CCD 148
CCD 148
CCD 148
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through this hot water extraction method. Extraction machines inject a cleaning solution and hot water into the carpet or upholstery that is subsequently rinsed. Some products also call for a prior pre-spraying of the fabric with the cleaner. The soiled solution is generally returned to a waste tank and disposed of to sewage systems. Machines differ in the amount of pressure applied to carpets and the temperature of water used, with retail/rental machines being the least powerful. Other cleaning methods include bonnet cleaning in which a rotary machine spins a mop-like bonnet over a carpet that has been pre sprayed with a cleaning solution. The bonnet is replaced when it becomes saturated and then rinsed clean before being used again. Other methods apply mechanical action with rotary brushes and use liquid or a foaming solution to clean. A distinct cleaning method involves spreading dry absorbent particles and solvent over the carpet and later vacuuming up the particles. Spot cleaners for use on stains and spills on carpets are also commonly used products to be sprayed or wiped on to stains and removed with a rag. Additionally cleaning products branded as pre-sprays or traffic lane cleaners are used in heavily soiled areas prior to the extraction or shampoo process. Many products are advertised for use in a variety of cleaning situations at different dilutions. Thus an extraction cleaner that is added to an hot water extraction machine at a 100:1 dilution may be used at a 10 to 1 dilution as a bonnet cleaner or a more concentrated version as a spot cleaner or a pre-spray. Extraction machine use will sometimes call for the use of a defoamer (typically this is a silicone emulsion). Cleaning of carpets and upholstery takes place in fixed contained indoor environments and carpet cleaning is linked to indoor air quality issues. Different regulatory bodies in North America (e.g., California, New Jersey, Pennsylvania) have set limits on the volatile content of cleaners. This, together with indoor air quality concerns, is leading to the replacement and substitution of solvents and a reduction in the amount of residue left on carpets after cleaning. Spot and stain removers are also commonly used intermittently. Other associated products include deodorisers, sanitizers and protectors/stainguards. The most common and effective soil and stainguards are fluoropolymer based and although potentially environmentally preferable alternatives exists (e.g., silicone as an active ingredient) these alternatives are not as effective against oily soils and may void carpet warranties because of interference with prior treatments. Typical active ingredients in carpet and upholstery care products differ from product type to product type. Generally cleaning solutions, shampoos and spot and stain removers provide cleaning action through surfactants (ethoxylated alcohols, polyglucosides), solvents (alcohols, glycol ethers), builders (ethylene diamine tetracetic acid, imminodisuccinates), amines, acids and bases, and fragrances.
Notice
Any reference to a standard means to the latest edition of that standard. The EcoLogoCM Program reserves the right to accept equivalent test data for the test methods specified in this
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document.
Notice of Intent
It is the intent of the EcoLogoCM Program to re-evaluate from time to time the relevance of requirements in line with increased evidence of environmental impacts, manufacturing advances and other changes in the marketplace. Future revisions of this document may revisit aquatic and mammalian toxicity limits as more data becomes available.
