Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS&STERLING_BT Paper -2(Adv-2022-P2-Model) Date: 18-08-2024
Time: 02.00Pm to 05.00Pm CTA-03/05 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 8 2 3 3 3 4 1 5 6 6 0

7 4 8 2 9 ACD 10 AD 11 ABCD 12 BC

13 ACD 14 ABC 15 B 16 B 17 D 18 B

PHYSICS
19 5 20 3 21 1 22 9 23 3 24 0

25 3 26 4 27 BD 28 AD 29 ABC 30 ABD

31 ABC 32 CD 33 C 34 C 35 D 36 A

CHEMISTRY
37 5 38 6 39 5 40 1 41 5 42 6

43 4 44 6 45 ABCD 46 BD 47 ABCD 48 B

49 AB 50 A 51 C 52 B 53 B 54 D
 Sri Chaitanya IIT Academy 18-08-2024_Sr.Super60_NUCLEUS & STERLING_BT_*Jee-Adv(2022-P2)_CTA-03/05_Key& Sol’s

SOLUTIONS
MATHEMATICS
 x2 , x 1
1. f ( x)   2
 x  x , x 1
The positive integers not belonging to the range of f  x  are n  n  1 ; n  N . So, they are
1
2, 6,12, 20, 30 Further as x 2  x   , f  x  can't attain any negative integer i.e. 3, 2,1 ,
4
tan   tan 
1 1
1
2. Using LMVT, 
  1  c2
Where 0    c    3
1 1  
So,   1 , So, 1   4 , So the answer is 3.
4 1  c2 tan 1   tan 1 
f    sin  2  . cos 3 x cos ec xdx
2
3. 1

So, f '    sin  2  cos3  2  cos ec  2  .2  2 cos  2  .1 cos 3 x cos ec xdx
2

 f    f '  
 2 cos3  2   cos  2  .    cot  2  f    cos 3  2 
 sin   
2
2

 3    1    1 k
Now putting   , we get, f '    f      64k 2  3
3 2   3 3  3 8 3
4. The region satisfying the given conditions is the region shaded in the following figure,
Area  2   11  1 sq. unit
1
2 

ln x 1  ln x
5. f  x   f ' x   0  x  e . Clearly f  x  . is many-one for 1  x   . So;
x x2
ln 2 ln b
1  a  e  a  2 . Now for  , b  l  .b must be of the type 2k , k  1
2 b
So, 2k  2k , which is true for k  2 but not for any k  3 as the difference between
2k and 2k increases as k increases k  2. So, k  2 and b  4 . So, a  b  6 .

6.
f3    f 3  7  T  3  7  T  3  7  T  f   3  7  T 
n
7 T1

2
1
n
2

n
1
n  1
n
1

g  2  2  T  g  2  2  T   2  2  T   2  2  T  g    2  2  T 
n n n n n
2 2 2 2 2

f T  3  7     
 f  3 7 T
    2  2  T 3  7  
n n n n
1
T 1 2
So, lim n  lim 0
f T  2  2   T g  2  2  T  2  2  

1
. .
  3  7  T
n n  n n n
2
2 1 2
 
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a x a a
7. f '   x f ' x 
 x  f  x x a
xf  
x
a
a2 f ' 
a x
f ''  x    
a 2
x 2 f   x3  f  a  
x   x 
  
f ' x   f '  x 
2

Using equation (1), (2) and (3), we get f ''  x    

x f  x
x  f  x 
2
f ' x xf ''  x 
 xf  x  f ''  x   f  x  f '  x   x  f '  x   
2
  0
f  x f  x  f  x
2

'
 xf '  x   xf '  x  f ' x c
Observe    0 . So, c 
 f  x  f  x f  x x
f  x  2  f  x 
8. Put n  1; f '  x   f  x  1  f  x  , n  2; f '  x  
2
f  x  2   f  x  1  f  x  1  f  x  1 1
So, f '  x   , f '  x    x  1  f '  x 
2 2 2
 f '  x   f '  x  1 x  R   f  x  1  f  x   '  0x  R
 f  x  1  f  x   c for a constant c  R  f '  x   c  f  x   cx  d
 x  1  0x  R
2
2x
9. f  x   x  ln 1  x 2   f '  x   1 

1 x 2
1  x2
So, f  x  is injective and at x  1 , tangent is not parallel to any of the chords
Again
 1  x2 
   2x   2 
lim x  f ( x )  lim x  ln e x  1  x 2   lim x  ln   x   lim x  ln   x   lim x  ln   x   
 e  e  e 
So, f is surjective also.
10. lim x 2 (log 3 (ax 2  3 x  1)) must be equal to 1
So, 4  7  3    1
 log 3 (  x 2  3x  1)  1  lim x2  ( x  1)(3  2 x)  1/3
Also,   elim  x 2
  e  e
 log 3  x  1   ( x  3 x  1) 
2

 1   
i.e.,  f    1 is reciprocal of  f  x   1 .
1 1
11. f    1 
  x    f  x   1  x 
 /2 cot 1 x
1 tan 1 x
Now; for f  x   , f  x 1 
, f    1 
tan 1 x tan 1 x  x cot 1 x
2 1  k ln x 1 1  k ln x
Also for f  x   , f  x 1  , f   1 
1  k ln x 1  k ln x  x 1  k ln x
12. As the point  ,   lies on both f  x  and g  x  , the point   ,   will also lie on both the
curves and as the functions are continuous they must cross (meet on) the line y  x in
between. f must be on decreasing path, for all these to happen.

