Hqfa 513 K 2 Lo 70709560 ECPPT

Presentation for Environmental Clearance before EAC (Industry-3), MoEFCC, New
Delhi on, 2022 and Agenda No.

FOR
Proposes Pesticide Products and Specialty Chemicals
(8712 MT/Annum) Manufacturing Unit
OF
M/s. SHREE GANESH REMEDIES LTD (UNIT-5)
Plot No. D-2/17/16, Dahej-II, GIDC Estate,
Tal: Vagra, Dist: Bharuch, Gujarat-392130.
Proposal No.: IA/GJ/IND3/241900/2021

TOR Letter.: IA-J-11011/396/2021-IA-II(I); Dated: 10 December 2021
Baseline Monitoring Season: October, 2020 to December, 2020
Category: A- 5(b) & 5 (f)
Prepared By:
Aqua-Air Environmental Engineers P. Ltd.
403, Centre Point, Nr. Kadiwala School, Ring Road, Surat – 395002
(NABET/QCI Accredited EIA Consultant):
NABET/EIA/2023/IA0062 (Rev. 03) till 7 October, 2023
(MoEF Accredited Testing Laboratory): 15018/24/2019-CPW
(NABL Accredited Testing Laboratory): TC - 7328
(GPCB Recognized Schedule-II Environmental Auditor)
ISO 9001: 2015 Certified Company
ISO 45001 : 2018 Certified Company
1
PROJECT STATUS
Name of Project: Proposes Pesticide Products and Specialty Chemicals (8712 MT/Annum) Manufacturing
Unit at Plot No. D-2/17/16, Dahej-II, GIDC Estate, Tal: Vagra, Dist: Bharuch, Gujarat-392130 By M/s. Shree
Ganesh Remedies Ltd (Unit-5) – Environmental Clearance.
Agenda No.:
 Date of Application Submission: 06/12/2021
 Date of Acceptance: 10/12/2021
 New/Expansion Project: New Project
 Total Capacity: Pesticide Products and Specialty Chemicals (8712 MT/Annum)
 Date of Public Hearing: Unit is located in PCPIR region of Notified Industrial estate of GIDC Dahej-II. So
Public Hearing is exempted
 Name of EIA Co-ordinator: Mr. Jayesh S. Patel

