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MSDS_rhenus EHM 10

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Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : rhenus EHM 10


Revision date : 13.02.2014 Version (Revision) : 2.2.0 (2.1.0)
Print date : 30.06.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier


rhenus EHM 10
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Lubricants, greases, release products ( cooling grease ) .
1.3 Details of the supplier of the safety data sheet
Supplier (manufacturer/importer/only representative/downstream user/distributor)
Rhenus Lub GmbH & Co KG
Street : Erkelenzer Str. 36
Postal code/city : 41179 Mönchengladbach
Telephone : +49 21 61 58 69 - 0
Telefax : +49 21 61 58 69 93
Information contact : Application technology - technical information:
+49 21 61 58 69 74 (Lubricants, greases, release products). Only available during office hours.
+49 21 61 58 69 77 (cooling grease). Only available during office hours.
QHSE-Information about Material-Safety-Data-Sheet:
+49 21 61 58 69 267 (Safety-Data-Sheet, QHSE [Quality-Health-Safety-Environment]). Only available during office hours.
eMail: sicherheitsdatenblatt@rhenusweb.de
1.4 Emergency telephone number
International (all languages, all informations, all time 24 h / 365 d): GBK Gefahrgut Büro GmbH +49 61 32 84 46 3.
CH: 145. --- S: 112. --- TR: 144.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Classification according to Regulation (EC) No. 1272/2008 [CLP]
Asp. Tox. 1 ; H304 - Aspiration hazard : Category 1 ; May be fatal if swallowed and enters airways.
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms

Health hazard (GHS08)


Signal word
Danger
Hazard components for labelling
SCHMIERÖLE (ERDÖL), C15-C30, ; CAS No. : 72623-86-0
Hazard statements
H304 May be fatal if swallowed and enters airways.
Precautionary statements
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331 Do NOT induce vomiting.
P405 Store locked up.
2.3 Other hazards
None

Page : 1 / 7
( EN / ROK )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : rhenus EHM 10


Revision date : 13.02.2014 Version (Revision) : 2.2.0 (2.1.0)
Print date : 30.06.2015

SECTION 3: Composition / information on ingredients

3.2 Mixtures
Description
Base oil with additives.
Hazardous ingredients
SCHMIERÖLE (ERDÖL), C15-C30, ; REACH registration No. : 01-2119474878-16-xxxx ; EC No. : 276-737-9; CAS No. : 72623-86-0
Weight fraction : 50 - < 100 %
Classification 1272/2008 [CLP] : Asp. Tox. 1 ; H304
DI-TERT-DODECYL POLYSULFIDE ; EC No. : 270-335-7; CAS No. : 68425-15-0
Weight fraction : 1 - < 10 %
Classification 1272/2008 [CLP] : Aquatic Chronic 4 ; H413
ISOPROPYLATED TRIPHENYL PHOSPHATE ; REACH registration No. : 01-2119535109-41-0002 ; EC No. : 273-066-3; CAS No. : 68937-41-7
Weight fraction : 0-<1%
Classification 1272/2008 [CLP] : Repr. 2 ;H361fd STOT RE 2 ; H373 Aquatic Chronic 2 ; H411
Additional information
Full text of R-, H- and EUH-phrases: see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures


General information
Avoid contact with skin, eyes and clothes. Remove contaminated, saturated clothing immediately.
In case of inhalation
Provide fresh air. When in doubt or if symptoms are observed, get medical advice.
In case of skin contact
Wash immediately with: Water and soap .
After eye contact
Remove contact lenses, if present and easy to do. Continue rinsing. Wash with plenty of water. Call a physician immediately.
After ingestion
Do NOT induce vomiting. Observe risk of aspiration if vomiting occurs. Call a physician immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
Respiratory complaints , Headache , Dizziness , Nausea .
4.3 Indication of any immediate medical attention and special treatment needed
None

SECTION 5: Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media
Water spray jet , Foam , Extinguishing powder , Carbon dioxide (CO2) , Sand .
Co-ordinate fire-fighting measures to the fire surroundings.
Unsuitable extinguishing media
Full water jet .
5.2 Special hazards arising from the substance or mixture
Hazardous combustion products
Carbon dioxide (CO2) , Nitrogen oxides (NOx). Sulphur oxides Carbon monoxide.

