VITEEE 2021 Question Paper

Vellore Institute of Technology Engineering Entrance Examination

Download more VITEEE Previous Year Question Papers: Click Here

 VITEEE
SOLVED PAPER nĀnĆ
(memory based)
GENERAL INSTRUCTIONS
• This question paper contains total 80 questions divided into four parts :
Part I : Physics Q. No - 1 to 25
Part II : Chemistry Q. No - 26 to 50
Part III : Mathematics Q. No - 51 to 75
Part IV : English & Logical reasoning Q. No - 76 to 80
• All questions are multiple choice questions with four options, only one of them is correct.
• For each correct response, the candidate will get 1 mark.
• There is no negative marking for the wrong answer.
• The test is of 1½ hours duration.

PART - I (PHYSICS) r2 - r1
(a) r2 + r2 (b)
1. The distance of the centres of moon and earth is r1r2
D. The mass of earth is 81 times the mass of the
moon. At what distance from the centre of the r1r2
earth, the gravitational force will be zero?
(c) r2 - r1
(d) r12 + r22
D 2D
(a) (b) 5. A charge q is moving with a velocity v parallel to
2 3 a magnetic field B. Force on the charge due to
4D 9D
(c) (d) magnetic field is
3 10
(a) q v B (b) q B/v
2. Two wires A and B are of the same material. Their
lengths are in the ratio of 1 : 2 and the diameter (c) zero (d) B v/q
are in the ratio 2 : 1. If they are pulled by the 6. Two spheres A and B of masses m and 2m and
same force, then increase in length will be in the radii 2R and R respectively are placed in contact
ratio of as shown. The COM of the system lies
(a) 2 : 1 (b) 1 : 4
(c) 1 : 8 (d) 8 : 1 A
3. If x = at + bt2, where x is the distance travelled B
by the body in kilometers while t is the time in 2R R
seconds, then the unit of b is
(a) km/s (b) kms
(c) km/s2 (d) kms2
(a) inside A
4. A soap bubble of radius r1 is placed on another
(b) inside B
soap bubble of radius r2 (r1 < r2). The radius R
(c) at the point of contact
of the soapy film separating the two bubbles is
(d) None of these
7. Identify the correct statement. 14. A sphere rolls down on an inclined plane of
(a) Static friction depends on the area of inclination q. What is the acceleration as the
contact sphere reaches the bottom?
(b) Kinetic friction depends on the area of 5 3
contact (a) g sin q (b) g sin q
7 5
(c) Coefficient of kinetic friction is more than
the coefficient of static friction 2 2
(c) g sin q (d) g sin q
(d) Coefficient of kinetic friction is less than 7 5
the coefficient of static friction 15. A given ray of light suffers minimum deviation
8. The distance travelled by a particle starting from in an equilateral prism P. Additional prisms Q
4 and R of identical shape and of same material as
rest and moving with an acceleration ms-2 , in that of P are now combined as shown in figure.
3
the third second is: The ray will now suffer
(a) 6 m (b) 4 m
10 19 Q
(c) m (d) m
3 3
9. Photoelectric work function of a metal is 1eV. P R

Light of wavelength l = 3000 Å falls on it. The

photo electrons come out with a maximum (a) greater deviation
velocity of : (b) no deviation
(a) 10 metres/sec (b) 102 metres/sec (c) same deviation as before
4
(c) 10 metres/sec (d) 106 metres/sec (d) total internal reflection
10. The coefficient of apparent expansion of mercury 16. The current in the 1W resistor shown in the
in a glass vessel is 153 × 10–6/ºC and in a steel circuit is
vessel is 144 × 10–6/ºC. If a for steel is 12 × 10–
6/ºC , then that of glass is 4W
(a) 9 × 10–6/ºC (b) 6 × 10–6/ºC
–6 1W
(c) 36 × 10 /ºC (d) 27 × 10–6/ºC 6V

11. A step-up transformer operates on a 230 V line 4W

and supplies a load of 2 ampere. The ratio of
the primary and secondary windings is 1 : 25. 2
The current in the primary is (a) A (b) 3A
3
(a) 15 A (b) 50 A
(c) 25 A (d) 12.5 A (c) 6 A (d) 2A
12. Two bodies of same mass are projected with the 17. The root mean square velocity of hydrogen
same velocity at an angle 30° and 60° molecules at 300 K is 1930 metre/sec. Then the
respectively. The ratio of their horizontal ranges r.m.s velocity of oxygen molecules at 1200 K will
will be be
(a) 1 : 1 (b) 1 : 2 (a) 482.5 metre/sec (b) 965 metre/sec
(c) 1930 metre/sec (d) 3860 metre/sec
(c) 1 : 3 (d) 2 : 2 18. Lenz’s law gives
13. Two point charges +3µC and +8µC repel each (a) the magnitude of the induced e.m.f.
other with a force of 40N. If a charge of –5µC is (b) the direction of the induced current
added to each of them, then the force between (c) both the magnitude and direction of the
them will become induced current
(a) –10N (b) +10N (d) the magnitude of the induced current
(c) +20N (d) –20N
 3

