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    CHE 400 Nov. 19 2021

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    parajasirene

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    CHE 400 Nov. 19 2021

    Uploaded by

    parajasirene
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    CHE-400-Nov.-19-2021

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    4 views2 pages

    CHE 400 Nov. 19 2021

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    parajasirene

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    CHE 400 (7-10/F) Nov.

    19, 2021

    Problem Solving

    1.What volume of 0.0105-M HBr solution is required to titrate 125 mL of a 0.0100-


    M Ca(OH)2 solution?

    Ca(OH)2(aq)+2HBr(aq)⟶CaBr2(aq)+2H2O(l)

    2.Titration of a 20.0-mL sample of acid rain required 1.7 mL of 0.0811 M NaOH to reach the end
    point. If we assume that the acidity of the rain is due to the presence of sulfuric acid, what was
    the concentration of sulfuric acid in this sample of rain?

    3.What is the concentration of NaCl in a solution if titration of 15.00 mL of the solution with
    0.2503 M AgNO3 requires 20.22 mL of the AgNO3 solution to reach the end point?

    AgNO3(aq)+NaCl(aq)⟶AgCl(s)+NaNO3(aq)

    4.In a common medical laboratory determination of the concentration of free chloride ion in blood
    serum, a serum sample is titrated with a Hg(NO 3)2 solution.

    2Cl−(aq)+Hg(NO3)2(aq)⟶2NO3−(aq)+HgCl2(s)

    What is the Cl− concentration in a 0.25-mL sample of normal serum that requires 1.46 mL of 8.25
    × 10−4M Hg(NO3)2(aq) to reach the end point?

    5.Potatoes can be peeled commercially by soaking them in a 3-M to 6-M solution of sodium
    hydroxide, then removing the loosened skins by spraying them with water. Does a sodium
    hydroxide solution have a suitable concentration if titration of 12.00 mL of the solution requires
    30.6 mL of 1.65 M HCl to reach the end point?

    6.A sample of gallium bromide, GaBr 2, weighing 0.165 g was dissolved in water and treated with
    silver nitrate, AgNO3, resulting in the precipitation of 0.299 g AgBr. Use these data to compute
    the %Ga (by mass) GaBr2.
    7.The principal component of mothballs is naphthalene, a compound with a molecular mass of about
    130 amu, containing only carbon and hydrogen. A 3.000-mg sample of naphthalene burns to give
    10.3 mg of CO2. Determine its empirical and molecular formulas.

    8.A 0.025-g sample of a compound composed of boron and hydrogen, with a molecular mass of ~28
    amu, burns spontaneously when exposed to air, producing 0.063 g of B 2O3. What are the
    empirical and molecular formulas of the compound?

    9.Sodium bicarbonate (baking soda), NaHCO3, can be purified by dissolving it in hot water (60 °C),
    filtering to remove insoluble impurities, cooling to 0 °C to precipitate solid NaHCO 3, and then
    filtering to remove the solid, leaving soluble impurities in solution. Any NaHCO 3 that remains in
    solution is not recovered. The solubility of NaHCO 3 in hot water of 60 °C is 164 g/L. Its solubility
    in cold water of 0 °C is 69 g/L. What is the percent yield of NaHCO 3 when it is purified by this
    method?

    10. What volume of 0.600 M HCl is required to react completely with 2.50 g of sodium hydrogen
    carbonate?
    NaHCO3(aq)+HCl(aq)⟶NaCl(aq)+CO2(g)+H2O(l)

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