Module 1 Electronic Structure of Matter STUDENTS
Module 1 Electronic Structure of Matter STUDENTS
MODULE
Electronic
Structure of
Matter
Overview
However, It could not explain why metals or
compounds of metals give off characteristic colors
when heated in a flame, or why objects–when
heated to much higher temperatures first glow to
dull red, then to yellow, and then to white.
Overview
A model different from Rutherford’s atomic model is
necessary to describe the behavior of atoms Niel’s
Bohr refined Rutherford’s model of an atom. Based
on his experiments, Bohr described the electron to
be moving in definite orbits around the nucleus.
(CF)
(CF)
NEILS BOHR’s MODEL
The postulates are as follows:
2: Only certain
circular orbits
are permitted.
(postulate, the
radii of three
orbits can be
calculated).
NEILS BOHR’s MODEL
The postulates are as follows:
3: The energy of
the electron in a given
orbit is fixed. As long
as the electron stays
in that orbit, neither
absorbs nor radiates
energy. The non-
radiating state is
called the stationary
state.
NEILS BOHR’s MODEL
The postulates are as follows:
4: The elec-
tron may move
from one
stationary state
to another. To
do so, it must
absorb or emit a
qualitative
energy exactly
equal to the
difference in
energy between
the two states.
NEILS BOHR’s MODEL
The postulates are as follows:
4: The electron
may move from
one stationary
state to another.
To do so, it must
absorb or emit a
qualitative
energy exactly
equal to the
difference in
energy between
the two states.
NEILS BOHR’s MODEL
The postulates are as follows:
Equation
Representation:
hf = E2 – E1
E1
Where:
h = Plank’s constant
f = frequency
E2 E2 and E1 = respective
energy levels between
an electron jumps
NEILS BOHR’s MODEL
The postulates are as follows:
E1 Excited state-
electrons goes to
a higher energy
state.
STRUCTURE OF AN ATOM
ENERGY LEVELS IN AN ATOM
MAIN ENERGY LEVELS
WHAT DOES “LEVELS OF ENERGY” MEAN IN TERMS
OF THE STRUCTURE OF ATOM?
The following information are needed in
answering this question:
A: The nucleus of an atom is positively
charged because of its protons.
B: The electrons surrounding the nucleus
are negatively charged.
C: In an atom, number of protons equals the
number of electrons.
MAIN ENERGY LEVELS
In 1914, Neil's Bohr proposed a theory about atomic
structure which explained the line spectra of elements.
He proposed that the movement of electrons is
analogous to the planets orbiting the sun.
MAIN ENERGY LEVELS
He referred to this as a model, a description or analogy
used to help visualize a phenomenon. He suggest that
there are several orbits where electrons may be located.
The orbits available to the electrons are said to be
quantized, meaning they are at definite distances from the
nucleus.
MAIN ENERGY LEVELS
He referred to this as a model, a description or analogy
used to help visualize a phenomenon. He suggest that
there are several orbits where electrons may be located.
The orbits available to the electrons are said to be
quantized, meaning they are at definite distances from the
nucleus.
M-shell P-shell
M-shell P-shell
M-shell P-shell
M-shell P-shell
M-shell P-shell
L-shell O-shell Q-shell
K-shell N-shell
1 2 3 4 5 6 7
I: The PRINCIPAL QUANTUM NUMBER (n)
PRINCIPAL QUANTUM NUMBER(n):
It also relates the average distance of the electron from
the nucleus in a particular orbit. The larger n is, the
greater the average distance of an electron in the orbital
from the nucleus and therefore the larger the orbital.
M-shell P-shell
L-shell O-shell Q-shell
K-shell N-shell
1 2 3 4 5 6 7
I: The PRINCIPAL QUANTUM NUMBER (n)
To summarize the
principal quantum
number is the
number of energy
level an atom has.
Example of n:
1
n:
2
45
63
7
I: The PRINCIPAL QUANTUM NUMBER (n)
Tips:
The principal
quantum number is
the number of
energy level.
The number of
energy level is also
presented in the
“PERIODS” of
Periodic table
I: The PRINCIPAL QUANTUM NUMBER (n)
I: The PRINCIPAL QUANTUM NUMBER (n)
Element n Element n
Helium (He) 1 Krypton (Kr) 4
Barium (Ba) 6 Zinc (Zn) 4
Carbon (C) 2 Magnesium (Mg) 3
Gold (Au) 6 Mercury (Hg) 6
Silver 5 Francium (Fr) 7
II: The AZIMUTHAL QUANTUM NUMBER (l)
The value of l is
Name of
the Orbital l
generally designated by
the letters, s 0
s, p, d, … as follows: p 1
d 2
f 3
g 4
h 5
II: The AZIMUTHAL QUANTUM NUMBER (l)
d-orbital
II: The AZIMUTHAL QUANTUM NUMBER (l)
direction, unlike the three kinds of p orbitals which
are oriented along the x, y, and z axes. So they
different orientations in space, px, py, and pz.