19. A parallel plate capacitor with air between the 25. A source producing sound of frequency 170 Hz
plates has a capacitance of 8 pF. Calculate the is approaching a stationary observer with a
capacitance if the distance between the plates is velocity 17 ms–1. The apparent change in the
reduced by half and the space between them is wavelength of sound heard by the observer is
filled with a substance of dielectric constant. (k (speed of sound in air = 340 ms–1)
= 6)
(a) 0.1 m (b) 0.2 m
(a) 72 pF (b) 81 pF
(c) 84 pF (d) 96 pF (c) 0.4 m (d) 0.5 m
20. For a particle executing S.H.M. the displacement
x is given by x = A cos wt. Identify the graph
PART - II (CHEMISTRY)
which represents the variation of potential 26. Consider the following reactions:
energy (P.E.) as a function of time t and NaCl + K2Cr2O7 + H2SO4 (Conc.)
displacement x. ® (A) + Side products
(A) + NaOH ® (B) + Side products
(B) + H2SO4 (dilute) + H2O2
® (C) + Side products
The sum of the total number of atoms in one
(a) I, III (b) II, IV molecule each of (A), (B) and (C) is ________.
(c) II, III (d) I, IV (a) 18 (b) 15
21. A radioactive sample contains 10–3 kg each of (c) 21 (d) 20
two nuclear species A and B with half-life 4 days 27. Xenon hexafluoride on partial hydrolysis
and 8 days respectively. The ratio of the amounts produces compounds 'X' and 'Y'. Compounds
of A and B after a period of 16 days is 'X', 'Y' and the oxidation state of Xe are
(a) 1 : 2 (b) 4 : 1 respectively :
(c) 1 : 4 (d) 2 : 1 (a) XeOF4(+6) and XeO3(+6)
22. A string of 7 m length has a mass of 0.035 kg. If (b) XeO2(+4) and XeO3(+6)
tension in the string is 60.5 N, then speed of a (c) XeOF4(+6) and XeO2F2(+6)
wave on the string is (d) XeO2F2(+6) and XeO2(+4)
(a) 77 m/s (b) 102 m/s 28. The edge length of unit cell of a metal having
(c) 110 m/s (d) 165 m/s molecular weight 75 g/mol is 5Å which
23. The following circut represents crystallizes in cubic lattice. If the density is 2g/
A
cc then find the radius of metal atom.
(NA = 6 × 1023). Give the answer in pm.
Y (a) 217 pm (b) 210 pm
(c) 220 pm (d) 205 pm
B
29. Consider the following statements:
(a) OR gate (b) AND gate I. Increase in concentration of reactant
(c) NAND gate (d) None of these increases the rate of a zero order reaction.
24. A straight section PQ of a circuit lies along the II. Rate constant k is equal to collision
a a frequency A if Ea = 0.
X-axis from x = - to x = and carries a
2 2 III. Rate constant k is equal to collision
steady current i. The magnetic field due to the frequency A if Ea = ¥.
section PQ at a point X = + a will be IV. In k vs T is a straight line.
(a) proportional to a V. In k vs 1/T is a straight line.
(b) proportional to a2 Correct statements are
(c) proportional to 1/a (a) I and IV (b) II and V
(d) zero (c) III and IV (d) II and III
30. To deposit 0.634 g of copper by electrolysis of 35. Secondary structure of protein refers to
aqueous cupric sulphate solution, the amount (a) mainly denatured proteins and structure of
of electricity required (in coulombs) is prosthetic groups
(b) three -dimensional structure, especially the
(a) 1930 (b) 3960 bond between amino acid residues that are
(c) 4825 (d) 9650 distinct from each other in the polypeptide
31. In the following skew conformation of ethane, chain
(c) linear sequence of amino acid residues in
H¢ – C – C – H¢¢ dihedral angle is : the polypetide chain
(d) regular folding patterns of continous
portions of the polypeptide chain
36. The increasing order for the values of e/m
(charge/mass) is
(a) e, p, n, a (b) n, p, e, a
(c) n, p, a, e (d) n, a, p, e
37. In which of the following pairs both the ions are
coloured in aqueous solutions ?
(a) Sc3+, Ti3+ (b) Sc3+, Co2+
(a) 58o (b) 149o
(c) Ni2+, Cu+ (d) Ni2+, Ti3+
(c) 151o (d) 120o 38. The total number of possible isomers for square-
32. What is the product of following reaction? planar [Pt(Cl)(NO2)(NO3)(SCN)]2– is:
(i) NaBH (a) 16 (b) 12
Hex-3-ynal ¾¾¾¾¾¾¾¾¾¾¾¾¾¾ ®?
4
(ii) PBr , (iii) Mg/ether, (iv) CO /H O +
3 2 3
(c) 8 (d) 24
39. For the reaction,
(a) COOH
ˆˆ† 2 SO3(g),
2SO2(g) + O2(g) ‡ˆˆ
(b) COOH
DH = – 57.2 kJ mol–1 and Kc = 1.7×1016
(c) COOH
Which of the following statement is
(d) COOH INCORRECT ?
33. In the following sequence of reactions, (a) The equilibrium constant is large
suggestive of reaction going to completion
and so no catalyst is required.
P +I Mg HCHO
CH 3CH 2 OH ¾¾¾
2 ® A ¾¾¾® B ¾¾¾¾
® (b) The equilibrium will shift in forward
ether
direction as the pressure increases.
H O
C ¾¾¾
2 ®D
(c) The equilibrium constant decreases as the
the compound D is temperature increases.
(a) propanal (b) butanal (d) The addition of inert gas at constant
(c) n-butyl alcohol (d) n-propyl alcohol. volume will not affect the equilibrium
34. Which of the following reactions can produce constant.
aniline as main product? 40. The half-life of a reaction is inversely
(a) C6H5NO2 + Zn/KOH proportional to the square of the initial
(b) C6H5NO2 + Zn/NH4Cl concentration of the reactant. Then the order of
the reaction is
(c) C6H5NO2 + LiAlH4
(a) 0 (b) 1
(d) C6H5NO2 + Zn/HCl
(c) 2 (d) 3
 5

