Assignment - Structure of Atom
Assignment - Structure of Atom
1. Cathode rays are 10. Number of electron, protons, neutrons present in 231
89𝑦
(A) electromagnetic waves (B) radiation (A) 89, 89, 242 (B) 89, 231, 89
(C) stream of ∝ particles (D) stream of electrons (C) 89, 89, 142 (D) 89, 71, 89
2. Which of the following does not characterizes x-rays? 11. The charge on an electron is 4.8 x 10-10esu, then What is the
(A) the radiation can ionize gases value of charge on Li+ ion?
(B) it causes ZnS to fluorescence (A) 9.6 x 10-10 esu (B) 1.44 x 10-9 esu
-10
(C) deflected by electric and magnetic field (C) 4.8 x 10 esu (D) 2.4 x 10-10 esu
(D) have wave length shorter than UV rays
12. Calculate the number of electron which can pass in 1s through
3. Bohr’s Orbits are called stationary states because a cross – section of a copper wire carrying 10-16 ampere
(A) Electrons in them are stationery (A) 624 (B) 100 (C) 62.4 (D) 62.40
(B) The orbits have fixed radii
(C) The electrons in them have fixed energy 12. The radius an atomic nucleus is of the order of
(D) The Protons remain in the nuclei and are stationery (A) 10-10 m (B) 10-15 m (C) 10-13 m (D) 10-8 m
4. Which of the following conclusion could not be observed 13. Which one has the highest e/m ratio
from Rutherford is α particle scattering experiment (A) H+ (B) He2+ (C) He+ (D) D+
(A) The radius of the atom is 10-10 m while nucleus is 10-15 m
(B) Most of the space in the atom is empty 14. If the radius of first Bohr orbit is x, then de-Broglie
(C) Electrons move in a circular path of fixed energy called wavelength of electron in 3rd orbit is nearly
orbits (A) 2πx (B) 6πx (C) 9x (D) x/3
(D) Electrons and the nucleus are held together by
electrostatic force of attraction 15. In the Bohr’s orbit, what is the ratio of total kinetic energy
and total energy of the electron?
5. Which of the following describes the emission spectrum of (A) -1 (B) -2 (C) +1 (D) +2
atomic hydrogen?
(A) A series of only four lines 16. The total energy of the electron in the hydrogen atom in the
(B) A continuous emission of radiation of a frequency ground state is -13.6 eV. The K.E of this electron is
(C) A discrete sense of equal intensity and equally spaced (A) Zero (B) 13.6 eV (C) -13.6eV (D) 6.8
with respect to wavelength eV
(D) Several discrete lines with both intensity and spacing
between lines decreasing as the Wavelength number 17. At what temperature will the total KE of 0.3mol of He to be
increases within each series the same as the total KE of 0.40 mol of Ar at 400k?
(A) 533K (B) 400K
6. According to Bohr’s atomic theory, which of the following is (C) 346K (D) 300K
correct?
(A) Coulombic force of attraction on the electron ∝ Z2 / n2 18. The amount of energy required to remove the electron from a
(B) Frequency of revolution of electron in an orbit ∝ 12 / n3 Li2+ ion in its ground state is how many times greater than the
(C) Potential energy of electron ∝ 12 / n2 amount of energy required to remove the electron from an H
(D) The product of velocity of electron and principle quantum atom in its ground state
number (n) ∝ Z2 (A) 2 (B) 9 (C) 3 (D) 5
7. Bohr radius of hydrogen atom is 19. Helium atom is two times heavier than a hydrogen molecule.
(A) 0.529 X10-8m (B) 0.529 X10-10m At 298 K the average kinetic energy of helium atom is
-3
(C) 5.29X10 m (D) 5.29X10-6m (A) four times that of a hydrogen molecule
(B) half that of hydrogen molecule
8. The value of 1 amu is equal to (C) same as that of a hydrogen molecule
(A) 1.66 x 10-24g (B) 12 g (D) Two times of hydrogen molecule
(C) 1.9924 x 10-24g (D) 1 g
20. According to law of photo chemical equivalence the energy
9. Proton is absorbed (ergs/mole) is (h = 6.62 x 10 -27 ergs, C=3 x 1010
(A) nucleus of deuterium (B) ionised hydrogen molecule cms-1 and NA = 6.02 x 1023 mole-1)
(C) ionised hydrogen atom (D) an ∝-particle
1.956 × 1016 1.956 × 108
(A) (B)
𝜆 𝜆
2.859 × 105 1.19 × 108 32. The angular speed of the electron in nth orbit of Bohr
(C) (D)
𝜆 𝜆 hydrogen atom is
(A) Inversely Proportional to n2
21. According to Somerfield’s model, only circular orbit is (B) Inversely proportional to N3
possible from the electron in (C) Directly proportional to n
(A) K shell (B) L shell (C) M shell (D) N shell
(D) Inversely proportional to √𝑛
22. Which is not deflected by magnetic field?
33. According to the Bohr theory, which of the following
(A) Neutron (B) positron
transitions in the hydrogen atom will give rise to the least
(C) proton (D) electron
energetic photon?
