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Cat Chem Cl. 12

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CONTINUOUS ASSESSMENT TEST SUBJECT: CHEMISTRY DURATION: 2

HOURS
Class 12
1. When benzene react completely with excess hydrogen in nickel catalyst, it forms
A. cyclohexene B. Cyclohexane C. Xylene D. phenol
2. The main reaction of aromatic compounds like benzene is ___ A. addition B. elimination
C. substitution D. esterification
3. Which of he following exhibits resonance? A. acetylene B. paraffin C. benzene D. alkanol
4. oxidation of the compound CH3-CHOH-CH3 using acidified K2Cr2O7 will produce __
A. proanone B. propanal C. propanoic acid D. propan-2-ol
5. A group that will turn blue litmus papr to red will correspond to the general formula __
A. CnH2n+2 B. CnH2n+1OH C. CnH2n+1COOH D. CnH2n+1X
6. The main product in the reaction; CH3-CH=CH2 + HBr is A. 2-bromopropane
B. 2-bromopropene C. 1-bromopropene D. 1-bromopropane
7. The organic product Y obtained in the reaction; CH3-CH2-CH2-OH heat/H2SO4 Y
is A. ethene B. propene C. ethane D. propane
10. The type of reaction CH3-CH2-CH2-OH heat/H2SO4 Y is A. dehydration
B. hydrolysis C. fermentation D. condensation
11. The product obtained when ethene react with acidified KMnO4 is
A. ethanol B. Propan-1,2-diol C. ethan-1,2-diol D. propanoinc acid.
12. Ethyne can undergo the following reactions except____ A. substitution
B. elimination C. addition D. polymerization.
13. Due to the unstable nature of ethyne, it is usually stored in ___ A. water B. paraffin
C. acetone D. ammonia
14. Alkynes are distinguished from alkenes using ___ A. bromine water B. ammoniacal silver
nitrate C. fehling’s solution D. million’s reagent.
15. When ethyne is passed through hot tube containing organo-nickel catalyst, the product is
_____ and the process is ____ A. hexyne, addition B. benzene, condensation C. benzene,
polymerization D. hexyne, polymerization
16. Which of the following will produce highest amount of soot when combusted under the
same conditions? A. C2H6 B. C2H4 C. C4H8 D. C2H2
17. The hybridization in the compound CH3-CH2=CH is/are
A. sp and sp2 B. sp2 and sp C. Sp3 only D. sp and sp3
18. A group of compound that will give a precipitate on reaction with ammoniacal AgNO 3 will
conform to the general formula A. CnH2n-2 B. CnH2n+2 C. CnH2n D. CnH2n+1
19. Identify X and Y respectively in the reaction:
CH=CH + H2 X + H2 Y A. ethane, ethene B. ethane, ethyne
C. ethene, ethane D. ethene, ethyne
20. When tertiary a alkanol are treated with acidified KMnO4, it will __ A. form alkanone B.
form alkanal C. not oxidize D. form alkanoic acid.
21. The alkyne that will NOT give a white precipitate on reaction with silvertrioxonitrate(V) is
A. CH3-CH2-C=C-CH2-CH3 B. H-C=C-CH2-CH2-CH3
C. CH3-CH2-CH2-CH2 –C=CH D. CH3-CH2-CH2-CH2 –C=CH
22. The intermediate product formed when ethanol is progressively oxidized to ethanoic acid
with potassium heptaoxodichromate (IV) is A. butanal B. ethanol C. methanol
D. propanal

23. The IUPAC name of the compound; CH3-CH2-CHBr-CH(C2H5) –C=C-CH3


A. 5-bromo-4-ethylhept-2-yne B. 3-bromo-4-ethylhept-2-ne
C. 5-bromo-4-methylhept-5-yne D. 5-bromo-4-ethylheptyne
24. A gaseous substance is slowly cooled and the temperature recorded every second.
The results are shown on the graph.
temperature A
/
°C B
C
D

