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  • Chemistry and Aliphatic Hydrocarbons: Questions1 Carry19 Marks and Questions 2, and 3 Carry18.5 Marks Each

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    Ingita Deymunshi
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    1. The document provides information about an exam for an inorganic chemistry course including: 2. The exam has 3 sections with questions worth varying marks and requires answers on separate answer scripts. 3. Section A focuses on inorganic chemistry and requires students to attempt 2 out of 3 questions provided which include topics like atomic structure, molecular orbitals, and ionic character calculations.

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    1. The document provides information about an exam for an inorganic chemistry course including: 2. The exam has 3 sections with questions worth varying marks and requires answers on separate answer scripts. 3. Section A focuses on inorganic chemistry and requires students to attempt 2 out of 3 questions provided which include topics like atomic structure, molecular orbitals, and ionic character calculations.

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    33 views2 pages

    Chemistry and Aliphatic Hydrocarbons: Questions1 Carry19 Marks and Questions 2, and 3 Carry18.5 Marks Each

    Uploaded by

    Ingita Deymunshi
    1. The document provides information about an exam for an inorganic chemistry course including: 2. The exam has 3 sections with questions worth varying marks and requires answers on separate answer scripts. 3. Section A focuses on inorganic chemistry and requires students to attempt 2 out of 3 questions provided which include topics like atomic structure, molecular orbitals, and ionic character calculations.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
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    of 2

    Unique Paper Code : 32175901

    Name of the Paper : GE-1 Atomic Structure Bonding, General Organic


    Chemistry and Aliphatic Hydrocarbons
    Name of the Course : B.Sc., (Hons.)
    Semester :I
    Duration : 3 hours Maximum marks: 75

    Attempt SECTIONS A & B on the DIFFRENT Answer Script.


    Questions1 carry19 marks and questions 2,and 3 carry18.5 marks each.

    Section A
    (Inorganic Chemistry)
    Attempt any TWO questions

    Gas constant, R= 8.314 JK-1 mol-1 = 0.08206 dm3 atm K-1 mol-1
    Avogadro’s number, NA= 6.022x1023 mol-1 nm: 1.6726 x 10-27 kg.
    pm: 1.6726 x 10-27 kg. em: 9.1 x 10-31 kg e: 1.6022 x 10-19 Coulomb

    1. (a) Why a new approach required to atomic structure?


    (b) Show how the LCAO approximation gives rise to bonding and
    anti-bonding orbitals. What orbital are formed by the axial
    overlap of p orbitals?
    (c) (i)What does it meant by anomalous electronic configurations?
    Give two examples.
    (ii) Write a electronic configurations of following ions: Re2+ and
    Gd+
    (d) Calculate the percentage of ionic character of HCl? The inter
    nuclear distance of HCl is 1.28410−10 m and its actual dipole (5,5,5,4)
    moment is 3.68910−30 Cm.

    2. (a) (i)Predict the molecular hybridization and geometry for the


    following molecules SO42-, H3O+ and XeO2F4 using
    VSEPR theory?
    (ii) Draw resonating structure: CO32- and N3-.
    (b) Calculate the first excited state energy of 31H ion?
    (c) Calculate the de Broglie wavelength of an electron travelling at
    20% of the speed of light.
    (d) Both NBr3 and NF3 are polar but their molecules align
    differently in a non-uniform electrostatic field: Why? (5,5,5,3.5)
    3. (a) How do you calculate lattice energy from the Born - Landé
    equation and What is the limitation of it?
    (b) (i) Sketch molecular orbital diagram for NC molecule and
    calculate bond order and magnetic properties.
    (ii) Based on the M.O diagram arrange the following in
    increasing order of their bond length. O2+, O2-, and O22+
    (c) For the 6s and 5dx2-y2 hydrogen-like orbitals, sketch the
    following:
    i) Radial function R
    ii) Radial probability distribution 4r2R2
    (d) If you wish to locate an electron in an atom within a distance of
    0.1Å. What is the uncertainty involved in the measurement of its
    velocity? (5,5,5,3.5)

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