Topic: Atomic structure Date: 11/11/2014

SINGLE OPTION CORRECT TYPE

1. Radius of first Bohr’s orbit of H like species made by fusing hydrogen and helium nuclei is
 1   1 
A) 0.529 A B) × 0.529 A C) 9 × 0.529 A D) × 0.529 A
3 9

2. If radiation corresponding to first line of "Balmer series" of He + ion knocked out electron
from 1st excited state of H atom, the kinetic energy of ejected electron from H atom would
be (eV.
A) 4.155 eV B) 8.310 eV C) 2.515 eV D) 5.550 eV

3. Three energy levels P, Q, R of a certain atom are such that E P  EQ  ER . If 1,  2 and  3 are
the wavelength of radiation corresponding to transition R → Q;Q → P and R → P
respectively. The correct relationship between 1,  2 and  3 is
1 1 1 2 1 1
A) 1 +  2 =  3 B) = + C) 3 = 12 D) = +
 3 1  2  3 1  2

4. An unknown particle having double charge as proton moves with wavelength  , if it is

V
accelerated from rest through a potential difference of volts. While proton itself moves
8
with same wavelength  , when accelerated from rest through a potential difference ‘V’ volts,
The particle is
A) He+ B) Li2+ ion C) He2+ D) Be2+

5. The probability of finding an electron residing in a p x orbital is not zero

A) In the yz plane B) In the xy plane
C) In the y direction D) In the z direction

ONE OR MORE THAN ONE OPTIONS CORRECT TYPE

6. For He+ ion, select incorrect option(s).

A) Difference between radius of II and III Bohr's orbit is greater than that of III and IV
Bohr orbit.
B) Ratio of velocity of electron in III and IV Bohr's orbit is less than one.
C) Energy difference between consecutive energy levels decreases continuously.
D) Ratio of wavelength of least energetic and most energetic photon of Lyman series is 0.75

7. Let An be the area enclosed by the nth orbit in a hydrogen atom. The graph of ln(An/A1)
against ln(n)
A) will pass through origin
B) will be straight line with slope = 4
C) will be a monotonically increasing linear curve
D) will be a circle
8. The given transition in the following species would have the same wavelength as transition
from n = 3 to n = 1 of H atom
A) B+4 spectrum, transition from n =15 to n = 5
B) He+ spectrum, transition from n =6 to n = 2
C) C+5 spectrum, transition from n =18 to n = 6
D) Li+2 spectrum, transition from n =9 to n = 3
9. Select the options in which the velocity of electron is greater than 1.3 106 m/s
{hc = 1240 eV.nm}
A) The electron which is accelerated from rest position by a potential of 45.5 V.
B) An electron moving in the first Bohr orbit of He +.

C) The electron having de-Broglie wavelength of 4  0.526 A .
D) The electron with maximum kinetic energy emitted from a metal whose threshold
wavelength is 400 nm and is subjected to electromagnetic radiation having wavelength 124
nm.

10. For electron, proton, deuterium molecule (D2) and  -particle a curve between '  ' (de Broglie
wavelength. v/s ‘u’ (speed) is plotted) Select the correct statement(s).

A) curve I for electron B) curve III for proton

C) curve II for  -particle D) curve III for Deuterium

INTEGER TYPE
11. In a collection of 'H' atoms all electrons jump from n = 5 to finally ground level directly or
indirectly. Without emitting any line in Paschen series the number of possible different
radiations are

12. Ratio of de-Broglie wavelength of electrons in two energy levels in a H-like atom is 1 : 2, the
ratio of frequency of revolution is

13. In a single hydrogen atom, the electron is excited to its 6 th orbit. The maximum number of
distinct lines possible when it comes to the ground state.

