SOLUTIONS

1. How many gram of concentrated nitric acid solution should be used to prepare 250mL of 2.0 M .
The concentrated acid is 70% ?
1) 45.0 g conc. 2) 90.0 g conc.
3) 70.0 g conc. 4) 50.0 g conc.
2. The normality of orthophosphoric acid having purity of 70% by weight and specific gravity 1.54 is
1) 11N 2) 22 N 3) 33 N 4) 44 N
3. 25.3 g of sodium carbonate, is dissolved in enough water to make 250mL of solution. If
sodium carbonate dissociates completely, molar concentration of sodium ion, and carbonate ions,
are respectively (Molar mass of =106g )
1) 0.477M and 0.477M 2) 0.955 M and 1.910 M
3) 1.910 M and 0.955 M 4) 1.90 M and 1.910 M
4. The percentage (by weight) of sodium hydroxide in a 1.25 molal NaOH solution is
1) 4.76% 2) 1.25% 3) 5% 4) 40%
5. How many ions are present in 100 mL of 0.25 M of NaCl solution?
1) 2) 3) 4)

6. When 1.04 g of is present in of solution the concentration of solution is

1) 0.104 ppm 2) 10.4 ppm 3) 0.0104 ppm 4) 104 ppm
7. The density of NH4OH solution is found to be 0.6 g/ml. It contains 35% by mass of NH4OH. The normality of
the solution is
1) 4.8N 2) 10N 3) 0.5N 4) 6N

8. 250 ml of sodium carbonate solution contains 2.65 g of . If 10 ml. Of this solution is diluted to
500ml, the concentration of the diluted acid will be
1) 0.01 M 2) 0.001 M 3) 0.05 M 4) 0.002 M
9. The mass of 80% pure required to completely neutralize 60g of NaOH is
1) 92g 2) 58.8g 3) 73.5g 4) 98g
10. 0.4 moles of HCl and 0.2 moles of CaCl2 were dissolved in water to have 500 ml solution. The molarity
of ion is
1) 0.8 M 2) 1.6 M 3) 1.2 M 4) 10 M
11. For preparing 0.1 N solution of a compound from its impure sample of which the percentage purity is
known, the weight of the substance required is
1) Less than the theoretical weight 2) More than the theoretical weight
3) Same as the theoretical weight 4) None
12. 20 ml of 0.1 M KMnO4 in acid medium is exactly reduced by
1) 20 ml of 0.5 M H2C2O4 2) 50 ml of 0.5 M H2C2O4
3) 50 ml of 0.1 M H2C2O4 4) 20 ml of 0.1 M H2C2O4
+
13. The molar concentration of Na ions in solution of Na2CO3 having 25.3 g Na2CO3in 250 ml is
1) 0.95 2) 1.91 3) 0.475 4) 19.1
14. What is the concentration of Nitrate ions if equal volumes of 0.1 M AgNO3 and 0.1 M NaCl are mixed
together?
1) 0.05 M 2) 0.2 M 3) 0.1 M 4) 0.25 M
15. The hydrated salt Na2CO3 n H2O undergoes 63% loss in mass on heating and becomes an- hydrous. The
value of ‘n’ is
1) 4 2) 6 3) 8 4) 10
16. How many moles of potassium chlorate should be decomposed completely to obtain 67.2 litres of
oxygen at STP?
1) 1 2) 2 3) 3 4) 4
17. The number of moles of KMnO4 that will be needed to react with one mole of sulphite ion in acidic
solution is
1) 3/5 2) 4/5 3) 2/5 4) 1
18. For an aqueous solution of the same solute, in terms of concentration,
1) 1 M = 1 m 2)1 M > 1 3) 1 M > 1 m 4) Any of these is possible
19. The temperature at which molarity of pure water is equal to its molality is
1) 273 K 2) 277 K 3) 298 K 4) None of these
20. The solubility of a gas in water at 300 K under a pressure of 100 atmospheres is .
Therefore, the mass of the gas in kg dissolved in 250 mL of water under a pressure of 250 atmospheres
at 300 K is
1) 2) 3) 4)
21. Out of molarity (M). molality (m), formality (F) and mole fraction (x), those independent of
temperature are
1) M, m 2) F, x 3) m, x 4) M, x

22. Molar depression constant for water is . The freezing point of a 0.05 m olal
solution of a non electrolyte in water is
a) b) c) d)
23. An aqueous solution of urea containing 18 g urea in 1500 of the solution has a density equal to
1.052 gr/CC. If the molecular weight of urea is 60, then the molality of the solution is
1) 0.200 2) 0.192 3) 0.100 4) 1.200
24. To a 4L of 0.2 M solution of NaOH, 2 L of 0.5 M NaOH are added. The molarity of resulting solution
is
1) 0.9 M 2) 0.3 M 3) 1.8 M 4) 0.18M
25. Concentrated sulphuric acid is approximately 18 molar. 5 cc of it are added to make 500 cc of the
solution. The approx. normality of the solution will be
1) 0.18 2) 0.09 3) 0.36 4) 0.27
26. How many grams of a dibasic acid (Mol. Wt. = 200) should be present in 100 mL of its aqueous
solution to give decinormal strength?
1) 1 g 2) 2 g 3) 10 g 4) 20 g
27. 5 litres of a solution contains 25 mg of . What is its concentration in ppm? (mol. wt. of
is 100)
1) 25 2) 1 3) 5 4) 2500
28. The graph observed by taking vapour pressure (P) of a liquid on y-axis and temperature (T) on x-axis
will be

a) b) c) d)
29. A solid dissolves in water if
1) lattice energy is greater than hydration energy
2) lattice energy is less than hydration energy
3) lattice energy is equal to hydration energy
4) dissolution is exothermic
30. The solubility of a gas in a liquid at any definite temperature depends upon
1) pressure of the gas 2) critical temperature of the gas
3) both critical temperature and pressure
4) neither pressure nor critical temperature but only on the nature of the solvent
31. A binary solution of ethanol and n – heptanes example of
1) ideal solution
2) non – ideal solution with + ve deviation
3) non – ideal solution with – ve deviation
4) unpredictable behavior

32. The number of moles of hydroxide ion in 0.3 litre of 0.005 M solution of is
1) 0.0075 2) 0.0015 3) 0.003 4) 0.0050
33. The volumes of 4 N HCl and 10 N HCl required to make 1 litre of 6 N HCl are
1) 0.75 litre of 4 N HCl and 0.25 litre of 10 N HCl
2) 0.25 litre of 4 N HCl and 0.75 litre of 10 N HCl
3) 0.67 litre of 4 N HCl and 0.33 litre of 10 N HCl
4) 0.80 litre of 4 N HCl and 0.20 litre of 10 N HCl
34. 138 g of ethyl alcohol is mixed with 72 g of water. The ratio of the mole fraction of alcohol to water is
1) 3 : 4 2) 1 : 2 3) 1 : 4 4) 1 : 1
35. The solubility of a gas in water at 300 K under a pressure of 100 atmospheres is .
Therefore, the mass of the gas in kg dissolved in 250 mL of water under a pressure of 250 atmospheres
at 300 K is
1) 2) 3) 4)
36. 2.0g of charcoal is placed in 100mL of 0.5M to form an adsorbed mono-acidic layer of
acetic acid molecules and thereby the molarity of reduces to 0.49. The surface area of
charcoal adsorbed by each molecule of acetic acid is