d-orbital
II: The AZIMUTHAL QUANTUM NUMBER (l)
Principal
Sharp orbital
Diffused orbitaloror
p-Orbital
s-Orbital
d-Orbital
Energy Level
II: The AZIMUTHAL QUANTUM NUMBER (l)
The diagram of s-orbital
II: The AZIMUTHAL QUANTUM NUMBER (l)
Right:
The diagram of s-orbital
into different energy
levels
1s 2s 3s
II: The AZIMUTHAL QUANTUM NUMBER (l)
The diagram of p-orbital
II: The AZIMUTHAL QUANTUM NUMBER (l)
The diagram of p-orbital
y
x y x
II: The AZIMUTHAL QUANTUM NUMBER (l)
The diagram of d-orbital
II: The AZIMUTHAL QUANTUM NUMBER (l)
The diagram of d- dxz and dyz
orbital
x y
y
y
s, p, d, f
s, p, d s, p
s, p s, p, d
Q-shell
s s, p, d, f
1 2 3 4 5 6 7
II: The AZIMUTHAL QUANTUM NUMBER (l)
No.
Color code of
electron
that
Orbitals
filled
out the
(EL)
s 2
p 6
d 10
f 14
g 18
h 22
i 26
1s2 2s2 2p6 3s2 3p6 4s23d10
II: The AZIMUTHAL QUANTUM NUMBER (l)
Principal
Sharp orbital
Diffused orbitaloror
p-Orbital
s-Orbital
d-Orbital
Energy Level
II: The AZIMUTHAL QUANTUM NUMBER (l)
Orbital Map
II: The AZIMUTHAL QUANTUM NUMBER (l)
Electron cloud
II: The AZIMUTHAL QUANTUM NUMBER (l)
4s
3s
2s
1s
Sharp orbital
2p 3p
Principal orbitals
3d
Diffuse orbitals
1s2 2s2 2p6 3s2 3p6 4s23d10
II: The AZIMUTHAL QUANTUM NUMBER (l)
THE ELECTRON CONFIGURATION: A designation of the
most probable distribution.
O V
1s 2s 3s 4s 5s 6s 7s
s 2
p 6 2p 3p 4p 5p 6p 7p
d 10
f 14 3d 4d 5d 6d 7d
4f 5f 6f 7f
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10
6p6 7s2 5f14 6d10 7p6 6f14 7d10 7f14
II: The AZIMUTHAL QUANTUM NUMBER (l)
THE ELECTRON CONFIGURATION: A designation of the
most probable distribution.
O V
Si Susan pumasok sa pinto,
s 2
Si Daddy pumunta sa dilim,
p 6
Paano si Fred Daddy (2x)
d 10
f
Paano Fred Daddy,
14
Fred
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10
6p6 7s2 5f14 6d10 7p6 6f14 7d10 7f14
II: The AZIMUTHAL QUANTUM NUMBER (l)
Let us try filling-up electrons using Bohr’s Model.
Element: 1s2
Chlorine (Cl)
Atomic No: 2s2
17
Elec. Con.: 2p6 Cl
1s2 2s2 2p6 3s2
3p5 3s2
3p5
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10
6p6 7s2 5f14 6d10 7p6 6f14 7d10 7f14
II: The AZIMUTHAL QUANTUM NUMBER (l)
Let us try filling-up electrons using Bohr’s Model.
Element: 1s2
Neon (Ne)
Atomic No: 2s2
10
Elec. Con.:
2p6 Ne
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10
6p6 7s2 5f14 6d10 7p6 6f14 7d10 7f14
II: The AZIMUTHAL QUANTUM NUMBER (l)
Let us try filling-up electrons using Bohr’s Model.
Element: 1s2
Magnesium
(Mg) 2s2
Atomic No:
12 2p6 Mg
Elec. Con.:
1s2 2s2 2p6 3s2 3s2
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10
6p6 7s2 5f14 6d10 7p6 6f14 7d10 7f14
II: The AZIMUTHAL QUANTUM NUMBER (l)
Let us try filling-up electrons using Bohr’s Model.
Element:
Phosphorus
1s2
(P)
Atomic No: 2s2
15
Elec. Con.:
2p6 P
1s2 2s2 2p6 3s2
3p3 3s2
3p3
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10
6p6 7s2 5f14 6d10 7p6 6f14 7d10 7f14
EXAMPLE
Let us try filling-up electrons using Bohr’s Model.
