The document outlines the evolution of atomic models, starting from Democritus's idea of indivisible particles to the plum pudding model by Thomson and Rutherford's nuclear model. It highlights Niels Bohr's advancements in 1913, introducing quantized energy levels and electron orbits, while also addressing the limitations of these models in explaining phenomena for larger atoms. Additionally, it discusses quantum numbers and their significance in describing electron behavior and energy levels within an atom.
The document outlines the evolution of atomic models, starting from Democritus's idea of indivisible particles to the plum pudding model by Thomson and Rutherford's nuclear model. It highlights Niels Bohr's advancements in 1913, introducing quantized energy levels and electron orbits, while also addressing the limitations of these models in explaining phenomena for larger atoms. Additionally, it discusses quantum numbers and their significance in describing electron behavior and energy levels within an atom.
in 1904. “The electrons are like negatively charged THE BOHR MODEL AND plums stuck to a positively THE QUANTUM charged pudding.” MECHANICAL MODEL OF - In 1911, Lord Ernest THE ATOM: Rutherford discovered the nucleus. Made up of EARLIER ATOMIC MODELS +charged particles at the - The first idea of the atom was center of the atom, which he proposed by Democritus, a found through his gold foil Greek philosopher. experiment. He called it the - “The world is made up of nuclear model, stating, tiny indivisible particles “-charged electrons called atomos.”, later it was surround the +charged coined as the atomism nucleus at the center of the theory. atom.”
- In 1803, John Dalton BOHR’S MODEL
proposed the solid sphere - Scientists found out that the model. nuclear model CANNOT - “The atom is a uniform solid explain certain physical sphere similar to a billiard observations such as the ball” “indivisible and capacity of atoms to emit eternal” light. It cannot account for the stability of the atom. - During the Industrial - So, in 1913, Niels Bohr Revolution of the 19th improved Rutherford’s model century , atomism saw a by adding orbits. resurgence. It acquired - “Electrons only move experimental evidence when around the nucleus in fixed Sir Joseph John Thomson circular orbits.” discovered the electron in - Orbits are also known as 1897. energy levels (n). Its values are any whole numbers from 1, 2, and onward. Example, the FOLLOW-UPS: first orbit of the first circle is also known as the first energy Alpha particles - +charged level (n=1). N is also known as radioactive protons that has the principal quantum 4x the mass of a hydrogen number. atom
- This model could account for - Lines with corresponding
light emissions because the wavelengths indicate the presence of orbits can explain release of energy the absorption of energy of an atom. The energy - Although, there is a fallback to transformations that result in the Bohr’s Model, which is, it the emission of light is due to fails to explain phenomena the movement of an electron for larger atoms, and it from one atomic orbit to a cannot account for atoms higher atomic orbit, and back. with more than one electron.
- When an electron absorbs - The emission of light due to
energy, it moves to an atomic excitation of electrons is the orbit with higher energy. THe reason why elements emit original atomic orbit is called characteristic light. For the ground state. The higher example, calcium releases A.O. is called the excited orange light, sodium state, which is unstable. releases yellow light and copper releases green light. - An electron can only jump in a This is how fireworks get their certain orbit. Instead of colors. having continuous energy levels, Bohr’s Model introduces - The collective term for protons the concept of quantized and neutrons is called the energy levels. nucleon - Protons tell us the identification of an element. - Each line in the atomic spectra - Electrons tell us the chemical corresponds to a definite properties of an atom. energy transformation within - Valence electron is the outermost the atom. part of an electron ATOMIC ORBITALS AND orbital. It represents the energy needed to maintain the QUANTUM NUMBERS attraction of an electron in an orbital and proton in the - In the quantum mechanical nucleus. Hence, model, an electron orbiting the The value of n increases nucleus will have a unique set with distance from the of four quantum numbers. The nucleus. set of quantum numbers acts as a sort of address for each - The maximum number of electron. electron in a shell can contains is computed by 2n^2, where n is the PQN. PRINCIPAL QUANTUM NUMBER (n) AZIMUTHAL QUANTUM NUMBER
- Refers to the distance of the - In the quantum mechanical
electron to the nucleus model, a shell consists of - Also known as the shell. subshells. They describe the - The values of n are 1,2,3, and shape of the atomic orbital. so on. It is also equal to the The subshell is also known as period where the element the Azimuthal Quantum belongs. Number (l) (As the value of n increases, *also called the orbital the electron becomes farther angular momentum away from the nucleus.) quantum number
- This set of electrons of orbitals - The values of l are zero to
represents the boundary n(PQN)-1. Each value of l surface diagrams. It encloses corresponds to a subshell a region of space where shape. electrons are usually found 90% of the time.
- The Principal Quantum
Number is also directly related to the main energy of an