1) 2) 3) 4)
37. Weight of concentrated nitric acid should be used to prepare 250 mL of 2.0M HNO3 is
(The concentrated acid is 70 % HNO3 by mass)
1) 70.0g Conc. HNO3 2) 54.0g Conc. HNO3
3) 45.0g Conc. HNO3 4) 90.0g Conc. HNO3

38. The volume of 96% (density ) required to prepare 2.0 L of 3.0 M solution is
(1) 33.47 mL (2) 3.347 mL (3) 334.7 mL (4) 393.7 mL
39. 1.342 kg of an aqueous solution of sucrose is cooled and maintained at – 3.720C. How much ice
will separate out, if the initial solution molality is one?

(1) 350 g (2) 400 g (3) 500 g (4) No ice formation

40. An azeotropic solution of two liquids has a boiling point lower than either of them when it
(1) shows negative deviation from Raoult’s law
(2) shows no deviation from Raoult’s law
 (3) shows positive deviation from Raoult’s law
(4) is saturated
41. 50 ml of an aqueous solution of glucose contains 6.02 x 1022 molecules. The concentration of solution is?
1) 0.1M 2) 1.0M 3) 0.2M 4) 2.0M
42. A binary solution contains 4 mol of A and 6 mol of B. Its vapour pressure is found to be 460 mmHg. To this
solution, when 10 mol of B is added, its vapour pressure becomes 480 mmHg. The vapour pressures of pure A
and pure B, respectively, are
(1) 300 mmHg, 600 mmHg (2) 400 mmHg and 500 mmHg
(3) 300 mmHg, 500 mmHg (4) 400 mmHg and 600 mmHg
43. A solution is obtained by mixing 300g of 25% solution and 400 g of 40% solution by mass. What will be the
mass percentage of the solute of resulting solution?
1) 23% 2) 12.5% 3) 33.6% 4) 50%
44. In an oxidation-reduction reaction, ion is converted to . What is the number of
equivalents of (mol.wt =158) present in 250 ml of 0.04 M solution?
1) 0.02 2) 0.05 3) 0.04 4) 0.07
45. The density of 2 M solution of acetic acid (Mol. Wt. 60) is 1.02 . The molality of the solution
‘X’ is
1) 1.0 2) 2.0 3) 2.22 4) 2.25
46. The weight of required to prepare 500ml of 0.2N solution is
1) 1.26g 2) 6.3g 3) 1.575g 4) 3.15g
47. An aqueous solution of Methyl alcohol contains 48g of alcohol. The mole fraction of alcohol is 0.6.
The weight of water in it is
1) 27g 2) 2.7g 3) 18g 4) 1.8g
. How many grams of concentrated nitric acid solution should be used to prepare 250ml of 2.0M
48
? The concentrated acid is 70%
1) 90.0 g conc . 2) 70.0g conc .

4) 45.0g conc .
3) 54.0g conc .
49. What is the mole fraction of the solute in a 1.00 m aqueous solution?
1) 0.0354 2) 0.0177 3) 0.177 4) 1.770
. What is the normality of a 1M solution of
50
1) 0.5N 2) 1.0N 3) 2.0N 4) 3.0N
51. Henry’s law constants for aqueous solution of CO, , and gases are respectively at
as , and . The solubility of these gases decreases in the order.
2)
1)
4)
3)
52. With increase of temperature, which of these changes
1) Molality 2) Molarity 3) Weight fraction of solute 4) Mole fraction
53. If 3 gm of glucose (mol. wt. 180) is dissolved in 60 gm of water at . Then the osmotic pressure
of this solution will be
1)0.34 atm 2)0.65 atm 3) 6.57 atm 4)5.57 atm
54. The concentration in gms per litre of a solution of cane sugar ( M=342 ) which is isotonic with a
solution containing 6 gms of urea ( M=60 ) per litre is
1) 3.42 2)34.2 3)5.7 4)19
55. Osmotic pressure is 0.0821 atm at temperature of . Find concentration in mole/litre
1)0.033 2)0.066 3) 4)3
56. The osmotic pressure of a 5% (wt/vol) solution of cane sugar at is
1)2.45 atm 2)5.078 atm 3)3.4 atm 4) 4 atm

57. The relationship between osmotic pressure at 273K when 10g glucose urea and 10g

sucrose are dissolved in 250mlof water is

2) 3) 4)
1)
58. Semipermeable membrane is that which permits the passage of
1)Solute molecules only 2)Solvent molecules only
3)Solute and solvent molecules both 4)Neither solute nor solvent molecules

59. A 5% solution of canesugar (mol. wt. =342) is isotonic with 1% solution of a substance X . The
molecular weight of X is
1)34.2 2)171.2 3)68.4 4) 136.8
60. Which of the following colligative properties can provide molar mass of proteins (or polymers or
colloids) with greater precision
1)Relative lowering of vapour pressure 2)Elevation of boiling point
3)Depression in freezing point 4)Osmotic pressure
61. The average osmotic pressure of human blood is 7.8 bar at . What is the concentration of an aqueous
NaCl solution that could be used in the blood stream

1) 2) 3) 4)
62. The osmotic pressure of 0.4% urea solution is 1.66 atm and. that of a solution of suger of 3.42 % is
2.46 atm. When both the solution are mixedthen the osmotic pressure of the resultant solution will be
1)1.64 atm 2)2.46 atm 3)2.06 atm 4)0.82 atm
63. The solution containing of a polyvinyl chloride polymer in 1 litre of dioxane was found to have
an osmotic pressure atmosphere at 300 K , the value of R used is 0.082 litre atmosphere
. The molecular mass of the polymer was found to be
1) 2) 3) 4)