41. A galvanic cell is set up from electrodes A and B 44. What will be the final product in the following
2-
Cr2O 7 / Cr 3 + ,
Electrode A : o = + 1.33 V reaction sequence –
Ered
3+ 2+ , o H + /H O NH NaOBr
Electrode B : Fe / Fe Ered = 0.77 V CH3CH2CN ¾¾¾¾®
2 A ¾¾¾
3 ® B ¾¾¾¾
®C
D
Which of the following statements is false ? (a) CH3CH2CONH2
(a) Standard e.m.f of the cell is 0.56 V (b) CH3CH2COBr
(b) Current will flow from electrode A to B in (c) CH3CH2NH2
the external circuit (d) CH3CH2CH2NH2
(c) A will act as cathode and have positive 45. In a set of reactions acetic acid yielded a product
polarity D.
(d) None of these
SOCl Benzene
42. Keto-enol tautomerism is observed in : CH3COOH ¾¾¾¾
2 ® (A) ¾¾¾¾® (B)
AlCl3
O O
|| || HCN HOH
(a) H5C6 – C – CH2 – C – C6H5 ¾¾¾® (C) ¾¾¾® (D)
The structure of (D) would be –
O
|| COOH
(b) H5C6 – C – CH3
CH2 – C – CH3
O (a)
|| OH
(c) H5C6 – C – H
(d) Both (a) and (b) CN
43. In a set of reactions, ethylbenzene yield a product
D. C – CH3
CH2CH3 (b)
KMnO Br OH
¾¾¾¾
4
® B ¾¾¾®
2
KOH FeCl3
C H OH OH
C ¾¾¾¾®
2 5
+ D
H
Identify D : CH2 – C – CH3
(c)
CH2 – CH – COOC 2H 5 CN
(a)
Br OH
Br
C – COOH
(d)
(b) CH3
Br 46. In fructose, the possible optical isomers are
CH2 COOC2H5 (a) 12 (b) 8
COOH (c) 16 (d) 4
47. The position of both, an electron and a helium
atom is known within 1.0 nm. Further the
(c) momentum of the electron is known within 5.0
OCH2CH3 × 10–26 kg ms–1. The minimum uncertainty in
COOC2H5 the measurement of the momentum of the
helium atom is
(a) 50 kg ms–1 (b) 80 kg ms–1
(d) (c) 8.0 × 10 kg ms (d) 5.0 × 10–26 kg ms–1
–26 –1
Br
48. ˆˆ† B
The value of log10 K for a reaction A ‡ˆˆ x x
is 55. If f ( x ) = x + + + ...to ¥ , then at
1 + x (1 + x ) 2
(Given : D r H °298K = -54.07 kJ mol- 1 ,
x = 0, f(x)
D r S°298K –1 –1
= 10 JK mol and R = 8.314 JK –1 (a) has no limit
mol ; –1 (b) is discontinuous
2.303 × 8.314 × 298 = 5705) (c) is continuous but not differentiable
(a) 5 (b) 10 (d) is differentiable
(c) 95 (d) 100 56. Radius of the circle (x + 5)2 + (y – 3)2 = 36 is
(a) 2 (b) 3
49. ® CO2(g); DH = R and
If C(s) + O2(g) ¾¾
(c) 6 (d) 5
1 ® ®
CO(g) + O2 (g) ¾¾ ® CO2 (g); DH = S, ®
2 57. If a = 2iˆ – 2 ˆj + kˆ and c = –iˆ + 2kˆ then | c | .
then heat of formation of CO is:
(a) R + S (b) R – S a is equal to :
(c) R × S (d) S – R (a) 2 5 iˆ + 2 5 ˆj + 5 kˆ
50. Which of the following compounds does not
(b) 2 5 iˆ – 2 5 ˆj + 5 kˆ
follow Markownikoff’s law ?
(a) CH3CH = CH2 (b) CH2CHCl (c) 5 iˆ + 5 ˆj + 5 kˆ
(c) CH3CH = CHCH3 (d) None
(d) 5 iˆ + 2 5 ˆj + 5 kˆ
PART - III (MATHEMATICS) 58. If (– 4, 5) is one vertex and 7x – y + 8 = 0 is one
51. The value of c in Rolle’s Theorem for the diagonal of a square, then the equation of second
function f(x) = ex sinx, x Î [0, p] is diagonal is
(a) x + 3y = 21 (b) 2x – 3y = 7
p p
(a) (b) (c) x + 7y = 31 (d) 2x + 3y = 21
6 4 59. p Þ q can also be written as
p 3p (a) p Þ ~ q (b) ~ p Úq
(c) (d)
2 4
52. The equations 2x + 3y + 4 = 0; 3x + 4y + 6 = 0 and (c) ~ q Þ ~ p (d) None of these
4x + 5y + 8 = 0 are
x1 / 2
ò
2
(a) consistent with unique solution 60. Let dx = gof ( x) + C , then
(b) inconsistent 1 - x3 3
(c) consistent with infinitely many solutions
(d) None of the above (a) f ( x) = x
53. The shortest distance between the lines (b) f (x) = x3/2 and g(x) = sin –1x
x = y + 2 = 6z – 6 and x + 1 = 2y = – 12z is (c) f (x) = x2/3
1 (d) None of these
(a) (b) 2 61. Which one of the following is an infinite set ?
2
(a) The set of human beings on the earth
3 (b) The set of water drops in a glass of water
(c) 1 (d)
2 (c) The set of trees in a forest
54. If the tangent at P(1, 1) on y2 = x(2 – x)2 meets (d) The set of all primes
the curve again at Q, then Q is 62. The domain of the function
(a) (2, 2) (b) (– 1, – 2)
x 2 - 5x + 6 + 2 x + 8 - x is
2
æ 9 3ö (a) [2, 3] (b) [–2, 4]
(c) ç , ÷ (d) None of these
è 4 8ø (c) [–2, 2] È [3, 4] (d) [–2, 1] È [2, 4]
 7

