Propane Gas MSDS

MATERIAL SAFETY DATA SHEET
1. Identification of the Substance/ Preparation and of the Company

Product Name: Propane Gas
Chemical Formula: Petroleum distillate, C3H8
2. Composition/ Information on Ingredients

Substance/ Preparation: Preparation
Components/ Impurities: Liquefied Propane Gas consisting of C3 Hydrocarbons (propane) with
typically <60ppm of ethyl mercaptan or other similar odorizing agent added to assist leak
detection.
Hazardous Components: Hydrocarbon C3-4 rich
3. Hazard Identification
• Extremely flammable (F+).
• Readily forms an explosive air-vapor mixture at ambient temperatures.
• Vapor is heavier than air and may travel to remote sources of ignition (e.g. along drainage
Systems, into basements etc)
• Liquid leaks generate large volumes of flammable vapor (approx 250:1)
• Cold burns (frostbite) will result from skin / eye contact with liquid.
• Liquid release or vapor pressure jets present a risk of serious damage to the eyes.
• Abuse involving willful inhalation of high concentrations of vapor, even for short periods, can
produce unconsciousness, or might prove fatal. Inhalation may cause irritation to the nose and
throat, headache, nausea, vomiting, dizziness and drowsiness.
In poorly ventilated areas unconsciousness or asphyxiation may result.
4. First Aid Measures

Inhalation:
Remove the affected person to fresh air. If breathing has stopped, administer artificial
respiration. Give external cardiac massage if necessary. If the person is breathing but
unconscious, place them in the recovery position. Obtain medical assistance immediately.
Skin:
In case of cold burns: flush with water to normalize temperature. Cover the burns with sterile
dressings. Do not use ointments or powders. Obtain medical assistance immediately.
Eyes: Cold burns should be flushed with water to normalize temperature, cover the eye with a
Sterile dressing and obtain medical assistance immediately.
Ingestion: Not applicable.
5. Fire Fighting Measures
These materials are delivered, stored, and used at temperatures above their flash point. Avoid
all naked flames, sparks, cigarettes etc.
• IN CASE OF FIRE IMMEDIATELY ALERT THE FIRE BRIGADE.
• Ensure an escape path is always available from any fire.
• If gas has ignited do not attempt to extinguish but stop gas flow and allow burning out.
Use water spray to cool heat-exposed containers, and to protect surrounding areas and
personnel effecting the shut off. Every precaution must be taken to keep containers cool to
avoid the possibility of a boiling liquid expanding vapor explosion (BLEVE)
Extinguishing Media:
• Large fire: none. Product flow must be stopped and container cooled by water spray. Water
fog should be used to assist approach to the source of the fire. Large fires should only be fought
by the Fire Brigade.
DO NOT USE WATER JET.
Small fire:
• Dry Powder
• DO NOT USE WATER OR FOAM
Special Protective Equipment for Fire Fighters:
In confined spaces use self-contained breathing apparatus
Hazardous Combustion Products:
Incomplete combustion may form carbon monoxide.
6. Accidental Release Measures
IMMEDIATE EMERGENCY ACTION:

• Clear people away from the area to a safe place.
• Do not operate electrical equipment unless flameproof;
• Summon the emergency services;
• Treat or refer casualties if necessary.
FURTHER ACTION-FIRE.
• Stop Product flow;
• Use dry powder or carbon dioxide extinguishers;
• Cool containers exposed to fire by using water / fog spray.
FURTHER ACTION – SPILLAGE
If Safe:
• Extinguish all naked lights –AVOID MAKINGSPARKS
• Position firefighting equipment;
• Try to stop flow of liquid product;
• Cover drains and disperse vapor with water spray. Note: vapor may collect in confined spaces.
7. Handling and Storage Handling:

Refer to NFPA Storage and Handling instructions.
• Cylinders must be stored and used in the vertical position.
Storage:
Store out of doors in a well ventilated storeroom.
Segregate from oxidant gases or other flammable materials in store.
Keep away from ignition sources.
8. Physical and Chemical Properties