Page : 2 / 7
( EN / ROK )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : rhenus EHM 10


Revision date : 13.02.2014 Version (Revision) : 2.2.0 (2.1.0)
Print date : 30.06.2015

5.3 Advice for firefighters


Special protective equipment for firefighters
Use suitable breathing apparatus.
5.4 Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Provide fresh air.
Avoid contact with skin, eyes and clothes.
Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to chemical a gents at
work
6.2 Environmental precautions
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
6.3 Methods and material for containment and cleaning up
Special danger of slipping by leaking/spilling product. Take up mechanically. Disposal: see section 13 .
6.4 Reference to other sections
None

SECTION 7: Handling and storage

7.1 Precautions for safe handling


No hazardous reaction when handled and stored according to provisions. ( Health hazards : None ) . Avoid contact with skin, e yes and
clothes.
Do not breathe vapour/aerosol. Provide fresh air.
Respiratory protection necessary at: Generation/formation of aerosols , insufficient ventilation , insufficient exhaust .
Protective measures
Measures to prevent aerosol and dust generation
If local exhaust ventilation is not possible or not sufficient, the entire working area should be ventilated by technical means.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Dispose according to legislation. Do not allow to enter into surface water or drains.
Hints on joint storage
Possibility of hazardous reactions : Oxidising agent .
Further information on storage conditions
Keep/Store only in original container. Notice the directions for use on the label.
Do not store at temperatures below : 0 °C .
Recommended storage temperature : 5 °C - 40 °C .
Protect against : Protect against direct sunlight. Keep away from heat.
Storage stability : 24 months ( 5 °C - 40 °C ) .
7.3 Specific end use(s)
None

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


None
8.2 Exposure controls

Page : 3 / 7
( EN / ROK )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : rhenus EHM 10


Revision date : 13.02.2014 Version (Revision) : 2.2.0 (2.1.0)
Print date : 30.06.2015

Appropriate engineering controls


See protective measures under point 7 and 8.
Personal protection equipment
General health and safety measures No special measures are necessary.
Eye/face protection
Additional eye protection measures : Wear eye/face protection.
Skin protection
Hand protection
Tested protective gloves must be worn Breakthrough time (maximum wearing time) : 4 hours ( NBR (Nitrile rubber) , Thickness of
the glove material : 0,4 mm ) . See information supplied by the manufacturer.
Respiratory protection
If technical exhaust or ventilation measures are not possible or insufficient, respiratory protection must be worn.
General health and safety measures
Avoid contact with skin, eyes and clothes. Remove contaminated, saturated clothing immediately. Wash hands before breaks and
after work. Keep away from food, drink and animal feeding stuffs. Directive 98/24/EC of 7 April 1998 on the protection of the health
and safety of workers from the risks related to chemical agents at work

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Appearance
liquid
Colour : colourless to light yellow
Odour
characteristic
Safety relevant basis data
Flash point : > 170 °C
formation of explosive
Danger of explosion:
mixture possible
Density : ( 20 °C ) ca. 0,828 g/cm3 DIN 51757
Solubility in / Miscibility with Water: Insoluble
pH value : ( 23 °C / 50 g/l ) not applicable DIN 51 369
Viscosity kinematic: ( 40 °C ) 10,2 mm2/s DIN 51562
9.2 Other information
None

SECTION 10: Stability and reactivity

10.1 Reactivity
No information available.
10.2 Chemical stability
No information available.
10.3 Possibility of hazardous reactions
No information available.
10.4 Conditions to avoid
Stable under recommended storage and handling conditions (See section 7).
10.5 Incompatible materials
Oxidising agent, strong.
10.6 Hazardous decomposition products
Does not decompose when used for intended uses. Thermal decomposition can lead to the escape of irritating gases and vapours.