(A) n = 5 to n = 3 (B) n = 5 to n = 4
23. The spectrum of He atom may be considered similar to the
(C) n = 6 to n = 1 (D) n = 6 to n = 5
spectrum
(A) H (B) Li (C) Na (D) He+
34. The third line in the Balmer series corresponds to an
electronic transition between which Bohr orbits in hydrogen.
24. The probability of finding an electron is maximum
(A) 5 → 2 (B) 4 → 2 (C) 3 → 2 (D) 6 → 2
(A) at the Bohr radius (B) at the nucleus
(C) at a large distance from the nucleus
35. Electrons are filled in increasing order of energy this
(D) in between the nucleus and the first Bohr radius
statement was given by
(A) Hund’s rule (B) Pauli’s rule
25. The gaseous iodine molecule absorb yellow light form the
(C) Planck’s rule (D) Aufbau principle
visible region. Its colour would be
(A) Red (B) Green
36. An electromagnetic radiation has a frequency of 16.7 MHz.
(C) Yellow (D) Violet
What is the wavelength of those radiations in metres?
(A) 16.96 m (B) 18.96 m
26. In photo – electron emission, the energy of the emitted
(C) 17.92 m (D) 23.92 m
electron is
(A) Same as that of the incident photon
37. Calculate the energy in corresponding to light of wavelength
(B) Greater than the incident photon
45 nm. (Planck’s constant h = 6.63 x 10 -34 Js speed of light is
(C) Smaller than the incident photon
C=3 x 108ms-1)
(D) proportional to the intensity of incident photon
(A) 6.67 x 1011 (B) 4.42 x 10-18
-15
(C) 4.42 x 10 (D) 6.67 x 1015
27. An electromagnetic radiation has frequency of 16.7 MHZ.
what will be the wave length of these radiation in meter?
38. In a given atom no two electrons can have the same values for
(A) 16.96 m (B) 18.05 m
all the four quantum numbers. This is called
(C) 20.70 m (D) 15.25 m
39. ∝ - particles can be detected using
27. How many photons of light having a wavelength 4000m are
(A) Gold foil (B) Barium sulphate screen
necessary to provide 1.00 J of energy?
(C) Thin aluminium sheet(D) Zinc sulphide screen
(A) 1.01 x 1018 (B) 2.01 x 1018
15
(C) 2.01 x 10 (D) 1.01 x 1015
40. Wave nature of electron is shown by
(A) photoelectric effect (B) Compton effect
28. Number of photons emitted by a 100W (Js-1) yellow lamp in
(C) Thomson effect (D) Diffraction experiment
1.0 s (𝜆 of yellow light is 560 nm) is
(A) 2.8 x 1020 (B) 2.8 x 1018
41. A gas absorbs a photon of 355 nm and emits at two wave
(C) 1.1 x 1020 (D) 2.2 x 1020
length. If one of the emission is 680 nm, the other emission
will be
29. Velocity of electron in the second orbit of H – atom as
(A) 325 nm (B) 743 nm (C) 1035 nm (D) 518 nm
compared to that light is nearly
(A) 1/ 10 (B) 1/ 100 (C) 1/ 274 (D) 1/ 548
42. The frequency of radiation emitted when electron falls from n
= 4 to n = 1 in H-atom would be
30. Energy of an electron (m= 9.1 x 10-31 kg) moving with a speed
(E1 for H = 2.18 x 10-18g/atom; h = 6.625 x 10-34 Js)
of 5x107 km/s
(A) 1.03 x 1015g (B) 1.54 x 1015 S-1
(A) 11.4 x 10-10 J (B) 11.4 x 10-16 J 15 -1
(C) 3.08 x 10 S (D) 2 x 1015 S-1