64. Osmotic pressure of a urea solution at is 500 mm Osmotic pressure of the solution become 105.3
mm. When it is diluted andtemperature raised to The extent of dilution is
1)6 Times 2)5 Times 3)7 Times 4) 4 Times
65. The amount of urea to be dissolved in 500 ml of water (K =18.6 K in 100g solvent) to produce
a depression of in freezing point is
1)9 g 2)6 g 3)3 g 4)0.3 g
66. The maximum freezing point falls in
1)Camphor 2)Naphthalene 3)Benzene 4)Water
67. If value of is 1.86. The value of for 0.1 m solution of non-volatile solute is
1)18.6 2)0.186 3)1.86 4)0.0186
68. A solution of urea (mol. mass 56g mol–1) boils at 100.18°C at the atmospheric pressure. If and
for water are 1.86 and 0.512K kg mol–1 respectively the above solution will freeze at
1)– 6.54°C 2)6.54°C 3)0.654°C 4)–0.654°C
69. Calculate the molal depression constant of a solvent which has freezing point and latent heat of
fusion .
1a)2.68 2)3.86 3)4.68 4)2.86t6
. What should be the freezing point of aqueous solution containing 17 gmof in 1000 gmof
70

water
1) 2) 3) 4)
71. The boiling point elevation constant for toluene is 3.32 K kg mol-. The normal boiling point of toluene
is 110.70C. The enthalpy of vaporization of toluene would be nearly.
1) 17.0 kJ mol-1 2)34.0 kJ mol-1 3)51.0 kJ mol-1 4) 68. kJ mol-1
o
72. The osmotic pressure at 17 C of an aqueous solution containing 1.75 g of sucrose per 150 ml solution is
1) 0.8 atm 2)0.08 atm 3)8.1 atm 4)9.1 atm
73. of 1,4-dioxane is 4.9 for 1000 g.The depression in freezing point for a 0.001 m solution in
dioxane is
1)0.0049 2)4.9 + 0.001 3)4.9 4)0.49
74. If osmotic pressure of a solution is 2 atmat 273K, then at 546 K, the osmotic pressure is
1)0.5 atm 2)1 atm 3)2 atm 4)4 atm
75. The addition of HCl will not suppress the ionization of
1. acetic acid 2. H2S 3.Benzoic acid 4.Sulphuric acid
76. and are the vapour pressure of pure liquid components A and B respectively of an ideal binary
solution. If represents the mole fraction of component A, the total pressure of the solution will be
2) 3) 4)
1)
77. In which case Raoult’s law is not applicable?
1) 1M NaCl 2) 1M urea 3) 1M glucose 4) 1M sucrose
78. Which of the following will show a negative deviation from Raoult’s law?
1) Acetone-benzene 2) Acetone-ethanol 3) Benzene-methanol 4) Acetone-chloroform
79. A solution of two liquids boils at a temperature more than the boiling point of either of them. Hence,
the binary solution shows
1) negative deviation from Rauolt’s law 2) positive deviation from Raoult’s law
3) no deviation from Raoult’s law
4) positive or negative deviation from Raoult’s law depending upon the composition
80. An aqueous solution is 1.00 molal in KI. Which change will cause the vapour pressure of the solution
to increase?
1) Addition of water 2) Addition of NaCl
3) Addition of 4) Addition of 1.00molal KI
81. Among the following, the azeotropic mixture is
1) 2)
3) 4) chlorobenzene+bromobenzene
82. The vapour pressure of pure solvent is 0.8mm of Hg at a particular temperature. On addition of a non-
volatile solute ‘A’ the vapour pressure of solution becomes 0.6mm of Hg. The mole fraction of
component ‘A’ is
1) 0.25 2) 0.75 3) 0.5 4) 0.35
83. At 300K, the vapour pressure of an ideal solution containing 1mole of liquid A and 2moles of liquid B
is 500mm of Hg. The vapour pressure of the solution increases by 25mm of Hg, if one more mole of
B is added to the ideal solution at 300K. Then the vapour pressure of A its pure state is
1) 300mm of Hg 2) 400 mm of Hg 3) 500 mm of Hg 4) 600 mm of Hg
84. Henry’s law constant of oxygen is at 298K. How much of oxygen is dissolved in
100mL at 298K when the partial pressure of oxygen is 0.5atm?
1) 1.4g 2) 3.2g 3) 22.4 mg 4) 2.24 mg
85. At 300K two pure liquids A and B have vapour pressures respectively 150mm Hg and 100mm Hg. In
an equimolar liquid mixture of A and B, the mole fraction of B in the vapour mixture at this
temperature is
1) 0.6 2) 0.5 3) 0.8 4) 0.4
86. Vapour pressure of pure ‘A’ is 70 mm of Hg at . It forms an ideal solution with ‘B’ in which
mole fraction of A is 0.8. If the vapour pressure of the solution is 84 mm of Hg at , the vapour
pressure of pure ‘B’ at is
1) 56 mm 2) 70 mm 3) 140 mm 4) 28 mm
87. If two substance A and B have and have mole fraction in solution 1:2 then mole fraction
of A in vapours is
1) 0.33 2) 0.25 3) 0.52 4) 0.2
88. To observe an elevation of boiling point of , the amount of a solute (molecular weight=100) to
be added to 100 g of water( =0.5) is
1) 2g 2) 0.05 g 3) 1 g 4) 0.75 g
89. 58.5 g of NaCl and 180 g of glucose were separately dissolved in 1000 ml of water. Identify the correct
statement regarding the elevation of boiling point of the resulting solution
1) NaCl solution will show higher elevation of bp
2) glucose solution will show higher elevation of bp
3) both the solution will show equal elevation of bp
4) the bp elevation will be shown by neither of the solutions
90. The mass of non-volatile solute of molar mass 40 g/mol that should be dissolved in 114g of octane to
lower its vapour pressure by 20% is
1) 11.4 g 2) 9.8 g 3) 12.8 g 4) 10 g
91. Which has the least freezing point?
1) 1% sucrose 2) 1% NaCl 3) 1% 4) 1% glucose
92. Dissolution of 1.5 g of a non-volatile solute (molecular weight=60) in 250 g of a solvent reduces its
freezing point by . Find the molal depression constant of the solvent
1) 0.01 2) 0.001 3) 0.0001 4) 0.1
93. If the elevation in boiling point of a solution of 10g of solute (molecular weight=100) in 100 g of water
is the ebullioscopic constant of water is

