Chemistry

NEET BHATI CHEM ACADEMY 12th

“Enhance Your Chemistry”
JEE (MAINS + ADVANCE), NEET(Medical Entrance), GUJCET

Date: 16/06/2024 Marks: 180 Time: 1 HR

Name of the student: ____________________________ Obt. Marks = _______ / 180

No. of correct answers = _____ (4) = ______ No. of wrong answers = _____ (-1) =______

OMR
Q Response Q Response Q Response Q Response Q Response

1. 2. 3. 4. 5.

6. 7. 8. 9. 10.

11. 12. 13. 14. 15.

16. 17. 18. 19. 20.

21. 22. 23. 24. 25.

26. 27. 28. 29. 30.

31. 32. 33. 34. 35.

(Question 36-50 Attempt any 10)

Q Response Q Response Q Response Q Response Q Response

36. 37. 38. 39. 40.

41. 42. 43. 44. 45.

46. 47. 48. 49. 50.

Gunvant singh bhati

 Chemistry

Gunvant singh bhati

 Chemistry

NEET BHATI CHEM ACADEMY 12th

“Enhance Your Chemistry”
JEE (MAINS + ADVANCE), NEET(Medical Entrance), GUJCET

Date: 16/06/2024 Marks: 180 Time: 1 HR

Name of the student: ____________________________ Obt. Marks = _______ / 180

No. of correct answers = _____ (4) = ______ No. of wrong answers = _____ (-1) =______

1.

2.

3.

4. Assertion : The reaction,


C12 H 22O11  H 2O 
H
 C6 H12O6  C6 H12O6 is a first order reaction.
Reason : Change in concentration of H20 is negligible.
(A)If both assertion and reason are true and reason is the correct explanation of assertion.
(B)If both assertion and reason are true but reason is not the correct explanation of assertion.
(C)If assertion is true but reason is false.
(D)If both assertion and reason are false.
Gunvant singh bhati
 Chemistry
5. Following mechanism has been proposed for a reaction 2A + B  D + E
A + B C + d …..(slow) A + C E …..(fast)
The rate law expression for the reaction is -
(A)r = k[A]2 [B] (B)r = k[A] [B] (C)r = k[A]2 (D)r = k[A][C
d[A]
6. In reaction, A + 2B → C + 2D, then initial rate - at t=0, was found to be 2.6 x 10-2 M s-1. What is
dt
d[B]
the value of - at t=0 ?
dt
(A)2.6 x 10-2 (B)5.2 x 10-2 (C)1.0 x 10-1 (D)6.5 x 10-3
7. In the formation of sulphur trioxide by the contact process 2SO2(g)  2SO3(g); the rate of reaction
d[O 2 ]
is expressed as - =2.5 x 10-4 mol L-1 s-1
dt
The rate of disappearance of (SO2) will be
(A)5 x 10-4 mol L-1 s-1 (B)-2.25 x 10-4 mol L-1 s-1
-4 -1 -1
(C)3.75 x 10 mol L s (D)50.0 x 10-4 mol L-1 s-1
8. For a reaction of the type A+B  products, it is observed that doubling the concentration of A causes
the reaction rate to be four times as great, but doubling the amount of B does not effect the rate.
The equation is -
(A) Rate = k[A][B] (B) Rate = k[A]2
2
(C) Rate = k[A] [B] (D) Rate = k[A]2[B]2
9. An endothermic reaction A  B have an activation energy 15 k cal/mol and the heat of the reaction
is 5 k cal/mol. The activation energy of the reaction B  A is -
(A)20 k cal/mol (B)15 k cal/mol (C)10 k cal/mol (D)zero
10. Which of the following plot is in accordance with the Arrhenius equation :-

11. The hypothetical reaction A2 + B2  2AB follows the mechanism as given below -
A2  A + A ………(fast)
A + B2  AB + B……….(slow)
A + B  AB……..(fast)
The order of the over all reaction is-
1
(A)2 (B)1 (C) 1 (D)zero
2
1
12. For the reaction A + B  products, it is found that the order of A is 1 and the order of B is when
2
the conc. Of both A and B are increased four time, the rate will increase by a factor of :-
(A)16 (B)8 (C)6 (D)4
13. The half life period for catalytic decomposition of AB, at 50 mm is found to be 4 hrs and at 100 mm
it is 2 hrs. The order of reaction is -
(A)3 (B)1 (C)2 (D)0