63. Area bounded by the curve y = log x and the 70. In a culture the bacteria count is 1,00,000. The
coordinate axes is number is increased by 10% in 2 hours. In how
(a) 2 (b) 1 many hours will the count reach 2,00,000 if the
(c) 5 (d) 2 2 rate of growth of bacteria is proportional to the
number present.
64. The angle of intersection to the curve y = x2,
6y = 7 – x3 at (1, 1) is : 2 2 log 2
(a) (b)
p p log
11 æ 11 ö
log ç ÷
(a) (b) 10 è 10 ø
2 4
log 2 log 2
p (c) (d)
(c) (d) p log11 æ 11 ö
3 log ç ÷
è 10 ø
65. Angle formed by the positive Y-axis and the
71. What is the angle between the two straight lines
æ 5 -3 ö y = (2 - 3 )x + 5 and y = (2 + 3) x - 7 ?
tangent to y = x 2 + 4 x - 17 at çè , ÷ø is
2 4
(a) 60° (b) 45°
p
(a) tan -1 9 (b) - tan -1 9 (c) 30° (d)
15°
2 x +1 y -1
72. If the angle q between the line =
p p z -2
1 2
(c) + tan -1 9 (d) = and the plane 2x – y + l z + 4 = 0 is
2 2 2
1
4 such that sin q = then the value of l is
æ 1ö 3
66. The value of (1 + i)4 ç 1 + ÷ is 5 -3
è iø (a) (b)
3 5
(a) 12 (b) 2
3 -4
(c) 8 (d) 16 (c) (d)
67. The relation R defined on the set A = {1, 2, 3, 4 3
4, 5} by R = {(x, y) : |x2 – y2 | < 16} is given by 73. The distance of the point (–5, –5, –10) from the
(a) {(1, 1), (2, 1), (3, 1), (4, 1), (2, 3)} point of intersection of the line
(b) {(2, 2), (3, 2), (4, 2), (2, 4)} r .= 2iˆ - ˆj + 2kˆ + l ( 3iˆ + 4ˆj + 2kˆ ) and the plane
(c) {(3, 3), (4, 3), (5, 4), (3, 4)}
(d) None of these r · ( ˆi - ˆj + kˆ ) = 5 is
(a) 13 (b) 12
2dx
68. ò (ex + e- x )2 = (c) 4 15 (d) 10 2
log p æ1 ö
(a)
-e - x
+C (b)
-1
+C
74. òlog p2
e 2 x sec 2 ç e 2 x ÷ dx is equal to :
è 3 ø
(e x + e - x ) (e x + e - x )
1
1 (a) 3 (b)
1 3
(c) +C (d) +C
x
(e + 1) 2 (e x + e - x ) 3 3 1
69. The value of tan–1(1) + tan–1(0) + tan–1(2) + tan–1 (3) (c) (d)
2 2 3
is equal to
x+3 +x
5p 75. If > 1, then x Î
(a) p (b) x+2
4
(a) (–5, –2) (b) (–1, ¥)
p (c) (–5, –2) È (–1, ¥) (d) None of these
(c) (d) None of these
2
 77. Which of the following is the main subject of
PART - IV (ENGLISH & LOGICAL the passage?
REASIONING) (a) preparing for hazmat certification
Directions (76-78): Study the paragraph and answer (b) the main goal of F.A.S.T.
the questions that follow. (c) completing F.A.S.T. membership
requirements
A training calendar and schedule for Fire Agency
Specialties Team (F.A.S.T.) membership is available (d) learning about your department's F.A.S.T.
in this office to all applicants for F.A.S.T. membership. membership
Training will take place the third week of each 78. Applicants must be available for training
month. Classes will be taught on Monday afternoons, (a) three days each month.
Wednesday evenings, and Saturday afternoons. (b) three days each week.
So that the F.A.S.T. can maintain a high level of (c) every third month.
efficiency and preparedness for emergency response (d) for 50% of classes.
situations, its members must meet certain 79. Jatin starting from a fixed point, goes 15 m
requirements. towards North and then after turning to his
First, in order for you to be considered for right, he goes 15 m. Then, he goes 10 m, 15 m
membership on F.A.S.T., your department must be a and 15 m after turning to his left each time.
member of the F.A.S.T. organization, and you must How far is he from his starting point ?
have written permission from your fire chief or your (a) 15 m (b) 5m
department's highest ranking administrator. (c) 10 m (d) 20 m
Once active, you must meet further requirements to 80. Examine the following statements:
maintain active status. These include completion of
technician-level training and certification in 1. All members of Mohan’s family are
hazardous material (hazmat) operations. In addition, honest.
after becoming a member, you must also attend a 2. Some members of Mohan’s family are not
minimum of 50% of all drills conducted by F.A.S.T. employed.
and go to at least one F.A.S.T. conference. You may 3. Some employed persons are not honest.
qualify for alternative credit for drills by proving 4. Some honest persons are not employed.
previous experience in actual hazmat emergency Which one of the following inferences can be
response. drawn from the above statements?
If you fail to meet minimum requirements, you will be (a) All members of Mohan’s family are
considered inactive, and the director of your team employed
will be notified. You will be placed back on active (b) The employed members of Mohan’s family
status only after you complete the training necessary are honest
to meet the minimum requirements. (c) The honest members of Mohan’s family
76. Potential F.A.S.T. members can attend less are not employed
than half of F.A.S.T. drills if they (d) The employed member of Mohan’s family
(a) complete technician-level training are not honest
requirements.
(b) indicate prior real emergency experience.
(c) receive permission from their fire chief.
(d) enroll in three weekly training sessions.
 9

SOLUTIONS
PART - I (PHYSICS) (6.6 ´ 10-34 )(3 ´ 108 )
\
3000 ´10-10
Gme Gmm
1. (d) = 1
x 2 ( D - x )2 = (1.6 ´10-19 ) + ´ (9.1´10-31 )v 2
2
G (81m) m
or = Solving we get, v @ 10 6 m/s
x2 ( D - x )2 x D
10. (a) g real = g app. + g vessel
9D
\ x=
10
.
So (g app. + g vessel )glass = (g app + g vessel )steel
2. (c) We know that Young's modulus -6
Þ 153 ´10 + ( g vessel )glass
FL
Y= ´ = 144 ´10-6 + ( g vessel )steel
2 l
pr
Since Y, F are same for both the wires, we Further,
have, ( g vessel )steel = 3a = 3 ´ (12 ´10-6 )
1 L1 1 L 2 l 1 r22 ´ L1 = 36 ´ 10-6 / °C
= or, = =
r12 l 1 r22 l 2 l 2 r12 ´ L 2 Þ 153 ´10-6 + ( g vessel )glass