2) 100 3) 4)
1) 10
94. The order of boiling points of four equilibrium aqueous solutions is C <B < A < D. The correct order of
their freezing point is
1) D < C < B < A 2) D > C < B < A
3) D < B > A < C 4) D > A > B > C
o
95. An aqueous solution freezes at -0.186 C (Kf=1.86, Kb=0.512). What is the elevation in boiling point?
1) 0.186 2) 0.512 3) 0.86 4) 0.0512
96. During depression of freezing point in a solution, the following are in equilibrium:
1) liquid solvent, solid solvent
2) liquid solvent, solid solute
3) liquid solvent, solid solute
4) liquid solute, solid solvent
97. Phenol dimerises in benzene having van’t Hoff factor 0.54. What is the degree of association?
1) 0.46 2) 0.27
3) 0.54 4) 0.92
98. Four solutions of with the concentrations 0.1 m, 0.01 m 0.001m, and 0.0001 m are available.
The maximum value of van’t Hoff factor, i, corresponds to
1) 0.0001 m solution 2) 0.001 m solution
3) 0.01 m solution 4) 0.1 m solution
99. A 0.6% solution of urea (molecular weight
=60 ) would be isotonic with
1) 0.1 M glucose
2) 0.1 M KCl
3) 0.6% glucose solution
4) 0.6% KCl solution
100. Two aqueous solutions S1 and S2 are separated by a semi-permeable membrane. S2 has lower vapour
pressure than S1. Then
1) More solvent will flow from S1 to S2
2) More solvent will flow from S2 to S1
3) Solvent from S1 and S2 will flow at equal rates
4) No flow will take place
101. A 5% solution (by mass) of cane sugar in water has freezing point of 271 K and freezing point of pure
water is 273.15 K. The freezing point of a 5% solution (by mass) of glucose in water is
1) 271 K 2) 273.15 K
3) 269.07 K 4) 277.23 K
102. The freezing point of a solution containing 50 cm3 of ethylene glycol in 50 g water is found to be -34oC.
Assuming ideal behaviour, the density of ethylene glycol is (Kf for water =1.86 K kg mol-1)
1) 1.13 g cm-3 2) 1.23 g cm-3
3) 1.33 g cm-3 4) 1.43 g cm-3
103. The depression in freezing point of 0.1 M aqueous solutions of Hcl, CuSO4 and 104 are in the ratio
1) 1:1:1 2) 1:2:3
3) 1:1:1.5 4) 2:4:3
104. 0.004 M solution of is isotonic with 0.010 M solution of glucose at the same temperature. The
apparent degree of dissociation of is
1) 25% 2) 50%
3) 75% 4) 85%
105. The degree of dissociation of a weak electrolyte Ax By is related to van’t Hoff factor (i) by the
expression
 1) 2)

3) 4)
106. Van’t Hoff factors of aqueous solutions of X, y and Z are 1.8, 0.8 and 2.5 respectively. Hence, correct
order of the property will be
1) F.pt: Y<X<Z
2) V.P: Y<X<Z
3) B.pt: Y<X<Z
4) Osmotic pressure: X=Y=Z
107. Which of the following is true?
1) For the same solution, elevation in boiling point =depression in freezing point
2) Van’t Hoff factor for a dilute solution of is 3
3) Elevation in boiling point is due to increase in vapour pressure
4) Depression in freezing point is due to increase in vapour pressure

108. Which of the following salt has the same value of Van’t Hoff factor as that of (Assume
complete ionisation of all electrolytes)
1) 2)
3) 4) NaCl
109. Which among the following will show maximum osmotic pressure?
1) 1M NaCl 2) 1 M
4)
3) 1 M
110. What is the normal b.p of an aqueous solution whose freezing point is-2.48oC?
(Kf=1.86oC. kg/mol, Kb=0.512oC.kg/mol)
1) 100.7oC 2) 102.5oC
3) 106.0oC 4) 66.3oC
111. Which of the following 0.10 m aqueous solution will have the lower freezing point?
1) 2)
4)
3) KI
112. What is the volume of solution containing 1 gm mole of sugar that will give rise to an osmotic pressure
1 atm at
1) 11.2 lit 2) 112 lit
3) 0224 lit 4) 22.4 lit
113. The osmotic pressure of a decimolar solution of urea at 27oC is
1) 2.46 bar 2) 5 bar
3) 3.4 bar 4) 1.25 bar
114. For a very dilute solution of van’t Hoff factor is
1) i=7 2) i=3
3) i=4 4) i=5
115. If a solute under goes dimerization and trimerization, the minimum values of the van’t Hoff factor are:
1) 0.50 and 1.50 2) 1.50 and 1.33
3) 0.50 and 0.33 4) 0.25 nad 0.67
116. 0.002 molar solution of NaCl having degree of dissociation of 90% at 27oC has osmotic pressure equal
to?
1) 0.94 bar 2) 9.4 bar
3) 0.094 bar 4) bar
117. Assertion: Depression of freezing point is a colligative property
Reason: The depression of freezing point for a solution is directly proportional to the molality of the
solution.
1) Assertion is true, reason is true; reason is a correct explanation for assertion
2) Assertion is true, reason is true; reason is not a correct explanation for assertion
3) Assertion is true, reason is false
4) Assertion is false, reason is true
118.The order of increasing freezing point of C2H5OH, Ba3(PO4)2,Na2SO4,KCl and Li3PO4 is
1) Ba3(PO4)2 < Na2SO4 < Li3PO4 < C2H5OH < KCl
2) Ba3(PO4)2 < C2H5OH < Li3PO4 < Na2SO4 < KCl
3) C2H5OH < KCl < Na2SO4 < Ba3(PO4)2 < Li3PO4
4) Ba3(PO4)2 < Li3PO4 < Na2SO4 < KCl < C2H5OH
119.The decreasing order of osmotic pressures of 10 gms glucose (P1) 10 gms Urea (P2) and 10 gms sucrose
(P3) at 273 K when dissolved in 250 ml of water separately is
1) P1 > P2 > P3 2) P2 > P3 > P1
3) P2 > P1 > P3 4) P3 > P2 > P1
120.45 gms of ethylene glycol (C2H6O2) is mixed with 600 gms of water. The freezing point of solution is (Kf
for water is 1.86 K)
1) 273.95 K 2) 270.95 K 3) 370.95 K 4) 373.95 K
121.Which one has the highest osmotic pressure.

1) 2)

3) 4)
122.The ratio of the value of any colligative property for KCl solution to that of sugar solution nearly
1) 1 2) 0.5
3) 2 4) 2.5
123.Benzoic acid undergoes dimerisation in benzene solution the Van’t Hoff’s factor ‘i’ is related to the
degree of association ‘x’ of the acid as
1) 2)

3) 4)
124.Which of the following has more B.P
1) 0.1 m KCl 2) 0.1 m NaCl
3) 0.1m CaCl2 4) 0.1m K4[Fe(CN)6]
125.A mixture of two completely miscible non-ideal liquids distils as such without change in its composition
at a constant temperature as though it were a pure liquid. This mixture is known as
1) Binary liquid mixture
2) azeotropic mixture
3) Eutectic mixture
4) ideal mixture
126.Two liquids X and Y form an ideal solution. At 300K vapour pressure of the solution containing 1 mole
of X and 3 mole of Y is 550 mm Hg. At the same temperature if 1 mole of Y added further to this
solution vapour pressure of solution increases by 10 mm Hg. Vapour pressure in mm Hg of X and Y in
 their pure states will be respectively
1) 200 and 300 2) 300 and 40
3) 400 and 600 4) 500 and 600
127.Which of the following will exhibit highest boiling point?
1) 0.015 M glucose 2) 0.01 M KNO3
3) 0.015 M Urea 4) 0.01 M Na2SO4
128. Two solutions (A) containing FeCl3(aq) and (B) containing K4 [Fe(CN)6] are separated by semi
permeable membrane as shown below. If FeCl3 on reaction with K4 [Fe(CN)6], produces blue colour
of Fe4[Fe(CN)6], the blue colour will be noticed in:

1) (A) 2) (B) 3) in both (A) and (B) 4) neither in (A) nor in (B)
129. The boiling point of an aqueous solution of a non-volatile solute is 100.15°C. What is the freezing point
of an aqueous solution obtained by diluting the above solution with an equal volume of water? The
values of Kb and K f for water are 0.512°C and 1.86°C.
1) – 0.544°C 2) – 0.512°C 3) – 0.272°C 4) – 1.86°C
130. The difference between the boiling point and freezing point of an aqueous solution containing sucrose
(molecular weight = 342 g ) in 100 g of water is 105.0°C. If and of water are 1.86 and
0.51 K kg respectively, the weight of sucrose in the solution is about
1) 34.2 g 2) 342 g 3) 7.2 4) 72.1 g
131. Which of the following statements about solution of electrolytes is not correct?
1) Conductivity of solution depends upon size of ions
2) Conductivity depends upon viscosity of solution
3) Conductivity does not depend upon salvation of ions present in solution.
4) Conductivity of solution increases with temperature
132. Each pair forms ideal solution except :
1)
2)

3)
4)
133. The mass of a non – volatile solute of molar mass that should be dissolved in 114 g of octane
to lower its vapour pressure by 20% is :
1) 10 g 2) 11.4 g
3) 9.8 g 4) 12.8 g

134. A 0.2 m aqueous solution of KCl freezes at -0.680°C. The percent apparent dissociation of KCl is (
for water = 1.86 K )
(1) 83 (2) 63 (3) 15 (4) 100
135. If the total vapour pressure of the liquid mixture A and B is give by the equation: P = 180X A + 90 mm
Hg then the ratio of the vapour pressure of the pure liquids A and B is given by
(1)3 : 2 (2) 4 : 1
(3) 3 : 1 (4) 6 : 2
136. for monobasic acid is 6. What will be its Vant’Hoff factor at 0.01M concentration
(1) 1.01 (2) 1.02
 (3) 1.03 (4) 1.10
137. 2 m aqueous solution of an electrolyte x3y2 is 25% ionized. The boiling point of the solution is

( for K kg/mol) :-
(1) 375.08 K (2) 374.04 K
(3) 377.12 K (4) 373.25 K

138. ‘a’ mole of KCl and ‘b’ mole of are dissolved in 1Kg water such that and a,b
ranges from 0 to 0.1. The observed range of elevation in boiling point of this solution would be

(1)

(2)

(3)

(4)
139. If vapour pressures of pure liquids ‘A’ & ‘B’ are 300 and 800 torr respectively at 25 0C. When these two
liquids are mixed at this temperature to form a solution in which mole percentage of ‘B’ is 92, then
the total vapour pressure is observed to be 0.95 atm. Which of the following is true for this solution.

(1) (2)

(3) (4)
140. At the osmotic pressure of urea solution is 500mm. The solution is diluted and temperature is

raised to the osmotic pressure of dilute solution is 105.3mm at . If and are initial
and final volumes of solution, the extent of dilution can be shown as

1) 2)

3) 4)
141. A molar solubility of Helium, nitrogen and oxygen are plotted against partial pressure of the gas at
constant temperature

Henrys law constant for these gases will lie in following sequence ?

2)
1)

3) 4)

142. The plots of osmotic pressure Vs concentration of a polymer at 300K gives a

straight line having slope . The molarmass of polymer is
1) 2)
 3) 4)
143. Which of the following aqueous solutions will have the lowest freezing point?
1) 0.1 molal sodium phosphate 2) 0.1 molal barium chloride
3) 0.1 molal sodium chloride 4) 0.1 molal acetic acid
144. 50 gms of antifreeze (ethylene glycol) is added to 200gms of water. What amount of ice will separate

out at
1) 14.2 mg 2) 64g
3) 38.71 gm 4) 13.08 mg
145. In an excited sample of ions with all the electrons in the same energy state (n) produces 3 different
spectral lines when all of them are now found to be in lst excited state. What can’t be the orbital
angular momentum of the electron present in state-n?
(1) (2) (3) 0 (4)
146. If sodium sulphate is considered to be completelydissociated into cations and anions in aqueous

solution,the change in freezing point of water , when 0.01mol of sodium sulphate is dissolved in
-1
1 kg of water, is:(Kf = 1.86 K kg mol )
1) 0.0186 K 2) 0.0372 K 3) 0.0558 K 4) 0.0744 K
147. An aqueous solution contains 5% urea and 10% glucose by weight. Freezing point of thesolution is
(Kf for water is 1.86 K.Kg.mol-1)
1) 3.040C 2) –1.750C 3) –11.20C 4)–3.040C
148. Four gases like have Henry’s constant values are 69.16,144.97, 0.413 and
1.67. The gas which is least soluble in liquid is
2)He 3) 4)
1)
149. 10% solution of glucose is isotonic with 6% solution of a non-volatile solute X. What is the molecular
mass of solute X?

1) 2) 3) 4)

150. When 1.04 g of is present in of solution the concentration of solution is

1) 0.0104 ppm 2) 0.104 ppm 3) 10.4 ppm 4) 104 ppm
51. .The relationship between osmotic pressure at 273K when 10 g glucose(p1), 10 g urea (p2) 10 g
1
sucrose(p3) are dissolved in 250 ml of water is
a) b) c) d)
152. 2 m aqueous solution of an electrolyte x3y2 is 25% ionized. The boiling point of the solution is (Kb for
H2O = 0.52 K kg/mol) :-
(1) 375.08 K (2) 374.04 K (3) 377.12 K (4) 373.25 K
153. What will be the molality of a solution of glucose in water which is 10% w/W?
1) 0.01 m 2) 0.617 m 3) 0.668 m 4) 1.623 m
154. Solubility of a gases in liquids depends upon
(i) nature of solute
(ii) nature of solvent
(iii) temperature
(iv) pressure
1) i, ii and iii 2) i, iii and iv
3) i and iv 4) i, ii, iii and iv
155. is a toxic gas used in qualitative analysis. If solubility of in water at STP is 0.195 m, what is
the value of
1) 0.0263 bar 2) 69.16 bar 3) 192 bar 4) 282 bar
156. Which of the following solutions is an example of negative deviation from Raoult’s law?
1) Acetone+Ethanol
2) Carbon tetrachloride+Chloroform
3) Acetone + chloroform
4) Water + Ethanol
157. 10% solution of urea is isotonic with 6% solution of a non-volatile solute X. What is the molecular mass
of solute X?
1) 2) 3) 4)
158. A solution containing 12.5 g of non-electrolyte substance in 185 g of water shows boiling point
elevation of 0.80 K. Calculate the molar mass of the substance ( )
1) 2) 3) 4)
159. Which of the following statements is correct?
1) a saturated solution will remain saturated at all temperatures
2) a plant cell swells when placed in hypertonic solution
3) the depression in freezing point is directly proportional to molality of the solution
4) lowering in vapour pressure is a colligative property
160. 3 moles of P and 2 moles of Q are mixed, what will be their total vapour pressure in the solution if their
partial vapour pressures are 80 and 60 torr respectively?
1) 80 torr 2) 140 torr 3) 72 torr 4) 70 torr
161. What will be the freezing point of a 0.5 m glucose solution? The molal freezing point constant of water
is
1) 2) 3) 4)

