CTA-09&17 Q.Paper

Sri Chaitanya IIT Academy.,India.
 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS & STERLING_BT Paper -2(Adv-2022-P2-Model) Date: 17-11-2024
Time: 02.00Pm to 05.00Pm CTA-09/17 Max. Marks: 180
17-11-2024_Sr.Super60_NUCLEUS & STERLING_BT _
Jee-Adv (2022-P2)_CTA-09/17_Syllabus
PHYSICS : Thermal physics, Heat Transfer, Ray Optics, Geometrical Optics, Experiments, Wave Optics,
Gravitation, Electrostatics, Gauss law, Capacitors & Current Electricity, Magnetism, EMI, Alternating
Current, X-rays, Nuclear Physics, General Physics, Kinematics, NLM, Friction, Circular motion, WPE, COM
& Collisions, Rigid body Dynamics-1, Rigid body Dynamics-2, Fluid statics & Dynamics
CHEMISTRY : Nomenclature, Isomerism, GOC, Alkanes, Alkene & Alkyne, Benzene, Alkyl Halides & Aryl Halides,
Alcohols, Phenols , Ethers, Alcohols, Phenols, Ethers, Aldehydes & Ketones, Amines, Carboxylic acids
& derivatives, Polymers, Biomolecules, Polymers, Chemistry in Everyday Life & POC., Classification of
Elements and Periodicity in Properties, Chemical bonding and Molecular Structure, Hydrogen and its
compounds, s-Block Elements, Group-13, Group-16, Group-17, d-block elements:, Compounds of Cr and
Mn, Coordination compounds, Qualitative analysis, Group-18, 1.f-block elements, 2.Metallurgy,
3.Environmental Chemistry, Gaseous State, Liquid Solutions and Colligative Properties,
Thermodynamics-I, Thermodynamics-II, Thermochemistry, Chemical Equilibrium, lonic equilibrium
MATHEMATICS : Function and Inverse Trigonometric Function, LCD, AOD, Total Differential Calculus, Indefinite
Integration, Definite Integration, Areas and Differential Equations, Total Integral Calculus, 3D and
Vectors, Matrices and Determinants, 3D and Vectors, Matrices and Determinants, Quadratic Equation
and Logarithms, Straight Lines and Complete Circles, Complete Circles and Parabola, Ellipse and
Hyperbola, Function and Inverse Trigonometric Function, LCD, AOD, Total Differential Calculus,
Indefinite Integration, Definite Integration, Areas and Differential Equations, Total Integral Calculus,
3D and Vectors, Matrices and Determinants, 3D and Vectors, Matrices and Determinants, Quadratic
Equation and Logarithms, Straight Lines and Complete Circles, Complete Circles and Parabola, Ellipse
and Hyperbola, Total Conic Sections, Complex Numbers , Progressions and Sets and Relations
Name of the Student: ___________________ H.T. NO:

Sri Chaitanya IIT Academy 17-11-2024_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2022-P2)_CTA-09/17_Q.P
JEE-ADVANCED-2022-P2-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N : 9 – 14) +4 -2 6 24
with partial mark
Sec – III(Q.N : 15 – 18) Questions with Single Correct Choice +3 -1 4 12
Total 18 60
PHYSICS:
Sec – I(Q.N : 19 – 26) Questions with Integer Answer Type +3 -1 8 24
Sec – II(Q.N : 27 – 32) +4 -2 6 24
with partial mark
Total 18 60
CHEMISTRY:
Sec – I(Q.N : 37 – 44 Questions with Integer Answer Type +3 -1 8 24
Sec – II(Q.N : 45 – 50) +4 -2 6 24
with partial mark
Total 18 60
Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 2

MATHEMATICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
1. Let  n be a real root of the cubic equation nx3  2 x  n  0 , there n is a positive integer.
 1 2025 
If  n   n  1 n  , n = 2,3,4.…., then the value of 
1013 1012    k   _____ (
 k 2 
. denotes greatest integer function)
2. If the real numbers x and y satisfy the equations x3  3x 2  5 x  1 and
y 3  3 y 2  5 y  5 then the value of  x  y  x y  _____
  1 
3. Let S be the set of ordered pairs  x, y  such that 0  x  1,0  y  1 , log 2    and
  x 
  1  m
 5    are both even. If that the area of the region covered by the graph of S is ,
log
  y  n
m  n
where m and n are relatively prime positive integers, then the value of  is equal
 3 
to___( The notation  x  denotes the greatest integer that is less than or equal to x )
1011
2024 7
sin8 x  7 cos8 x  2023  2024 tan x 
4. 

