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    Activation Energy - Temperature

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    iSega Roman

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    © All Rights Reserved
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    Activation Energy - Temperature

    Uploaded by

    iSega Roman
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    Download as xlsx, pdf, or txt
    1 views6 pages

    Activation Energy - Temperature

    Uploaded by

    iSega Roman

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 6

    DETERMINING THE ACTIVATION ENERGY OF A REACTION

    Na2S2O3 (aq) + 2HCl (aq) --> 2NaCl (aq) + SO2 (g) + S (s) + H2O (l)
    S2O3 (2-) + 2H (+) --> SO2 + S + H2O
    0.1M Na2S2O3
    0.1M HCl Limiting Reagent

    Investigating the impact of temperature on the activation energy of the reaction of 10ml Na2S2O3 wit
    Range of Temperature: 300K to 337K
    Observe when the cross/dark spot disappears, precipitate will have formed. Activation energy will be

    Only one trial as temperature is irrealistically hard to reproduce twice exactly.

    T (*C) T (*K) time (s) k = 1/t (s^-1)


    24.8 297.8 64.13 0.015593326
    32.3 305.3 48.13 0.020777062
    45.6 318.6 21.56 0.046382189
    49.9 322.9 17.72 0.056433409
    54.1 327.1 14.32 0.069832402

    ln k over
    0

    -0.5

    -1

    -1.5

    -2

    ln k
    -2.5
    f(x) = − 5136.24320806033 x + 13.
    -3 R² = 0.99405619730538

    -3.5

    -4

    Flawed data, collected with thermometer closed


    -4.5
    T (C) time (s) 0.003 0.00305 0.0031 0.00315
    60.1 0
    -4

    -4.5
    0.003 0.00305 0.0031 0.00315

    36.8 22.37
    35.5 23.06
    30.2 41.32
    OF A REACTION
    s) + H2O (l) OILRIG Oxidation is Loss of Electrons
    Reduction is Gain of Electrons

    reaction of 10ml Na2S2O3 with 10ml HCl ARRHENIUS EQUATION


    https://en.wikipedia.org/wiki/Arrhenius_equation
    med. Activation energy will be reached.

    1/T (*K^-1) ln k k=
    T (oC) T (oK) Time (s)
    0.003357958 -4.16091227 (s-1)
    0.003275467 -3.87390568 24.8 297.8 64.13 0.01559333
    0.003138732 -3.07083975 32.3 305.3 48.13 0.02077706
    0.003096934 -2.87469395 45.6 318.6 21.56 0.04638219
    0.003057169 -2.66165716 49.9 322.9 17.72 0.05643341
    54.1 327.1 14.32 0.0698324

    ln k over 1/T (oK-1)

    Y=mx+c
    ln(k) = m(1/T) + ln(A)
    M = -Ea/R

    f(x) = − 5136.24320806033 x + 13.0318273579685 R=8.31


    R² = 0.99405619730538
    Ea = 5136.2 x 8.31
    Ea = 42681.822 J/mol
    Ea = 42.7 kJ/mol

    00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034

    1/T (K-1)
    00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034

    1/T (K-1)
    Arrhenius_equation

    Table 2: Vertical Error Bar Calculations


    Max Error Max lnk Min lnk
    (oK-1) ln(k) ln(k)
    = Max ln(k) - ln(k) = ln(1/t-5) = ln(1/t+5)
    0.00335796 -4.1609123 0.081173890167 -4.07973841 -4.1609123 -4.23598879
    0.00327547 -3.8739057 0.10968688934 -3.76421881 -3.8739057 -3.97274174
    0.00313873 -3.0708397 0.263849551043 -2.80699015 -3.0708397 -3.27940632
    0.00309693 -2.8746939 0.331518342088 -2.54317556 -2.8746939 -3.12324559
    0.00305717 -2.6616572 0.429494571303 -2.23216263 -2.6616572 -2.96114083

    Table 3: Horizontal Error Bar Calculations


    Max Error Max Min
    (oK-1)
    = (1/T-1) - (1/T) = 1/T-1 = 1/T+1
    1.13122372E-05 0.003369272 0.00335796 0.00334672
    1.076069339E-05 0.003286231 0.00327547 0.003264773
    9.884609572E-06 0.003148615 0.00313873 0.003128911
    9.624830693E-06 0.003106555 0.00309693 0.003087373
    9.374004906E-06 0.003066544 0.00305717 0.003047851
    Min Error Error Bar Value
    = ln(k) - Min ln(k) = (Max Error - Min Error)/2
    0.075076489957 0.00304870010504388
    0.098836040463 0.00542542443869798
    0.208566624608 0.0276414632173267
    0.248551693853 0.0414833241175367
    0.299483628784 0.0650054712590642

    Min Error Error Bar Value


    = (1/T) - (1/T+1) = (Max Error - Min Error)/2
    1.12397858E-05 3.62256934293564E-08
    1.06969017E-05 3.18958321731452E-08
    9.81886108E-06 3.28742477211617E-08
    9.55735412E-06 3.37382855600515E-08
    9.31873514E-06 2.7634882372252E-08

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