(D 2 / 2) 2 ´ L1 = 144 ´ 10 -6 + 36 ´ 10 -6
(D1 / 2) 2 ´ L 2 Þ ( g vessel )glass = 3a = 27 ´10-6 / °C

l 1 D 22 ´ L1 D 22 L 1 Þ a = 9 ´ 10 -6 / °C
or, = = ´ 2 = 11. (b)
l 2 D12 ´ L 2 (2 D 2 ) 2 2 L 2 8
12. (a) Horizontal range is same when angle of
So, l1 : l2 = 1:8 projection is q or (90° – q).
3. (c) [x] = [bt2]. Hence [b] = [x /t2] = km/s2. 13. (a)
4. (c)
g sin q g sin q 5
5. (c) 14. (a) a= 2
= = g sin q
6. (c) As mass of B is twice that of A. K 2 7
1+ 1+
r1 m 2 R2 5
And, = 15. (c) When the ray suffers minimum deviation, it
r2 m1
becomes parallel to the base of prism P. As
7. (d) mk < ms coefficient of static friction is always prisms Q and R are of same material and
greater than kinetic friction. have identical shape, therefore, the ray
8. (c) Distance travelled in the nth second is continues to be parallel to base of Q and R.
a
given by dn = u + (2n - 1) Hence final deviation of the ray remains the
2 same as before.
4 -2
put u = 0, a = ms , n = 3 Q
3
4 4 10
\ d= 0 + (2 × 3 –1) = ´ 5 = m P R
3´ 2 6 3
1 2 hc 1 16. (d) Two 4W resistors are in parallel
9. (d) hn = W + mv or = W + mv 2 combination. Their equivalent resistance
2 l 2
Here l = 3000 Å = 3000 × 10–10 m 4 ´ 4 16
= = = 2W
and W = 1 eV = 1.6 × 10–19 joule 4+4 8
 4W 1 1
= : = 22 : 24
4W
24 22
= 4 : 16, = 1 : 4
22. (c) Given : Length (l) = 7 m
Mass (M) = 0.035 kg and tension (T) = 60.5
1W 6v N. We know that mass of string per unit
\ Total resistance of the network = 2 + 1 = length (m)
3W 0.035
= = 0.005 kg / m
7
6
\ Current through 1W resistor = = 2A and speed of
3
T 60.5
17. (b) Root-mean square-velocity is given by wave = = = 110 m / s .
m 0.005
v rms =
3RT æTö
i.e., v rms µ ç ÷ 23. (d) Output of upper AND gate = AB
M èMø
Output of lower AND gate = AB
é TO M H2 ù
(v rms )O 2
= ê 2´ ú \ Output of OR gate, Y = A B + BA
( v rms )H 2 êë TH 2 M O 2 úû This is boolean expression for XOR gate.
24. (d) Magnetic field at a point on the axis of a
éæ 1200 ö æ 2 öù 1 current carrying wire is always zero.
= êç ÷ ´ ç ÷ú = Y
ëè 300 ø è 32 øû 2
1 1930 P i Q
\ ( v rms )O 2 = ( v rms )H 2 ´ = = M
2 2
965 m/s a a
x=- x=
18. (b) Lenz’s law helps to identify the direction of 2 2
induced current. x a
19. (d) Capacity of parallel plate capacitor v 340 340
25. (a) l= = = 2m, n ' = ´ 170
ke A n 170 340 - 17
C= 0 (For air kr = 1)
d n ' = 178.9 Hz
e0 A v 340
So, = 8 ´10-12 Now = l' ==1.9
d n ' 178.9
d Þ l - l ' = 2 - 1.9 = 0.1m
If d ® and kr ® 6 then new capacitance
2 PART - II (CHEMISTRY)
e0 A e0 A
C' = 6 × = 12 = 12 × 8 pF = 96 pF 26. (a) 4NaCl + K2Cr2O4 + 3H2SO4 ¾® 2CrO2Cl2
d/2 d
20. (a) In x = A cos wt , the particle starts oscillating + K2SO4
from extreme position. So at t = 0, its (Conc.) (A)
potential energy is maximum. + 2NaSO4 + 3H2O
21. (c) Ratio of number of half life taken is given CrO2Cl2 + NaOH ¾® Na2CrO4 + H2O + NaCl
as: (A) (B)
After 16 days Na2CrO4 + H2SO4 + H2O2 ¾® CrO5 + Na2SO4 + H2O
16 16 (B) (dilute) (C)
nA1/2 = = 4 ; nB1/2 = =2 The sum of total no. of atoms in one molecules
4 8
n each of A, B & C = 5 + 7 + 6 = 18
æ1ö NA
N = 0ç ÷ Þ N
N partial
+6
è2ø B 27. (c) XeF6 + H 2O ¾¾¾¾¾
® Xe OF4 + 2HF
hydrolysis 'X '
 11

+6
P +I
X eO F4 + H 2 O ¾¾
® Xe O 2 F2 + 2HF 33. (d) CH3CH 2 OH ¾¾¾
2 ® CH CH I
3 2
'X' 'Y' A
ZM
28. (a) r= ¾¾¾®
Mg
NA V Ether
CH 3CH 2 MgI
23 -8 3 (B)
rNA V 2 ´ 6 ´ 10 ´ (5 ´10 )
Z= =
M 75 CH 2 CH 3
Z = 2, which represents bcc structure
HCHO
|
\ r=
3
a=
3
´ 5 = 2.165Å = 216.5 pm » ¾¾¾¾ ® H - C - OMgI
4 4 |
217 pm H
29. (b) According to Arrhenius equation, (C)
k = Ae–Ea/RT
\ when Ea = 0, k = A
Also ln k vs 1/T is a straight line with slope = – CH 2 CH3
Ea/R. H2 O
|
\ Statements (ii) and (v) are correct. ¾¾¾
® H - C - OH
30. (a) In the electrolysis of cupric sulphate, the |
reaction that occurs at cathode is H
Cu 2+ + 2e- ¾¾ ® Cu (D)
n- Propylalcohol
Thus 2F or 2 × 96500 C of electricity is required
to deposit 34. (d) Various products are formed when
= 1 mol of Cu = 63.5 g of Cu nitroarenes are reduced. These are given below
It means that to deposit 63.5 g of Cu, the amount
of electricity required = 2 × 96500 C for C6H5NO2.
So, to deposit 0.634 g of Cu, the amount of Medium Main product
2 ´ 96500 (d) In acidic medium Aniline (C 6 H 5 NH 2 )
electricity required = ´ 0.634
63.5 (metal/HCl)
» 1930 C (b) In neutral medium Phenyl NHOH
31. (b) hydroxylamine, (Zn/NH4Cl)