14. The hydrolysis of ethyl acetate CH3COOEt + H2O  CH3COOH + EtOHis a reaction of
H

(A)First order (B)Second order (C)Third order (D)Zero order

15. If 75% of a first order reaction is complete in 8 min, then time taken to decompose 50% of its
initial amount is
(A)2 min (B)4 min (C)12 min (D)1 min
16. The time taken for 90% of a first order reaction to complete is approximately
(A) 1.1 times that of half-life (B) 2.2 times that of half-life
(C) 3.3 times that of half-life (D) 4.4 times that of half-life
17. An endothermic reaction A  B has an activation energy of 15 kcal/mole and energy of reaction 5
kcal/mole. The activation energy of the reaction B  A is
(A)20 kcal/mole (B)15 kcal/mole (C)10 kcal/mole (D)None
18.The rate constant for a first order reaction whose half-life is 480 sec. is
(A)2.88  10-3 s-1 (B)1.44  10-3 sec-1 (C)1.44 sec-1 (D)0.72  10-3 sec-1
19. The temperature dependence of rate constant (k) of a chemical reaction is written in terms of
Arrhenius equation, k=Ae-E*/RT. Activation energy (E*) of the reaction can be calculated by plotting
1 1 1
(A) k vs (B) log k vs (C) log k vs (D)k vs T
log T log T T

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 Chemistry
20. The correct order indicated against the rate of reaction A + B 
k
 C is
d [C] d [C] d [ A] d [ A]
(A)  k[A] (B)   k[A][B] (C)   k[A][B] (D)   k[A]
dt dt dt dt
21. The differential rate law for the reaction, H2 + I2  2HI is:
d [H2 ] d[ I 2 ] d [HI] d H2 d [ I 2 ] d [HI]
(A)   (B)  
dt dt dt dt dt dt
1 d [H2 ] 1 d [ I 2 ] d [HI] d [H2 ] d [ I 2 ] d [HI]
(C)   (D) 2  2 
2 dt 2 dt dt dt dt dt
22. Rate of a first order reaction is 1.5 x 10-2 mol L-1 min-1 at 0.5 M concentration of reactant. Half-life
of the reaction is
(A)7.53 min (B)0.383 min (C)23.1 min (D)8.73 min
23. What happens when the temperature of a soluti increased from 25°C to 65°C?
(A)The rate of the reaction remains unchanged and the rate constant k decreases.
(B)The rate of the reaction increases and rate constant k decreases.
(C)The rate of the reaction decreases and so does the rate constant k.
(D)The rate of the reaction increases and so does the rate constant k.
24. The rate constant is given by the equation K=P.Ze-E/RT. Which factor should register a decrease for
the reaction to proceed more rapidly ?
(A)T (B)Z (C)E (D)P
25. The rate of certain hypothetical reaction A+B+C  product is given by
-d[A]
r= =K[A]1/2 [B]1/3 [C]1/4 the order of the reaction -
dt
1 13
(A)1 (B) (C)2 (D)
2 12
26. Select the law that corresponds to data shown for the following reaction 2A + B  C+D–
Exp. [A] [B] Initial rate
(mol L-1 min-1)
1. 0.1 0.1 7.5x10-3
2. 0.3 0.2 9.0x10-2
3. 0.3 0.4 3.6x10-1
4. 0.4 0.1 3.0x10-2

(A) Rate = k[A]2[B] (B) Rate = k[A][B]2

3
(C) Rate = k[A][B] (D) Rate = k[A][B]
27. Which plots will give the value of activation energy.
(A)K vs T (B)1/K vs T (C)In K vs T (D)In K vs 1/T
28. Which of the following statement is correct for a reaction X + 2Y  product
(A)The rate of disappearance of X = twice the rate of disappearance of Y
(B)The rate of disappearance of X = ½ rate of appearance of product
(C)The rate of appearance of products = ½ the rate of disappearance of Y
(D)The rate of appearance of products = ½ the rate of disappearance of X
29. Which of the following rate law has an overall order of 0.5 for reaction involving substances x, y & z?
(A)Rate = K(Cx) (Cy) (Cz) (B)Rate = K (Cx)0.5 (Cy)0.5(Cz)0.5
1.5 -1 0
(C)Rate = K (Cx) (Cy) (Cz) (D)Rate = K (Cx)(Cz)0 / (Cy)2
30. For the reaction H2(g) + Br2(g)  2HBr(g), the experimental data suggests, Rate = K[H 2] [Br2]1/2
The order for this reaction is -
1 1
(A)2 (B) 1 (C)1 (D) 2
2 2
31. In the sequence of reaction A  k1
 B  C  D ; K3>K2>K1, then the rate determining step of
k2 k3

