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Introduction

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INTRODUCTION:

Dyes are coloured substances which can adhere to the surface of materials and
are used to give colour to paper, foodstuffs and various textiles such as cotton ,
wool , synthetic fibres , silk etc.
For example: alizarin, indigo, congo red, etc.
Chemically a dye contains:
Some group (such as azo, indigoid ,triphenylmethyl ,anthraquinone , etc.)
which is responsible for the colour of the dye.
Some groups (such as –NH2 , -SO3H , -COOH ,etc ) which makes the dye
stick to the fabric by formation of some salt.

Dyeing is the process of adding colour to textile products like fibres, yarn and
fabrics. The temperature and time controlling are two key factors in dyeing.
The primary source of dye, historically has been nature , with the dyes being
extracted from plants and animals. Since the 18 thcentury, humans produced artificial
dyes to achieve a broader range of colours and to render the dyes more stable to
resist washing and general use.
The dyed fabrics appear to be coloured because a particular dye absorbs
radiations of some specific wavelengths from the visible region of electromagnetic
radiations which fall on the surface. The remaining radiations(complementary
colours ) of light are reflected. The colour which we observe is due to the reflected
light. For example: If a dye absorbs the light in the wavelength region
corresponding to red , then it would appear green , which is the complementary
colour to red. Similarly , if a dye absorbs blue colour , it would appear orange.
METHODS TO APPLY DYE:
Dyes are applied to textile goods by dyeing from dye solutions and by printing
from dye pastes. Methods include:
1.Direct application
2.Yarn dyeing

CHARACTERISTICS OF A DYE:
1.It must have a suitable colour.
2.It must be capable of being fixed to the material.
3.When fixed it must be fast to detergents, soaps, water , dry cleaning
solvents ,light and dilute acids.

TYPES OF DYE:
The dyes are classified by dye manufacturers for marketing into the following
types :

1. Acid dyes :These are azo dyes and are characterized by the presence of
acidic groups. The presence of soluble and serves as the reactive points for fixing
the dye to the fibre. They are briefly used for dyeing wool ,silk and nylon. For
example : Orange I and Orange II.

2.Basic dyes :These dyes contain NH2 or NR2 . In acidic solutions, these
form water soluble cations and use the anionic sites on the fabric to get used for
dyeing wool ,silk and nylon. For example : aniline yellow , butter yellow.

3.Direct dyes :These are also azo dyes and are used to dye fabrics directly by
placing in aqueous solution of the dye. These dyes attach to the fabrics by means of
hydrogen bonding.
4.Disperse dyes :These dyes are applied in the form of dispersion of minute
particles of the dye in a soap solution in the presence of phenol or benzoic acid .
These dyes are used to dye rayons, Dacron ,nylon , polyesters etc. For
example :Celliton fast pink B and celliton fast blue B.

5.Fibre reactive dyes :These dyes are linked to the fibre by –OH or –NH
group present on the fibre. These dyes induce fast colour on fabrics which is
retained for a longer time. These dyes are used for dyeing cotton ,wool and silk.

PROCEDURE:
4.Preparation of dye solution: Take about a 0.1g of malachite green dye and
add to it 400 ml of water. On warming a clear solution of the dye results.

5.Dyeing of wool:

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