Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd
Upload
14 views

Module Problem Set

The document contains a practice problem set focused on general equilibrium in chemistry, presenting various scenarios involving equilibrium constants, partial pressures, and reactions. Each problem requires calculations to determine equilibrium constants or predict the direction of reactions under different conditions. Answers to the problems are provided at the end, including specific values for equilibrium constants and concentrations.

Uploaded by

schoolva372
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
14 views

Module Problem Set

The document contains a practice problem set focused on general equilibrium in chemistry, presenting various scenarios involving equilibrium constants, partial pressures, and reactions. Each problem requires calculations to determine equilibrium constants or predict the direction of reactions under different conditions. Answers to the problems are provided at the end, including specific values for equilibrium constants and concentrations.

Uploaded by

schoolva372
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 3

Practice Problem Set

General Equilibrium

1. A sample of BrF at 300 K with an internal pressure of 0.743 atm decomposes into Br2(g)
and BrF3(g). At equilibrium, the partial pressure of BrF has decreased by 0.201 atm.
Determine the equilibrium constant, K p.

2. When carbon monoxide gas reacts with hydrogen gas, methanol (CH 3OH) gas is
produced. A reaction mixture at 400 K initially contained CO and H 2 at partial pressures
of 0.750 atm and 1.000 atm, respectively. At equilibrium, the partial pressure of CO was
found to be 0.295 atm. What is the K p for this reaction?

3. If 5.2 atm of ICl 5 achieves equilibrium in the reaction below, determine the equi librium
partial pressures at room temperature for all reaction components. Assume ‘x’ is small
and can be neglected (5% approximation is valid); Kp = 7.4 × 10–10.

ICl 5(g) ⇌ ICl 3(g) + Cl 2(g)

4. Calculate the equilibrium partial pressure of ammonia with ammonium carbamate in


the reaction below at 48 K. K p = 6.74 × 10–5.
NH4CO2NH2 (s) ⇌ CO2(g) + 2 NH3(g)

5. For the reaction: CO(g) + H2O(g) ⇌ CO2(g) + H2(g)


The value of the equilibrium constant, K c is 1.845 at a given temperature. We place
0.500 mole CO and 0.500 mole H2O in a 1.00-L container at this temperature and allow
the reaction to reach equilibrium. What will be the equilibrium concentrations of all
substances present?

6. Predict the direction that the reaction would proceed to re -establish equilibrium based
on the reaction below:
N2(g) + O3(g) ⇌ N2O(g) + O2(g) + heat
a. The volume of the system is increased
b. The temperature of the system is increased
c. The pressure is increased by adding O 2(g)
d. O3(g) is added to the system

7. If a reaction mixture contains P(I 2) = 0.114 atm, P(Cl 2) 0.102 atm, and P(ICl) = 0.355 atm,
what direction will the reaction proceed to establish equilibrium given the following
reaction information:
I2 (g) + Cl 2 (g) ⇌ 2 ICl (g) Kp = 81.9
8. Consider the following reaction: Ni (s) + 2 V 3+(aq) ⇌ Ni 2+(aq) + 2 V 2+(aq)
When a chunk of nickel was added to a 0.250 M V 3+ solution at 298 K, the final
equilibrium concentration of V 3+ was found to be 0.056 M.
a. What is the value of K c?
b. If the same reaction was analyzed and found to contain 0.0784 M V 3+, 0.0458 M
Ni 2+, and 0.0987 M V 2+, what would you expect to see happen to the
concentration of Ni 2+? Explain.

9. N2O4 (g) decomposes to form NO 2 (g) at high temperatures. Initially, 0.0370 moles of
N2O4 (g) was placed in a 1.0 L glass flask and allowed to reach equilibrium. At
equilibrium, 0.0310 moles of N 2O4 (g) remained in the mixture. What is K c for the
reaction?
a. How does an increase in pressure affect the amount of NO 2 (g) in the equilibrium
mixture? Explain.
b. When the reaction is repeated at a temperature 100 K larger than the original
reaction, the value for K c was found to be ~75 times larger. Does this show that
the reaction is endothermic or exothermic? Explain.
Practice Problem Set
General Equilibrium
Answers

1. 2.8 × 10–2
2. 190
3. PICl3 = PCl2 = 6.2 × 10–5 atm, PICl5 = 5.2 atm
4. 0.0513 atm
5. [CO] = [H2O] = 0.212 M; [CO2] = [H2] = 0.288 M
6. no change, left, left, right
7. to right, towards products
8. 1.16, Qc < Kc, so Ni 2+ would increase
9. 0.00465, Amount of NO2 would decrease, Endothermic

You might also like