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Term Test For GM1 and BM1 Chemistry ch1,2,7,8,9

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Concordia College Bahawalpur

Examination: FSc. 2nd year TERM TEST Maximum Marks: 85


Paper: CHEMISTRY (1,2,7,8,9) Time Allowed: 3 Hour

Name: Class: RollNo.

SECTION-I
Q.No.1 Chose the correct answer and mark it circle. (17x1=17)

1.

2. Trona is:
(a) NaCl (b) Na2CO3.H2O (c) Na2B4O7.10H2O (d) Na2CO3.2NaHCO3.2H2O

3.

4.

5.

6.

7.

8.

9.

10.

For: BM-1, GM-1


Concordia College Bahawalpur

11.

12.

13.

14.

15.

16. The nitride ion in lithium nitride is composed of:


(a) 7 pistons + 7 electrons (b) 10 protons + 7 electrons
(c) 7 protons + 10 electrons (d) 10 protons + 10 electrons

17. The formula of ions of some elements are shown below N−3, O−2, F−1, Li+1, Mg+2. Which statement about these
ions is correct? They all have same.

(a) Number of electrons in their outer shells (b) Electronic structure as noble gases
(c) Number of neutrons in their nuclei (d) Number of protons and electrons

For: BM-1, GM-1


Concordia College Bahawalpur
SECTION-II
QNo2: Short Answers (Any Eight):- (8x2=16)
1) Define hydration energy of ions with an example.
2) How does Lanthanide contraction control atomic sizes of 6th and 7th periods?
3) Melting points of Group VIIA (Halogens) Elements increase down the group. Why?
5) Metallic character increases down the group. Why?
6) Hydration energies of the following ions are in order. Explain Al3+ > Mg2+ > Na+.
7) Why fluoride have the highest lattice energies among the pure ionic compounds give two reason
8) Why members of second group are called Alkaline-Earth metals?
9) Write chemical formulae of following minerals: (a) Beryl (b) Barite
10) Give reasons that alkali metals are strong reducing agents.
11) Write any two points of difference of Be with its family members.
12) Which two major problems are faced during working of diaphragm cell?
QNo3: Short Answers (Any Eight):- (8x2=16)
1) Give idea about knocking in the internal combustion engine.
2) Give boiling range (oC) and composition of: (a) kerosene (b) naphtha
3) How octane number of gasoline is improved? Explain with example.
4) Sigma bond is relatively inert. Why?
5) Why is there no free rotation about a double bond but a free rotation about a single bond?
6) Convert HC  CH into oxalic acid.
7) Give name and reaction of alkene whit is used to indicate the position of double bond.
8) How will you synthesize ethyl nitrile from Ethyne?
9) Convert Ethane ⎯⎯→ 1-Butanol.
10) How will you distinguish acetylene and ethene?
11) Write down structural formulas of the following.
(a) 2-Methylpropane (b) Neopentane
(c) 3-Ethylpentane (d) 2,2-Dimethylpropane
12) Ideality A, B and C in the following reaction.
Br Alcoholic KOH
Ethene ⎯⎯→
2
A ⎯⎯⎯→ B ⎯⎯→ C
CCl4 KOH
QNo4: Short Answers (Any Six):- (6x2=12)
1) Give reactions of : (a) Phenol with Zinc (b) Benzene with SO3
2) How Hexane and Heptane can give Benzene and Toluene respectively?
3) Write down mechanism for halogenation of benzene.
4) Prepare m-chloronitrobenzene from benzene in two steps.
5) How benzene is converted into maleic acid by catalytic oxidations?
6) Write two objections to Kekule formula of Benzene.
7) How will you have distinguished chemically between toluene and benzene?
8) How will you convert benzene into orthochloronitro-benzene?
9) How will you prepare 2,4,6 – Trinitrotoluene (TNT)
SECTION III
Extensive Questions (Attempt any Three) : - (24)M
Q.No.1
a) Write two similarities and two dissimilarities of hydrogen with IV A group carbon family elements.
b) Give eight points of differences between Lithium and other members of the family.
Q.No.2
a) Write a note on acidic character of alkynes or Ethyne. Elaborate your answer with chemical equations
at least three examples.
b) Give four types of structural isomerism along with an example in each case.
Q.No.3
a. Explain the polymerization of acetylene (Linear).
b. Write a note on Friedal Craft reactions.
Q.No.4
a) Detail out two reactions in which Benzene behaves as saturated hydrocarbon and two reactions in
which it behaves as unsaturated.
b) How is ethane prepared by Kolbe's electrolytic method? Write its mechanism.
Q.No.5

a. Define Alicyclic compounds and Aromatic compounds with one example in each case.
b. Describe the manufacture of Sodium Hydroxide by Diaphragm Cell.

For: BM-1, GM-1

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