Interpretation
1. In this criteria document: "aerosols" means a cloud or fine spray of particles of a liquid or a gas; "asthmagens" substances known to cause asthma; "bioaccumulate" means an ingredient tends to remain in biological systems. An ingredient is bioaccumulating if it has a bioconcentration factor > than 100 or Log BCF >2 when tested according to one of the following: Code of Federal Regulation 40CFR797.1520, or ASTM E-1022-84 Standard Practice for conducting bioconcentration test with fishes and saltwater bi-valve mollusk, or OECD Guidelines for Testing of Chemicals, 305C, Bioaccumulation: Degree of Bioconcentration in Fish; The following ingredients are considered non-bioaccumulative and do not have to be tested for BCF those that are readily biodegradable; those that have a water solubility greater than 1500 mg/L when tested using a method consistent with ASTM E1148-87, Standard Test Method for Measurement of Aqueous Solubility, and those that have an octanol-water partition coefficient of log P less than 3 when calculated, or tested using the OECD Guidelines for Testing of Chemicals, method 117 or 107; "bioconcentration factor" means the ratio of chemical concentration in an organism to that in surrounding water; "biocidal" means destructive to life. Biocides that may in carpet cleaners include quaternary ammonium compounds; "Biosafety Level" means a classification of biological safety that may be documented on a material safety data sheet (MSDS) for a microbial culture. ATCC (American Type Culture Collection) has the
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following three classifications for microbial cultures: Biosafety Level 1: the culture is not known to cause disease in healthy human adults or animals, Biosafety Level 2: the culture may cause disease in humans or animals, Biosafety Level 3: the culture is known to cause serious or potentially lethal disease in humans or animals, and Biosafety Level 4: dangerous/exotic agents which pose high risk of life-threatening disease, aerosol-transmitted lab infections; or related agents with unknown risk of transmission
"carpet and upholstery cleaner" means a cleaning product designed to eliminate dirt and stains on rugs, carpeting, and the interior of motor vehicles and/or on household furniture or objects upholstered or covered with fabrics such as wool, cotton, nylon or other synthetic fabrics. Carpet and upholstery cleaners do not include dedicated stainguard products, absorbent cleaning powders, carpet deodorizers or solutions that claim an antibacterial effect; "carpet deodorizer" means a dedicated powder or liquid chemical mixture designed to be applied directly to carpet or upholstery to remove malodors; "Chemicals that are known to the State of California to cause reproductive or developmental toxicity" means an annually updated list of chemicals said to cause developmental toxicity published by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (otherwise known as Proposition 65); "chlorinated plastic material" means packaging materials made of polyvinyl chloride (PVC) or other chlorinated compound; "cleaners" means a chemical mixture designed to remove soil from carpet, upholstery and other fibers and for use in extraction machines, rotary machines and bonnet cleaning machines; "EC50 bacteria > X mg/l" means that the product must not have a toxic effect at a concentration lower than X mg/L when tested using one of the following methods: ASTM D5660-96(2004), Standard Test Method for Assessing the Microbial Detoxification of Chemically Contaminated Water and Soil Using a Toxicity Test with a Luminescent Marine Bacterium, 2004, or ISO 11348-1:2007, Water quality -- Determination of the inhibitory effect of water samples on the light emission of Vibrio fischeri (Luminescent bacteria test) -- Part 1: Method using freshly prepared bacteria, International Organization for Standardization, 2007, or Report EPS 1/RM/24,Biological Test Method: Toxicity Test Using Luminescent Bacteria Photobacterium phosphoreum, Environment Canada, November 1992; "endocrine disruptor" means an exogenous substance or mixture that alters function(s) of the endocrine system and consequently causes adverse health effects in an intact organism, or its progeny, or
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(sub)populations. Candidate endocrine disruptors are listed in Appendix 1 of Towards the Establishment of a Priority List of Substances for Further Evaluation of Their Role in Endocrine Disruption prepared for the European Union; "fluorescent brightening dyes" means dyes that fluoresce ultraviolet into visible light thereby making carpet or upholstery fibres appear brighter in sunlight or other light composed of ultraviolet wavelengths. These dyes are associated with yellowing of carpets over time; "fluorinated surfactants" means wetting agents containing fluorine atoms. Fluorinated surfactants may be used to reduce resoiling and provide stainguard / repellency attributes to cleaners; "IARC" means International Agency for Research on Cancer, an organization which lists known and suspected carcinogens; "institution" means office, school, hospital, retail store, and other commercial or public workplace setting where, generally, professional cleaning companies (e.g., janitorial services), provide floor care; "phosphorous based detergent builders" means phosphorous containing chemicals (e.g., sodium tripolyphosphate and trisodium phosphate) used to maintain a high solution pH, bind metal ions and emulsify soil; "post-consumer" means material that has served its end-use at the consumer level, has been discarded by the consumer, and unless diverted, would enter the waste stream; "propellants" means compressed gases or vapours in a container which, upon release of pressure and expansion through a valve, carry another substance from the container. Typical propellants are carbon dioxide, propane, butane, and isobutane; "readily biodegradable" for a component, is