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13. For f  x  to be bounded, its denominator should never become zero. So, its discriminant
must be negative. Also, for some finite x, f  x  must be equal to lim x  f  x  i.e.,
ax 2  bx  c a
  bdx  cd  aex  af   ae  bd  x  cd  af
dx 2  ex  f d
So, ae  bd
1 1 1 
   g  x  dx
1     0
14. g x dx 
1 
  g  x dx  1     g  x  dx
 0

Add  f  x dx both sides
0
 
  f  x dx   f  x  dx
0 0

Add  f  x dx
0
both sides
(B) Cauchy-schwarz inequality to the functions f  t  and g  t   1t  0,1
15. f ( x  4)  (0.1)3[ x  4]   (0.1)  81 3[ x ]  8  3[ x ]  (0.1)3[ x ]   (0.1)3[ x ]   f ( x)
1 1 1
16. f ( x)   (1  { x})  { x}   1  f ( x)  2   1.( AM  GM )  f min  2  1
2{ x} 2{ x} 2
1 1 1
which occurs when { x}   x  n   x  n ,n I
2 2 2
17. For x    Q c , f    0 and lim x f  x  is also zero because if x moves towards  through
irrational numbers then it is zero, or if through rational numbers then the denominator can
be made as large as possible.
1 f  x 1 f  x
18. ,  0x  1,3
x x
2 1 f  x 21 f  x
1 x dx  1 2 dx
31 f  x 31 f  x
2 x dx  2 2 dx
31 f  x 31 f  x
  dx    dx
2 x 2 2
3 f  x
Adding equation (1) and (2), we get ln 2  ln    2
3
dx
2 x
 1; 1  x  2
Equality holds for f  x   
1; 2  x  3

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PHYSICS
19. In steady state
T
Q dT Q dT Q
t 0

t 0  TdT
 kA  TA dx   TA
t dx t dx 3T0

T T  dT
3T0 T0

x
dx
Q
  4 AT02 ---------- (1)
t

Similarly
Q 
A
 9T02  T 2 
………. (2)
t 2 2
Dividing (ii) by (i)
9T02  T 2  4T02 T 2  5T02 T 2  5T0
KA 1   2  1
20. Q K 
l 1   2
GM GM  GM / 8  GM  1 1 
21. V1   V2     
2R 2 R  3R / 2  R 12 2 
GM  1  6  5 GM V1 1 12 6
      1.2
2 R  12  12 R V2 2 5 5
22. There will be no deviation due to slab, hence the deviation is 90
3kQ kQ 3kQ kQ kQ
23. Vo   V0'     V0  V0' 
2R R 2R R R
24. A   2, 2 and B   4,1
B B
 
WA B  q VB  VA   q  dV  q  qE.dr
A A
B B
 q   
yiˆ  xjˆ . dxiˆ  dyjˆ   q   ydx  .  xdy 
A A
 4,1

 q  4  4  0
4,1
 q  d  xy   q  xy  2,2 
 2,2 
25.

 
R 
 3
   
3 0
1 1 1 1 a
26. If u   v  f If u  R  2 f 2   b.......  2  4
2 f 
2 2
v f v b

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27. TA  T Loss by radiation > absorption by radiation

TB  T Loss by radiation < absorption by radiation
28. Centre of the Earth is focus of any path of satellite. Such a path will definitely pass over
the equator. The smallest time period is for a satellite, which is near to the surface of
R
Earth. Tmin  2
g
1 kq 2 1 2 R
29. 1) o  mv02   mv , 2) mv0  mvR
2 R 2 2
1 2  p cos   2QP cos    
30. mv  Q  2 
0 Or v     
 4 0 r  4 0 mr  2
2
2 
Circular motion of bead requires a centripetal force
V 2 P cos  mv 2
Er    , Note that QEr 
r 4 0 mr 3 r
31. If I 3 is an image, mirror can be plane or convex
32. Apply snell’s law
33.

1
i) When charge is at corner part remains inside cube.
8
1
ii) When charge is at any face part remains inside cube.
2
1
iii) When charge is on any side part remains inside cube.
4
2
1 K
V  0 E 2  0  2   U   4
1
34.  log r  4 log r  K
2 2  r 
GM  5M L
35. 2
 5M   2 
L 6

6GM
 
L3
L3
 T  2
6GM
36. Apparent depth is less at far from the man

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 Sri Chaitanya IIT Academy 18-08-2024_Sr.Super60_NUCLEUS & STERLING_BT_*Jee-Adv(2022-P2)_CTA-03/05_Key& Sol’s

CHEMISTRY
37. Isomerism-concept
38.
H
H'
H 35o

H" 1200

120  350  1550 x  155

0

x
So  6.2
25
8 26
39. C4 H 6 , DU  2
2

40. enantiomenic pair(s) 1only

41.
Br
C C C C C C C C C  C C C

E / Z  2

C C C C C C
C C  C C C C

1

E / Z  2

42. total number of pairs of lone pair between phenol and the final products 6
43. Compound 3,6,7,8
44.
HO

HO
OH OH

OH
OH

45.
Br
C2 H 5OH

Here, substituted as well as Eliminated products will be obtained.

46. Reimer-Tiemann Reaction
47. I,II,II potential energy diagram for S N 1 , S N 2

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48. Fridel-Craft acylation reaction based

49. Allylic substitution
50.
CF3  CH  CH 2 HCl CF3  CH  CH 2
I 
Less stable
CF3  CH  CH 2
 I 
Norestable
51. 10 Benzenoid isomers possible for C6 H 3ClBrI
52.
Cl Cl

Cl Cl

2
Cl 
excess Cl
hv
 Cl

Cl Cl
Cl Cl


Zn
excess 
Cl Cl
Cl Cl

Cl Cl
Cl Cl
53. Friedel-craft Alkylation
54.

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