OG SR (ENGINEERING) KCET GT-1(ONLY KA all batches ) Dt-06-08-2021

TIME-1-00 HR Max Marks: 60M

CHEMISTRY
1. The correct order of the packing efficiency in different types of unit cells is
(1) fcc<bcc<simple cubic (2) fcc> bcc > simple cubic
(3) fcc<bcc> simple cubic (4) bcc<fcc>simple cubic
2. The correct increasing order of ionic radii of the following is
(1) Yb3+  Pm3+  Ce3+  La 3+ (2) Ce3+  Yb3+  Pm3+  La3+
(3) Yb3+  Pm3+  La3+  Ce3+ (4) Pm3+  La3+  Ce3+  Yb3+
3. The limiting molar conductivities  0 forNaCl,KBr andKClare126,152and150 Scm2 mol−1

respectively. The  0 for NaBr is

(1) 128 Scm2 mol−1 (2) 302 Scm2 mol−1
(3) 278 Scm2 mol−1 (4) 176 Scm2 mol−1
4. The quantity of charge required to obtain one mole of aluminium from Al2O3 is
(1) 1F (2) 6F (3) 3F (4) 2F
5. A first order reaction is 50% completed in 1.26 1014 s .How much time would it take for
100% completion?
(1) 1.26  1015 s. (2) 2.52  1014 s (3) 2.52 1028 s (4) infinite
6. Which of the following liquid pairs shows a positive deviation from Raoult’slaw?
(1) H2O+HCl (2) Acetone + chloroform (3) H2O+HNO3 (4) C6H6 +CH3OH
7. Which one of the elements with the following outer orbital configurations may exhibit
the largest number of oxidation states?
(1) 3d 2 4s1 (2) 3d3 4s 2 (3) 3d5 4s1 (4) 3d5 4s 2
8. Z in the following sequence is
 (1) Toluene (2) Benzene
(3) Benzoic acid (4) Benzaldehyde
9. The major product of dehydration of the following reaction is

(1) (2)

(3) (4)
10. The major organic product formed in the following reaction

(1) (2)

(3) (4)
11.
 The product ‘C’ in the above reaction is

(1) (2)

(3) (4)
12. When 1 mole of CrCl3.6H 2O is treated with excess of AgNO3 , 3 moles of AgCl are
obtained. The formula of the complex is
(1) CrCl3 ( H 2O )3  .3H 2O (2) CrCl2 ( H 2O )4  Cl.2 H 2O

(3) CrCl ( H 2O )5  Cl2 .H 2O (4) Cr ( H 2O )6  Cl3

The CFSE for octahedral CoCl6  is18,000cm−1. The CFSE for tetrahedral CoCl4 
4− 2−
13. will

be
(1) 18,000 cm−1 (2) 16,000 cm−1 (3) 8,000 cm−1 (4) 20,000 cm−1
14. Which of the following arrangements is possible?
n l m s
1
(1) 5 2 2 +
2
1
(2) 2 2 0 −
2
 1
(3) 3 -2 1 +
2
1
(4) 0 0 1 +
2

15. According to Bohr’s theory, the angular momentum of an electron in 5th orbit is
(1) 25 h /  (2) 1.0 h /  (3) 10 h /  (4) 2.5 h / 

16. Which one of the following has dipole moment (  ) = 0?

(1) CH 2Cl2 (2) SO3 (3) NH 3 (4) H 2O

17. Match the species given in column I with the shape given in column II and mark the
correct option
Column I Column II
A) SF4 i) Tetrahedral
B) BrF3 ii) Pyramidal

C) BrO3− iii) Sea-saw shaped

D) NH 4+ iv) Bent T-shaped

Code:-
1) A (iii); B (ii); C (i); D (iv) (2) A (iii); B (iv); C (ii); D (i)
3) A (i); B (ii); C (iii); D (iv) (4) A (i); B (iv); C (iii); D (ii)
18. Smallest internuclear distance is found in
(1) O2 (2) O22+ (3) O2− (4) O22−
19. The pair of gases with same rate of diffusion
1) CO,NO (2) N 2O, CO (3) N 2O, CO2 (4) CO2 , NO2
20. Maximum number of Oxygen atoms are present in
(1) 2g of carbon dioxide (2) 2g of carbon monoxide
(3) 2g of water (4) 2g of Sulphur dioxide.
21. The structure of diborane ( B6 H 6 ) contains

(1) Four 2c-2e bonds and four 3c-2e bonds

(2) Two 2c-2e bonds and two 3c-2e bonds
(3) Two 2c-2e bonds and four 3c-2e bonds
 (4) Four 2c-2e bonds and two 3c-2e bonds
22. The enthalpy of formation of NH 3 is − 46kj moj −1. The enthalpy change for the reaction:
2 NH 3( g ) → N2( g ) + 3H 2( g ) is

