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    Ch111 General Chemistry-I (Mid - Mo22)

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    Ch111 General Chemistry-I (Mid - Mo22)

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    Ch111 General Chemistry-i (Mid_mo22)(1)

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    Ch111 General Chemistry-I (Mid - Mo22)

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    of 1

    BIRLA INSTITUTE OF TECHNOLOGY, MESRA, RANCHI

    (MID SEMESTER EXAMINATION MO2022)


    CLASS: IMSC SEMESTER: I
    BRANCH: MATHEMATICS & COMPUTING / PHYSICS SESSION: MO22

    SUBJECT: CH111 GENERAL CHEMISTRY-I


    TIME: 02 HOURS FULL MARKS: 25

    INSTRUCTIONS:
    1. The question paper contains 5 questions each of 5 marks and total 25 marks.
    2. Attempt all questions.
    3. The missing data, if any, may be assumed suitably.
    4. Tables/Data handbook/Graph paper etc., if applicable, will be supplied to the candidates
    -----------------------------------------------------------------------------------------------------------------------------

    CO BL
    Q.1(a) Discuss the significance of Heisenberg’s uncertainty principle [2] 1 1
    Q.1(b) The wavelength of first spectral line in the Balmer series is 6561 Aο. Calculate [3] 3 4
    the wavelength of the second spectral line in Balmer series.

    Q.2(a) Radius of the fourth orbit in hydrogen atom is 0.85 nm. Calculate the velocity of [2] 1 4
    the electron in this orbit (mass of electron = 9.1 × 10 -31 kg).
    Q.2(b) Draw the shapes of d- orbitals properly. [3] 1 1

    Q.3(a) Explain the Bohr Bury’s rule. [2] 1 1


    Q.3(b) What is radial probability distribution functions? Draw radial probability [3] 3 3
    distribution function for 2s orbital.

    Q.4(a) Arrange the following carbocations in the increasing order of stability. [2] 4 4

    Q.4(b) Discuss the structure and geometry of a carbocation. [3] 4 1

    Q.5(a) Write down the IUPAC name for the following compounds: [2] 2 2

    Q.5(b) Discuss “hyperconjugation” and its role in stability of free radical with examples. [3] 3 4

    :::::: 18/01/2023 ::::::M

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