PCS 213 Lab 2
PCS 213 Lab 2
PCS 213 Lab 2
EXPERIMENTERS:
AUTHORS OF THIS REPORT: Shivang Patel (500376688) [fake my sign here] ) [sign here] Kody Baum (
EXPERIMENT PERFORMED ON: 6 Feb 2012 REPORT SUBMITTED ON: 13 Feb 2012 TA S NAME: David Dalla Rosa
Objectives
The purpose of this experiment was to measure the wavelength produced by a monochromatic light source [sodium lamp], as well as to measure the Rydberg constant for hydrogen light bulb. [1]
Background
An American astronomer, David Rittenhouse, made the first diffraction grating in 1785, and reported constructing a half-inch wide grating with fifty-three apertures. A diffraction grating is a collection of reflecting elements separated by a distance comparable to the wavelength of light under study. It may be thought of as a collection of diffracting elements, such as a pattern of transparent slits in an opaque screen. For a diffraction to occur the light source(s) must be in a constant phase. Furthermore, constructive interference will occur only for certain discrete angles of the transmitted rays. [2] [3] The diffraction angles, , at which constructive interference occurs can be found from the equation: eq. 1 [1] Rydberg constant describes the wavelengths or frequencies of light in various series of related spectral lines, such as those emitted by hydrogen atoms. The value of this constant is based on the premise that the nucleus of the atom emitting light is exceedingly massive compared with a single orbiting electron. [4] The literature value of the Rydberg constant R is 1.097373157 107 per meter.
In this experiment, the Rydberg constant for hydrogen will be found using the equation known as Balmer s expression. eq. 2 [1]
Apparatus
Part A
L Diffraction Grating
FIGURE 2
Procedure
Part A 1) The sodium lamp was lit and allowed to warm up for about 10 minutes. 2) A meter stick was then mounted in front of the sodium lamp just below it. 3) The diffraction grating stand was then positioned 0.75 meters away from the meter stick. 4) The diffraction grating was the positioned so that images of the slit were visible along the meter stick. 5) The exact distance between the meter stick and diffraction grating was then measured. 6) The positions of the first two images of the slit on each side of the central image were then recorded along with the position of the central image. Part C 1) The room lights were turned off to improve the results of the experiment. 2) The meter stick was first set up horizontally and slightly elevated in front of the hydrogen discharge tube. 3) The diffraction grating was then positioned 0.75 meters away from the meter stick. 4) The diffraction grating was the positioned so that spectrum lines were visible along the meter stick. 5) The positions of the first two images of the slit on each side of the central image were then recorded along with the position of the central image.
Observations
n 1(Left) 2(Left) 1(Right) 2(Right) Red (Left) Red(Right) N 100 100 100 100 100 100 d(mm) 1/100 1/100 1/100 1/100 1/100 1/100 1/100 1/100 1/100 1/100 y(cm) 60-55.5= 4.5 60-50.9= 9.1 64.4-60= 4.4 69.1-60= 9.1 60-55= 5 64.7-60= 4.7 60-56.5= 3.5 63.5-60= 3.5 60-56.3= 3.7 63.4-60= 3.4 x(cm) 75 75 75 75 75 75 75 75 75 75 =tan-1(y/x) () 3.43 6.92 3.36 6.92 3.81 3.58 2.67 2.67 2.82 2.59 Sin 0.0598 0.1204 0.0586 0.1204 0.0664 0.0624 0.0466 0.0466 0.0491 0.0452 (nm) 598 602 586 602 664 624 466 466 491 452
= dsin /n = (0.00001x0.0598)/1 = 598nm = dsin /n = (0.00001x0.1204)/2 = 602nm = dsin /n = (0.00001x0.0586)/1 = 586nm = dsin /n = (0.00001x0.1204)/2 = 602nm avg= 597nm
percentage error = (estimate - actual) / actual * 100 = ((597-589.3)/589.3) x 100= 1.31 %
Hydrogen Lamp:
Red:
=tan-1(y/x)= tan-1(0.05/0.75)= 3.81 =tan-1(y/x)= tan-1(0.047/0.75)= 3.58 Sin = Sin(3.81 ) =0.0664 Sin = Sin(3.58 ) =0.0624 = dsin /n = (0.00001x0.0664)/1 = 664nm = dsin /n = (0.00001x0.0624)/1 = 624nm
Blue-Green:
=tan-1(y/x)= tan-1(0.035/0.75)= 2.67 =tan-1(y/x)= tan-1(0.035/0.75)= 2.67 Sin = Sin(2.67 ) =0.0466 Sin = Sin(2.67 ) =0.0466 = dsin /n = (0.00001x0.0664)/1 = 466nm = dsin /n = (0.00001x0.0624)/1 = 466nm
Violet:
=tan-1(y/x)= tan-1(0.037/0.75)= 2.82 =tan-1(y/x)= tan-1(0.034/0.75)= 2.59 Sin = Sin(2.82 ) =0.0491 Sin = Sin(2.59 ) =0.0452 = dsin /n = (0.00001x0.0491)/1 = 491nm = dsin /n = (0.00001x0.0452)/1 = 452nm Average experimental wavelength for Red, blue-green and violet respectively: Red = 644 nm Blue-Green = 466 nm violet = 471 nm
Using Balmer's equation to find the Rydberg constant for red, blue-green, and violet:
Error calculated for Rydberg constant for blue-green because that was the largest uncertainty in the entire procedure.
For this particular experiment the average experimental wavelength for Red, blue-green and violet respectively: Red = 644 nm Blue-Green = 466 nm violet = 471 nm Using Balmer's equation to find the Rydberg constant for red,
The actual Rydberg constant is 1.097373157 107 per meter. However, for this experiment the % error calculated for Rydberg constant is 4.29% for blue-green as that color has the largest uncertainty in the entire procedure. To insure the quality of the experiment the lights were turned off, however, the reasoning for the % error could be the way we were taking the readings as all of readings were close estimation of the real values on the meter stick. In conclusion, both the equations eq.1 and eq. 2 were verified through this experiment.
References
http://www.physics.ryerson.ca/sites/default/files/u3/2011/06/DiffractionandInterferen ceofLight.pdf [1] http://physics-animations.com/Physics/English/DG10/DG.htm [2] http://optics.sgu.ru/~ulianov/Students/Books/Applied_Optics/E.%20Loewen%20Diffract ion%20Grating%20Handbook%20(2005).pdf [3] http://scienceworld.wolfram.com/physics/RydbergConstant.html [4]