162. Which of the following aqueous solutions will have the highest boiling point?

2) 3) 4)
1)
163. What is the mass percentage of carbon tetrachloride if 22 g of benzene is dissolved in 122 g of carbon
tetrachloride?
1) 84.72% 2) 15.28% 3) 50% 4) 44%
164. At high altitudes the partial pressure of oxygen is less than that at the ground level. This leads to
1) low concentration of oxygen in the blood and tissues
2) high concentration of oxygen in the blood and tissues
3) release of dissolved gases and formation of bubbles of nitrogen in the blood
4) thickening of blood and tissues
165. An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point
of the solvent. What is the molecular mass of the solute?
1) 23.4 g/mol 2) 41.35 g/mol 3) 10 g/mol 4) 20.8 g/mol
166. What weight of glycerol should be added to 600 g of water in order to lower its freezing point by

1) 496 g 2) 297 g 3) 310 g 4) 426 g

167. A Solution of urea (molar mass 60) boils at 100.180C at atmospheric pressure. If Kf and Kb for water are
1.86 and 0.512 K molality-1 respectively, the above solution will freeze at

1) 2) 3) 4)
168. 3.9 g of benzoic acid is dissolved in 49 g of benzene shows a depression in freezing point of 1.62k. if
Kf for benzene is 4.9 k kg mol-1 and molar mass of benzoic acid is 122 g mol-1 then
1) benzoic acid dimerises by 98.6% in the solution
2) benzoic acid dimerises by 50.7% in the solution
3) benzoic acid is dissociated by 98.6% in the solution
4) benzoic acid is dissociated by 50.7% in the solution
169. Henry’s law constants for aqueous solution of CO, O2, CO2 and C2H2 gases are respectively at 250C as
and . The solubility of these gases decreases in the order:
1)
2)
3)
4)
170. Solution A=0.1 mNaCl
Solution B=0.01 mNaCl
Solution C=0.001 mNaCl
The value of Vant Hoff factor for these solutions will be in the order( for incomplete dissociation)
1) 2)
4)
3)
171. Molarity of a 4% NaOH solution by weight having density 1.2 gm/ml will be
(1) 1.2 M (2) 1.4 M (3) 1.6 M (4)1.8 M
172. Which one of the following solutions exhibits the maximum elevation in boiling point
1) 0.1m NaCl 2) 0.1m CaCl2 3) 0.1m BaCl2 4) 0.1m FeCl3
173. Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid
components are 105.2 kPa and 46.8 kPa respectively, what will be the vapour pressure of a
mixture of 26.0 g of heptane and 35 g of octane ?
(1) 7.308 kPa (2) 73.08 kPa (3) 730.8 kPa (4) 7308 kPa
174. The molal depresion constant is the ratio of the depresion in Freezing point to____
(1) molarity (2) molality
(3) mole fraction of solute (4) mole fraction of solvent
175. A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. What will be the
freezing point of 5% glucose in water if freezing point of pure water is 273.15 K?
(1) 273.15 K (2) 279.07 K (3) 269.07 K (4) 293.07 K
176. The mass of a non – volatile solute of molar mass that should be dissolved in 114 g of
octaneto lower its vapour pressure by 20% is :
1) 10 g 2) 11.4 g 3) 9.8 g 4) 12.8 g

177. The Henrys law constant for the solubility of gas in water at 298 K is the mole fraction
of in air is 0.8. The number of moles of from air dissolved in 10 moles of water at 298K at 5
atm pressure is
 a) b) c) d)

178. is isotonic with 0.01M glucose. Degree of dissociation of is:

a) 75% b) 50% c) 25% d) 85%
(a)
179. The freezing point of equimolal solution in aqueous medium will be highest for (assume 100%
ionization)

b) c) d)
a)
180 Dissolving 120 g of urea (mol wt 60) in 1000g of water give a solution of density 1.15 g/ml. the
molarity of the solution.
a) 1.78 M b) 2.00 M c) 2.05 M d) 2.22 M
181 A mixture of volatile components A and B has total vapour pressure in torr where
is mole fraction of A in mixture. Hence and are in torr
a) 254, 119 b) 119, 254 c) 135, 254 d) 154, 119
182. The correct relationship between the boiling point of very dilute solution of and
having the same molar concentration is
b) c) d)
a)

183. If two substances A and B have and have mole fraction in solution 1 : 2, then mole
fraction of A in vapour phase is
1) 0.33 2) 0.25 3) 0.52 4) 0.2
184. Two liquid X and Y form an ideal solution. The mixture has a vapour pressure of 400 mm at 300 K
when mixed in the molar ratio of 1 : 1 and a vapour pressure of 350 mm when mixed in the molar ratio
of 1 : 2 at the same temperature. The vapour pressures of the two pure liquids X and Y respectively are
1) 250 mm, 550 mm 2) 350 mm, 450 mm
3) 350 mm, 700 mm 4) 550 mm, 250 mm
185 The freezing point depression constant for water is If 5.00 g is dissolved in 45.0
g H2O, the freezing point is changed by .Calculate the van’t Hoff factor for
1) 0.381 2) 2.63 3) 2.05 ` 4) 3.11
186. The vapour pressure of two liquids P and Q are 80 torr and 60 torr respectively. The total vapour
pressure obtained by mixing 3 mole of P and 2 mole of Q would be
1) 68 torr 2) 20 torr 3) 140 torr 4) 72 torr
187. At , the vapour pressure (in torr) of methyl alcohol (A) and ethyl alcohol (B) solution is
represented by ; Where is mole fraction of methyl alcohol. The value of at
lim and at lim are
1) 120, 138 2) 258, 138 3) 138, 258 4) 138, 120
188. When 1 mole of is introduced in a closed vessel of one litre capacity maintained at constant
temperature, the following equilibrium is established
 If the pressure at equilibrium twice the initial pressure calculate if
1) 3:1 2) 4:1 3) 2:1 4) 1:2
189. What will be the equivalent weight of in the following reaction.

