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10.haloalkanes and Haloarenes KCET PYQs

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Haloalkanes and Haloarenes

For: KCET

1. Prolonged exposure of chloroform in humans a) R – F > R – Cl > R – Br > R – I


may cause damage to liver. It is due to the b) R – I > R – Br > R – Cl > R – F
formation of the following compound (2020) c) R – I > R – Cl > R – Br > R – F
a) CCl4 b) COCl2 d) R – F > R – I > R – Br > R – Cl (2016)
c) CH2Cl2 d) Cl2 6. The arrangement of following compounds:
2. Which of the following halide shows highest i) Bromomethane ii) Bromoform
reactivity towards SN1 reaction? (2020)
iii) Chloromethane iv) Dibromomethane
a) C6H5CH2Cl b) CH3−CH2Cl
In the increasing order of their boiling point
c) CH5−CH2−CH2−CH2I
d) C6H5Cl is
3. Which of the following halides undergoes a) iv < iii < i < ii b) I < ii < iii < iv
hydrolysis on warming with water/aqueous c) iii < i < iv < ii d) ii < iii < i < iv
NaOH? (2015)
7. The hydrolysis of optically active 2-
bromobutane with aqueous NaoH results in
the formation of
a) (-)- butan-2-ol b) (±)-butan-2-ol
c) (+)-butan-2-ol d) (±)-butan-1-ol
(2019) (2015)
4. The compound having longest C – Cl bond 8.
is

(2015)
(2019)
3. Which of the following statements is true in
case of alkyl halides?
a) They are polar in nature
b) They can form hydrogen bonds
c) They are highly soluble in water
d) They undergo addition reactions (2018)
4. Tertiary alkyl halide is practically inert to
substitution by SN2 mechanism because of
a) insolubility b) instability
c) inductive effect d) steric hindrance
(2018)
5. Reactivity order of halides for
dehdrohalogenation is

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