(C) 22.75 x 10-21 J (D) 22.75 x 10-24 J
43. The order of filling up of electrons in the orbitals of an atom
31. The kinetic energy of 10 moles of CO2 at 27o C is
will be
(A) 3741 KJ (B) 3900 KJ
(A) 4s, 3d, 4p, 5s, 4d (B) 3d, 4s, 4p, 4d, 5s
(C) 374.1 KJ (D) 390 KJ
(C) 5s, 4p, 3d, 4d, 5s (D) 4s, 3d, 4p, 5s, 4d
44. Total number of orbitals associated with third shell will be 56. Aufbau principle does not give the correct arrangement of
(A) 4 (B) 2 (C) 9 (D) 3 filling up of atomic orbitals in
(A) Co and Zn (B) Cu and Cr
45. The quantum numbers of the last electron in a particular (C) Mn and Cr (D) Cu and Zn
element are l = 3, m = -2, s = + 1/2. In which block of the
periodic table is this element present 57. The shape of d-orbital is
(A) d-Block (B) p-block (C) s-block (D) f- (A) doughnut (B) clover
block (C) dumb-bell with doughnut (D) dumb bell with doughnut
46. Maximum number of electrons that can be associated with the 58. What is the maximum numbers of orbitals that can be
following set of quantum numbers n=3 ℓ=1 m= −1 identified with the following quantum number n = 3, l = 1, m
(A) 6 (B) 4 (C) 2 (D) 10 =0
(A) 1 (B) 2 (C) 3 (D) 4
47. The maximum number of electron in a subshell is determined
by the following 59. Magnetic quantum number specify
(A) 2n2 (B) 4l + 2 (A) shape of orbitals (B) orientation of orbitals in space
(C) 2l + 2 (D) 4l – 2 (C) energy of orbitals (D) size of orbitals
48. The total number of atomic orbitals in fourth energy level of 60. How many quantum numbers are needed to describe an
an atom electron orbital in three dimension?
(A) 8 (B) 16 (C) 32 (D) 4 (A) 4 (B) 3 (C) 2 (D) 1
49. The energy of electron in hydrogen atom is -328 KJ/mol. 61. According to the Bohr theory, which of the following
Then the energy level in which the electron present is transitions in the hydrogen atom will give rise to the least
(A) 4 (B) 3 (C) 2 (D) 1 energetic photon?
(A) n = 5 to n = 3 (B) n = 5 to n = 4
50. In hydrogen atom an orbit has a diameter of about 16.92 Ao. (C) n = 6 to n = 1 (D) n = 6 to n = 5
What is the maximum number of electrons that can be
accommodated? 62. The energy ratio of a photon of wavelength is 3000Å is 6000
(A) 18 (B) 32 (C) 50 (D) 72 Å is
(A) 2 : 1 (B) 1 : 2 (C) 1: 4 (D) 1 : 1
51. In hydrogen spectrum, the third line from the red end
corresponds to which one of the following inter – orbit jump 63. Which of the expressions given below gives IE of H – atoms
of the electron for Bohr orbits in an atom of hydrogen. in terms of Rydberg’s constant (RH)
(A) 4 → 1 (B) 5 → 2 (A) RH.hc (B) RH.c
(C) 2 → 5 (D) 3 → 2 (C) RH NA.hc (D) RH(2hc)
52. Which electronic level will allow the hydrogen atom to absorb 64. The total number of spectral lines obtained in Lyman series
photon but not to emit? when a electron drops from 6th level is
(A) 3d (B) 2p (C) 1s (D) 3p (A) 15 (B) 20 (C) 6 (D) 10
53. Which of the following should be the possible sub shells for n 65. The energy of second Bohr atomic theory, which of the