9
sec5 x  9 cos ec5 x
log 
 2023  2024cot x 
 dx 
2024
5. Let z1, z2 , z3 ,...., z12 be complex numbers representing the vertices of a regular dodecagon
inscribed in circle z  2  1 . If pk be any complex number lying on the circle z  2  k ,
12 12
2
where k  1,2,3,...,10,11,12 then the value of  pi  zk N.
i 1 k 1
The remainder when N is divided by 7 is equal to____

6. Let y  f  x  be a curve which satisfy the differential equation e x dy   x  1 dx  0 and
f  0   0 . If the area enclosed by the curve, x-axis, y-axis and a line x = c, where (c, f(c))
 p
is the point of inflection on the curve is  1    p, q  N  , then the value of (p +q) is
 eq 
equal to
 12r 2  1  1 
7. If N   then the value of    ______ ( . denotes greatest
r 2 
64 r 6
 48 r 4
 12 r 2
 1   8N
integer function)
x2 y2
8. A variable chord of the hyperbola   1 , subtends a right angle at the centre of the
3 6
hyperbola. If this chord touches a fixed circle having radius r, concentric with the
hyperbola, then the number of even divisors of r 2 is equal to

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
9. If f : R  R; f  x   4 x  cos  x and g : R  R; g  x   x3  4 x  cos  x

 d 
then Which of the following option(s) is/are TRUE ?  h '  x    h  x   
 dx 
     
' 1 ' 1
A) g 1 f 1  x   B) g 1 f 1  x  
16 36  9
x 3 x 3
     
' 1 ' 1
C) f 1 g 1  x   D) f 1 g 1  x  
28 30
x 4 x 4

4 1 7
10. Let  ,  ,  be three real numbers satisfying      1 3 8    4 2 10. If the point
 
 3 4 9
x9 y 8 z 3
P  ,  ,   lies on a plane   0 containing the lines L1 :   and
1 2 1
x 9 y 8 z 3
L2 :   , then which of the following option(s) is/are correct?
4 3 0

A) Distance of plane   0 from the point 0, 11, 2 2 is 2 units
x  10 y  6 z  2
B) Line L :   completely lies in plane   0
3 1 1
C) 6      6
D) If plane   0 intersect the coordinate axes at points A, B and C respectively then
volume of tetrahedron OABC, (O being origin) is

 44 3
cubic units
360
11. For any 3  3 matrix M, let M denote the determinant of M. Let
1 3 9  10 2 2  0 1 0 1 5 2
A  2 2 10 , B  11 3 1 , C  0 0 1 . If D   3 7 4  is a matrix such that
     
       
 3 1 11  9 1 3  1 0 0   2 m 1 
m  2 , then which of the following statement(s) is(are) INCORRECT?
2024 2023
A)  AD   AD B) AD  C 2 BD 1  AD  CBD 1
1 0 0 
C) B  CAand C  0 1 0 
3
D) C 2024 B 2C 2024  AC 2 A
 
0 0 1 
2 x    cos x    
12. If the function f  x   , x  , f    0 divides the circle x 2  y 2   2 in
  2 x  2 2
two parts having area A1 & A2 (where A1  A2 ) then which of the following statement(s)
is(are) CORRECT?
A1    2  3  4 3  4 A1 1
A)   B) A1  C) A2  D) 
A2    2  2 2 A2 2
 1 1 1 1 
13. Let f  x   lt  sin 4 x  2 sin 4 2 x  4 sin 4 22 x  6 sin 4 23 x  ....  2 n sin 4 2n x  , then which of
n 
 2 2 2 2 
the following is/are true?
 