time /
At which point is the s
substance a solid?
26. aqueous barium chloride is added to an unknown solution followed by dilute hydrochloric
acid, white precipitate was formed which remain insoluble in excess dilute HCl, what is the
ion in the unknown? A. SO32- B. SO42- C. S2- D. CO32-
27. brown ring test is usually for the identification of which ion?
A. NO3- B. SO42- C. S2- D. CO32-
x
28. C11H10O5 + H2O C6 H12 O6 in the equation, x and y are respectively _ and
y
_ A. hydration and condensation B. condensation and hydration C. condensation and addition
D. addition and hydrolysis
29. Arrange the following compounds in order of increasing boiling point
l.CH 3CH2CH2OH
II.CH 3CH 2OH
III.CH3CH2CH2CH2OH
IV. CH3CH 2CH2CH 2CH 3
A. I < II < IV < III B. IV < III < II < I C. I < II < III < IV D. IV < II < I < III
30. A hydrocarbon containing 88.9% carbon has the empirical formula [H = 1 C = 12]
A. CH B. CH2 C. C2H3 D. C2H5
31. The equation for the reaction between sodium carbonate and excess dilute hydrochloric acid
is shown.
Na2CO3 + 2HCl → 2NaCl + H2O + CO2
When 26.5 g of sodium carbonate reacts with excess dilute hydrochloric acid, what is the
maximum volume of carbon dioxide produced?
A 6 dm3 B 12 dm3 C 18 dm3 D 24 dm3
32. When chlorine gas dissolves in water a reaction occurs.
Cl 2 + H2O → HCl + HClO
Which row of the table identifies the oxidation number for chlorine in the chlorine-
containing species?
Cl 2 HCl HClO
A −1 −1 −1
B 0 −1 −1
C −1 +1 +1
D 0 −1 +1

33. The structure of ester W is shown.

H O
H C C H

H O C H

Which row gives the names of ester W and the carboxylic acid and alcohol from which it is
made?

name of ester W carboxylic acid alcohol


A ethyl methanoate ethanoic acid methanol
B ethyl methanoate methanoic acid ethanol
C methyl ethanoate ethanoic acid methanol
D methyl ethanoate methanoic acid ethanol

34. The equation for the reaction between butane, C4H10, and chlorine is shown.

C4H10 + Cl 2 -> C4H9Cl + HCl

Which type of reaction does butane undergo when it reacts with chlorine?
A addition B. reduction C. acid–base D. substitution
Butene has three structural isomers which are alkenes.
Which statements about these isomers are correct?

1 They have the same molecular formula.


2 They have different numbers of bonds in the molecule.
3 They have a C=C bond in the structure.

B 1 and 2 B 1 and 3 C 2 only D 3 only


36. The hydrocarbon C12H26 is cracked to give X and Y, as shown.
C12H26 -> X + Y
Which statement is correct?
A. If X is C6H12 then Y will react with aqueous bromine.
B. If X is C10H22 then Y can be used to make a polymer. C. If X is a hydrogen molecule
then Y is an alkane.
D. X and Y could be structural isomers.
37. An ester, C4H8O2, is made by reacting 0.06 mol of ethanol, C2H6O, and 0.05 mol of ethanoic
acid, C2H4O2.
C2H6O + C2H4O2 -> C4H8O2 + H2O
0.0375 mol of the ester was made. [C=12, H=1, O=16]
What is the percentage yield and the Mr of the ester?

percentage
yield / Mr
%
A 62.5 48
B 75.0 48
C 62.5 88
D 75.0 88

38. Which type of compound is made when a protein is


hydrolyzed?
A. alkene B. amino acid C. carboxylic acid D. sugar
39. The alkanol with the structure given here is A. primary,
tertiary and trihydric B. tertiary and dihydric C.
secondary, primary and dihydric D. secondary, primary
and monohydric
40. When propanoic acid react with sodium, the organic product formed is __ A. sodium
propoxide B. sodium propanoate C. sodium ethoxide D. sodium ethanoate

THEORY ANSWER ALL QUESTIONS


1. (a) Consider the following reaction sequence.
(i) What process leads to the formation of K?
(ii) Write the formula of K.
(iii) Write the structural formula of L and name L.
(iv) Name An
(v) Write the structure of M and name M.

2. (a) Consider the compound with the structure


(i) name the compound
(ii) which homologous series does it belong?
(iii) give the (I) word equation (II) symbol equation for formation of the compound from its
reactants.
(iv) state the condition and reagent for the reaction in
(iii) above
(v) draw a compound of carboxylic acid that is its isomer.
b. What is meant by isomerism?
3. (a) Mention two information that can be gotten from qualitative analysis of organic
compounds.
(b) define alcoholic fermentation Give the equation for the fermentation of glucose.
(c) For the complete combustion of ethanol equation, determine the number of moles of CO 2
formed if 2.3g of ethanol combusted completely in excess oxygen.
4. (a) Name the type of reaction involved in converting propanol to the following compounds;
(i) propanoic acid (ii) chloropropane (iii) calcium propoxide (iii) sodium propoxide
(b) state three properties of a homologous series
5. Consider the compound with the given structure. The compound can undergo addition
polymerization.
(a) (i) state the reagent and condition for the compound to be polymerize.
(ii) Draw the structure of the polymer formed showing at least two
repeating units.
(iii) What is a polymerization?
(b) copy and complete the following reactions:
(i) CH3-CH2OH + PCl5 
(ii) CH3-CH2-COOH + NH3 
(iii) CH3 -CH(CH3)-COOH + NaHCO3 

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