CHMT 2009 Week 7 BIC
CHMT 2009 Week 7 BIC
CHMT 2009 Week 7 BIC
Bavisha Koovarjee
The Bushveld Igneous complex
• The world’s largest layered igneous complex, covers 66, 000 km2 and up to 9 km thick
• World class ore deposit
• Precambrian in age - ~2,06 billion years old
• Made of the main mafic/ultramafic body (Rustenburg Layered Suite)
• The roof is made of felsic volcanics (Rooiberg Group) and Rashoop + Lebowa granitic rocks
• Flat, funnel shaped intrusion into the Transvaal Supergroup
• The Rustenburg layered Suite (RLS) outcrops as four limbs (eastern, western, northern and far western)
• Mineralization includes; Platinum group metals, (PGEs), Cr, Ni, Fe, Cu, V
• Mineralization in granites includes;
Sn, F, Mo, REEs
• Eales, H.V. and Cawthorn, R.G. (1996). The Bushveld Complex. In: Cawthorn,
R.G. (Eds) Layered Intrusions. Elsevier Science B.V., Amsterdam, pp. 181-230.
Stillwater Complex
https://www.bizvibe.com/blog/top-5-platinum-producers-in-the-world/
https://www.statista.com/statis
tics/273624/platinum-metal-res
erves-by-country/
https://www.bizvibe.com/blog/top-10-largest-platinum-mining-companies/
Active
Waterberg Project-JOGMEC
mining
Platreef Project-JOGMEC in the
Bushveld
Igneous
Complex
http://www.overendstudio.co.za/websites/rbplats/bus-man-rasimone-venture.php
Bushveld Ultramafic`s
PLATINUM GROUP ELEMENTS (PGEs)
• Principle commodity
• Platinum, palladium, rhodium,
iridium, ruthenium & osmium
• Mostly from UG2 & Merensky
Reef
CHROMITE
• Cr2O3
• Chromium
• Stainless steel
MAGNETITE
• Fe3O4
• Source of vanadium
• Upper Zone
UG1
VANADIUM
• V2O5
• Derived from magnetite CHROMITITE
Bifurcating chromitite seams exposed at
• Used for hardening steel
Dwars River in the eastern Bushveld Complex
Bushveld Granites
DIMENSION STONE
• MZ gabbronorites- Pyramid Hills in Brits-Pretoria • Gravestones
• Working surfaces (kitchen, bathroom etc) • Face stones for buildings
TIN FLOURITE •
ANDALUSITE
Contact MM of mudstones Transvaal
• Cassiterite (SnO2)
• CaF2 SPG BIC
• Hardening effect on copper
• Lebowa Granite • Forms new minerals = andalusite
• Lebowa Granite
• High melting temperatures = 2000°C
• Others: • Used to manufacture refectory bricks
• Rare Earth
Elements (REEs)
• Molybdenuim
(Mo)
1. The volcanic event: Rooiberg Group
1. Normal MR: sheet like reef (planar normal) that has experienced uniform erosion
2. Pothole MR: near circular excavations that cut into the footwall of the MR
3. Anti-pothole MR: mound like masses of footwall rocks that stand above the planar
normal MR
Latypov et al., 2015
• Magmatic chambers develop by
Mechanisms of layering in the RLS:
in situ growth, mostly inwards
from their margins. In situ (in place) crystallization
• As the magma chamber
gradually loses heat, minerals
crystallize from margins inwards.
• Thermal currents prevent settling
of crystalized grains
• crystallisation occurs directly at
a crystal–liquid interface.
• All minerals including chromite
and sulphides crystallize in situ,
directly on the chamber floor,
accompanied by redeposition of
the minerals in association with
convection in the magma
chamber
• PGE bearing sulphides also
accumulate by in situ
crystallization Latypov et al., 2015
The origin of platinum deposits in
layered intrusions
• PGEs concentrated within sulphide mineralization
• Base metal sulphides: pyrrhotite, pentlandite,
chalcopyrite, galena+ sphalerite, pyrite + cubanite.