(a) In alkaline medium

NH NH
Hydrazobenzene
Thus, aniline will be main product in case of (d).
35. (d)
\ Angle between H’ and H’’ = 120° + 29° = 149° e 0
36. (d) for (i) neutron = = 0
32. (d) m 1
2
(ii) a-particle = = 0.5
4
1
(iii) proton = = 1
1
1
(iv) electron = = 1837
1 1837
37. (d) Sc3+ (Z = 18) : 1s2, 2s2p6, 3s2p6d0, 4s0; no
unpaired electron.
Cu+ (Z = 28) : 1s2, 2s2p6, 3s2p6d 10, 4s0; no
unpaired electron.
 Ni2+ (Z = 26) : 1s2, 2s2p6, 3s2p6d 8, 4s0; O O
unpaired electrons are present. || a ||
Ti3+ (Z = 19) : 1s2, 2s2p6, 3s2p6d 1, 4s 0; (a) ˆˆ†
H5 C6 - C - C H 2 - C - C6 H5 ‡ˆˆ
unpaired electron is present keto form
Co2+ (Z = 25) : 1s2, 2s2p6, 3s2p6d 7, 4s0;
O OH
unpaired electrons are present || |
So from the given options the only correct H 5 C6 - C - C = C - C 6 H 5
combination is Ni2+ and Ti3+. |
38. (b) The square planar complex of the type H
enol form
[Mabcd]n±, where all four ligands are different, (b)
has 3 geometrical isomers. But if one of the ligands
O OH
is ambidentate, then 2 × 3 = 6 geometrical isomers || a |
are possible. But if two ligands are ambidentate, ˆˆ† C6 H 5 - C = CH 2
H5C6 - C - C H3 ‡ˆˆ
keto form enol form
then 4 × 3 = 12 geometrical isomers are possible.
In the given example, NO2– and SCN– are O
ambidentate ligands. ||
(c) C6 H5 - C - H
39. (a) Equilibrium constant has no relation with no a- H atom
catalyst. Catalyst only affects the rate of the
CH2 – CH3
reaction.
Catalyst, V2O5 in the given reaction, is used to
43. (d) (i) [O]
¾¾¾¾¾¾¾®
speed up the reaction. (ii) KMnO 4 , KOH
1 COOH
40. (d) t1/2 µ 2
a
1
We know that t1/ 2 µ n -1
a COOH COOC2H5
i.e. n = 3
Thus reaction is of 3rd order. C H OH
¾¾¾®
2 Br ¾¾¾¾
2 5
+
®
41. (d) FeCl 3 H
42. (d) Keto-enol tautomerism is shown by Br Br
carbonyl compounds having a-hydrogen atom.
H + /H O NH
44. (c) CH3CH2CN ¾¾¾¾®
2 CH3CH 2 COOH ¾¾¾
3®
(A) D

Hoffman bromide reaction

CH3CH 2CONH2 ¾¾¾¾¾¾¾¾¾¾
® CH3CH 2 NH 2
(B) NaOBr (C)
O
||
SOCl
45. (d) CH 3 COOH ¾¾¾¾
2® CH3 - C- Cl OH
(A)
Benzene
¾¾¾¾® C – CH3
AlCl3 HOH
¾¾®
O OH COOH
|| (D)
C – CH3 C – CH3 46. (b) Fructose has 3 chiral centres and hence
HCN
¾ ¾® number of optical isomers are 23 = 8
CN
(B) (C)
 13