determined using any of the six test methods described in OECD Guidelines for Testing of Chemicals, 301A-301F; for a whole formulation, is determined using one of the methods described in OECD Guidelines for the Testing of Chemicals, provided that all measurements and calculations are based on the carbon content of the mixture and its degradation, i.e. dissolved organic carbon (DOC) removal (301A or 301E), CO2 evolution (301-B) or oxygen consumption in the presence of an inhibitor of nitrogen metabolism (301C, 301D, 301F); "resoiling" means the appearance of soil on a recently cleaned carpet. One potential cause of quick resoiling is inadequate removal of residue from the cleaning solution; "solvent" means a general term for a diverse range of liquid substances with dissolve other materials; "spot and stain remover" means any product designed to clean localized areas, or remove localized spots or stains on carpets, and upholstery;
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"surfactants" or surface active agent means an ampiphillic (dually water repelling and water attracting) substance that reduces the surface tension of water; "toxic" means the degree to which a substance or mixture of substances can harm humans or animals. Acute toxicity is the ability of a substance / mixture to cause harmful effects in an organism through a single or short-term exposure. Subchronic toxicity is the ability of the substance / mixture to cause effects for more than one year but less than the lifetime of the exposed organism. Chronic toxicity is the ability of a substance / mixture to cause harmful effects over an extended period, usually upon repeated or continuous exposure sometimes lasting for the entire life of the exposed organism; "volatile organic compound" or "VOC" means any organic compound which participates in atmospheric photochemical reactions to create smog. It excludes those organic compounds which have been designated as having negligible photochemical reactivity found in Appendix 2. The methods to calculate VOC content are: EPA Method 24-24A, 40 C.F.R., Part 60, Appendix A (1991), Method 18,48 Federal Register 48, no. 202, October 18, 1983, Method 1400 NIOSH Manual of Analytical Methods, Volume 1, February 1984, Environmental Protection Agency Method 8240 GC/MS Method for Volatile Organics, September 1986; or demonstrated through calculation from records of the amounts of constituents used to make the product where volatile means vapour pressure >0.01 KPa at 20C.
Category Definition
2. This category includes all carpet and upholstery care products as further defined in the subcategories below: (a) (b) cleaners, and spot and stain removers.
Note: Other sub-categories may be added at a later date. The Program reserves the right to determine which sub-category will be assigned to a particular applicant.
General Requirements
3. To be authorized to carry the EcoLogoCM, the carpet and upholstery care product must: (a) (b) meet or exceed all applicable governmental and industrial safety and performance standards; and be manufactured in such a manner that all steps of the process, including the disposal of waste
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products arising therefrom, will meet the requirements of all applicable governmental acts, by laws and regulations.
Efficient and Safe Use (a) demonstrate cleaning efficacy, lack of resoiling, and no acceleration of color change of carpet dyes in standardized tests, when performed by accredited labs and measured visually by a colour scale or with a spectrophotometer (see Appendix 1 for details); if the pH of the product during use is above 9, demonstrate that the product will not adversely effect the stain resisting properties of common carpet manufacturer treatments; not require warning labels as corrosive under: (i) if sold to individual consumers for use in the home: in the US, the Federal Hazardous Substances Act (16 CFR Part 1500), and/or in Canada, Part 1 and Part 2 of the Consumer Chemicals and Containers Regulations of the Hazardous Products Act; if sold for use in institutional and/or industrial settings (e.g. the workplace): in the US, the Federal Hazardous Substances Act (16 CFR Part 1500), and/or in Canada, Class D (Division 1 Subdivision A and Division 2 Subdivision A) or Class E of the Controlled Products Regulations (SOR/88-66) of the Hazardous Products Act; and
(b) (c)
(ii)
(d)
be accompanied by warnings that asthmatics and other chemically sensitive individuals should avoid recently cleaned areas for a period of at least 24 hours. It is suggested that when complying with this criterion, manufacturers stress that all carpet cleaning products introduce substances to the indoor environment and the certified product has comparatively reduced risk; be accompanied with instructions advising a thorough vacuuming of the carpet after it dries to remove any potential residue remaining from the cleaner; be accompanied by detailed instructions on safe use and handling procedures; be accompanied with indications for proper waste disposal of product;
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(h) (i)
be accompanied with instructions on the recyclability of the container and/or packaging materials; as demonstrated by the due diligence of the manufacturer: (i) (ii) not be packaged in chlorinated plastic materials, and efforts have been made to ensure packaging with post-consumer recycled content;
(j) (k)
not be formulated or manufactured with propellants; not be sold in a disposable wipe format;
Prohibited and restricted components (l) not be formulated or manufactured with solvents belonging to the following groups; (i) (ii) (iii) (iv) (v) (vi) (vii) (m) (n) (o) (p) (q) (r) (s) (t) halogenated solvents; aromatic solvents; ethylene glycol monomethyl ether or its acetate; ethylene glycol monoethyl ether or its acetate; ethylene glycol monobutyl ether or its acetate; ethylene glycol monopropyl ether or its acetate; or diethylene glycol monomethyl ether.