(1) +184 kj (2) +23 kj (3) +92 kj (4) +46 kj

23. One mole of PCl5 is heated in a closed 2dm3 vessel. At equilibrium 40% PCl5 is
dissociated. Calculate the equilibrium constant.
(1) 0.066 (2) 0.154 (3) 0.133 (4) 0.266
HBr / ( C H CO ) O
24. CH 3CH 2CH = CH 2 ⎯⎯⎯⎯⎯⎯⎯
6 5 2 2 → Y ⎯⎯⎯⎯
C2 H5ONa
→Z
Identify Z in the given option

(1) ( CH3 )2 CH − O − CH 2CH3 (2) CH3CH2CH ( CH3 ) − O − CH2CH3

(3) CH3 ( CH2 )3 − O − CH2CH3 (4) CH3 ( CH2 )4 − O − CH3

25. Equal masses of CH 4 and H 2 are mixed in an empty chamber. The partial pressure of
methane expressed as the fraction of total pressure is

1 8 1 8
(1) (2) (3) (4)
2 19 9 9
26. In the Lassaigne’s test for sulphur in the organic compound with sodium nitroprusside

solution the purple colour formed is due to

(1) Na4  Fe ( CN )5 NOS  (2) Na3  Fe ( CN )5 S 

(3) Na2  Fe ( CN )5 NOS  (4) Na3  Fe ( CN )6 

27. IUPAC name of the compound OHC − CH2 − CH2 − COOH is

(1) 3-formylbutanoic acid (2) 3-formylpropanoic acid
(3) 4-oxobutanoic acid (4) butane-4-al-1-oic acid
28. A hydrocarbon with molecular formula C4 H 6 gives a white precipitate with ammoniacal
AgNO3 . On passing through dil. H 2SO4 containing HgSO4 gives 2-butanone. The
hydrocarbon is
(1) 2-butyne (2) 1-butene (3) cyclobutene (4) 1-butyne
29. 1.42g of methyl iodide was completely converted into methyl magnesium iodide and the
 product was decomposed by excess of ethanol. The volume of the gaseous hydrocarbon
produced at STP will be

(1) 22.7 litre (2) 227 litres (3) 0.227 litre (4) 2.27 litre
30. The product B in the following reaction is

(1) (2) (3) (4)

31. Consider the following bromides

The correct order of SN1 reactivity is

(1) A>B>C (2) B>C>A (3) B>A>C (4) C>B>A

32. ( )
Uncertainly in the position of an electron mass = 9.1 10−31 kg moving with a velocity

300 ms −1 accurate up to 0.001%, will be

(1) 5.76 10−2 m (2) 1.92 10−2 m (3) 3.84 10−2 m (4) 19.2 10−2 m
33. In which of the following arrangements the order is NOT according to the property
indicated against it?

(1) Al 3+  Mg 2+  Na+  F − − Increasing ionic size

(2) B  C  N  O − Increasing first ionization enthalpy

(3) I  Br  F  Cl − Increasing electron gain enthalpy

(4) Li  Na, K  Rb − Increasing metallic radius

34. A pair of compounds which cannot exist together in aqueous solution is
 (1) NaCl and NaHCO3 (2) NaCl and Na 2CO3
(3) NaHCO3 and Na 2CO3 (4) NaHCO3 and NaOH

35. Hydrolysis of XeF4 do not produce

(1) XeO3 (2) HF (3) O 3 (4) Xe
36. In which of the following arrangements, the sequence is not strictly according to the
property written against it?
(1) CO2 < SiO2 < SnO2 < PbO2 : increasing oxidising power
(2) HF <HCl<HBr< HI: increasing acid strength
(3) NH3 < PH3 < AsH3 < SbH3 : increasing basic strength
(4) H2O < H2S < H2Se < H2Te : increasing acidic strength
37. Oxidation state of Thallium in the compound TlI 3 is
(1) +1/3 (2) +1 (3) +3 (4) -3
38. The enthalpy of vaporization of water at 1000C is 40.63 kJ mol−1 . The value of E for
this process in kJ mol−1 is
(1) 37.53 (2) 39.08 (3)43.73 (4)40.63
39. Given

