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SOIL REACTION

Soil reaction is one of the most important

physiological characteristics of the soil

solution.

The presence and development of micro-

organisms and higher plants depend upon the

chemical environment of soil.

There fore study of soil reaction is important in

soil science.
Soil
Acidic Reaction
Neutral

Alkalin
e
ACIDIC 

It is common in region where precipitation is high.

The high precipitation leaches appreciable amounts

of exchangeable bases from the surface layers of the

soils so that the exchange complex is dominated by

H ions.

Acid soils, therefore, occur widely in humid regions

and affect the growth of plants markedly.


ALKALINE

Alkali soils occur when there is comparatively high

degree of base saturation.

Salts like carbonates of calcium, magnesium and

sodium also give a preponderance of OH ions over

H ions in the soil solution.

When salts of strong base such as sodium carbonate

go into soil solution and hydrolyze, consequently

they give rise to alkalinity.


NEUTRAL

Neutral soils occur in regions where H ions just

balance OH ions.
Extremely acid: < than 4.5; lemon=2.5; vinegar=3.0; stomach
acid=2.0; soda=2–4
Very strongly acid: 4.5–5.0; beer=4.5–5.0; tomatoes=4.5
Strongly acid: 5.1–5.5; carrots=5.0; asparagus=5.5; boric
acid=5.2; cabbage=5.3
Moderately acid: 5.6–6.0; potatoes=5.6
Slightly acid: 6.1–6.5; salmon=6.2; cow's milk=6.5
Neutral: 6.6–7.3; saliva=6.6–7.3; blood=7.3; shrimp=7.0
Slightly alkaline: 7.4–7.8; eggs=7.6–7.8
Moderately alkaline: 7.9–8.4; sea water=8.2; sodium
bicarbonate=8.4
Strongly alkaline: 8.5–9.0; borax=9.0
Very strongly alkaline: > than 9.1; milk of magnesia=10.5,
ammonia=11.1; lime=12
SOIL pH

The reaction of a solution represents the degree of acidity

or alkalinity caused by the relative concentration of H ions

(acidity) or OH ions present in it.

Acidity is due to the excess of H ions over OH ions, and

alkalinity is due to the excess of OH ions over H ions.

A neutral reaction is produced by an equal activity of H and

OH ions.

According to the theory of dissociation, the activity is due

to the dissociation or ionization of compounds into ions.


MEASURING SOIL pH

Soil pH provides various clues about soil properties and is

easily determined.

The most accurate method of determining soil pH is by a

pH meter.

A second method which is simple and easy but less

accurate then using a pH meter, consists of using certain

indicators or dyes.
Many dyes change colour with an increase or decrease of

pH making it possible to estimate soil pH.

In making a pH determination on soil, the sample is

saturated with the dye for a few minutes and the colour

observed.

This method is accurate enough for most purposes.


Hydrangea is a genus of 70–75 species of flowering

plants native to southern and eastern Asia (China, Japan,

Korea, the Himalayas, and Indonesia) and the Americas.

By far the greatest species diversity is in eastern Asia,

notably China, Japan, and Korea.

Most are shrubs 1 to 3 meters tall, but some are

small trees, and others reaching up to 30 m (98 ft) by

climbing up trees.

In most species the flowers are white, but in some species,

can be blue, red, pink, light purple, or dark purple.


In these species the colour is affected by soil pH.

The flower colour can be determined by the relative acidity

of the soil: an acidic soil (pH below 7), by the influence

alum or iron, will usually produce flower colour closer to

blue, whereas an alkaline soil (pH above 7) will produce

pinker flowers.

This is caused by a colour change of the flower pigments in

the presence of aluminium ions which can be taken up

into hyper accumulating plants.


Causes of Soil Acidity

Acid Rain

Fertilizer

Decomposition of organic matter

Correction of Soil Acidity

Adding of Lime
Causes of Soil Alkalinity

Over liming

Alkaline water irrigation

Weathering of calcium carbonate rich

rocks

Correction of Soil Alkalinity

Adding of Fertilizers/Organic matter


pH AFFECTS NUTRIENTS, MINERALS AND GROWTH

The effect of soil pH is great on the solubility of minerals

or nutrients. Fourteen of the seventeen essential plant

nutrients are obtained from the soil.

Before a nutrient can be used by plants it must be

dissolved in the soil solution.

Most minerals and nutrients are more soluble or

available in acid soils than in neutral or slightly alkaline

soils.
Phosphorus is never readily soluble in the soil but is

most available in soil with a pH range centred around

6.5.

Extremely and strongly acid soils (pH 4.0-5.0) can have

high concentrations of soluble aluminium, iron and

manganese which may be toxic to the growth of some

plants.

A pH range of approximately 6 to 7 promotes the most

ready availability of plant nutrients.


But some plants, such as azaleas, rhododendrons,

blueberries, white potatoes and conifer trees, tolerate

strong acid soils and grow well.

Also, some plants do well only in slightly acid to

moderately alkaline soils.

However, a slightly alkaline (pH 7.4-7.8) or higher pH soil

can cause a problem with the availability of iron to pin oak

and a few other trees in Central New York causing

chlorosis of the leaves which will put the tree under stress

leading to tree decline and eventual mortality.


The soil pH can also influence plant growth by its

effect on activity of beneficial microorganisms

Bacteria that decompose soil organic matter are

hindered in strong acid soils.

This prevents organic matter from breaking down,

resulting in an accumulation of organic matter and

the tie up of nutrients, particularly nitrogen, that are

held in the organic matter.

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