• PGE enrichment occurs by:
1. Gravity settling and in situ crystallization
2. Magma mixing: Influx of magma with different
composition e.g. cyclic units in RLS
3. Sulphide immiscibility
4. Reaction of magma with country rocks e.g. Platreef
https://www.researchgate.net/figure/Three-examples-of-base-metal-sulfide-assemblages-of-the-B
d-Complex-From-left-to_fig2_257331008
Mineralization in the Bushveld Granites
--Northern Limb
Four main associations:
1. Cassiterite-tourmaline sulphide association = Zaaiplaats
2. Fluorite-haematite association = Blokspruit
3. Polymetallic molybdenite-fluorite-sulphide association =
Vergenoeg
4. Sulphide carbonate ore-bodies in both Bushveld acid rocks +
in the surrounding Transvaal SPG = Spoedwel
Zaaiplaats Zaaiplaats
Lease Granite Bobbejaankop Granite
Flourite + sulphides:
Bobbejaankop
Granite
• Armitage, P.E.B., McDonald, I., Edwards, J.S. and Manby, G.M. (2002). Platinum-group element mineralization in the Platreef and calc-silicate footwall at Sandsloot, Potgietersrus District, South Africa . Applied Earth
science (Transactions of the Institute of Mining and Metallurgy B), 111, B36-B45.
• Buchanan, D.L., Nolan, J., Suddaby, P., Rouse, J.E., Viljoen, M.J. and Davenport, J.W.J. (1981). The genesis of sulphide mineralization in a portion of the Potgietersrus limb of the Bushveld Complex. Economic Geology,
76, 568-579
• Cawthorn, R.D. and Walraven, F. (1998). Emplacement and Crystallization Time for the Bushveld Complex, Journal of Petrology, 39, 1669-1687.
• Cawthorn, R.G., and Webb, S.J. (2001). Connectivity between the western and eastern limbs of the Bushveld Complex, Tectonophysics, 330, 195-209.
• Gain, S.B. and Mostert, A.B. (1982). The geological setting of the platinoid and base metal sulphide mineralization in the Platreef of the Bushveld Complex on Drenthe, north of Potgietersrus. Economic Geology, 77,
1395-1404.
• Harris, C. and Chaumba, J.B. (2001). Crustal contamination and fluid-rock interaction during the formation of the Platreef, Northern Limb of the Bushveld Complex, South Africa. Journal of Petrology, 42, 1321-1347.
• Kinnaird, J.A. 2005, The Bushveld large igneous province, http://www.largeigneousprovinces.org/sites/default/files/BushveldLIP.pdf (August 2020)
• Kinnaird, J.A. (2005). Geochemical evidence for multiple emplacements in the southern Platreef. Applied Earth Science (Transactions of the Institute of Mining and Metallurgy), 114, 225-242.
• Kinnaird, J.A., Kruger, F.J., Nex, P.A.M. and Cawthorn, R.G. (2002). Chromitite formation- a key to understanding processes of platinum enrichment, Trans.Inst Min. Metall, (Sect, B: Appl. Earth sci.), 111, 23-35.
• Kinnaird, J.A., Hutchinson, D., Schurmann, L., Nex, P.A.M. and de Lange. (2005). Petrology and mineralisation of the southern Platreef: northern limb of the Bushveld Complex, South Africa . Mineralium Deposita.
40, 576–597
• Latypov, R., Chistyakova, S., Barnes, S. J., Hunt, E. J. (2017). Origin of platinum deposits in layered intrusions by in situ crystallization: evidence from undercutting Merensky Reef of the Bushveld Complex. Journal of
Petrology, 58 , 715-761.
• Latypov, R., Chistyakova, S., Page, A. and Hornsey. 2015. Field Evidence for the In Situ Crystallization of the Merensky Reef. Journal of Petrology. 56, 2341-2372
• Lee, C.A. (1996). A review of mineralization in the Bushveld Complex and some other layered mafic intrusions. In: Cawthorn, R.G. (Eds) Layered Intrusions. Amsterdam: Elsevier Science, 103-146.
• Pollard. P.J., Taylor, R,G., Taylor, R.P. and Groves. D.L. (1991). Petrographic and geochemical evolution of pervasively altered Bushveld granites at the Zaaiplaats tin mine. Economic Geology, 86(7), 1401-1433
A review of the behaviour of PGEs within Natural magmatic sulphide ore systems (Holwell and McDonald, 2010, page 26)
https://scholar.google.co.za/scholar?hl=en&as_sdt=0%2C5&q=A+review+of+the+behaviour+of+PGEs+within+Natural+magmatic+sulphide+ore+systems+%28Holwell+and+McDonald%2C+2010%29&btnG=