2) 3) 4)
1)

190. 20g of naphthoic acid is dissolved in 50g of benzene,then freezing point depression of 2K is
observed for solution. The vanthoff factor will be ( for benzene=1.72 Kg )
1)0.75 2) 2 3) 0.5 4) 3
191. The vapour pressure of a dilute solution of glucose is 750 mm of Hg at 373K. The mole fraction of
solute is

2) 3) 4)
1)
192. The osmotic pressure of a solution at is 4 atmospheres. What will be its osmotic pressure at 546 K
under similar conditions?
1) 4 atm 2) 2 atm 3) 8 atm 4) 1 atm
193. The degree of dissociation of in a dilute aqueous solution containing 7.0 g of the salt per 100
g of water at is 70%. If the vapour pressure of waterat is 760 mmHg, calculate the
vapour pressure of the solution.
1) 743.13 mm Hg 2)
746.13 mm Hg
3) 760 mm Hg 4) 754.2 mm Hg
194. 0.1 M NaCl and 0.1 M are found to have osmotic pressures of and respectively then
what is the correct statement?
1) 2) 3) 4)

195. If two substances A and B have and have mole fraction in solution 1 : 2, then mole
fraction of A in vapour phase is
1) 0.33 2) 0.25 3) 0.52 4) 0.2
196. Two liquid X and Y form an ideal solution. The mixture has a vapour pressure of 400 mm at 300 K
when mixed in the molar ratio of 1 : 1 and a vapour pressure of 350 mm when mixed in the molar ratio
of 1 : 2 at the same temperature. The vapour pressures of the two pure liquids X and Y respectively are
1) 250 mm, 550 mm 2) 350 mm, 450 mm
3) 350 mm, 700 mm 4) 550 mm, 250 mm

197. Phenol associates in benzene as If degree of association of phenol is

40%. Vantoff ‘s factor i is
1) 1 2) 0.8 3) 1.4 4) 0.6
198. The value of Henry’s law constant for argon (Ar), carbon dioxide , methane and
formaldehyde (HCHO) are respectively 40.3 K bar, 1.67 K bar, 0.413 K bar and K bar at
298 K. The correct order of their solubility is
1)
2)
3)

4)
199. At 300 K two pure liquids A and B have 150 mm Hg and 100 mmHg vapour pressures, respectively. In
an equimolar liquid mixture of A and B, the mole fraction of B in the vapour mixture at this
temperature is
1) 0.6 2) 0.5
3) 0.8 4) 0.4
200. 0.1 M NaCl and 0.005 M solutions are separated by a semipermeable membrane in a container.
For this system, choose the correct answer.
1) There is no movement of any solution across the membrane
2) Water flows from solution to NaCl solution
3) Water flows from NaCl solution to solution
4) Osmotic pressure of 0.1 M NaCl is lower than that of (assume complete dissociation)
201. Pure benzene freezes at 5.3°C. A solution of 0.223 g of phenyl acetic acid (C6H5CH2COOH) in 4.4 g of
benzene (Kf = 5.12 K kg mol-1) freezes at 4.47°C. From this observation, one can conclude that
phenyl acetic acid
1) exists as such in benzene 2) undergoes partial ionisation in benzene
3) undergoes complete ionisation in benzene 4) dimerises in benzene
202. Of the following 0.1 m aqueous solutions, which one exhibits the largest freezing point depression?
1) Al2(SO4)3 2) K2SO4 3) KCl 4) C6H12O6
203. PA and PB are the vapour pressures of pure liquids A and B respectively of an ideal binary solution. If

represents mole fraction of compound A, the total vapour pressure of solution will be

2) 3) 4)
1)
204. Which of the following statements is false?
1) The correct order of osmotic pressure of 0.01 M aqueous solution of each compound is BaC1 2 >
KC1 > CH3COOH > Sucrose
2) Osmotic pressure of a non electrolytic solution is given by the equation, MRT where M is the
molarity of the solution
3) Raoult's law states that the vapour pressure of a component over a solution is proportional to its mole
fraction.
4) Two sucrose solution of same molarity prepared in different solvents will have the same freezing
point depression
205. At 80°C, the vapour pressure of pure liquid 'A' is 520 mm of Hg and that of pure liquid 'B' is 1000 mm
of Hg. If a mixture of solution 'A' and 'B' boils at 80°C and 1 atm pressure, the amount of 'A' in the
mixture is
1) 50 mol per cent 2) 52 mol per cent 3) 34 mol per cent 4) 48 mol per cent
206. If and are the vapour pressures of pure A and B at 298 K, P A and PB are their partial pressures in

mixture, and 206mixture, YA and YB are their mole fractions in vapour phase and P T is the
total vapour pressure, which of the following is the correct relation?

2) 3) 4)
1)

207. Osmotic pressure of 6% urea and 6% glucose related to each other as

2) 3) 4)
1)
209.In an experiment, 200mL of 0.5M oxalic acid (Mwt=90) is shaken with 10g of activated charcoal and
filtered. The concentration of the filtrate is reduced to 0.4M. The amount of adsorption (x/m) is
1) 0.9 2) 1.8 3) 0.18 4) 0.09
210. A 5% solution by mass of cane sugar in water has freezing point of 271 K and freezing point water
is 273.15K. The freezing point of a 5% solution (by mass) of glucose in water is:
1) 271 K 2) 273.15 K 3) 269.07 K 4) 277.23 K
211. 2 moles each of liquids and are dissolved to form an ideal solution. What will be the mole
fraction of in the vapour phase?
torr; torr.
1) 1/4 2) 1/2 3) 3/5 4) 2/5
212. Which of the following solution has maximum freezing point?
1) 0.01 M NaCl 2) 0.01 M BaCl2
3) 0.01 M glucose 4) 0.001 M Urea
213. An aqueous solution of urea containing 6g per 500 ml (density 1.05 g/ml) will have the molality
1) 0.20 m 2) 0.10 m 3) 0.193 m 4) 0.0193 m
214. The values observed and theoretical molecular masses of an electrolyte AB are 65.4 and
114.45 respectively. The electrolyte AB in the solution dissociates to the extent of
1) 85% 2) 25% 3) 90% 4) 75%
215. An aqueous solution contains 0.1M and 0.2 M HCl .If Ka1and Ka2 of are
then the concentration of in aqueous solution is
1) 2)