A) f    1
2
 3 
B) f    1
 2 
C) f  x  is even function
D) f  x  is periodic function with no fundamental period
4 x2  1 2 x4  2 x2  3
14. Consider the following function f  x    ;x  0.
4
x x 2
 x  1
2 4
x 2
If y  f  x  attains its minimum value  m  at x   , then which of the following option(s)
is/are correct?
A) sin 1  m  

4  
B) cot cos 1  4  m  2   3 
  D) cos  sin  m 3    cot 1 1
 2  1
C) tan 1 m 2  3  sec1  
2

 3
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
15. Three circles, each of radius 1, are packed inside an ellipse
x2 y2
  1 a  b  0  ,  2  ABC  , as shown in the figure. Two of these circles, touch
a2 b2
the ellipse at two points each and the middle circle touches other both circles and ellipse at
the end of minor axis. A, B and C are centres of these circles.

If the area of ellipse is minimum, then the value of cos is

1 1 1 1
A) B) C) D)
3 6 3 6
x2 y2
16. A line meets   1 at A, B and the parabola y 2  4ax at C and D. The segment
2 2
9a 4a
AB subtends 90 at centre of ellipse. If the locus of point of intersection of tangents to the
parabola at C and D is px 2  qy 2  36a 2 then the value of p  q is equal to

A) 4 B) 22 C) 3 D) 18
 2x  
1 1  x
2
 2x 
17. If f  x   sin 1    cos    tan 1  ; x  1
2  2 2
1 x  1 x  1 x 
then which of the following option is INCORRECT?
1 5  1 2
A) f      2 tan
1 5  3 5
1 2 
B) f  1
  2 tan 3  2 2  
1 2 
 1  1  2 
C) f    6cos  
 2  3 
D) f  7   2 tan 1  7 
2 2
 x 
18. If  
3  dx  1 tan 1  3 x  1   1  1  C , where C is constant of
 
3  4 3x  9x4 6 6  2  6 3 f  x
integration and x 
1
3
, f  0   1 , then value of f  3  is
A) 4 B) -4 C) 2 D) -2

PHYSICS Max Marks: 60
SECTION-I
19. Consider a configuration of n identical units, each consisting of three layers. The first
1
layer is a column of air of height h  cm , and the second and third layers are of equal
3
3 1 3
thickness d  cm , and refractive indices 1  and 2  3 , respectively. A light
2 2
source O is placed on the top of the first unit, as shown in the figure. A ray of light from O
is incident on the second layer of the first unit at an angle of   60 to the normal. For a
specific value of n , the ray of light emerges from the bottom of the configuration at a
4
distance l  cm, as shown in the figure. The value of n is _____.
3
20. A uniform circular Arc(AB) symmetrical to y-axis of thin wire from of radius
R= 2  cm and mass M makes an angle of 90 at the origin Find the y coordinate of the
C.M. taking O as the origin in cm.

y
A B
x
O
21. A small ball moves toward right with a velocity v. It collides with the wall and return
back and continues to and fro motion. If the average speed for first to and fro motion of
ball is 2/3 v. Find the coefficient of restitution of impact in multiples of 101 .
22. A conducting liquid of density 13.6  103 kgm3 is contained in a u-tube of uniform square
cross-sectional side a = 4 mm, Electrodes A and D are sealed inside as in fig.
An electric current I = 10A passes between the electrodes A to D and a magnetic field
B = 326.4  103 tesla is applied across the horizontal arm perpendicular to the plane of
the fig. and inside to the plane. Calculate the difference in liquid levels in mm in the u-
tube. Surface tension is negligible.  g  10mS 2 
 
23. A current I flows along the length of a thin walled, long metallic hollow cylinder of radius
  I2   1 
R, distributed uniformly on its surface. If the pressure on the wall is P   0     .
  2R2   x 
 
Find the value of x.