Appearance/ Color: Colorless liquid/ gas.
Odor: Odorless /odorant added to provide a distinctive smell.
Boiling Point: -42.1ºC
Flash Point -104ºC (PMCC)
Flammability Limited: 2.3% – 9.4 % in air
Auto Flammability: 460 - 580°C
Vapor Pressure: 4 bar at 15°C
Specific gravity (Liquid): 0.558
9. Toxicological Information
Eye Contact:
Contact with liquid Propane gas will present a risk of serious damage to the eyes.
Skin Contact;
Contact with liquid propane gas will cause cold burns and frostbite to the skin.
Inhalation:
Low vapor concentrations may cause nausea, dizziness headaches and drowsiness. May
have a narcotic effect if high concentrations of vapor are inhaled, they may produce symptoms
of Oxygen deficiency, which, coupled with central nervous system depression, may lead to
rapid loss of consciousness.
Abuse:
Under normal conditions of use the product is not hazardous; however, abuse involving
deliberate inhalation of very high concentrations of vapor, even for short periods can produce
unconsciousness and/or result in a sudden fatality.
10. Transport Information
Proper Shipping Name : PROPANE GAS, LIQUIFIED

UN-NO. : 1978
CLASS : 2.1
ENERGAS GENERAL SAFETY AND HANDLING DATA

1. GENERAL
Only trained persons should handle compressed gases. Observe all regulations and local requirements regarding the
storage of containers. Ascertain the identity of the gas before using it. Know and understand the properties and
hazards associated with each gas before using it. When doubt exists as to the correct handling procedure for a
particular gas contact the supplier.
2. HANDLING AND USE

Wear stout gloves. Never lift a container by the cap or guard unless the supplier states it is designed for that purpose.
Use a trolley or other suitable device or technique for transporting heavy containers, even for a short distance. Where
necessary wear suitable eye and face protection. The choice between safety glasses, chemical goggles, or full-face
shield will depend on the pressure and nature of the gas being used. Where necessary for toxic gases see that self-
contained positive pressure breathing apparatus or full face air line respirator is available in the vicinity of the working
area. Employ suitable pressure regulating devices on all containers when the gas is being emitted to systems with a
lower pressure rating than that of the container. Assertion that all electrical systems in the area are suitable for service
with each gas. Never use direct flame or electrical heating devices to raise the pressure of a container. Containers
should not be subjected to temperatures above 45°C. Never re-compress a gas mixture without
Consulting the supplier. Never attempt to transfer gases from one container to another. Do not use containers as
rollers or supports, or for any other purpose than to contain the gas as supplied. Never permit oil, grease or other
Readily combustible substances to come into contact with valves of containers containing oxygen or other oxidants.
Keep container valve outlets clean and free from contaminants, particularly oil and water. Do not subject containers to
abnormal mechanical shocks, which may cause damage to their valves or safety devices. Never attempt to repair or
modify container valves or safety relief devices. Damaged valves should be reported immediately to the supplier.
Close the container valve whenever gas is not required even if the container is still connected to the equipment.
3 .STORAGE
Containers should be stored in a well-ventilated area. Some gases will require a purpose built area. Store containers
In a location free from fire risk and away from sources of heat and ignition. Designation as a no smoking area may be
desirable. Gas containers should be segregated in the storage area according to the various categories. The storage
area should be kept clear and access should be restricted to authorized persons only, the area should be clearly
marked as a storage area and appropriate hazard warning signs displayed (Flammable Toxic etc,).
The amount of flammable or toxic gases should be kept to a minimum. Flammable gases should be stored away from
other combustible materials. Containers held in storage should be periodically checked for general condition and
leakage. Containers in storage should be properly secured to prevent toppling or rolling. Vertical storage is
recommended where the container is designed for this. Container valves should be tightly closed and where
Appropriate, valve outlets should be capped or plugged. Protect containers stored in the open against rusting and
extremes of weather. Containers should not be stored in conditions likely to encourage corrosion. Store full and
empty containers separately and arrange full containers so that the oldest stock is used first.
PRODUCTION SITE ADDRESS

UNITED GAS COMPANY –
UNIGAS, Sharjah, United Arab
Emirates Tel: +9716
5360012/13
Fax: +9716 5360014
www.unigastt.com

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MATERIAL SAFETY DATA SHEET

1. Identification of the Substance/ Preparation and of the Company

2. Composition/ Information on Ingredients

4. First Aid Measures

6. Accidental Release Measures

IMMEDIATE EMERGENCY ACTION:

7. Handling and Storage Handling:

8. Physical and Chemical Properties

Proper Shipping Name : PROPANE GAS, LIQUIFIED

ENERGAS GENERAL SAFETY AND HANDLING DATA

2. HANDLING AND USE

PRODUCTION SITE ADDRESS

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