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Molecules of Life: 1.1 WATER 1.2 Carbohydrates 1.3 Lipids 1.4 Proteins 1.5 Dna & Rna

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BIOLOGY UNIT BIOLOGY 1 SB015

SEMESTER 1
KOLEJ MATRIKULASI MELAKA

CHAPTER 1: MOLECULES OF LIFE

1.1 WATER
1.2 CARBOHYDRATES
1.3 LIPIDS
1.4 PROTEINS
1.5 DNA & RNA

UPS 1 PSPM
7 marks -
CHAPTER 1 : BIOLOGY 1 SB015
SEMESTER 1
MOLECULES OF LIFE

1.1 : WATER
LEARNING OUTCOMES
a) State the structure and properties of water
molecules.
b) Relate the properties of water and its
importance:
i. universal/ versatile solvent
ii. high specific heat capacity
iii. high latent heat of vaporization
iv. cohesion of water molecules
v. maximum density at 4OC 2
STRUCTURE OF ONE WATER MOLECULE

❖Chemical formula: H2O


❖Shape: V shape with angle 104.50
❖2 hydrogen atoms joined to 1 oxygen atom
by single covalent bond.

Covalent bond

Schematic diagram
showing covalent bond
within a water molecule
STRUCTURE OF ONE WATER MOLECULE

❖ Water is a polar molecule:


⮚opposite ends of water molecule have opposite charges
• due to unequal distribution of shared electrons.
• O atom is more electronegative compared to H
atoms.
• Hydrogen: partial positive charge; δ+
• Oxygen: partial negative charge; δ–
STRUCTURE OF ONE WATER MOLECULE

Why oxygen is partially negative, and hydrogen is


partially positive?
FORMATION OF HYDROGEN BOND

• Polar property allows water molecules to form


hydrogen bonds with each other which is
constantly break & reformed.
• Hydrogen bond: A chemical bond that formed
when the partially positive (δ+) H of one
molecule is attracted to the partially negative
(δ–) oxygen in another water molecule,
causing them to stick together.

Hydrogen bond between


water molecule
FORMATION OF HYDROGEN BOND

⮚Hydrogen bonds are weaker than


covalent bonds but, strong enough to
hold water molecules together
Schematic Diagram Showing Hydrogen Bonds
Between Water Molecules
⮚ONE water molecule will form hydrogen bond
to a maximum of FOUR water molecules

4
2
3
QUESTIONS

1. Why is it unlikely that two


neighboring water molecules
would be arranged like this?

2. What would be the effect on the properties


of the water molecule if oxygen and hydrogen
had equal electronegativity?
PROPERTIES OF WATER

1. Is universal/versatile solvent
2. Has high specific heat capacity
3. Has high latent heat of vaporization
4. Cohesion of water molecules
5. Has maximum density at 4°C
1. IS UNIVERSAL/ VERSATILE SOLVENT

❖ Due to its polarity, water act as


universal solvent
❖ It can dissolve ionic and polar
molecules
e.g. sodium chloride (NaCl)
• Oxygen atoms (partially
negative charge) are attracted
to positively charged sodium
ion (Na+)
• Hydrogen atoms (partially
positive charged) are attracted
to negatively charged chloride
ion (Cl-)
When you pour some table salt (NaCl)
into a cup of water, what really happens?

Hydration shell
The sphere of water
molecules around each
dissolved ion

Water molecule surround


sodium and chloride ions,
separate and avoid them from each other.
BIOLOGICAL IMPORTANCE OF
WATER IS UNIVERSAL/ VERSATILE SOLVENT

❖ Capable of dissolving different types of


substances (especially polar and ionic
compounds)
- due to its ability to form hydrogen bonds

❖ Provides an aqueous medium


for biochemical reactions
(i.e. enzymatic reactions)

❖ Major transport medium in living


organisms (e.g. in blood capillaries
of human and in xylem of plants)
2. HIGH SPECIFIC HEAT CAPACITY

Definition of high specific heat capacity :


Large @ high amount of heat energy
that must be absorbed or lost for
1 gram of water molecules to change
its temperature by 1ºC