24. An electric dipole consist of equal and unlike charges of equal magnitude 2.0  108 C
separated by a distance of 2.0  103 m . Mass of each particle is 2.0 g. It is placed near a
long line charge of linear density 2.0  104 C / m as shown in figure, such that the dipole
at a distance of 2.0 cm from the line charge. The angular acceleration of the dipole at this
instant is 1.8  10n rad/s2. Find n.
+ 
+
2 cm
+ +
+
25. A thick spherical shell has two equally thick layers with conductivities for inner & outer
layers nk & k respectively. If the interface temperature is arithmetic mean of inner & outer
surface temperature of composite shell then the value of  is (Assume inner radius R &
other radius 2R for composite layer)
26. A uniform solid cylinder of radius 15 cm rolls over a horizontal plane passing into an
inclined plane forming an angle   300 with horizontal as shown in figure. Find the
maximum value of the V0 in m/s, which still permits the cylinder to roll onto the inclined
plane section without a jump (means does not leave the contact with mating surface). The
sliding is assumed to be absent.
V0
SECTION – II
27. A double slit setup is shown in the figure. One of the slits is in medium 2 of refractive
index n2 . The other slit is at the interface of this medium with another medium 1 of

refractive index n1   n2  . The line joining the slits is perpendicular to the interface and
the distance between the slits is d . The slit widths are much smaller than d . A
monochromatic parallel beam of light is incident on the slits from medium 1. A detector is
placed in medium 2 at a large distance from the slits, and at an angle  from the line
joining them, so that  equals the angle of refraction of the beam. Consider two
approximately parallel rays from the slits received by the detector.
Which of the following statement(s) is (are) correct?

A) The phase difference between the two rays is dependent on d .
B) The two rays interfere constructively at the detector.
C) The phase difference between the two rays depends on n1 but is independent of n2
D) The phase difference between the two rays vanishes only for certain values of d and
the angle of incidence of the beam, with  being the corresponding angle of refraction.
28. A hydrogen atom having kinetic energy E collides with a stationary hydrogen atom.
Assume all motions are taking place along line of motion of the moving hydrogen atom.
For this situation, mark out the correct statement (s).
A) For E > 20.4 eV, collision could be elastic
B) For E > 20.4 eV, collision could be inelastic
C) For E = 2.4 eV, collision would be perfectly inelastic
D) For E = 18 eV, the KE of initially moving hydrogen atom after collision is zero.

29. In the circuit diagram shown:
E
A) The steady state current through the battery is
2R
E
B) The initial rate of rise of current in the inductor is (just after connecting the battery
2L
in the circuit)
EC
C) The charge on the capacitor in steady state will be
2
E
D) The initial rate of rise of charge on the capacitor is (just after connecting the
3R
battery in the circuit)
30. A tank is placed on a horizontal surface and is full of water up to height ‘H’. Two very
small holes are created simultaneously on the vertical side of tank at height h1 & h2 from
bottom of tank as shown in figure and R1 & R2 are the ranges corresponding height
h1 & h2 respectively. h1  h2
Choose the correct statement
A) If R1  R2 then H = h1  h2
B) If t1 & t2 are the time taken by water ejecting from holes ‘A’ and ‘B’ to reach on
horizontal surface, then t1  t2 if R1  R2
C) The water ejected from both holes strikes on horizontal surface with velocity 2gH
D) If the ratio of the velocity head of water just after ejecting from holes A to B is 3 : 2,
then H   3h2  2h1 
J
31. If gravitational potential in a region is given by equation V = 20 (x + y) and a particle
kg
of mass 0.5 kg is placed at the origin then choose the correct statement
A) Magnitude of gravitational force experienced by particle is 10 N
B) Magnitude of gravitational force experienced by particle is 10 2N
 N
C) Gravitational field at a point (x, y) is given by, E  (20iˆ  20 ˆj )
kg
 N
D) Gravitational field at a point (x, y) is given by, E  ( 20 2iˆ  20 2 ˆj )
kg
32. A bimetallic strip is formed out of two identical strips one of copper and the other of
brass. The coefficients of linear expansion of the two metals are  C and  B On heating,
the temperature of the strip goes up by T and the strip bends to the form an arc of radius
of curvature R. Then R is:
A) proportional to T B) inversely proportional to T
C) proportional to  B   C D) inversely proportional to  B   C
SECTION – III
33. Area of the cross-section of a wire is measured using a screw gauge. One
main scale division is 0.5 mm. The circular scale has 100 divisions and for one full
rotation of the circular scale, it shifts by two divisions on the main scale. The measured
readings are listed below.
Measurement condition Main scale reading Circular scale reading
Two arms of gauge touching each 0 division 4 divisions
other without wire
Attempt-1: With wire 4 divisions 20 divisions
Attempt-2: With wire 4 divisions 16 divisions
What are the diameter and cross-sectional area of the wire measured using the screw
gauge?
A) 2.22  0.02mm,  1.23  0.02  mm 2 B) 2.22  0.01mm,  1.23  0.01 mm 2