Page : 4 / 7
( EN / ROK )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : rhenus EHM 10


Revision date : 13.02.2014 Version (Revision) : 2.2.0 (2.1.0)
Print date : 30.06.2015

Hazardous decomposition products : Carbon monoxide. Carbon dioxide (CO2). aldehydes. Ketone , Sulphur oxides , Nitrogen oxides
(NOx).

SECTION 11: Toxicological information

11.1 Information on toxicological effects


Irritant and corrosive effects
Repeated exposure may cause skin dryness or cracking. After eye contact : Irritation to eyes .
Primary irritation to the skin
Practical experience/human evidence
No hazardous reaction when handled and stored according to provisions. ( Health hazards : None known. )
Sensitisation
No information available.

SECTION 12: Ecological information

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
12.1 Toxicity
No information available.
12.2 Persistence and degradability
No information available.
12.3 Bioaccumulative potential
No information available.
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB assessment
No information available.
12.6 Other adverse effects
No information available.
12.7 Further ecological information
None

SECTION 13: Disposal considerations

Do not allow to enter into surface water or drains.


13.1 Waste treatment methods
Product/Packaging disposal
Waste treatment options
Appropriate disposal / Product
ASN 12 01 07: mineral-based machining oils free of halogens (except emulsions and solutions).
Appropriate disposal / Package
Contaminated packages must be completely emptied and can be re-used following proper cleaning. Completely emptied packages
can be recycled. Packing which cannot be properly cleaned must be disposed of. Handle contaminated packages in the same way
as the substance itself.
Other disposal recommendations
Dispose according to legislation. Do not allow to enter into surface water or drains.

SECTION 14: Transport information

14.1 UN number

Page : 5 / 7
( EN / ROK )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : rhenus EHM 10


Revision date : 13.02.2014 Version (Revision) : 2.2.0 (2.1.0)
Print date : 30.06.2015

No dangerous goods in sense of this transport regulation.


14.2 UN proper shipping name
No dangerous goods in sense of this transport regulation.
14.3 Transport hazard class(es)
No dangerous goods in sense of this transport regulation.
14.4 Packing group
No dangerous goods in sense of this transport regulation.
14.5 Environmental hazards
No dangerous goods in sense of this transport regulation.
14.6 Special precautions for user
None
14.8 Additional information
No dangerous goods in sense of these transport regulations.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation
REACH Regulation – the European Parliament and Council Regulation (EC) No 1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals
CLP Regulation – the European Parliament and Council Regulation (EC) No 1272/2008 concerning reclassification, labelling and
packaging of substances and mixtures
Classification for mixtures and used evaluation method according to regulation (EC) 1272/2008 [CLP] .
15.2 Chemical Safety Assessment
No information available.

SECTION 16: Other information

For further information refer to our technical data sheet.


16.1 Indication of changes
02. Classification of the substance or mixture · 02. Label elements · 02. Labelling according to Regulation (EC) No. 1272/200 8 [CLP] ·
02. Labelling according to Regulation (EC) No. 1272/2008 [CLP] - Hazard components for labelling · 03. Hazardous ingredients
16.2 Abbreviations and acronyms
None
16.3 Key literature references and sources for data
None
16.4 Relevant H- and EUH-phrases (Number and full text)
H304 May be fatal if swallowed and enters airways.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.
16.5 Training advice
None
16.6 Additional information
Please refer to our internet website for more information: www.rhenuslub.com

The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The
information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storag e, processing,
transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the
case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

Page : 6 / 7
( EN / ROK )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : rhenus EHM 10


Revision date : 13.02.2014 Version (Revision) : 2.2.0 (2.1.0)
Print date : 30.06.2015

Page : 7 / 7
( EN / ROK )

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