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    Chem Exam

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    ngqktkjfty

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    Chem Exam

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    ngqktkjfty
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    Chem exam

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    Chem Exam

    Uploaded by

    ngqktkjfty

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    You are on page 1of 7

    Name: ________________________ Class: ___________________ Date: __________ ID: A

    Midterm 2 sample

    Constants and equations:


    Avogadro's number: NA = 6.0221×1023 mol-1
    log(10x) = x pH = -log[H+]
    Molarity M = mol / V mol = M × V
    percent yield = actual yield / theoretical yield × 100%

    Multiple Choice (5 pts each)


    Identify the choice that best completes the statement or answers the question.

    1. When propane undergoes complete combustion, the products are carbon dioxide and water.
    __ C3H8(g) + __ O2(g)  __ CO2(g) + __ H2O(g)
    What are the respective coefficients when the equation is balanced with the smallest whole numbers?
    a. 1, 1, 1, 1
    b. 1, 3, 1, 3
    c. 1, 3, 3, 1
    d. 1, 5, 3, 4
    e. 2, 5, 3, 4

    2. Which of the following statements is/are CORRECT?


    1. All ionic compounds that are soluble in water are electrolytes.
    2. All ionic compounds dissolve in water.
    3. Molecular compounds are never soluble in water.

    a. 1 only
    b. 2 only
    c. 3 only
    d. 1 and 2
    e. 2 and 3

    3. Which of the following compounds is a weak base?


    a. NaOH
    b. H2CO3
    c. NaCl
    d. NH3
    e. CH3CO2H

    2
    Name: ________________________ ID: A

    4. How many moles of sodium bromide can be produced from the reaction of 1.50 moles of sodium with 0.950 moles
    of bromine gas?
    2 Na(s) + Br2(g)  2 NaBr(s)
    a. 0.650 mol
    b. 1.08 mol
    c. 1.50 mol
    d. 2.06 mol
    e. 0.515 mol

    5. How many liters of 0.2207 M KCl(aq) contain 0.333 mol of KCl?


    a. 0.277 L
    b. 0.903 L
    c. 3.71  103 L
    d. 1.51 L
    e. 5.94  104 L

    6. If 25.00 mL of 1.50 M HCl(aq) is diluted with water to a volume of 250.0 mL, what is the molarity of the diluted
    HCl(aq)?
    a. 1.50  101 M
    b. 5.00  102 M
    c. 2.07  103 M
    d. 4.50  101 M
    e. 1.35  103 M

    7. A 25.00 mL sample of NaOH is titrated with 30.25 mL of 0.1250 M HCl(aq). What is the concentration of the
    NaOH solution?
    a. 1.995  104 M
    b. 0.09149 M
    c. 0.1830 M
    d. 0.1513 M
    e. 0.08945 M

    8. The reaction of tetraphosphorus decaoxide with water produces phosphoric acid.


    __ P4O10 + __ H2O  __ H3PO4
    What are the respective coefficients when the equation is balanced with the smallest integer values?
    a. 1, 1, 1
    b. 1, 3, 1
    c. 2, 4, 1
    d. 2, 6, 2
    e. 1, 6, 4

    9. All of the following compounds are insoluble in water except ____.


    a. BaCO3
    b. PbI2
    c. Fe(OH)3
    d. NH4Cl
    e. PbCl2

    2
    Name: ________________________ ID: A

    10. Write a balanced chemical equation for the reaction of aqueous solutions of sodium sulfide and zinc(II) chloride.
    a. Na2S(aq) + ZnCl2(aq)  ZnS(s) + 2 NaCl(aq)
    b. Na2S(aq) + ZnCl2(aq)  ZnS(s) + 2 NaCl(s)
    c. Na2S(aq) + ZnCl2(aq)  Na2Zn(s) + SCl2(aq)
    d. Na2S(aq) + ZnCl2(aq)  Na2Zn(aq) + SCl2(g)
    e. No reaction occurs.

    11. What are the spectator ions in the reaction between aqueous hydrobromic acid (HBr) and aqueous sodium
    hydroxide (NaOH)?
    a. Na+ only
    b. H+ and OH–
    c. Na+ and Br–
    d. Br– only
    e. H+, Br–, Na+, and OH–

    12. All of the following are oxidation-reduction reactions EXCEPT


    a. CaCO3(s)  CaO(s) + CO2(g)
    b. 2 Na(s) + Br2(g)  2 NaBr(g)
    c. Fe(s) + 2 HCl(aq)  FeCl2(aq) + H2(g)
    d. 2 C(s) + O2(g)  2 CO(g)
    e. 2 H2O(™ )  2 H2(g) + O2(g)

    13. Potassium (K) reacts with chlorine gas (Cl2) to produce potassium chloride (KCl). How many moles of K will react
    with 0.40 moles of Cl2?
    a. 0.20 mol
    b. 0.32 mol
    c. 0.40 mol
    d. 0.60 mol
    e. 0.80 mol