C) 2.14  0.02mm,  1.14  0.02  mm 2 D) 2.14  0.01mm,  1.14  0.01 mm2
34. An ac voltage source V  V0 sin t is connected across resistance R and capacitance C as

1
shown in figure. It is given that R  . The peak current is I 0 . If the angular frequency
C

of the voltage source is changed to keeping R and C fixed, then the new peak current
3
in the circuit is:
R
V0 sin t ~ C
I I I I
A) 0 B) 0 C) 0 D) 0
2 2 3 3
35. Find equivalent capacitance across AB (all capacitances in  F)
20
A) F B) 9  F C) 48  F D) None
3
36. Two blocks A and B are joined by means of a slacked string passing over a massless
pulley as shown Figure. The system is released from rest and it becomes taut when B falls
a distance 0.5m.
2kg
A
Clamp
B
1kg
No friction any where.

Find the magnitude of impulse on the pulley by the clamp during the small interval while
string becomes taut.
4 5 2 5 10 3 2 10
A) B) C) D)
3 3 3 3
CHEMISTRY Max Marks: 60
SECTION-I
 f G0
37. Calculate in kJ/mol for  NH 4Cl , s  at 350 K. Given:
91.775
 f H 0  NH 4Cl , s   314.5kJ / mol
S 0 N  g   192 JK 1mol 1; S 0 H  g   130.5 JK 1mol 1;

2 2
S 0Cl  g   223JK 1mol 1; S 0 NH Cl  s   94.5 JK 1mol 1;

2 4
All given data at 300K
 350 
 r C p  20 J / mol  K ; ln    0.15
 300 
38. Calculate the value of x + y + z
Complex Number of geometrical
isomers
i)  Pt  gly 2  NH 3 2  Cl2 X
2 Y
ii) Co  NH 2  CH 2  CH 2  NH 2 2  NH 3  Cl 
2 Z
iii) CoCl  H 2O   NH 3 4 
39. An organic compound A of molecular formula C8 H 8O gives yellow precipitate on
heating with iodine in the presence of sodium hydroxide. It neither reduces Tollen’s or
Fehling’s reagent, nor does it decolourizes bromine water or Baeyer’s reagent. On drastic
oxidation with chromic acid, it gives a carboxylic acid B of molecular formula C7 H 6O2 .
Compound A on reaction with 2, 4-DNP gives an orange-red precipitate C. If the degree
of unsaturation of C is x, then x-5 is.

