Larry Brown

Tom Holme

www.cengage.com/chemistry/brown

Chapter 3
Molecules, Moles, and
Chemical Equations

Jacqueline Bennett • SUNY Oneonta

Chapter Objectives
• List at least three characteristics of explosive chemical
reactions.

• Explain balancing a chemical reaction as an application of the

law of conservation of mass.

• List at least three quantities that must be conserved in

chemical reactions.

• Write balanced chemical equations for simple reactions, given

either an unbalanced equation or a verbal description.

2
Chapter Objectives
• Explain the concept of a mole in your own words.

• Interpret chemical equations in terms of both moles and

molecules.

• Interconvert between mass, number of molecules, and

number of moles.

• Determine a chemical formula from elemental analysis (i.e.,

from % compositions).

3
Chapter Objectives
• Define the concentration of a solution and calculate the
molarity of solutions from appropriate data.

• Calculate the molarity of solutions prepared by dilution or

calculate the quantities needed to carry out a dilution to
prepare a solution of a specified concentration.

• Distinguish between electrolytes and nonelectrolytes and

explain how their solutions differ.

4
Chapter Objectives
• Describe the species expected to be present (ions, molecules,
etc.) in various simple solutions.

• Recognize common strong acids and bases.

• Write molecular and ionic equations for acid-base

neutralization reactions.

5
Explosions
1. Explosions release a large
amount of energy when a
fairly complex molecule
decomposes into smaller,
simpler compounds.

2. Explosions occur very

quickly.

3. Modern explosives are

generally solids.

6
Explosions

• Dynamite is an explosive made from liquid nitroglycerin and

an inert binder to form a solid material.

• Solids are easier to handle than liquids

7
Explosions

• The destructive force of explosions is due in part to expansion

of gases, which produces a shockwave.
8
Chemical Formulas and Equations

• Chemical formulas provide a concise way to represent

chemical compounds.

• Nitroglycerin, shown earlier, becomes C3H5N3O9

• A chemical equation builds upon chemical formulas to

concisely represent a chemical reaction.

9
Writing Chemical Equations
• Chemical equations represent the transformation of one or
more chemical species into new substances.

• Reactants are the original materials and are written on the

left hand side of the equation.

• Products are the newly formed compounds and are

written on the right hand side of the equation.

Reactants  Products

10
Writing Chemical Equations
• Chemical formulas represent reactants and products.

• Phase labels follow each formula.

• solid = (s)
• liquid = ()
• gas = (g)
• aqueous (substance dissolved in water) = (aq)

• Some reactions require an additional symbol placed over

the reaction arrow to specify reaction conditions.
• Thermal reactions: heat ()
• Photochemical reactions: light (h)

11
Writing Chemical Equations

• Different representations for the reaction between hydrogen

and oxygen to produce water.
12
Balancing Chemical Equations
• The law of conservation of matter: matter is neither created
nor destroyed.

• Chemical reactions must obey the law of conservation of

matter.

• The same number of atoms for each element must

occur on both sides of the chemical equation.

• A chemical reaction simply rearranges the atoms into

new compounds.

13
Balancing Chemical Equations

• Balanced chemical equation for the combustion of methane.

14
Balancing Chemical Equations
• Chemical equations may be balanced via inspection, which
really means by trial and error.

• Numbers used to balance chemical equations are called

stoichiometric coefficients.

• The stoichiometric coefficient multiplies the number of

atoms of each element in the formula unit of the
compound that it precedes.

• Stoichiometry is the various quantitative relationships

between reactants and products.

15
Balancing Chemical Equations
• Pay attention to the
following when balancing
chemical equations:
• Do not change species
• Do not use fractions
(cannot have half a
molecule)
• Make sure you have the
same number of atoms of
each element on both
sides

16
Example Problem 3.1

• Write a balanced chemical equation describing the reaction

between propane, C3H8, and oxygen, O2, to form carbon
dioxide and water.