Specific heat capacity for water


= 1 cal/gºC @ 4.2 J/gºC
2. HIGH SPECIFIC HEAT CAPACITY

❖ Large amount of heat energy is


absorbed to break ALL hydrogen
bonds between water molecules in
order to increase the temperature
of water molecules
❖ Large amount of heat energy is
released to form hydrogen bonds
between water molecules in order to
decrease the temperature of water
molecules
BIOLOGICAL IMPORTANCE OF
WATER HAS HIGH SPECIFIC HEAT
CAPACITY

❖ Can stabilize the ocean


temperature & enable
aquatic organisms to
survive in favorable
environment

❖ Act as heat buffer


to prevent large
fluctuation in body
temperature of
terrestrial organisms 16
3. HIGH LATENT HEAT OF VAPORIZATION

Definition of high latent heat of


vaporization :

Large @ high amount of heat energy


that must be absorbed for 1 gram of
water molecule to change from liquid
water into water vapour
Latent heat of vaporization for
water = 580 cal/g
3. HIGH LATENT HEAT OF VAPORIZATION

Large amount of heat energy is absorbed


to break ALL hydrogen bonds between
water molecules in order to change liquid
water into water vapour
BIOLOGICAL IMPORTANCE OF
WATER HAS HIGH LATENT HEAT OF VAPORIZATION

❖ Give the evaporative cooling effects


during:
⮚ Evaporation of sweat on
human skin
- To dissipates body heat
and help prevent terrestrial
organisms from
overheating on hot day/
strenuous activity//

- To maintain body
temperature
19
BIOLOGICAL IMPORTANCE OF
WATER HAS HIGH LATENT HEAT OF VAPORIZATION

❖ Give the evaporative cooling effects


during:
⮚ transpiration from leaves of
plants help keep the tissues
in leaves from becoming too
warm in the sunlight

⮚panting in animals
e.g. dog

20
QUESTIONS

1. Why must water absorb relatively large


quantity of heat in order to change its
temperature?

2. State ONE property of water based on


question above.
4. COHESION OF WATER MOLECULES

❖ Definition of cohesion:
Force of attraction (hydrogen
bonds) between the water molecules

⮚ One result of cohesion due to the


hydrogen bonding is high surface
tension; a measure of how difficult
it is to stretch / break the surface of
a liquid
4. COHESION OF WATER MOLECULES

❖ Water molecules on the surface is bonded by hydrogen


bonds with water molecules at the below to form a ‘skin
like’ layer at the surface of water
4. COHESION OF WATER MOLECULES

• In the body of water, water molecule within


are attracted equally by cohesion.
• At the air-water interface, cohesive force
only form interior.
• The unequal attraction cause the inwardly
forces that cause high surface tension at
the surface of water.
• E.g.: Surface of pond
BIOLOGICAL IMPORTANCE OF
COHESION OF WATER MOLECULES
❖ Allows insects to walk on the water
surface.
• The high surface tension of water, resulting
from collective strength of hydrogen bonds,

e.g. water skater/


raft spider

25
BIOLOGICAL IMPORTANCE OF
COHESION OF WATER MOLECULES
❖ Transport of water and
dissolved nutrients
against gravity in plants
water-conducting cells.
• Water from the roots reaches the
leaves through a network of water-
conducting cells.

• Adhesion of water by hydrogen


bonds to the molecules of cell walls
helps counter the downward pull of
gravity
6. MAXIMUM DENSITY AT 4°C

❖ At temperature above 4⁰C, water behave like other liquid,


expanding as it warms and contracting as it cools
❖ Water reaches its greatest density at 4⁰C
❖ Ice is less dense than liquid water at 4 ⁰C

❖ As temperature falls from 4⁰C to 0⁰C, water begin to


freeze because more water molecules are moving slowly
to break hydrogen bonds. 27
6. MAXIMUM DENSITY AT 4°C

❖ At 0°C, liquid water transforms into ice (solid)


❖ The water molecules become locked into crystalline
lattice; each water molecule hydrogen bonded to four
partner.
❖ Ice floats in liquid water because hydrogen bond keeps
the water molecule far enough apart, making ice less
dense.
BIOLOGICAL IMPORTANCE OF
MAXIMUM DENSITY AT 4°C

❖ Allow aquatic organisms to survive under


the floating ice during winter
• As ice floats, it acts as insulator to
prevent ponds, lakes, oceans from
freezing.
Test your knowledge….

How does aquatic life survive in


extremely cold conditions ?

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