40. Initial volume of H 2 gas saturated with water vapour is confined under a piston in a
container is 10 litres as shown in the given figure.
The container also contains some liquid water. The total pressure over liquid water is
80cm of Hg. Now the piston is pulled in such a manner that volume of container is
doubled, and final total pressure over liquid water in the container becomes P. If vapour
P
pressure of water is 20cm of Hg and volume of liquid is negligible. The value of
10
is_____cm of Hg
41. ‘X’ is the number of combination can produce coloured gases on sufficient heating
i) Na2 S  dil HCl ii) Na2 SO3 _ dil HCl
iii) CH 3COOH  dil HCl iv) NaCl  conc HCl  MnO2
v) KBr  con H 2 SO4 vi) KI  conc H 2 SO4
‘Y’ is the number of compounds which are soluble (by forming soluble precipitate) in
excess of ammonia
CuSO4 , AgNO3 , Pb  NO3 2 , ZnSO4 , NiSO4 , CoCl2
‘Z’ is the number of salts which give coloured bead in borax bead test
Cu  NO3 2 , FeSO4 , Fe2  SO4 3 , Cr2  SO4 3 , MnSO4 , CoSO4 , NiSO4 , ZnSO4
Then value of (X+Y-Z) is

42. The treatment of an aqueous solution of 1.87 g of Cu  NO3 2 with excess KI results in a
brown solution along with the formation of a precipitate. Passing H 2 S through this brown
100
solution gives another precipitate X. The amount of X (in gm) is _______ 
2
(Given Atomic mass of H  1, N  14, O  16, S  32, K  39, Cu  63, I  127 )
43. How many number of the following reaction(s) that yield benzene as one of the products?
I) II)
III) IV)
44. How many of the following polymers listed are thermoplastic polymers?
Polyethene, Polypropylene, Melamine formaldehyde resin, Polyvinyl chloride, Phenol
formaldehyde resin, phenol formaldehyde resin, Polystyrene
SECTION – II
45. Choose the correct statement(s) among the following:
A) Ni 2 ion does not form inner orbital octahedral complexes.
2
B) The complex  MnCl2 Br2  has two geometrical isomers.
3 3 3 3
C) Co  en 3   Co  en 2  NH 3 2   Co  en   NH 3 4   Co  NH 3 6 
(Stability order of complexes)
2  
D)  Fe  CO 6    Mn  CO 6   Cr  CO 6   V  CO 6  (CO stretching frequency
order-bond order)
46. Which of the following is/are correct?

A) Heating the iodide salt with conc. H 2 SO4 , deep violet vapours with a pungent smell
are evolved.
B) Acidified Nitrite turns starch iodide blue.
C) Yellow ppt of PbCrO4 is soluble in hot sodium hydroxide solution
D) White gelatinous ppt of Al  OH 3 is soluble in excess of sodium hydroxide.
NBS Q R (i ) s T,
h  A  B  C 
 (ii ) H 
 D 
pyridine E
47.
For the sequence of reactions above,the correct option(s) is /are
A) C=Phenol,R=P.C.C B) Q=Aqueous acetone, D=Salicylic acid
C)T=Acetyl chloride,E=Asprin D) R= KmnO4 / H  ,C=Phenol
48. Choose the correct statement(s) regarding given reaction scheme
Ac O
A) Q 
2  Aspirin B) Q and R are functional isomers
H 2 SO4
C) P and R are positional isomers D) S is a less acidic than picric acid

49. Fill the missing reagents from the options given for the following reaction schemes

A) P  H 2O / H  ; Q  Hg  OAc 2  H 2O; NaBH 4
B) R  OsO4 / NaHSO3 , H 2O; S  mCPBA : H 2O; H 
C) P  Hg  OAc 2  H 2O; NaBH 4 ; Q  B2 H 6 ; H 2O2  OH 
D) P  H 2O / H  ; Q  B2 H 6 ; H 2O2  OH 
50. With respect to compound I – IV select correct statements
A) Compound III is more acidic than IV

B) Conjugate base of II is more stable than conjugate base of I
C) All C  H bonds of II are in same plane.
D) Compound (I) has maximum 4 atoms in same plane.
SECTION – III
51. The correct match of the molecules in column I and reactions in column II is
Column I Column II
O (L) Coloration with FeCl3
NH2
i) CH3
O (M) Effervescence with NaHCO3
CH3
ii) NH2
O (N) Yellow precipitate with NaOH and I 2
H
H3C
N
iii) H
(O) Yellow oil with NaNO2 , HCl at 0 C

