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    Model Exam SD3

    Uploaded by

    Booma Jegaraja

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    © All Rights Reserved
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    Model Exam SD3

    Uploaded by

    Booma Jegaraja
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    13 views2 pages

    Model Exam SD3

    Uploaded by

    Booma Jegaraja

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 2

    SIR SIVASWAMI BALAVIDHYALAYA MATRIC HR.

    SEC SCHOOL, THIRUKATTUPALLI


    CLASS XII
    MODEL EXAM - CHEMISTRY
    TIME : 2.30 HRS MARKS : 70
    PART I
    Choose the correct answers: 15 x 1 = 15
    1. Which of the following is used in cryosurgery?
    a) Liquid N2 b) NH3 c) Liquid CO2 d) CO2
    2. The shape of Ozone molecule is
    a) Linear b) Trigonal c) Bent shaped d) Pyramidal
    3. Which of the following is Prismatic Sulphur?
    a) Rhombic Sulphur b) Colloidal Sulphur c) Plastic Sulphur d) Monoclinic Sulphur
    4. Which transition metal is present in Ziegler Natta catalyst?
    a) Sc b) Ti c) V d) Cr
    5. The actinoid elements which show the highest oxidation state of +7 are
    a) Np, Pu, Am b) U, Fm, Th c) U, Th, Md d) Es, No, Or
    6. Which of the following contain transition metal?
    a) Vitamins b) Proteins c) Lipids d) Enzymes
    7. Which of these is not likely to act as Lewis base?
    a) BF3 b) PF3 c) CO d) F-
    8. With increase in temperature, ionic product of water
    a) increases b) decreases c) no change d) none of these
    9. When the solution is in equilibrium and saturated
    a) ionic product = Ksp b) ionic product < Ksp
    c) ionic product > Ksp d) all the above
    10. According to 2nd law of thermodynamics, the maximum work done by the system is equal to
    a) Gibb’s free energy change b) internal energy
    c) average Kinetic energy d) Entrophy change
    11. A solution of salt of metal was electrolysed for 15 minutes with a current of 0.15 A. The
    electrochemical equivalent of the metal is 5.8 x 10-3. Mass of the metal deposited in gms at Cathode is
    a) 0.783 b) 0.873 c) 0.387 d) 0.378
    12. Limiting molar conductance is the basis for which of the following law?
    a) Ostwald’s dilution law b) Electrochemical series
    c) Kohlrausch law d) Faraday’s law
    13. In which of the following reactions new carbon-carbon bond is not formed?
    a) Aldol Condensation b) Friedel – Craft reaction
    c) Kolbes reaction d) Wolf Kishner reaction
    14. Ozonolysis of but-3-ene gives
    a) Ethanal b) Propanal c) Proponol d) Methanal
    15. Which of the following carboxylic acid has both -CHO and -COOH group?
    a) Formic acid b) acetic acid c) Oxalic acid d) Adipic acid

    PART II
    Answer any six of the following questions 6 x 2 = 12
    Question no:24 is compulsory
    16. Draw the structure of Sulphur di oxide and write the hybridization.
    17. Why do transition metals form complexes?
    18. Give any two uses of Krypton.
    19. Why Gd3+ and Lu3+ have extra stability?
    20. Write applications of Kohlrausch law.
    21. Explain Arrhenius concept of acids and bases with example.
    22. How will you convert ethyne into ethanol?
    23. Give any two tests for carboxylic acids.
    24. What is aldimine? How is it prepared?

    PART III
    Answer any six of the following questions 6 x 3 = 18
    Question no:31 is compulsory
    25. Explain the bleaching action of Chlorine.
    26. How does Phosphorous react with concentrated Nitric acid?
    27. Why first ionization enthalpy of Chromium is lower than that of Zinc?
    28. Write the electronic configuration of Ce4+ and Yb2+
    29. Write the three types of buffet solution and give example for each.
    30. What is specific conductance? Give its expression and Unit
    31. How will you prepare malachite green from benzaldehyde?
    32. Explain Clemmensen reduction.
    33. Explain Etard reaction with equation.

    PART IV
    Answer the following questions 5 x 5 = 25
    34. a) (i) Give two similar properties of NH3 and H2O.
    (ii) Draw the structure of Caro’s acid and Marshall’s acid.
    (or)
    b) (i) Write the differences between Lanthanoids and actinoids.
    (ii) Which is more stable Fe2+ or Fe3+. Explain.

    35. a) (i) At a particular temperature, the Kw of a neutral solution was equal to 4 x 10-14. Calculate the
    concentration of [H3O+] and [OH-]
    (ii) Explain Lewis concept of acids and bases with examples.
    (or)
    b) (i) Write the balanced equation from the association of the following in water and identify the
    conjugate acid base pairs. i) 𝑁𝐻4+ ii) CH3COOH
    (ii) Why does conductance increases with increase in temperature?

    36. a) (i) Explain standard hydrogen electrode.


    (ii) Explain Knoevenagal reaction
    (or)
    b) (i) Write the IUPAC names for
    1. HOOC(CH2)3COOH
    2. (CH3)2C=CHCOCH3
    3. CH2-CH=CH-CHO
    (ii) What is glacial acetic acid? How is it obtained?

    37. a) (i) Explain the reducing action of formic acid.


    (ii) What is electrochemical equivalent?
    (or)
    b) (i) Calculate the pH of 1.5 x 10-3 M solution of Ba(OH)2
    (ii) Write the properties of interhalogen compounds.

    38. a) (i) Complete the reaction:


    ∆
    1. 𝐾𝐶𝑙𝑂3 →
    2. 𝑋𝑒𝐹6 + 𝐻2 𝑂 →
    (ii) What are inner transition elements? Give example.
    (or)
    b) (i) Write the mechanism of Cannizaro reaction.
    (ii) Write and state the rule that governs the oxidation of Unsymmetrical ketones.

    -------ALL THE BEST-------

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