47. (d) By Heisenberg uncertainty Principle \ x = –2 and y = 0

h Now this solution satisfies all the equations, so
Dx ´ Dp = (which is constant) the equations are consistent with unique
4p
As Dx for electron and helium atom is same thus solution.
momentum of electron and helium will also be x y + 2 z -1
53. (b) The lines are = =
same therefore the momentum of helium atom is 6 6 1
equal to 5 × 10–26 kg. m.s–1. x +1 y z
and = =
ˆˆ† B
48. (b) A ‡ˆˆ 12 6 -1
DG° = D H° – TDS° r r r
Here, a1 = -2jˆ + k,
ˆ b = 6iˆ + 6ˆj + k,
1
ˆ a 2 = -i,
ˆ
DG° = – 2.303 RTlog10 K r
– 2.303 RT log10 K = DH° – TDS° b2 = 12iˆ + 6jˆ - kˆ
2.303 RT log10 K = TDS° – DH° ˆi ˆj k
T DS ° - DH ° r r
log10 K = b1 ´ b 2 = 6 6 1 = -12iˆ + 18ˆj - 36kˆ
2.303RT
298×10 +54.07×1000 12 6 -1
= r r r r
2.303×8.314×298 ( a 2 - a1 ) . ( b1 - b2 )
= 9.998 » 10 Shortest distance = r r
b1 ´ b 2
49. (b) Let, C(s) + O2 (g) ¾¾ ® CO2(g); DH = R
.......... (i) ( -ˆi + 2jˆ - kˆ ) . ( -12i + 18jˆ - 36kˆ )
=
1
and CO(g) + O 2 (g) ¾¾ ® CO2(g); DH = S ( -12)2 + (18)2 + ( -36) 2
2
.......... (ii) +12 + 36 + 36 84
= =2=
Subtracting equ. (i) from equ (ii), we get 1764 42
1 54. (c) y2 = x(2 – x)2 Þ y2 = x3 – 4x2 + 4x ...(i)
C(s) + O 2 (g) ¾¾ ® CO (g); DH = R – S
2 dy dy 3x - 8x + 4 2
Hence, heat of formation of CO = R – S Þ 2y = 3x2 – 8x + 4 Þ =
dx dx 2y
50. (c) Both the doubly bonded carbon atoms are
identical. é dy ù 3-8+ 4 1
Þê ú = =-
ë dx û P 2 2
PART - III (MATHEMATICS)
1
51. (d) Since Rolle’s theorem is satisfied \ Equation of tangent at P is: y – 1 = - (x – 1)
2
c c
\ f ¢(c) = 0 Þ e sinc + e cos c = 0 Þ x + 2y – 3 = 0
3-x
Þ ec {sin c + cos c} = 0 Using y = in (i),
2
(
c
\ sinc + cosc = 0 Q e ¹ 0 ) æ 3- x ö
we get: ç
2
÷ = x3 – 4x2 + 4x
-1 p 3p è 2 ø
Þ tanc = – 1 Þ c = tan ( -1) = p - = Þ 4x3 – 17x2 + 22x – 9 = 0 ...(ii)
4 4
52. (a) Consider first two equations : which has two roots 1, 1
2x + 3y = –4 and 3x + 4y = –6 (Because of (ii) being tangent at (1, 1)).
2 3 17 17 9
We have D = = -1 ¹ 0 Sum of 3 roots = \ 3rd root = –2=
3 4 4 4 4
9
-4 3 2 -4 3- æ 9 3ö
Dx = =2 and Dy = =0 Then, y = 4 = 3 \ Q is ç , ÷
-6 4 3 -6 2 8 è 4 8ø
55. (b) For x ¹ 0 , we have, 61. (d) In the given sets, the set of all primes is an
x /1+ x x /1+ x
infinite set.
f (x) = x + =x+ = x +1
1 x /1+ x 62. (c) f (x) = ( x - 2) ( x - 3) + -( x - 4) ( x + 2)
1-
1+ x The first part is real outside (2, 3) and the second is
ì x + 1, x ¹ 0 real in [–2, 4] so that the domain is [–2, 2] È [3, 4].
For x = 0 , f(x) = 0. Thus, f ( x ) = í 63. (b) Observing the graph of log x, we find that
î 0, x =0 the required area lies below x-axis between x = 0
Clearly, lim f ( x ) = lim f ( x ) = 1 ¹ f (0). and x =1.
x ®0 - x®0+
So, f(x) is discontinuous and hence not differen- Y
tiable at x = 0.
56. (c) Comparing the equation of the circle
( x + 5) 2 + ( y - 3) 2 = 36
(1, 0)
with ( x - h ) 2 + ( y - k ) 2 = r 2
O X
\ –h = 5 or h = –5, k = 3, r2 = 36 Þ r = 6
\ Centre of the circle is (–5, 3) and radius = 6
r r
57. (b) If a = 2iˆ – 2 ˆj + kˆ and c = –iˆ + 2kˆ
r
| c |= (–1)2 + 2 2 = 1 + 4 = 5
r r 1
| c |. a = 5.(2iˆ – 2 ˆj + kˆ)
r r
So required area = ò log x dx 1
= (x log x - x) 0
\ | c |.a = 2 5iˆ – 2 5 ˆj + 5kˆ 0
58. (c) One vertex of square is (– 4, 5) and equation = | – 1| =1
of one diagonal is 7x – y + 8 = 0 64. (a) Let m1 and m2 be slope of curve y = x2 and
Diagonal of a square are perpendicular and bisect 6y = 7 – x3 respectively.
each other
Let the equation of the other diagonal be y = mx dy
+ c where m is the slope of the line and c is the y- Now, y = x2 Þ = 2x
dx
intercept.
æ dy ö
Since this line passes through (– 4, 5) Þ ç ÷ = 2 i.e. m1 = 2
\ 5 = –4m + c … (i) è dx ø (1,1)
Since this line is at right angle to the line
dy
7x – y + 8 = 0 or y = 7x + 8, having slope = 7, and 6y = 7 – x3 Þ 6 = -3x 2
-1 dx
\ 7 × m = – 1 or m= dy 3 1 2
7 Þ = - x2 = - x
dx 6 2
Putting this value of m in equation (i) we get
æ
Þ ç ÷dy ö 1 1
æ -1 ö = - (1)2 = -
5 = -4 ´ ç ÷ + c è dx ø (1,1) 2 2
è 7 ø 1 1
4 4 31 \ m2 = - \ m1 m2 = 2 . - = – 1
or 5 = + c or c = 5 - = 2 2
7 7 7 p
Hence equation of the other diagonal is \ Angle of intersection is 90° i.e.
2
1 31 or 7y = – x + 31
y=- x+ 65. (b) Y
7 7
or x + 7y – 31 = 0 or x + 7y = 31. 0 q X
59. (b) p Þ q º ~ p Ú q P æ 5, - 3ö
3 ç ÷
60. (b) Put x
3/ 2
= t Þ x1 / 2 dx = dt è 2 4ø
2 p
\ integral is -q
2
2
dt
2 2
ò 1 - t 2 = 3 sin -1 t + C = 3 sin -1 (x 3/ 2 ) + C
3
(–2, –21)
 15

y = x 2 + 4 x + 4 - 4 - 17 y
Þ log y = kt + log y0 Þ log = kt ...(iii)
y0
y = ( x + 2) - 21 Þ Vertex is (–2, –21)
2