the reaction is:-

(A)A  B (B) C  D (C) B  C (D) A  D
32. Activation energy of a reaction is -
(A)The energy released during the reaction
(B)The energy evolved when activated complex is formed
(C)Minimum extra amount of energy needed to overcome the potential barrier of reaction
(D)The energy needed to from one mole of the product
33. The rate constant of a reaction depends on
(A)Temperature (B)Pressure
(C)Extent of reaction (D)Initial concentration of the reactant

Gunvant singh bhati

 Chemistry
34. In a reaction 2A + B  A2B, the reactant A will disappear at
(A)Half the rate at that B will decrease (B)The same rate at that B will decrease
(C)The same rate at that A2B will form (D)Twice the rate at that B will decrease
35. Rate of first order reaction depends upon
(A)Time (B)Concentration of reactant (C)Temperature (D)All the three
36. Order of reaction is decided by
(A)Temperature (B)Mechanism of reaction as well as relative concentration of reactant
(C)Molecularity (D)Pressure
37. For a zero order reaction
(A)The reaction rate is double when the initial concentration is doubled
(B)The time for half change is half the time taken for completion of the reaction
(C)The time for half change is independent of the initial concentration
(D)The time for completion of the reaction is independent of the initial concentration

38. The hydrolysis of ethyl acetate CH3COOEt + H2O  H
CH3COOH + EtOHis a reaction of
(A)First order (B)Second order (C)Third order (D)Zero order
39. Units of rate constant for first and zero order reactions in terms of molarity (M) unit are
respectively
(A)sec-1, M sec-1 (B)sec-1, M (C)Msec-1, sec-1 (D)M, sec-1
40. The temperature coefficient of most of the reactions lies between
(A)1 and 3 (B)2 and 3 (C)1 and 4 (D)2 and 4
41. Molecularity of reaction and which values are not real of reaction order?
(A)4, 0 (B)1.5, 8 (C)2, 1.5 (D)3, -0.5
42. Rate constant is K=p.ze-E/RT than which factor is decrease than reaction is decreasing?
(A)E (B)T (C)Z (D)R
1 3
43. X + 2Y  2Z rate is K [X]2 [Y]2 . If we increase four times of concentration of X and increase double of
concentration of Y. Which effect occurs?
(A)4.5 times increases (B)5.64 times increases (C)4 times increases (D)2.82 times increases
44. 99% of a first order reaction was completed in 32 min. When will 99.9% of the reaction complete?
(A)50 min (B)46 min (C)49 min (D)48 min
45. If a reaction A + B  C is exothermic to the extent of 30 kJ/mol and the forward reaction has an
activation energy of 70 kJ/mol, the activation energy for the reverse reaction is
(A)30 kJ/mol (B)40 kJ/mol (C)70 kJ/mol (D)100 kJ/mol
46. The activation energy of a reaction is 9 kcal/mole. The increase in the rate constant when its
temperature is raised from 295 to 300 K is approximately
(A)10% (B)50% (C)100% (D)25%
47. The rate constants k1and k2for two different reactions are 1016. e-2000/T and 1015 e-1000/T respectively. The
temperature at which K1 = k2is
(A)1000 K (B)2000/2.303 K (C)2000 K (D)1000/2.303 K
48. A human body required the 0.01  activity of radioactive substance after 24 hours. Half life of
radioactive is 6 hours. Then injection of max. activity of radioactive substance that can be injected:
(A)0.08 (B)0.04 (C)0.16 (D)0.32
49. If the rate of the reaction is equal to the rate constant, the order of the reaction is:-
(A)0 (B)1 (C)2 (D)3
50. The radioisotope, tritium ( 13 H ) has a half-life of 12.3 years. If the initial amount of tritium is 32 mg, how
many milligrams of it would remain after 49.2 years
(A)1 mg ` (B)2 mg (C)4 mg (D)8 mg

Gunvant singh bhati