3) 4)
216. A 5% solution of cane sugar (342) is isotonic with 1% solution of a substance X. The molecular weight
of ‘X’ is
a) 34.2 b) 68.4
c) 136.8 d) 171.2
217. A solution containing 12.5 gm of a non-electrolyte substance in 175 gm of water gave a boiling point
elevation of 0.7 K. Then molar mass of the substance if (Kb=0.52 K kg mol-)
a) 96 b) 23 c) 106 d) 53
218. 6 gm of Urea is dissolved in 90 gms of boiling water. The vapour pressure of solution is
a) 744.8 mm b) 758 mm
c) 761 mm d) 760 mm
219. Two elements A and B form compounds having molecular formula and .When
dissolved in 25 g of benzene 1 g of lowers the freezing point by
1.6 K, where as 1 g of lowers it by 1.25 K, then atomic masses of A and B respectively

( for benzene = 5.12 K kg mol-)

a) 64.4 , 128.2 b) 25.5 ,42.6
c) 56.3 , 35.8 d) 101.3 ,186.5
220. Which of the following conditions is not correct for ideal solution?
a) No change in volume on mixing
b) No change in enthalpy on mixing
c) It obeys Raoult’s law
d) Ionization of solute should occur to a small extent
221. A binary solution of ethanol and n-heptane is an example of
a) ideal solution
b) Non ideal solution with positive deviation
c) Non ideal solution with negative deviation
d) Unpredictable behavior
222. Which of the following aqueous solutions have higher freezing point?
a) 0.1 m Al2(SO4)3 b) 0.1 m BaCl2 c) 0.1m AlCl3 d) 0.1m NH4Cl
223. The average osmotic pressure of human blood is 7.8 bar at 370C. What is the concentration of
an aqueous NaCl solution that could be used in blood stream
a) 0.15 mol/lit b) 0.30 mol/lit c) 0.45 mol/lit d) 0.60 mol/lit
224. Vapour pressure of benzene and toluene in pure state are160 mm and 60 mm respectively. The mole
fraction of toluene in vapour phase incontact with equimolar mixture of benzene and toluene is
a) 0.50 b) 0.16
c) 0.27 d) 0.73
225. The solubility of common salt is 36 gr in 100 gr of water at 200C. If systems I, II and III contain 40gr,
36gr and 20 gr of the salt added to 100gr of water in each case, the vapour pressures would be in the
order
a) I < II < III b) I > II > III
c) I = II > III d) I = II < III

226. A mixture of volatile components ‘A’ and ‘B’ has total vapour pressure (in torr) P = 254 –119 XA,
where XA is the mole fraction of ‘A’ in the mixture. The vapour pressure of pure liquids ‘A’ and ‘B’
respectively are (in torr)
a) 254, 119 b) 119, 254
c) 135, 254 d) 154, 119
227. Azeotropic mixture of HNO3 and H2O has
a) 48% HNO3 b) 68% HNO3
c) 36% HNO3 d) 20.2% HNO3
228. The amount of ice that will be separated out on cooling the solution containing 50g of ethylene glycol
in 200 g of water at is
( for water =1.86 K Kg mol-)
a) 276 g b) 188 g
c) 138 g d) 38.7 g
229. The plots of (where and are the mole fraction of liquid ‘A’ in liquid and vapour
phase respectively) is linear with slope and intercepts respectively

a) b)

d)
c)

230. Which of the following statements is not true regarding vapour pressure of solvent and that of the
solution containing non – volatile solute?
a) Both increase on increasing temperature
b) increases on increasing temperature
c) For a solution of CS2 and acetone is positive and is positive

d) decreases on increasing temperature

231. If the vapour pressure of solutions of two liquids are more than those expected from ideal solution they
are said to have
a) Negative deviations from Ideal behavior
b) Positive deviations from ideal behavior
c) Ideal behavior
d) Positive deviation for lower concentration and negative deviations for higher concentrations
232. What is relative lowering of vapour pressure of 26% of a non volatile solute (M.wt = 52) in di ethyl
ether
a) 0.5 b) 0.33 c) 0.25 d) 0.125

KEY
1) 1 2) 3 3) 3 4) 1 5) 2 6) 2 7) 4 8) 4 9) 1 10) 2

11) 2 12) 3 13) 2 14) 1 15) 4 16) 2 17) 3 18) 3 19) 2 20) 1

21) 3 22) 2 23) 2 24) 2 25) 3 26) 1 27) 3 28) 3 29) 2 30) 3

31) 2 32) 3 33) 3 34) 1 35) 1 36) 1 37) 3 38) 3 39) 3 40) 3

41) 4 42) 3 43) 3 44) 2 45) 3 46) 2 47) 3 48) 4 49) 2 50) 4
51) 3 52) 2 53) 3 54) 2 55) 3 56) 2 57) 3 58) 2 59) 3 60) 4

61) 2 62) 3 63) 2 64) 2 65) 3 66) 1 67) 2 68) 4 69) 2 70) 1

71) 2 72) 1 73) 1 74) 4 75) 4 76) 4 77) 1 78) 4 79) 1 80) 1

81) 1 82) 1 83) 1 84) 3 85) 4 86) 3 87) 4 88) 3 89) 1 90) 4

91) 3 92) 4 93) 3 94) 3 95) 4 96) 1 97) 4 98) 1 99) 1 100) 1

101) 3 102) 1 103) 3 104) 3 105) 1 106) 3 107) 2 108) 3 109) 3 110) 1

111) 1 112) 4 113) 1 114) 2 115) 3 116) 3 117) 4 118) 4 119) 3 120) 2

121) 3 122) 3 123) 3 124) 4 125) 2 126) 3 127) 4 128) 4 129) 3 130) 4

131) 3 132) 4 133) 1 134) 1 135) 3 136) 1 137) 1 138) 2 139) 2 140) 1

141) 2 142) 2 143) 1 144) 3 145) 1 146) 3 147) 4 148) 3 149) 3 150) 3

151) 3 152) 1 153) 2 154) 4 155) 4 156) 1 157) 3 158) 4 159) 4 160) 3

161) 1 162) 3 163) 1 164) 1 165) 2 166) 2 167) 3 168) 1 169) 3 170) 1

171) 1 172) 4 173) 2 174) 2 175) 3 176) 1 177) 1 178) 1 179) 4 180) 3

181) 3 182) 2 183) 4 184) 4 185) 2 186) 4 187) 3 188) 2 189) 2 190) 3

191) 3 192) 3 193) 2 194) 1 195) 4 196) 4 197) 2 198) 3 199) 4 200) 2

201) 4 202) 1 203) 4 204) 4 205) 1 206) 1 207) 1 208) 2 209) 3 210) 3

211) 4 212) 4 213) 3 214) 4 215) 3 216) 2 217) 4 218) 1 219) 3 220) 4

221) 2 222) 4 223) 2 224) 3 225) 4 226) 3 227) 2 228) 4 229) 2 230) 4

231) 2 232) 2 233) 234) 235) 236) 237) 238) 239) 240)