y = æç y0 + ö 11y0 when t = 2
10
dy y0 ÷ = ,
Also y = x 2 + 4 x - 17 Þ = 2x + 4 è 100 ø 10
dx
11y 0
æ5 3ö
Þ Slope of tangent at ç , - ÷
è2 4ø So, from (iii), we get log 10 = k (2)
y0
dy 5
m= = 2 ´ + 4 = 9 ; q = tan–1 9 1 11
dx 2 Þ k= log ... (iv)
2 10
p
\ angle by y-axis = - tan -1 9 = cot -1 9 y 1 æ
= ç log
11 ö
10 ÷ø
2 Using (iv) in (iii) log t
y0 2è
4 ... (v)
æ 1ö
66. (d) (1 + i)4 × ç 1 + ÷ = (1 + i)4 × (1 – i)4 = 24 let the number of bacteria become 1, 00, 000 to
è iø 2,00,000 in t1 hours. i.e., y = 2y0
67. (d) We have R = {(x, y) : |x2 – y2 | < 16} when t = t1 hours. from (v)
Let x = 1, |x2 – y2 | < 16 Þ |1 – y2 | < 16 2y 1æ 11 ö 2 log 2
Þ |y2 – 1| < 16 Þ y = 1, 2, 3, 4 log 0 = ç log ÷ t1 Þ t1 = 11
Let x = 2, |x2 – y2 | < 16 Þ |4 – y2 | < 16 y0 2è 10 ø log
10
Þ |y2 – 4| < 16 Þ y = 1, 2, 3, 4
Let x = 3, |x2 – y2 | < 16 Þ |9 – y2 | < 16 2 log 2
Þ |y2 – 9| < 16 Þ y = 1, 2, 3, 4 Hence, the reqd. no. of hours = 11
Let x = 4, |x2 – y2 | < 16 Þ |16 – y2 | < 16 log
10
Þ |y2 – 16| < 16 Þ y = 1, 2, 3, 4, 5 71. (a) The given lines are:
Let x = 5, |x2 – y2 | < 16 Þ |25 – y2 | < 16
Þ |y2 – 25| < 16 Þ y = 4, 5 y = (2 - 3) x + 5 and y = (2 + 3) x – 7
\ R = {(1, 1), (1, 2), (1, 3), (1, 4), (2, 1), (2, Therefore, slope of first line = m1 = 2 - 3 and
2), (2, 3), (2, 4), (3, 1), (3, 2), (3, 3), (3, 4), (4, 1),
(4, 2), (4, 3), (4, 4), (4, 5), (5, 4), (5, 5)}. slope of second line = m2 = 2 + 3
2dx 2e 2 x \
68. (a) ò
(e x + e - x ) 2
=
ò
(e 2 x + 1) 2
dx
tan q =
m 2 - m1
=
2+ 3-2+ 3
1 + m1m 2 1 + (4 - 3)
1 e-x
=- +c =- +c
(e 2 x + 1) e x + e -x =
2 3
= 3 = tan
p p
Þ q = = 60°
69. (a) tan–1(1) + tan–1(0) + tan–1(2) + tan–1(3) 2 3 3
p -1 æ 2 + 3 ö 72. (a) If q is the angle between line and plane
= + p + tan çè ÷ (as 2.3 > 1)
4 1 - 2.3 ø æp ö
then çè - q÷ø is the angle between line and
5p 5p p 2
= + tan -1 ( -1) = - =p normal to plane given by
4 4 4
70. (b) Let y denote the number of bacteria at any
instant t × then according to the question æp ö
cos ç - q÷ =
( )( )
$i + 2 $j + 2kˆ . 2$i - $j + l kˆ

dy dy è2 ø 3 4 +1+ l
ay Þ = k dt ... (i)
dt y
æp ö 2-2+2 l
k is the constant of proportionality, taken to be cos ç - q ÷ =
+ ve on integrating (i), we get è2 ø 3´ 5 + l
log y = kt + c ... (ii)
c is a parameter. let y0 be the initial number of 2 l 1 5
bacteria Þ sin q = = Þ 4l = 5 + l Þ l = .
3 5 +l 3 3
i.e., at t = 0 using this in (ii), c = log y0
73. (a) Given equation of line is Case II : When x + 3 < 0, i.e. x < –3
r = 2iˆ - ˆj + 2kˆ + l ( 3iˆ + 4jˆ + 2kˆ ) x+3 –2 –x – 3 – 2
>0Þ >0
( xiˆ + yjˆ + zkˆ ) = ( 2 + 3l ) ˆi + ( -1 + 4l ) ˆj + ( 2 + 2l ) kˆ x+2 x+2
Any point on the line is – ( x + 5) x+5
(2 + 3l , – 1 + 4l, 2 + 2l) Þ >0Þ <0
x+2 x+2
Since it also lie on the plane r · ( ˆi - ˆj + kˆ ) Þ (x + 5 < 0 and x + 2 > 0) or (x + 5 > 0)
So, ëé(2 + 3l) iˆ + ( -1+ 4l) ˆj+ ( 2 + 2l) kˆ ûù.(ˆi - ˆj+ kˆ ) = 5 and x + 2 < 0)
Þ 2 + 3l + 1 – 4 l + 2 + 2l = 5 Þ l = 0 Þ (x < –5 and x > –2) or (x > –5 and x < –2)
Therefore, coordinate of the point of intersection it is not possible.
of line and plane is (2,–1, 2). Þ x Î (–5, –2) ... (ii)
\ Distance Combining (i) and (ii), the required solution is
x Î (–5, –2) È (–1, ¥).
d = ( 2 + 1) + ( -1 + 5 ) + ( 2 + 10 ) = 13
2 2 2

log p æ1 ö
PART - IV (ENGLISH & LOGICAL
74. (a) I=ò e 2 x sec 2 ç e 2 x ÷ dx REASIONING)
log p 2 è3 ø
Put e 2 x = t Þ 2e 2 x dx = dt 76. (b) See the last sentence of the fourth
paragraph.
2 log p 2
When x = log p 2 , t = e 77. (c) Virtually, the whole passage deals with
F.A.S.T. membership requirements. The other
log p 2 p
=e = choices are too narrow to be main ideas.
2
78. (a) See the first paragraph.
When x = log p , t = e 2 log p = p 79. (c) Let the fixed point from where Jatin starts
p his journey be A. Also, his walking directions
p1 æ1 ö 1 1é t ù
\ I =ò sec 2 ç t ÷ dt = . tan .ú are as follows.
p2
è3 ø 2 1 êë 3 ûp2
2 15 m
3 C D

10 m
3 é p pù 3 é 1 ù
15 m

= ê tan 3 - tan 6 ú = 2 ê 3 - ú= 3
15 m
2 ë û ë 3û B E
x+3 +x 5m
F
15 m

75. (c) We have >1

x+2
x+3 +x x+3 –2 A
Þ –1>0Þ >0 \ AF = AB – FB = 15 – 5 = 10 meters
x+2 x+2
So, Jatin is 10 meters away from the starting
Now, two cases arise : point.
Case I : When x + 3 ³ 0, i.e. x ³ –3. Then, 80. (b) F — Mohan’s family members
x+3 –2 x +3– 2 E — Employed members
>0Þ >0 H — Honest members
x+2 x+2
x +1
Þ >0
x+2
Þ {(x + 1) > 0 and x + 2 > 0}
or {x + 1 < 0 and x + 2 < 0}
Þ {x > –1 and x > –2}
or {x < –1 and x < –2} Here, shaded area denotes the employed
Þ x > –1 or x < –2 members of Mohan’s family members, who are
Þ x Î (–1, ¥) or x Î (–¥, –2) honest.
Þ x Î (–3, –2) È (–1, ¥) [Since x ³ –3] ... (i)