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    Mini Project On: Manufacturing of Polyvinyl Chloride: by Kamlesh Choudhary (1032171100) Yash Bhutada (1032171401)

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    yash bhutada
    The document summarizes the manufacturing process of polyvinyl chloride (PVC). It discusses that PVC is produced via the suspension polymerization of vinyl chloride monomer. This exothermic reaction occurs between 35-70°C and 0.4-1.2 MPa pressure. The suspension process disperses monomer droplets in water with suspending agents. After polymerization, the PVC slurry is separated and the polymer recovered. The document also provides market details on PVC producers and consumers as well as a process flow diagram and references for the PVC production method.

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    Mini Project On: Manufacturing of Polyvinyl Chloride: by Kamlesh Choudhary (1032171100) Yash Bhutada (1032171401)

    Uploaded by

    yash bhutada
    80 views9 pages
    The document summarizes the manufacturing process of polyvinyl chloride (PVC). It discusses that PVC is produced via the suspension polymerization of vinyl chloride monomer. This exothermic reaction occurs between 35-70°C and 0.4-1.2 MPa pressure. The suspension process disperses monomer droplets in water with suspending agents. After polymerization, the PVC slurry is separated and the polymer recovered. The document also provides market details on PVC producers and consumers as well as a process flow diagram and references for the PVC production method.

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    The document summarizes the manufacturing process of polyvinyl chloride (PVC). It discusses that PVC is produced via the suspension polymerization of vinyl chloride monomer. This exothermic reaction occurs between 35-70°C and 0.4-1.2 MPa pressure. The suspension process disperses monomer droplets in water with suspending agents. After polymerization, the PVC slurry is separated and the polymer recovered. The document also provides market details on PVC producers and consumers as well as a process flow diagram and references for the PVC production method.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    80 views9 pages

    Mini Project On: Manufacturing of Polyvinyl Chloride: by Kamlesh Choudhary (1032171100) Yash Bhutada (1032171401)

    Uploaded by

    yash bhutada
    The document summarizes the manufacturing process of polyvinyl chloride (PVC). It discusses that PVC is produced via the suspension polymerization of vinyl chloride monomer. This exothermic reaction occurs between 35-70°C and 0.4-1.2 MPa pressure. The suspension process disperses monomer droplets in water with suspending agents. After polymerization, the PVC slurry is separated and the polymer recovered. The document also provides market details on PVC producers and consumers as well as a process flow diagram and references for the PVC production method.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    of 9

    Mini Project on :

    MANUFACTURING OF POLYVINYL CHLORIDE


    By
    Kamlesh Choudhary (1032171100)
    Yash Bhutada (1032171401)

    Guided By: Dr. Dinesh Bhutada


    Introduction:
    • A synthetic resin made from the polymerization of vinyl chloride.
    • Versatile properties: Lightweight, Durable, Low Cost and Easy Processability
    • Polymerization of PVC is an exothermic reaction.
    • The raw material for the PVC production is vinyl chloride monomer, Initiator (Benzoyl Peroxide)
    • The pressure in the reactor is usually in the range of 0.4 – 1.2 MPa and the reaction temperature is
    between 35 – 70°C.
    • For polymerization of PVC we use Suspension technique according to the literature survey.
    Market Survey:
    • Globally, Polymer industry is one of the leading contributors to economic growth.
    • Global PVC demand in 2013 was observed to be approximate 39.3 million metric tons (MMT). Asia
    having 43% share.
    • Currently PVC consumption in India is about 2.3 MMT against domestic production capacity of 1.3
    MMT, this is leading to demand-supply imbalance resulting in imports of 1 MMT PVC resin in the
    country.
    • Top 5 PVC producing countries includes China, USA, Germany, Japan, France.
    • Shin-Etsu, Formosa Group, Occidental, Solvay, INEOS, LG Group, Georgia Gulf and Reliance
    Industries being some of the leading producers of PVC in the world.
    Selection of Process:
    • Suspension polymerization is the most prevalent technology in the world today
    • Licensors for this technology are INEOS Technologies (UK) and Oxy Vinyl Corporation (US).
    • In this process Vinyl Chloride Monomer (VCM) droplets are dispersed in water medium aided with suspending agents
    and agitated in the Reactors
    • The polymer slurry from the reactors is first separated from unconverted VCM by steam stripping.
    • Emulsion polymerization is the difficulty in coagulating and separating the polymer from the latex.
    • On the other hand, suspension polymerization can produce a granular product directly of high productivity per unit
    reactor volume, its flexibility with regard to polymer composition and resin particle characteristics and the granular
    nature of its product.
    • The Emulsion Polymerization process is similar to the suspension process except that large amounts of emulsifying
    agents are used which result in very fine PVC particles. Consequently, separation of these fine PVC particles from
    water cannot be done by centrifuging action
    Process Flow Diagram: (PFD)

    Ref: [2]
    Thermodynamics:

    ΔH= Hid - H° 2866.8

    ΔS= Sid - S° 122.885982


    C:\Users\Admin\3D Objects\MINI PROJECT\EXCEL PVC.xlsx

    T 328
    T° 298

    ΔG = ΔH- TΔS   
    ΔG -37439.802J/mol
      -37.439802KJ/mol
    For
    1. Material Balance & Energy Balance
    2. Equipment Design
    C:\Users\Admin\3D Objects\MINI PROJECT\EXCEL PVC.xlsx

    For
    Costing
    Costing OF PVC plant (1).xlsx
    Piping & Instrumentation Diagram
    References:
    1. The European Council of Vinyl Manufacturers, May 2015, Reviewer: Matthias Schulz, DEKRA Assurance Services GmbH, Stuttgart, Germany.
    2. VCM- Based PVC Production, Scribd: 424947416
    3. https://www.polarismarketresearch.com/
    4. https://www.techsciresearch.com/
    5. Chemicals and Petrochemicals Manufacturers Association, India (CPMA)
    6. http://environmentclearance.nic.in/
    7. S-PVC Manufacturing Technology, Luqman Ahmad Shahid, Engro Polymer & Chemicals Ltd.
    8. Drying of Polymers, by Arun S. Majumdar & Mainul Hasan; DOI:10.1201/9781420017618.ch41, Nov 2016.
    9. http://environmentclearance.nic.in/
    10.Chemical Process Design: Computer-Aided Case Studies. Alexandre C. Dimian and Costin Sorin Bildea, 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim ISBN:
    978-3-527-31403-4
    11.Modelling of industrial S-PVC reactor. Thor Mejdell, Torbjorn Pettersen, Christian Naustdal, Hallvard F. Svendsen, SINTEF Applied Chemistry, N-7034 Trondheim, Norway.
    12.CRC HANDBOOK of CHEMISTRY & PHYSICS, David R. Lide, 84 th Edition 2003-2004.
    13.www.chemeo.com
    14.http://polymerdatabase.com/
    15.Chemical Engineering Design by Sinnot & Towler
    16.Using the max. ratio, Perry's Chemical Engineers Handbook 8th Edition 18-14
    17.Plant Design & Economics for Chemical Engineering 5th Edition by Peters and Timmerhaus
    18.Hazard & Operability Analysis of a PVC Manufacturing Plant at Karachi, Pakistan; Journal of Applied and Emerging Sciences, 2019, Vol (9), Issue (01).

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