    14. What is the pH of 5.0  104 M HCl(aq)?


    a. –1.01
    b. 2.46
    c. 3.30
    d. 1.01
    e. 5.65

    15. Which of the following compounds are soluble in water: K2CO3, CaCO3, NiCO3, and Fe2(CO3)3?
    a. K2CO3 only
    b. K2CO3 and CaCO3
    c. CaCO3 and NiCO3
    d. NiCO3 and Fe2(CO3)3
    e. CaCO3, NiCO3, and Fe2(CO3)3

    3
    Name: ________________________ ID: A

    16. A precipitate will form when aqueous Pb(NO3)2 is added to an aqueous solution of ____.
    a. Cu(NO3)2
    b. NaI
    c. NaCH3CO2
    d. Pb(ClO4)2
    e. KNO3

    Written Answer (10 pts each)


    Equations and calculations must be shown to get full credit

    17. The net ionic equation for the reaction of calcium chloride (CaCl 2) and sodium carbonate (Na2CO3) is shown
    below.
    Ca2+(aq) + CO32–(aq)  CaCO3(s)

    (a) What are the spectator ions in this reaction? Hint: they are not involved in the reaction.

    (b) Write the full balanced euqation for this reaction with the () to indicate physical states.

    (c) What type of reaction is this?

    (d) If a mineral sample containing CaCl2 is mixed with Na2CO3 to produce 100. g CaCO3, how many grams of
    CaCl2 is in the sample?

    Blank

    4
    Name: ________________________ ID: A

    18. PCl3 can be produced from the reaction of P4 with Cl2.


    P4(s) + 6 Cl2(g)  4 PCl3(g)
    (a) If 124 g P4 reacts with 355 g Cl2, how many mol of each reactants?

    (b) How many mol of Cl2 should react with 124 g P 4? Which reactant is the limiting reactant? Explain your reason.

    (b) What mass of PCl3 can be produced?

    (c) If the actual yield is 411 g, what’s the percent yield?

    Blank

    19. Bonus question 10 pts


    A 1.7832 g sample of a hydrocarbon is combusted to give 1.2345 g of H 2O and 6.0353 g of CO 2.
    (a) How many mol of H and C are in this sample?

    (b) What’s the molar ratio between C and H? (Hint: use x:1 or 1:x to represent the ratio)

    (c) If the moles of this sample is determined to be 0.02286 mol, what is the molecular formula of the compound?

    Blank

    5
    ID: A

    Midterm 2 sample
    Answer Section

    MULTIPLE CHOICE

    1. ANS: D PTS: 1 TOP: 3.2 Balancing Chemical Equations


    2. ANS: A PTS: 1 TOP: 3.4 Aqueous Solution
    3. ANS: D PTS: 1 TOP: 3.6 Acids and Bases
    4. ANS: C PTS: 1
    TOP: 4.2 Reactions in which One Reactant is Present in Limited Supply
    5. ANS: D PTS: 1 TOP: 4.5 Measuring Concentrations of Compounds in Solution
    6. ANS: A PTS: 1 TOP: 4.5 Measuring Concentrations of Compounds in Solution
    7. ANS: D PTS: 1 TOP: 4.7 Stoichiometry of Reactions in Aqueous Solution
    8. ANS: E PTS: 1 TOP: 3.2 Balancing Chemical Equations
    9. ANS: D PTS: 1 TOP: 3.4 Aqueous Solution
    10. ANS: A PTS: 1 TOP: 3.5 Precipitation Reactions
    11. ANS: C PTS: 1 TOP: 3.6 Acids and Bases
    12. ANS: A PTS: 1 TOP: 3.9 Classifying Reactions in Aqueous Solution
    13. ANS: E PTS: 1 TOP: 4.1 Mass Relationships in Chemical Reactions: Stoichiometry
    14. ANS: C PTS: 1 TOP: 4.6 pH, A Concentration Scale for Acids and Bases
    15. ANS: A PTS: 1 TOP: 3.4 Aqueous Solution
    16. ANS: B PTS: 1 TOP: 3.5 Precipitation Reactions

    SHORT ANSWER

    17. ANS:
    (a) Chloride and sodium ions
    (b) CaCl2(aq)+ Na2CO3(aq) CaCO3(s) + 2NaCl(aq)
    (c) precipitation
    (d) 111. g

    PTS: 1
    18. ANS:
    1 mol P4 and 5 mol Cl2
    Chlorine is the limiting reactant
    5 mol Cl2 * 4 mol PCl3/6mol Cl2 * (31+35.5*3)g/mol = 458 g PCl 3 may be produced.
    411/458 = 89.7%

    PTS: 1

    1
    ID: A

    19. ANS:
    mol H = 1.2345g/18g/mol*2 = 0.13717 mol H
    mol C = 6.0353g/44g/mol*1 = 0.13717 mol C
    C:H= 1:1
    Molar mass = 1.7832g/0.02286mol=78.00g/mol
    (CH)n : n=78g/mol/(12+1)g/mol = 6
    C6H6

    PTS: 1

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