 0, 0, 
2
1
(D) 5, 1, 0, 
2

41. The ionisation energy of hydrogen atom is 1.312 106 Jmol1 . The energy required to excite the
electron in the atom from n = 1 to n = 2 is :-
(A) 9.84 105 J mol 1
(B) 8.51 105 J mol 1
(C) 6.56 105 J mol1
(D) 7.56 105 J mol1

42. Find the value of wave number v in terms of Rydberg’s constant, when transition of electron takes
place between two levels of He+ ion whose sum is 4 and difference is 2.
8R
(A)
9
32R
(B)
9
3R
(C)
4
(D) None of these

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43. A 600 W mercury lamp emits monochromatic radiation of wavelength 331.3 nm. How many photons
are emitted from the lamp per second?
( h  6.626 1034 Js , velocity of light  3 108 ms1 )
(A) 11019
(B) 11020
(C) 11021
(D) 11022

44. A gas absorbs a photon of 355 nm and emits two wavelengths. If one of the emission is at 680 nm, the
other is at :-
(A) 518 nm
(B) 1035 nm
(D) 325 nm
(D) 743 nm

45. Radius of a nucleus is proportional to (where A is the atomic number of nucleus)

(A) A
(B) A1/3
(C) A2
(D) A2/3

46. A light whose frequency is equal to 6 1014 Hz is incident on a metal whose work function is
2 eV  h  6.63  10 34 Js  , 1 eV  1.6  10 19 J  . The maximum energy of electrons emitted will be :-
(A) 2.49 eV
(B) 4.49 eV
(C) 0.49 eV
(D) 5.49 eV

47. Which of the following atoms contains the least number of neutrons?
235
(A) 92 U
238
(B) 92 U
239
(C) 93 Np
240
(D) 93 Np

48. Principal, azimuthal and magnetic quantum number are respectively related to :
(A) size, shape and orientation
(B) shape, size and orientation
(C) size, orientation and shape
(D) none of the above

49. For photo-electric effect experiment, which of the following graphs is incorrect?
(  : frequency of incident radiation;  : wavelength of incident radiation; K.E.e .max : maximum kinetic
energy of ejected electron; V : magnitude of stopping potential)

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 

(A)

K.E e ,max

(B)

K.E e ,max

(C)

1

(D)

50. If a0 be the radius of first Bohr's orbit of H-atom, the de-Broglie's wavelength of an electron revolving
in the third Bohr's orbit of He+ ion will be
(A) 6a0
(B) 3a0
(C) 2a0
(D) a0

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 MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE
IIT – JEE: 2023 TW TEST (ADV) DATE: 20/06/21
TOPIC: ATOMIC STRUCTURE

Answer Key

26. (C)
27. (C)
28. (D)
29. (B)
30. (A)
31. (B)
32. (C)
33. (B)
34. (C)
35. (D)
36. (C)
37. (C)
38. (D)
39. (C)
40. (C)
41. (A)
42. (B)
43. (C)
44. (D)
45. (B)
46. (C)
47. (A)
48. (A)
49 (B)
50. (B)

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