So heat of formation of carbon disulphide is

(1) 85 kJ (2) 125 kJ (3) 165 kJ (4) 205 kJ
40. One of the essential amino acid is
(1) lysine (2) glycine (3) serine (4) proline
41. The radii of Na + and Cl − ions are 95pm and 181 pm respectively. The edge length of
NaClunit cell is
(1)138 pm (2) 276 pm (3)415 pm (4) 552 pm
42. If ‘a’ stands for the edge length of the cubic systems: simple cubic , body centred cubic
 and face centredcubic , than the ratio of radii of the spheres in these systems will be
respectively :
1 1 1 3 2 1 3 1
(1) a : 3a : a (2) a: : a (3) a : 3a : 2a (4) a : a: a
2 2 2 2 2 2 4 2 2
43. At a given temperature solubility product of silver chloride is 10−10 at 298 K. The
solubility of AgCl in 0.01 MKCl in moles per dm3 is
1) 10−10 (2) 10−5 (3) 2 10−11 (4) 10−8
44. The final product in the sequence of reaction is

The structure of the product ‘D’would be:

(1) C6H5 NHOH (2) C6 H5 NHC2H5
(3) C6 H5CH 2OH (4) C6H5CH2 NH2
45. In which of the following compound manganese is amphoteric?
(1) MnO (2) Mn 2O3 (3) Mn 2O7 (4) All
46. Incorrect statement is
(1) Lanthanide contraction is due to electrons in f-orbital of penultimate shell
(2) Basic strength of lanthanides decreases from La ( OH )3 to Lu ( OH )3

(3) Atomic radii of Nb& Ta are almost same

(4) Actinides have more ability to form complexes over lanthanides.
47. The hydrogen electrode is dipped in a solution of pH=3 at 250C . It’s reduction potential
would be
(1) 0.177 V (2) -0.177 V (3) 0.3546 V (4) -0.3546 V
48. When a quantity of electricity is passed through CuSO4 solution, 0.16 g of copper gets
deposited. If the same quantity of electricity is passed through acidulated water, then the
volume of H 2 liberated at STP will be Given at Wt.Cu=64

(1) 56.75 cm3 (2) 4.0 cm3 (3) 8.0 cm3 (4) 604 cm3
49. For a first order reaction the time taken for 50% and 90 % completion are in the ratio of
(1) 1 : 1 (2) 1 : 2 (3) 3 : 10 (4) 5 : 9
50. The rate constants k1 and k 2 for two different reactions are 1016.e−2000/T and

1015.e−1000/T respectively. The temperature at which k1 = k 2 is:

2000 1000
(1) K (2)2000K (3) K (4)1000 K
2.303 2.303
51. Which is adsorbed minimum by activated charcoal under similar conditions
(1) H 2 (2) CO 2 (3) SO3 (4) CO
52. Consider the following aqueous solutions and assume 100% ionization of electrolytes
I) 0.1 m urea II) 0.04m Al2 (SO4 )3

III) 0.05 m CaCl2 IV) 0.005 m NaCl

The correct statement regarding the above solutions is
(1) Freezing point will be lowest for solution I
(2) Freezing point will be highest for solution IV
(3) Boiling point will be highest for solution III
(4) Vapour pressure will be highest for solution II
53. Henry’s Law constant for methane in benzene at 298K is 4.27 105 mm Hg . Calculate the
mole fraction of methane in benzene at 298K under 760mm Hg.
(1) 1.2 10−4 (2) 1.78 10−3 (3) 2 10−4 (4) 2.8 10−3
54. The electrolyte will have maximum flocculation value for Fe ( OH )3 sol. Obtained from

hydrolysis of FeCl3 is

(1) Na 2S (2) NaCl (3) K 2SO4 (4) ( NH4 )3 PO4

55. Mustard gas can be prepared by the reaction of ethylenewith

(1) SF6 (2) SF4 (3) S2Cl2 (4) SCl4
56. The reaction of Xe with an excess of F2 at high pressure and 573 K yields
(1) XeF2 (2) XeF4 (3) XeF6 (4) XeF3
57. What are X andY in the following reaction sequence
C2H5OH ⎯⎯
Cl2
⎯→ X ⎯⎯
Cl2
⎯→Y
(1) C2H5Cl,CH3CHO (2) CH3CHO,CH3CO2H
(3) CH3CHO,CCl3CHO (4) C2H5Cl,CCl3CHO
58. In a face centered cubic arrangement of A and B atoms whose A atoms are at the corner of
the unit cell and B atoms at the face centres. One of the A atom is missing from one corner
in unit cell. The simplest formula of compound is
(1) A7 B3 (2) AB3 (3) A7 B24 (4) A8 B21

59. Iodine is more soluble in aqueous solution of KI because it forms soluble

(1) KI (2) KI3 (3) KI4 (4) K 2 I2
60. Pyrimidine bases present in RNA are
(1)Adenine and guanine (2)Thymine and uracil
(3)Uracil and cytosine (4)Thymine and cytosine