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Bleaching

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Bleaching

Bleaching: Bleaching is a chemical process which removes the natural


color of Textile fibers. The fiber/yarns/ fabric become permanent white.

Objective of Bleaching
 It removes the natural color from textile materials.
 It brings the textile materials permanent white.
 Improve the absorbency of the textile materials.
 Produce textile materials for the next process.
 Some fabrics are sold as bleached goods.

The bleaching process can be divided into two processes depending on the bleaching
agent:

1. Bleaching by Oxidizing agents


2. Bleaching by Reducing agents

Oxidizing bleaching agents


 Chlorine gas
 Bleaching powder {Ca(OCl)Cl
 Sodium hypo-chloride (Na2OCl)
 Calcium hypo-chloride {Ca(OCl)2}
 Potassium di-chromate (K2Cr2O7)
 Sodium di-chromate (Na2Cr2)
 Potassium permanganate ( KMnO4)
 Potassium Chlorate (KClO3)
 Sodium peroxide (Na2O2)

Reducing bleaching agents


 Hydrogen (H2)
 Carbon (C)
 Carbon mono oxide
 Hydrogen sulfide (H2S)
 Sulphur dioxide(SO2)
 Ferrous sulphate (FeSO4)
 Titenous chloride(TiCl2)
 Sodium Sulphate (Na2SO4
The bleaching agents mentioned above all are not used only the bleaching
process. Some bleaching agents are very costly. Some agents cannot
bleach completely. Reducing bleaching agents only used for protein fibers.
Hydrogen peroxide can bleach all kinds of fibers. So, it is called universal bleaching
agents.

Oxidizing bleaching agents


Oxidizing agents generally are used for cellulosic fibers. If reducing agents
are used then after bleaching when fabrics come in contact with air they
become yellowish or reddish that is come back to the original color. But
oxidizing agents bleach goods free from this defect. So, goods become
permanent white. Therefore Oxidizing bleaching agents are generally
favored.

Reducing bleaching agents

Protein fibers wool and silk generally bleached with reducing bleaching
agents. Because chlorine present in oxidizing agents damages proteins
fibers without bleaching action. This is why animal fibers are bleached with
reducing agents.

Fiber types choice the bleaching process to be used. Generally, need


basis bleaching is made may be half bleach or full bleaching.

Factors considered in the bleaching process


 Concentration of chemicals
 Liquor ratio (L: R)
 pH of the chemical solution.
 Time of treatment.

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