17
Aqueous Solutions and Net Ionic Equations

• Reactions that occur in water are said to take place in

aqueous solution.

• Solution: homogeneous mixture of two or more

substances.

• Solvent: solution component present in greatest

amount.

• Solute: solution component present in lesser amount.

• The preparation of a solution is a common way to

enable two solids to make contact with one another.
18
Solutions, Solvents, and Solutes
• For solutions, the concentration is a key piece of information.

• Concentration: relative amounts of solute and solvent.

• Concentrated: many solute particles are present.

• Dilute: few solute particles are present.

19
Solutions, Solvents, and Solutes
Solution preparation:

• Solid CuSO4, the solute, is

transferred to a flask.

• Water, the solvent, is added.

• The flask is shaken to speed

the dissolution process.

• Two solutions of CuSO4.

• Solution on the left is
more concentrated, as
seen from its darker
color.

20
Solutions, Solvents, and Solutes
• Compounds can be characterized by their solubility.

• Soluble compounds dissolve readily in water.

• Insoluble compounds do not readily dissolve in water.

• Solubility can be predicted using solubility guidelines.

21
Solutions, Solvents, and Solutes
• Solubility guidelines for soluble salts

22
Solutions, Solvents, and Solutes
• Solubility guidelines for insoluble salts

23
Example Problem 3.2

• Which of the following compounds would you predict are

soluble in water at room temperature?

a) KClO3

b) CaCO3

c) BaSO4

d) KMnO4

24
Solutions, Solvents, and Solutes
• Electrolytes are soluble compounds that conduct current
when dissolved in water.

• Weak electrolytes dissociate partially into ions in solution.

• Strong electrolytes dissociate completely into ions in

solution.

• Nonelectrolytes do not dissociate into ions in solution.

25
Solutions, Solvents, and Solutes

a) Sugar, a nonelectrolyte, does not conduct current when dissolved in water.

b) Acetic acid, a weak electrolyte, weakly conducts current when dissolved in
water.
c) Potassium chromate, a strong electrolyte, strongly conducts current when
dissolved in water.
26
Chemical Equations for Aqueous Reactions

• When a covalently bonded material dissolves in water and the

molecules remain intact, they do not conduct current. These
compounds are nonelectrolytes.

C6 H12O6 (s) 

 C6 H12O6 (aq)

• The water molecules are not shown explicitly, although

their presence is indicated by the “(aq)” on the product
side.

27
Chemical Equations for Aqueous Reactions

• When an ionic solid dissolves in water, it breaks into its

constituent ions. This is called a dissociation reaction. These
compounds conduct electric current and are electrolytes.


NaCl (s) 
 Na (aq) + Cl (aq) +

28
Chemical Equations for Aqueous Reactions

• Aqueous chemical reactions can be written as a molecular

equation. The complete formula for each compound is
shown.

• Note, all of the species may not be molecules.

HNO 3 (aq) + NH 3 (g) 

 NH 4 NO 3 (aq)

29
Chemical Equations for Aqueous Reactions

• Dissociation of reactants and products is emphasized by

writing a total ionic equation.

H + (aq) + NO 3 (aq) + NH 3 (g) 

 NH +4 (aq) + NO 3 (aq)

• Note: HNO3 is a strong acid and thus dissociates completely,

while NH3 does not dissociate

30
Chemical Equations for Aqueous Reactions

• Spectator ions are ions uninvolved in the chemical reaction.

When spectator ions are removed, the result is the net ionic
equation.
• Total ionic equation

H + (aq) + NO 3 (aq) + NH 3 (g) 

 NH +4 (aq) + NO 3 (aq)

• Net ionic equation

H (aq) + NH 3 (g) 
+
 NH (aq) +
4

Spectator ion = NO 3

31
Acid-Base Reactions
• Acids are substances that dissolve in water to produce H+ (or
H3O+) ions.

• Examples: HCl, HNO3, H3PO4, HCN

• Bases are substances that dissolve in water to produce OH–

ions.