not be formulated or manufactured with ethylene diaminetetracetic acid; not be formulated or manufactured with phosphorous based detergents; not be formulated or manufactured with alkylphenol ethoxylate (APEOs) surfactants; not be formulated or manufactured with fluorinated surfactants; not be formulated or manufactured with fluorescent brightening dyes; when measured at the at-use dilution, not contain more than 0.1% by weight VOCs (for cleaners) and 8.0% by weight VOCs (for spot and stain removers); not be formulated or manufactured with ingredients with a sole purpose of adding to the scent of the product; if sold or advertised as containing specific odor destroying or odor neutralizing ingredients, demonstrate that these ingredients remove malodors through a physio-chemical process that is not simply masking and overpowering odors;
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(u) (v)
not be formulated or manufactured with ingredients with a sole purpose of adding to the biocidal or antimicrobial effect of the product on carpets or upholstery; if formulated or manufactured with bacteria and/or enzymes, then the bacteria/enzyme mixture must: (i) (ii) be in compliance with federal legislation regarding toxicity and biodegradation, including, for Canada, the New Substances Notification Regulations as per the Canadian Environmental Protection Act, 1999, and use (or be derived from) only those bacterial cultures that are derived from a Biosafety Level 1 ATCC microbial culture (or equivalent);
(w)
not be formulated or manufactured with any ingredients that are included in the International Agency for Research on Cancer (IARC) lists for proven (Group 1), probable (Group 2A) or possible (Group 2B) carcinogens; not be formulated or manufactured with any ingredients that are known to the State of California to cause reproductive or developmental toxicity; not be formulated or manufactured with any ingredients identified for priority for research as endocrine disruptors by the European Union; not be formulated or manufactured with any ingredients identified as asthmagens by the Association of Occupational & Environmental Clinics;
Toxicity and Biodegradation (aa) demonstrate low toxicity to aquatic and terrestrial life as described in the table below;
Cleaners: Extraction at use dilution EC50 bacteria > 10,000 mg/l And Calculated LD50 (oral rat) > 5,000 mg/kg Cleaners: Shampoo, Bonnet Cleaner, Pre-Spray at use dilution EC50 bacteria > 15 mg/l And Calculated LD50 (oral rat) > 5,000 mg/kg Spot & Stain removers at use dilution EC50 bacteria > 3,500 g/l And Calculated LD50 (oral rat) > 5,000 mg/kg
(bb) (cc)
be formulated or manufactured with ingredients that are readily biodegradable or demonstrate that the entire product is readily biodegradable; and not be formulated or manufactured with ingredients that bioaccumulate.
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Verification
5. To verify a claim that a product meets the criteria listed in the document, the EcoLogoCM Program will require access, as is its normal practice, to relevant quality control and production records and the right of access to production facilities on an announced basis. Compliance with section 3(b) shall be attested to by a signed statement of the Chief Executive Officer or the equivalent officer of the manufacturer. The EcoLogoCM Program shall be advised in writing immediately by the licensee of any non-compliance which may occur during the term of the license. On the occurrence of any non-compliance, the license may be suspended or terminated as stipulated in the license agreement.
