INDIAN SCHOOL DARSAIT

DEPARTMENT OF CHEMISTRY
Subject: Chemistry Topic :Structure of atom Date of Worksheet: 26.5.2019

Resource Person: Rohitha Date of Submission:___________

Name of the Student: ______________ Class &Division: XI Roll Number: __________

1. Calculate the energy and radius of the first orbit of He+ ion. 1
2. Why is energy of electron negative? 1
3. Why atomic spectra are called finger prints of an atom? 1
4. Define electromagnetic spectrum. 1
5. What are the main features of Planck’s quantum theory of radiation? 2
6. An electron beam from an accelerator is with kinetic energy 1.6 x 10-17J. What is its de 2
Broglie wavelength?
7. Calculate the uncertainty in the velocity of a cricket ball if the mass is 200 g. 2
Uncertainty in the position is 1pm.
8. Calculate the de Broglie wavelength of a bullet of mass 2.2 x 10-3 Kg fired with a 2
velocity of 300 m/s.
9. Calculate the wavelength of the photon that is emitted when an electron in Bohr’s orbit 2
n=2 returns to the orbit n=1 in the hydrogen atom.
10. a)Why are half filled and completely filled orbitals more stable? 2
b) How many subshells are there with n=3?
11. Calculate the energy of each of the photons which i) correspond to light of frequency 2
3x 1015 Hz. ii) have wavelength of 0.50 A0
12. What are the possible values of l and m for a) n=3 b) n=2? 2
Draw the shapes (boundary surfaces) of the following orbitals.
(i) 2py (ii) 3dz2 (iii) 3dx2– y2
13. i) State (n+l) rule. 2
ii) Give reason: Energy of the electron is quantized.
14. How many electrons are possible in a) 4p b) 5pz c) n= 3, l= 2 d) n= 4, l=2, s= + ½ 2
15. What is the energy of light emitted when the electron in a hydrogen atom undergoes 2
transition from an energy level with n = 4 to an energy level with n = 2?
16. a)Based on Bohr Bury rules arrange the following orbitals in the increasing order of 3
energy.(i) 5f , 4d , 7s , 7p (ii) 5p , 4d , 5d , 4f , 6s
b) How many electrons in an atom may have the following quantum number?
(i) n = 4 ,m s = +1/2 (ii) n = 3 , l = 0
c) What are the atomic numbers of elements whose outermost electrons are represented
by (i) 3s1 (ii) 2p3 (iii) 3d6
17. a)List the quantum numbers of a) unpaired electron in F , b) valence electrons in P, Ca. 3

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 18. A photon of wavelength 4 × 10–7 m strikes on metal surface, the work function of the 3
metal being 2.13 eV. Calculate (i) the energy of the photon (eV)
(ii) the kinetic energy of the emission, and
(iii) The velocity of the photoelectron (1 eV= 1.6020 × 10–19J).
19. a) What do you understand by quantum numbers? What is their significance? 5
b) Describe the orbital: a) n=2, l=0 b) n=6, l = 4 c) n= 2, l =3
20. a)Differentiate 5
i. Absorption and emission spectrum. ii. Orbit and orbital
b)Define
i. Photoelectric effect. ii. Black body radiation
21. a)Electrons are emitted with zero velocity from a metal surface when it is exposed to 5
radiation of wavelength 6800Ao.Calculate the threshold frequency and work function
of the metal.
b) The approximate mass of an electron is 10-27g. Calculate the uncertainty in its
velocity if the uncertainty in its position were of the order of 10-11m.
22. a) Which is more stable a) Mn2+ or Mn3+ b) Fe2+ or Fe3+? Give reason. 5
b) Which rule is disobeyed while writing electronic configuration of carbon as
1s2,2s2,2px2? State the rule and write the correct configuration.
c) Electronic configuration in Copper is [Ar] 4s1 3d10 and not [Ar] 4s2 3d9.Why?
d) Among the following pairs of orbitals which orbital will experience the larger
effective nuclear charge? (i) 2s and 3s, (ii) 4d and 4f, (iii) 3d and 3p.
23. a)Explain Bohr’s atom model. What are its limitation? 5
b) Which of the four quantum numbers (n, l, ml, m s) determine a) the energy of
electron in a hydrogen atom and in a many electron atom b) size of the orbital c) shape
of the orbital d) orientation of the orbital e) Spin of orbital?
24. a) State uncertainty principle and explain its significance. 5
b) What are degenerate orbitals?
c) How many electrons in an atom have the following quantum numbers?
i) n=4, m s = -1/2 ii) n =3 , l=0
25. a) Why are orbits known as energy levels? 5
b) Write electronic configurations of atoms of Cr (at.no. 24) and Cu (at.no. 29).
c)Explain , giving reasons, which of the following sets of quantum numbers are not
possible.
(a) n=0, l=0; ml = 0, ms= + ½
(c)n=1, l=0; ml = 0, ms= - ½
(b) n=1, l=1; ml =- 0, ms= + ½
(d)n=2, l=1; ml = 0, ms= + ½
26. a) The energy associated with the first orbit in the hydrogen atom is -2.18 x1018 J/atom. 5
What is the energy associated with the fifth orbit?
b) Calculate the radius of Bohr’s fifth orbit for hydrogen atom.
c) State (i)Hund’s Rule of maximum Multiplicity (ii) Aufbau Principle iii)Pauli’s
exclusion principle

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