+ l = 7. following is -328 KJ mol-1, hence the energy of fourth Bohr
(A) 4f, 5p, 5s, 4d (B) 4s, 5d, 6p, 7s orbit would be
(C) 7s, 6p, 5d, 4f (D) 7s, 6p, 5d, 6d (A) -164KJ mol-1 (B) -41KJ mol-1
-1
(C) -82KJ mol (D) -1312KJ moI-1
54. How many moles of electron weight one kilogram?
1 66. If ‘r’ is the radius of first orbit, the radius of nth orbit of the H
(A) 6.023 x 1023 (B) x 1031
9.108 atom will be
6.023 1
(A) rn2 (B) rn (C) r/n (D) r2n2
(C) x 1054 (D) x 108
9.108 9.108×6.023
67. If the radius of first Bohr orbit is x, then De-Broglie
55. Calculate the energy in joules corresponding to light wavelength of electron in 3rd orbit is
wavelength 45nm. Given (h = 6.63 x 10-34Js, speed of light c= (A) 9x (B) x/3 (C) 6πx (D) 2πx
3 x 108 m/s)
(A) 6.67 x 1011 (B) 6.67 x 1015
-15
(C) 4.42 x 10 (D) 4.42 x 10-18
68. The first emission line in the atomic spectrum hydrogen in the 79. The angular momentum of d-orbital is
Balmer series appears at ℎ ℎ ℎ
(A) zero (B) √6 ( ) (C) (D) √2 ( )
3𝑅 7𝑅 2𝜋 2𝜋 2𝜋
(A) cm-1 (B) cm-1
4 144
5𝑅 9𝑅
(C) cm-1 (D) cm-1 80. The increasing order of energies of x-rays, 𝛾 rays and u-v rays
36 400
is
(A) u-v rays < x – rays < 𝛾 rays
69. The number of photons of light having wave number ‘x’ in 2J (B) x – rays < u-v rays < 𝛾 rays
of energy source is (C) 𝛾 rays < x – rays < u-v rays
ℎ𝑐 2 2𝑥 (D) 𝛾 rays < u-v rays < x – rays
(A) 2hcx (B) (C) (D)
2𝑥 ℎ𝑐𝑥 ℎ𝑐
81. The angular momentum produced due to spin of electron is
70. Which of the following is not permissible arrangement of given by
electron in an atom? ℎ √3 ℎ
−1 (A) 1/2 x (B) x
(A) n = 4; l = 0; m = 0; s = 2𝜋 2 2𝜋
2
1
−1 (C) (− ) h/2π (D) √3 h/2π
(B) n = 3; l = 2; m = -2; s = 2
2
94. If an electron travels with the velocity equal to the velocity of 104. Li and a proton are accelerated by the same potential. Their
light, its mass will be de-Broglie wavelength λLi and λP have ratio (assume m Li = 9
(A) zero (B) uncertain mp)
(C) infinite (D) unpredicted (A) 1: 2 (B) 1: 4 (C) 1 : 1 (D) 1 : 3 √3
95. Which one of the following rule states that the electrons are 105. In uncertainty in position and momentum are equal then
filled in increasing order of energy uncertainty in velocity is
(A) Aufbau principle (B) Pauli’s rule ℎ
(C) Planck’s rule (D) Hund’s rule (A) √ℎ / 2π (B) 1/2m √
𝜋
√ℎ
96. In Aufbau principle, the word "Aufbau" (C) 1/m √ℎ / π (D) d)
𝜋
(A) is a German word
(B) is related to the energy of electron 106.In Heisenberg uncertainly principle, uncertainty in the
(C) is a Greek word position of an electron (mass = 9.1 x 10-31 kg) moving with
(D) represents the name of scientist a velocity is 300ms-1, accurate up to 0.001% will be (h=
6.63 x 10-34 JS)
97. If an electron has spin quantum number of + ½ and a (A) 3.84 x 10-2 m (B) 1.92 x 10-2 m
magnetic quantum number of -1, it cannot be presented in (C) 19.2 x 10 m
-2 (D) 5.76 x 10-2 m
(A) d-orbital (B) f-orbital
(C) s-orbital (D) p-orbital 107. Two particles A and B are in motion. If the wave length
associated with the particle A is 5 x 10-8m find the wave
98. Aufbau principle does not give the correct arrangement of length of particle B is its momentum is half of A.
filling up of atomic orbitals in (A) 10-6 m (B) 10 -8 (C) 10-7 m (D) 2 x 10-8 m
(A) Co and Zn (B) Cu and Cr
(C) Mn and Cr (D) Cu and Zn 108. What will be the momentum of a particle which has a
wavelength 2Ao
99. Which of the following rule states that in a given atom no two (A) 3.3 x 10-34 kg ms-1 (B) 3.3 x 10-24kg ms-1
-26 -1
electrons can have the same values for all the four quantum (C) 3.3 x 10 kg ms (D)13.2 x 10-44 kg ms-1
numbers.
(A) Hund’s rule 109. How many nodal planes for f-orbital?