H
NH (P) Heating with NaOH gives out a gas that turns

moist turmeric paper brown
iv) OH
A) i-N, ii-L, iii-O, iv-M B) i-O, ii-N, iii-L, iv-P
C) i-P, ii-O, iii-L, iv-M D) i-P, ii-N, iii-O, iv-L
52. The reactions of Cl2 gas with cold-dilute and hot –concentrated NaOH in water give
sodium salts of two (different) oxoacids of chlorine, P and Q . Respectively. The Cl2 gas
reacts with SO2 gas in the presence of charcoal, to give a product R. R reacts with white
phosphorous to give a compound S.
On hydrolysis S gives on oxoacid of phosphorous T. R,S and T respectively are
A) SO2Cl2 , PCl5 and H 3PO4 B) SO2Cl2 , PCl3 and H 3PO3
C) SO2Cl2 , PCl3 and H 3 PO2 D) SO2Cl2 , PCl3 and H 3 PO4
53. Choose the wrong statements among the following:

2
A)  Ni  CN 4  has square planar geometry
B)  Pt  NH 3 2 Cl2  has 2 geometrical isomers
3
C) Fe in  Fe  CN 6  has t2g 5eg 0 electronic configuration

D) The bond order of CO in V  CO 6  is more than bond order of CO in Cr  CO 6 
54. Match the processes gives under column-I with the given under column-II
COLUMN-I COLUMN-II
P) For the process H 2O  l   H 2O  S  , H & S are 1 Ve, Ve
Q) 2 Ve, Ve
1
2 A  s   O2  g   2 A2O  s 
For the endothermic reaction 2
S & G are
R) C  diamond   C  graphite  , Favourable conditions for 3 Ve, Ve
formation of diamond are high pressure and high temperature.
Then s for formation of Graphite from diamond H for
formation of graphite from diamond
For the given reaction 4 Ve, Ve
S) N 2O4 g   2 NO2  g  , Ea forward   57.2 KJ and
Ea backword   3.2 KJ H & S
5 Ve,0
A) P  1, Q  2, R  3, S  4 B) P  4, Q  1, R  2, S  2
C) P  4, Q  1, R  2, S  3 D) P  1, Q  4, R  3, S  3


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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

Name of the Student: ___________________ H.T. NO:

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 2

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 3

6. Let y  f  x  be a curve which satisfy the differential equation e x dy   x  1 dx  0 and

hyperbola, then the number of even divisors of r 2 is equal to

9. If f : R  R; f  x   4 x  cos  x and g : R  R; g  x   x3  4 x  cos  x

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 4

volume of tetrahedron OABC, (O being origin) is

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 6

If the area of ellipse is minimum, then the value of cos is

parabola at C and D is px 2  qy 2  36a 2 then the value of p  q is equal to

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 7

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 8

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 9

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 10

Which of the following statement(s) is (are) correct?

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 11

29. In the circuit diagram shown:

A) 2.22  0.02mm,  1.23  0.02  mm 2 B) 2.22  0.01mm,  1.23  0.01 mm 2

34. An ac voltage source V  V0 sin t is connected across resistance R and capacitance C as

No friction any where.

S 0 N  g   192 JK 1mol 1; S 0 H  g   130.5 JK 1mol 1;

S 0Cl  g   223JK 1mol 1; S 0 NH Cl  s   94.5 JK 1mol 1;

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 15

Then value of (X+Y-Z) is

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 16

46. Which of the following is/are correct?

C) P and R are positional isomers D) S is a less acidic than picric acid

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 18

A) P  H 2O / H  ; Q  Hg  OAc 2  H 2O; NaBH 4

B) R  OsO4 / NaHSO3 , H 2O; S  mCPBA : H 2O; H 

C) P  Hg  OAc 2  H 2O; NaBH 4 ; Q  B2 H 6 ; H 2O2  OH 

A) Compound III is more acidic than IV

(O) Yellow oil with NaNO2 , HCl at 0 C

NH (P) Heating with NaOH gives out a gas that turns

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 20

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 21

Sec: Sr.Super60_NUCLEUS & STERLING_BT Space for rough work Page 22

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