14. For 3s orbital of hydrogen atom, the normalized wave function is given by
3/2 r
1  1   18r 2r2  3a0
3s =    27 − + 2 e
81 3  a 0   a0 a0 
The above-mentioned orbital (3s) has two nodes at 1.9 a0 and ‘x’ a0. The value of ‘x’

15. The maximum number of moles of radiations of Paschen series when 6 moles of excited
Hydrogen atoms make transition to Ground state from 6 th Bohr's Orbit.

PASSAGE – 1
In a sample of hydrogen atom in ground state, electrons make transition from ground state
to a particular excited state, where path length is four times of de-broglie wavelength.
Electrons make back transition to the ground state producing all possible photons.

16. Velocity of electron in final excited state in the above sample of hydrogen atom is
2.18  106 2.18  106 2.18  106 2.18  106
A) m /s B) m /s C) m /s D) m /s
4 8 2 6

17. de-Broglie wavelength of electron which is emitted from the final excited state of above
hydrogen sample, when photon of 1eV collide with it
 
A) 5 2 A B) 82.6 nm C) 1240 nm D) 10 10 A
PASSAGE – 2
In a hypothetical atom, electron revolves around the proton at a separation, r under the
action of force which is different from electrostatic force of attraction. The potential energy
−k
between an electron and the proton due to this force is given by U = 4 where ‘k’ is a
r
constant. The atom obeys Bohr’s quantization condition.

18. The radius of nth orbit is

 2 4 8
A) rn = km B) rn = km C) rn = km D) rn = km
nh nh nh nh

19. The total energy of electron in the nth orbit is

n4 h4 n4 h4
A) En = − B) E n =
1284 m2k 1284 m2k
n4 h4 n4 h4
C) En = D) E n = −
2564 m2k 2564 m2k
PASSAGE – 3

A H-like species is in some excited state "A" and on absorbing a photon of energy 10.2 eV
gets promoted to a new state "B" . When the electrons from state "B" return back to ground
state directly or indirectly, photons of fifteen different wavelengths are observed in which
only nine photon have energy greater than 10.2 eV. [Given: hc = 1240 eV.nm]

20. Find the ionization energy in eV of hydrogen like species

A) 54.4 B) 122.4 C) 217.6 D) 340

21. Find the maximum and minimum wavelengths in nm of the emitted fifteen photons
A) 104.2, 288.88 B) 288.88, 104.2 C) 828.88, 10.42 D) None of these

MATRIX MATCHING TYPE

22.
Column – I Column – II

A) Work function P) Wave length of photon

B) Threshold frequency Q) Photo intensity of light

Distance of point source

C) Stopping potential R)
from metal plate

D) Photo current S) Metal used

23.
Column – I Column – II
A) 2s P) Number of radial nodes=1

Number of maxima in radial

B) Q)
probability distribution curve = 2

C) R) Number of angular nodes =0

D) 4d S) (angular) depends on ‘l’

24.
Column – I Column – II
(Radial Function) ( (r) vs r graph)
 3s

A) P)

 4s
B) Q)

2p
C) R)

3p
D) S)

25. rn,Z = radius of nth orbit of single electron species having atomic number ‘Z’
vn,Z =velocity of electron in nth orbit of single electron species with atomic number ‘Z’
Tn,Z = Time period of electron in nth orbit of single electron species with atomic number ‘Z’

Column – I Column – II
r2,3
A) P) 1:4
r1,3
v1,2
B) Q) 3:4
v 2,3
T1,2
C) R) 4:3
T1,1
r1,1
D) S) 4:1
r2,3
1. B 2. A 3. B 4. C 5. B

6. ABD 7. ABC 8. ABCD 9. ABD 10. AD

11. 6 12. 8 13. 5 14. 7 15. 6

16. A 17. D 18. C 19. C 20. B

21. C 22. A-S; B-S; C-P,S; D-Q,R 23. A-P,Q,R; B-P,Q,S; C-R; D-P,Q,S

24. A – P; B- S; C-Q; D-R 25. A-S; B-R; C-P; D-Q