Element:
Phosphorus
1s2
(P)
Atomic No: 2s2
15
Elec. Con.:
2p6 P
1s2 2s2 2p6 3s2
3p3 3s2
3p3 Last mnemonics: 3p3
n= 3
l= (n-1)= 2
ml= +1
ms = +1/2
-1 0 +1
II: The AZIMUTHAL QUANTUM NUMBER (l)
Writing your Electron configuration in shortcut method.
BACK
II: The AZIMUTHAL QUANTUM NUMBER (l)
There are three (3) rules applied on this distribution:
-1 0 +1 0 -2 -1 0 +1 +2
ml = +1 ml = 0 ml = +2
III: The MAGNETIC QUANTUM NUMBER(ml)
-1 0 +1 0 -2 -1 0 +1 +2
ml = -1 ml = 0 ml = +1
III: The MAGNETIC QUANTUM NUMBER(ml)
-1 0 +1 0 -2 -1 0 +1 +2
ml = 0 ml = 0 ml = +2
III: The MAGNETIC QUANTUM NUMBER(ml)
-1 0 +1 0 -2 -1 0 +1 +2
ml = -1 ml = 0 ml = 0
IV: The SPIN QUANTUM NUMBER (ms)
If the electrons are thought of as spinning on
their own axes, as Earth does, their magnetic
quantum properties can be accountable for.
IV: The SPIN QUANTUM NUMBER (ms)
e- e-
IV: The SPIN QUANTUM NUMBER (ms)
-1 0 +1 0 -2 -1 0 +1 +2
-
ms =+1/2 ms = 1/2 ms =+1/2
+ - -
IV: The SPIN QUANTUM NUMBER (ms)
-1 0 +1 0 -2 -1 0 +1 +2
-
ms =+1/2 ms = 1/2 ms =+1/2
+ - -
Summary
Electron Configuration
In an atom, electrons and the nucleus interact to
make the most stable arrangement possible.
Electron Configuration
The way in which electrons are distributed in the
different orbitals around the nucleus of an atom is
called the electron configuration.
Electron Configuration
1H = element hydrogen with an atomic number of 1.
Atomic number is the number of proton = the
number of electron for an atom
Electron Configuration
Use this table as guide for the next activity.
Electron Configuration
The properties of elements depend mainly on the arrangement of
electrons outside the nucleus. Although there are other known
particles in an atom, only the electron is located outside the
nucleus.
The arrangement of electrons in the orbitals of an atom is called
electron configuration. It is important for us to work out electron
arrangement to be able to understand more and predict the
properties of elements.
Activity No. 3
Electron Configuration
Electron Configuration
Based on Activity 3, you were able to write the
electron configuration of an element using the
periodic table as a guide.
Electron Configuration
Recall from Grade 8 that the elements are
arranged in the periodic table in the order of
increasing atomic number.
Electron Configuration
This also means that the elements are arranged
according to the number of electrons.
Electron Configuration
If you noticed from Table 3, both hydrogen and
lithium have one electron in the highest energy level.
Beryllium has two, and boron has three.
Electron Configuration
So, the number of electrons in the highest
energy level of the elements is the basis of their
location on the periodic table.
Electron Configuration
Since the experimental basis of the periodic table is
chemical properties of the elements, knowing the
arrangement of electrons in an element will help us
understand and predict their chemical properties.
Summary:
Rutherford’s nuclear atomic model describes the
atom as mostly empty space.
Its mass is
concentrated in the
nucleus that consist
of protons and
neutrons.
However it
could not explain the
chemical properties
of elements.
Summary:
• Bohr’s atomic model describes the atom like a solar system,
where the electron is found only in specific circular paths, or
orbits, around the nucleus.
• In the Bohr model, each electron carries a fixed amount of energy
and does not lose energy as long as it stays in its given orbit. The
fixed energies that the electrons have are called energy levels. An
electron that has received enough energy can jump to a higher
energy level. When the electron returns to a lower energy level,
energy is emitted in the form of light.
• The Bohr model was later replaced by a model of the atom that
showed that electrons are not limited to fixed orbits around the
nucleus.
• Through mathematical calculations, scientists explained that
there is only a probability that the electron can be found in a
certain volume in space around the nucleus. This volume or
region of space around the nucleus where the electron is most
likely to be found is called an atomic orbital
Summary:
• Schrodinger formulated a mathematical equation that
describes the behavior of the electron. The solution to the
equation is used to calculate the probability of finding the
electron at a particular region in space around the nucleus.
• The quantum mechanical model of the atom describes the
atom as having a nucleus at the center around which the
electrons move. This model describes a region in space
where the electron is most likely to be found.
• An electron is imagined to be a cloud of negative charge
having a certain geometrical shape. The electrons are
arranged in principal or main energy levels that consist of
one or more sublevels.
• The way in which electrons are distributed in the different
orbitals around the nucleus of an atom is called the electron
configuration. Filling of electrons start from lower energy
level to highest energy level