• Examples: NaOH, Ca(OH)2, NH3

32
Acid-Base Reactions
• Strong acids and bases completely dissociate in water.


HCl(g) + H 2O(l ) 
 H 3O (aq) + Cl (aq)
+


NaOH(s)
  
 Na (aq) + OH+
(aq)

33
Acid-Base Reactions
• All common strong acids and bases.

34
Acid-Base Reactions
• Weak acids and bases partially dissociate in water.

• Notice the two-way arrows, which emphasize that the

reaction does not proceed completely from left to right.


CH 3COOH(aq) + H 2O(l ) 
 + 
 H 3O (aq) + CH 3COO (aq)

NH 3 (aq) + H 2 O(l ) 


 NH +
4 (aq) + OH 
(aq)


35
Acid-Base Reactions

• Some common weak acids and bases.

36
Acid-Base Reactions
• Mixing an acid and a base leads to a reaction known as
neutralization, in which the resulting solution is neither acidic
nor basic.

• Net ionic equation for neutralization of strong acid and

strong base.


H
 3O +
(aq) + OH (aq)  
 2H 2 O(l )

37
Example Problem 3.3
• When aqueous solutions of acetic acid and potassium
hydroxide are combined, a neutralization reaction will occur.
Write the following equations:

a) molecular

b) total ionic

c) net ionic

38
Precipitation Reactions
• A precipitation reaction is an aqueous reaction that produces
a solid, called a precipitate.

• Net ionic reaction for the precipitation of lead(II) iodide.


Pb (aq)  2I (aq) 
2+
 PbI2 (s)

39
Precipitation Reactions

• Precipitation reaction between aqueous solutions of KI and Pb(NO3)2, which are

both colorless.
• The bright yellow solid, PbI2, is produced.
• PbI2 is insoluble as predicted by the solubility guidelines.
40
Example Problem 3.4
• When aqueous sodium carbonate and barium chloride are
combined, the solution becomes cloudy white with solid
barium carbonate. Write the following equations:

a) molecular

b) total ionic

c) net ionic

41
Interpreting Equations and the Mole

• Balanced chemical equations are interpreted on the

microscopic and macroscopic level.

• Microscopic interpretation visualizes reactions between

molecules.

• Macroscopic interpretation visualizes reactions between

bulk materials.

42
Interpreting Chemical Equations
• Balanced chemical reactions provide stoichiometric ratios
between reactants and products. Ratios relate relative
numbers of particles.

2H 2 (g) + O 2 (g) 
 2H 2O(g)

• 2 molecules H2 : 1 molecule O2 : 2 molecules H2O

• 100 molecules H2 : 50 molecule O2 : 100 molecules H2O

43
Avogadro’s Number and the Mole

• A mole is a means of counting the large number of particles in

samples.

• One mole is the number of atoms in exactly 12 grams of

12C (carbon-12).

• 1 mole contains Avogadro’s number (6.022 x 1023

particles/mole) of particles.

• The mass of 6.022 x 1023 atoms of any element is the

molar mass of that element.

44
Avogadro’s Number and the Mole

• One mole samples of various elements. All have the same number of particles.

45
Avogadro’s Number and the Mole

• Balanced chemical reactions also provide mole ratios

between reactants and products.

2H 2 (g) + O 2 (g) 
 2H 2O(g)

• 2 moles H2 : 1 mole O2 : 2 moles H2O

46
Determining Molar Mass
• The molar mass of a compound is the sum of the molar
masses of all the atoms in a compound.

 1.0 g H   16.0 g 
 2 mol H   +  1 mol O  
1 mol H 1 mol O

= 18.0 g/mol H 2O

47
Example Problem 3.5
• Determine the molar mass of each of the following
compounds:

a) PbN6

b) C3H5N3O9

c) Hg(ONC)2

48
Calculations Using Moles and Molar Mass

• Molar mass allows conversion from mass to number of

moles, much like a unit conversion.