(B) Pauli’s exclusion principle (A) 1 (B) 2 (C) 3 (D) 0
(C) Heisenberg uncertainty principle
(D) Aufbau principle
110. Magnetic quantum number specifies 121. Maximum number of electrons that can be associated with
(A) orientation of orbital in space (B) nuclear stability the following set of quantum numbers n=4, ℓ=2, m= 2 to -1
(C) shape of orbital’s (D) size of orbital (A) 6 (B) 4 (C) 8 (D) 10
111. In Bragg’s equation for diffraction of x- rays ‘h’ represents 122. The circumference of the circular orbit of an electron is an
(A) order of reflection (B) momentum integral multiple of its
(C) Avogadro number (D) wavelength (A) angular velocity (B) mass
(C) momentum (D) static energy
112. The orientation of an atomic orbital is governed by
(A) Azimuthal quantum number 123. The quantum numbers of the last electron in a particular
(B) Spin quantum number element are l = 2, m = -2, s = + 1/2. In which block of the
(C) Principal quantum number periodic table is this element present
(D) Magnetic quantum Number (A) d-Block (B) p-block
(C) s-block (D) f-block
113. The shape of atomic orbitals is given by
(A) spin quantum number 124. The binding energy of 8O16 is 148 MeV. Its binding energy
(B) principle quantum number per nucleon is
(C) magnetic quantum number (A) 9.25 MeV (B) 2.5875 MeV
(D) subsidiary quantum number (C) 8.94 MeV (D) 12.875 MeV
114. The energy of an orbital in a multi electron atom depends on 125. The energy of an electron in the nth Bohr orbit of hydrogen
the atom is
(A) Principal, azimuthal and magnetic quantum number 13.6 13.6 13.6 13.6
(A) − 4 ev (B) − 3 ev (C) − ev (D) − 2 ev
𝑛 𝑛 𝑛 𝑛
(B) Principal, azimuthal, magnetic and spin quantum numbers
(C) Principal quantum number only
126. Ionisation potential of hydrogen atom is 13.6 ev hydrogen
(D) Principal and azimuthal quantum number only
atom in the ground state are excited by monochromatic light
of energy 12.1 ev. The spectral lines emitted by hydrogen
115. Principle quantum number specify
according to Bohr theory will be
(A) Energy level of orbitals
(A) Two (B) Three (C) One (D) Four
(B) orientation of orbitals in space
(C) energy of orbitals
127. The first orbital of H is represented by:
(D) size of orbitals 1
Ψ = (1/ao)3/2𝑒 −𝑟/𝑎𝑜 where ao is Bohr’s radius. The
√𝜋
116. Two electrons occupying the same orbital are distinguished by probability of finding the electron at a distance ‘r. from the
(A) Spin quantum number nucleus in the region dv is
(B) Azimuthal quantum number (A) Ψ 4𝜋r2dr (B) Ψ 2 dr
2 2
(C) Principal quantum number (C) ∫ Ψ 4𝜋r dr (D) ∫ Ψ dr
(D) Magnetic quantum number
128. The value of plank’s constant is 6.63 x 10 -34 JS. The velocity
117. Which one is represents the Schrodinger’s wave equation? of light is 3 x 108 m/s. Which value is closest to the
(A) Orbit (B) Energy wavelength in nanometer of a quantum of light with a
(C) wave function (D) Magnetic property frequency of 10 x 1014s-1
(A) 3 x 10-15 (B) 2 x 10-20 (C) 4 x 10-8 (D) 3 x 10-7
118. Plus and minus signs in the representation of orbital
129. The value of plank’s constant is 6.63 x 10 -34 JS. The velocity
representation the of light is 3 x 108 m/s which value is closest to the wavelength
(A) sign of wave function (B) addition and subtraction in nanometre of a quantum of light with a frequency of 8 x
(C) probability area (D) nodal plane 1015s-1
(A) 5 x 10-18 (B) 2 x 10-25
119. A 0.66 kg ball is moving with a speed of 100 m/s. The (C): 4 x 10 -18
(D) 3 x 107
associated wavelength will be (h = 6.6 x 10-34 JS)
(A) 6.6 x 10-34m (B) 1.0 x 10-32m 130. what is the wave length associated with an electron moving
-35
(C) 1.0 x 10 m (D) 6.6 x 10-32m with a velocity of 106 m/s? (given h = 6.63 × 10-34) JS and m
= 9.11 × 10-31 kg)
(A) 7.27 nm (B) 0.727 nm
120. Pauling’s electronegativity values for elements are useful in (C) 72.7 nm (D) -0.727 nm
predicting
(A)Electronegativity of the element
(B) Polarity of the molecules
(C) Electron affinity
(D) Dipole moments