6.
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Appendix 1: Procedure to Demonstrate Product Efficacy When Recognized Standard Not Available
At the time of publication, the EcoLogoCM Program is awaiting the publication of a North American wide accepted test method available to evaluate the efficacy of carpet cleaners and spot and stain removers. However, it has been confirmed that at least one testing laboratory is recognised by the cleaning industry for its work in testing the performance of cleaners and an industry association is planning to publish a recognized standard. The EcoLogoCM Program will accept efficacy test data that indicate the product is able: to clean the intended surface (e.g., achieve at least a 3 rating on a American Association of Textile Chemists and Colorists (AATCC) Gray Scale), not promote resoiling, and not significantly adversely impact color fastness. The tests may be done as a comparison to a nationally available brand product in which the tested product performs as well or better than the reference product. If sufficient methods exist, the tests may be done against other standardized controls (e.g., resoiling of a recently cleaned versus a non-cleaned carpet sample). Whatever method is employed, efficacy testing must comply with the following general conditions: 1. 2. 3. 4. 5. 6. Testing must be performed by a third party accredited laboratory. Testing must be carried out under controlled, replicable conditions; in situ or anecdotal data is not acceptable for EcoLogoCM certification. Preference is given to objective results quantified in recognized metric units. All control conditions must be specified. The product must be tested at its maximum recommended dilution (i.e., minimum concentration). A complete copy of the testing protocol and final report must be made available to the EcoLogoCM Program.
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This EcoLogoCM designated list includes the following compounds: (a) (b) (c) (d) (e) (f) (g) (h) (i) (j) (k) (l) (m) (n) (o) (p) (q) (r) (s) (t) (u) (v) (w) (x) (y) (z) acetone ammonium carbonate carbon monoxide carbonic acid ethane metallic carbides or carbonates methane methylene chloride (dichloromethane) cyclic, branched, or linear completely methylated siloxanes parachlorobenzotrifluoride (PCBTF) perchloroethylene (tetrachloroethylene) 1,1,1-trichloroethane trichlorofluoromethane (CFC-11) dichlorodifluoromethane (CFC-12) trichlorotrifluoroethane (CFC-113) dichlorotetrafluoroethane (CFC-114) chloropentafluoroethane (CFC-115) chlorodifluoromethane (HCFC-22) dichlorotrifluoroethane (HCFC-123) dichlorofluoroethane (HCFC-141b) chlorodifluoroethane (HCFC-142b) 2-chloro-1,1,1,2-tertrafluoroethane (HCFC124) trifluoromethane (HFC-23) 1,1,1,2,3,4.4,5,5,5-decafluoropentane (HFC-43-10mee) pentafluoroethane (HFC-125) 1,1,2,2-tetrafluoroethane (HFC-134) (aa) (bb) (cc) (dd) (ee) (ff) tetrafluoroethane (HFC-134a) 1,1,1-trifluoroethane (HFC-143a) 1,1-difluoroethane HFC-152a) 3,3-dichloro-1,1,1,2,2-pentafluoropropane (HCFC-225ca) 1,3-dichloro-1,1,2,2,3-pentafluoropropane (HCFC-225cb) perfluorocarbons (classes of): (A) cyclic, branched, or linear, completely fluorinated alkanes (B) cyclic, branched, or linear, completely fluorinated ethers with no unsaturations (C) cyclic, branched, or linear, completely fluorinated tertiary amines with no unsaturations (D) sulfur-containing perfluorocarbons with no unsaturations with the sulfur bonds only to carbon and fluorine
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The following compounds would not be considered aromatic: Phenyl ethyl alcohol (C8H10O). This compound has two substitutions - one ethyl (C2H6) and one alcohol (OH). Ethyl is not considered a simple substitution. Therefore, the solvent is not considered aromatic. Phenoxyethanol (C8H10O2). This compound has three substitutions - one ether (ROR), one alcohol (OH) and one methyl (CH3). Although all substitutions are simple, there are more than two. Therefore the solvent is not
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