• 1 mol C7H5N3O6 = 227.133 g C7H5N3O6

1 mol C 7 H 5 N 3O 6
300.0 g C 7 H 5 N 3O 6 
227.133 g C 7 H 5 N 3O 6

= 1.320 mol C 7 H 5 N 3O 6

49
Calculations Using Moles and Molar Mass

• Avogadro’s number functions much like a unit conversion

between moles to number of particles.

• 1 mol C7H5N3O6 = 6.022  1023 C7H5N3O6 molecules

• How many molecules are in 1.320 moles of

nitroglycerin?
6.022  10 23 molecules C 7 H 5 N 3O6
1.320 mol C 7 H 5 N 3O 6 
1 mol C 7 H 5 N 3O 6

= 7.949  10 23 molecules C 7 H 5 N 3O 6

50
Example Problem 3.6
• A sample of the explosive TNT (C7H5N3O6) has a mass of
650.5 g.

• How many moles of TNT are in this sample?

• How many molecules are in this sample?

51
Example Problem 3.7
• How many pounds of halite (C2H6N4O5) correspond to 315
moles? (1 pound = 454 g)

52
Elemental Analysis: Determining Empirical
and Molecular Formulas

• Empirical formulas can be determined from an elemental

analysis.

• An elemental analysis measures the mass percentage of

each element in a compound.

• The formula describes the composition in terms of the

number of atoms of each element.

• The molar masses of the elements provide the connection

between the elemental analysis and the formula.

53
Elemental Analysis: Determining Empirical
and Molecular Formulas

• Assume a 100 gram sample size

• Percentage element  sample size = mass element in compound. (e.g.,

16% carbon = 16 g carbon)

• Convert mass of each element to moles using the molar mass.

• Divide by smallest number of moles to get mole to mole ratio for

empirical formula.

• When division by smallest number of moles results in small rational

fractions, multiply all ratios by an appropriate integer to give whole
numbers.

• 2.5  2 = 5, 1.33  3 = 4, etc.

54
Example Problem 3.8
• The explosive known as RDX contains 16.22% carbon, 2.72%
hydrogen, 37.84% nitrogen, and 43.22% oxygen by mass.
Determine its empirical formula.

55
Elemental Analysis: Determining Empirical
and Molecular Formulas

• A molecular formula is a whole number multiple of the

empirical formula.

• Molar mass for the molecular formula is a whole number

multiple of the molar mass for the empirical formula.

• If the empirical formula of a compound is CH2 and its

molar mass is 42 g/mol, what is its molecular formula?

56
Example Problem 3.9
• An alloy contains 70.8 mol % palladium and 29.2 mol %
nickel. Express the composition of this alloy as weight
percentage (wt %).

57
Molarity
• Molarity, or molar concentration, M, is the number of moles of
solute per liter of solution.

• Provides relationship among molarity, moles solute, and

liters solution.

moles of solute
Molarity (M ) =
liter of solution

• If we know any two of these quantities, we can

determine the third.

58
Example Problem 3.10
• A solution is prepared by dissolving 45.0 g of NaClO in
enough water to produce exactly 750 mL of solution. What is
the molarity of this solution?

59
Dilution
• Dilution is the process in which solvent is added to a solution
to decrease the concentration of the solution.

• The number of moles of solute is the same before and

after dilution.

• Since the number of moles of solute equals the product of

molarity and volume (M  V), we can write the following
equation, where the subscripts denote initial and final
values.
M i  Vi = M f  Vf
60
Example Problem 3.11
• A chemist requires 1.5 M hydrochloric acid, HCl, for a series
of reactions. The only solution available is 6.0 M HCl. What
volume of 6.0 M HCl must be diluted to obtain 5.0 L of 1.5 M
HCl?

61
Explosive and Green Chemistry
• Green chemistry: the philosophy that
chemical processes and products
should be designed with the goal of
reducing environmental impacts

• Firing of guns involves detonating

a primer, which then induces a
larger explosion.

• Traditional primers are lead-

based, e.g., Pb(N3)2

• Research is underway to find

less toxic primers

62