 Name of Consultant: M/s. Aqua Air Environmental Engineers Pvt. Ltd.
 NABET Accreditation No.: NABET/EIA/2023/IA0062 (Rev. 03) till 7 October, 2023
 Details of Earlier ECs with Past Productions Details: Not Applicable, This is new project
Details of Earlier CTOs with Past Productions: Not Applicable, This is new project
2
INTRODUCTION OF THE PROJECT
Brief Description about Project: Proposes Pesticide Products and Specialty Chemicals (8712 MT/Annum)
Manufacturing Unit at Plot No. D-2/17/16, Dahej-II, GIDC Estate, Tal: Vagra, Dist: Bharuch, Gujarat-392130
By M/s. Shree Ganesh Remedies Ltd (Unit-5)
 Total Plot Area: 40554.30 m2
% of green belt provided: Total 40554.30 sq. meter land area is available at site; out of this area about
13382.92 sq. meter (33 %) area is covered as greenbelt and other forms of greenery.
 Land use Change required: Total land area is 40554.30 m2, Processing Area (Plant facilities, ETP Area and
Engineering/Utility Services) = 14037.65 m 2 and Non Processing Area (Green belt, Raw material storage
area, finished storage area, Administration Building, Road and etc.) = 26516.65 m 2
 Sources of Air Pollution: The main sources of air pollution will be 7 nos. of Flue gas emission, 5 nos. of
Process gas emission and fugitive emission.
 Sources of Noise Pollution: High noise generating equipment, DG Sets, Transportation activities, etc.
33
PRODUCTS WITH CAPACITIES FOR THE PROPOSED PROJECT
Sr. Name of Products Quantity CAS No. LD50 (mg/Kg) Category
No. MT/Annum
Agro Chemicals
1 2,4 dichlorophenoxyacetic acid (2,4-D) 94-75-7 3670 5(b)
2 Benfuresate 68505-69-1 2031 5(b)
3 Fluopicolide 239110-15-7 5000 5(b)
4 Anilofos 1200 64249-01-0 1681 5(b)
5 Triazophos 24017-47-8 1100 5(b)
6 Deltamethrin 52918-63-5 5 5(b)
7 Flumethrin 69770-45-2 2000 5(b)
Intermediates
8 1-[4-[2-(cyclopropylmethoxy)ethyl]phe noxy]-3-(propan-2- 1200 56392-17-7 -- 5(f)
ylamino)propan-2-ol
9 (R)-3-Amino-1-butanol 61477-40-5 -- 5(f)
10 2-Aminomethyl-1- ethylpyrrolidine 22795-99-9 -- 5(f)
11 1,3-Dimethyladamantane 702-79-4 -- 5(f)
12 (R)-2-hydroxy-4- phenylbutanoic acid ethyl ester 90315-82-5 -- 5(f)
13 Trans-4-aminocyclohexanol 27489-62-9 -- 5(f)
14 2-Ethyl-2-methylbutanoic acid 19889-37-3 -- 5(f)
15 49708-81-8 -- 5(f)
trans-4-(4- Chlorophenyl)cyclohexanecarb oxylic acid
16 4,4’-dimethylbiphenyl 613-33-2 -- 5(f)
17 4-Phenylbenzonitrile 2920-38-6 -- 5(f)
18 2-Methyl-[1,1'-biphenyl]-3- yl)methanol-- 76350-90-8 -- 5(f)
19 3-Chloro-2-methyl-1,1'- biphenyl 20261-24-9 -- 5(f)
20 2-Fluorophenol 367-12-4 -- 5(f)
21 2-Fluoroanisole 321-28-8 -- 5(f)
22 2-Chloro-6-fluoroanisole 363-51-9 -- 5(f)
23 (2-Chloro-4-fluoro-3- methoxyphenyl)boronic acid 944129-07-1 -- 5(f)
24 1H-Pyrrole 109-97-7 -- 5(f)
44
No. MT/Annum
25 2-Chlorobenzonitrile 873-32-5 -- 5(f)
26 1-Methoxy-2-propylamine 37143-54-7 -- 5(f)
27 Bicyclo[4.2.0]octa-1,3,5-triene [Benzocyclobutene] 694-87-1 -- 5(f)
28 N,N'-(2-(4-(2-aminobenzamido)butyl)pentan e-1,5- 951-985-7 -- 5(f)
diyl)bis(2- aminobenzamide)
29 4,5,6,7-Tetrahydrothieno[3,2- c]pyridine Hydrochloride 28783-41-7 -- 5(f)
30 3,5-Dimethylbenzoyl chloride 6613-44-1 -- 5(f)
31 1-(4-Chlorophenyl)-4,4- dimethyl-3-pentanone 66346-01-8 -- 5(f)
32 2,4,6-triaminopyrimidine 1004-38-2 -- 5(f)
33 dl-2,2-Dimethyl cyclopropane- 1-carboxylic acid 931-26-0 -- 5(f)
34 4-Morpholinopiperidine 53617-35-9 -- 5(f)
35 4,4'--DIMETHOXYTRITYL CHLORIDE 40615-36-9 -- 5(f)
36 4-Hydroxy Benzyl Alcohol 623-05-2 -- 5(f)
37 4 (2-chloro Ethyl ) MorpholineHCl 3647-69-6 -- 5(f)
38 Di Methyl Amino Isopropyl Chloride HCl 4584-49-0 -- 5(f)
39 4- ChloroButyryl Chloride 4635-59-0 -- 5(f)
40 Methyl 4- chlorobutyrate 3153-37-5 -- 5(f)
41 Cyclorpropane Carbonyl Chloride 4023-34-1 -- 5(f)
42 Cyclohexane Carbonyl chloride 2719-27-9 -- 5(f)
43 2- Furoyl Chloride 527-69-5 -- 5(f)
44 O- Acetylsalicloyl Chloride 5538-51-2 -- 5(f)
Building Blocks
45 1,1-Cyclobutane dicarboxylic acid 1200 5445-51-2 -- 5(f)
46 Cyclobutane carboxylic acid 3721-95-7 -- 5(f)
47 Cyclobutane carbonyl chloride 5006-22-4 -- 5(f)
48 Cyclobutyl carbinol 4415-82-1 -- 5(f)
5
No. MT/Annum
49 Cyclobutyl carboxaldehyde 3019-25-8 -- 5(f)
50 Cyclobutyl methyl Chloride 5911-08-0 -- 5(f)
51 Cyclopropyl boronic acid 411235-57-9 -- 5(f)
Aroma
52 1-Cyclopropylmethyl-4-methoxybenzene 1200 16510-27-3 -- 5(f)
53 2-(3,5-dimethylhex-3-en-2-yloxy)-2-methylpropyl 676532-44-8 -- 5(f)
cyclopropanecarboxylate
54 4-Methylpropiophenone 5337-93-9 -- 5(f)
55 Cyclopropyl 4-methoxyphenyl ketone 7152-03-6 -- 5(f)
56 1-(4-Chlorophenyl)cyclopropanecarboxylic acid 72934-37-3 -- 5(f)
57 Para Anisyl Acetate 104-21-2 -- 5(f)
58 (E,Z)-7,9-Dodecadienyl acetate 55774-32-8 -- 5(f)
59 (Z)-13-Icosen-10-one 63408-44-6 -- 5(f)
60 cis-7,8-Epoxy-2-methyloctadecane 29804-22-6 -- 5(f)
61 (Z,E) -9,12-Tetradecadienyl acetate 69775-62-8 -- 5(f)
62 (Z)-11-Tetradecenyl acetate 20711-10-8 -- 5(f)
63 (E,Z)-3,13-Octadecadien-1-ol 53120-26-6 -- 5(f)
64 (Z,Z)-3,13-Octadecadien-1-ol 53120-27-7 -- 5(f)
65 (Z)-4-Tridecen-1-yl acetate 65954-19-0 -- 5(f)
66 (E)-4-Tridecen-1-yl acetate 72269-48-3 -- 5(f)
67 (E,E) -8,10-Dodecadien-1-ol 77967-64-7 -- 5(f)
68 (Z)-11-Hexadecenyl Acetate 34010-21-4 -- 5(f)
69 Methyl p-anisate 121-98-2 -- 5(f)
Fine Chem
70 Norcamphor 1200 497-38-1 -- 5(f)
71 Anethol 104-46-1 -- 5(f)
6
No. MT/Annum
72 2,4 Dihydroxy Benzophenone 131-56-6 -- 5(f)
73 7-Octyne-1-ol 871-91-0 -- 5(f)
74 4-Pentenoic Acid 591-80-0 -- 5(f)
75 4-Hexy Resorcinol 136-77-6 -- 5(f)
76 2-Cyano Phenol 611-20-1 -- 5(f)
77 7 – Bromo, 1 - heptene 4117-09-3 -- 5(f)
78 1-Cyano-Cyclobutane-1,2-dicarboxylic acid dimethyl ester 14132-45-7 -- 5(f)
79 E-Tetraacetate 15956-28-2 -- 5(f)
80 N-Methyl-4-Chloro Piperidine HCl 5570-77-4 -- 5(f)
81 Syringaldehyde 134-96-3 -- 5(f)
82 Indoline 120-72-9 -- 5(f)
83 2-p-Anisyl Propanal 5462-06-6 -- 5(f)
84 4-Amino Benzonitril 873-74-5 -- 5(f)
85 Acrylamide Purified 79-06-1 -- 5(f)
86 Ethylenediaminetetraacetic Acid Metal Chelate salts 60-00-4 -- 5(f)
87 Sodium Selenite Pentahydrate 26970-82-1 -- 5(f)
88 Peonile 10461-98-0 -- 5(f)
89 4,5-Dichloro phthalic Acid 56962-08-4 -- 5(f)
90 2-Nitro 4-Methoxy Aniline 96-96-8 -- 5(f)
91 97-52-9/ -- 5(f)
4 - Nitro-2-MethoxyAniline and 5-Nitro 2-Methoxy Aniline 99-59-2
Inorganic Products
92 Sodium Sulfite 867 7757-83-7 -- 5(f)
93 Calcium Chloride Fused Powder / Lumps 1785 7440-70-2 -- 5(f)
94 R&D 60 --
TOTAL 8712 --
MT/ANNUM 7
 Flue gas emission:
STACK PARAMETERS
Sr. AIR POLLUTION
SOURCE OF EMISSION HEIGHT FUEL
No. CONTROL SYSTEM
(METER)
Imported Coal - 13.5 ESP + Water
1 Boiler -(8 TPH) 30 MT/Day Scrubber
Imported Coal - 6.5 MCS + Bag filter +
2 Boiler -(3 TPH) 30 MT/Day Pollutants Water Scrubber
Natural Gas - 150 M3/Hr SPM=≤ 150 Adequate stack
3 Boiler -(3 TPH) 20 mg/Nm3 height
Thermic Fluid Heater (3 Lakhs Adequate stack
4 20 Natural Gas - 50 M3/Hr SOX=≤ 262
Kcal/Hr) height
mg/Nm3
HAG – 1 Lakh Kcal/Hr - 2 Nos. Natural Gas – 30 M3/Hr Adequate stack
5 20
(For Spray Dryer) NOX=≤ 94 height
HSD - 480 Liters/hr mg/Nm3 Adequate stack
6 D G Set(1000 KVA) 12
height
HSD - 240 Liters/hr Adequate stack
7 D G Set(500 KVA) 12
height
 Process gas emission:

Sr. VENT ATTACHED TO STACK POLLUTANTS AIR POLLUTION CONTROL SYSTEM
No. HEIGHT
(METER)
1 Process vent (Product No - 29) 12 HCl Two Stage Water Scrubber
2 Process vent (Product No - 94) 12 Cl2 Two Stage Water+ Alkali Scrubber
3 Process vent (Product No - 26) 12 NH3 Two Stage Water Scrubber
4 Process vent (Product No - 83) 12 HBr Two Stage Water Scrubber
5 Process vent (Product No - 3) 12 HCl & SO2 Two Stage Water +Alkali Scrubber
88
 Estimated Project Cost: Total cost of the project will be Rs. 55 Crores
 EMP Cost: Rs. 5 Crores
 CER Cost: Rs. 110 Lakh (2% of Total Project Cost)
 Manpower: 100 Nos.
 Details of Environment Officer: Mr. Akash kanani
 Water Consumption: 570.5 KL/Day (Fresh: 300 KL/Day + Reused: 270.5 KLD) from GIDC water supply)
 Wastewater Generation: Total: 360 KL/Day (Industrial: 348.5 KL/Day + Domestic: 11.5 KL/Day)
 Source of water: GIDC Water Supply of quantity : 300 KL/Day
 Permission from GIDC water supply: Water supply letter No. GIDC/DEE/WS/BRH/1311, Dated:
11/01/2022
 Energy Consumption: From DGVCL = 1000 KVA
DG Set = 500 KVA* 1 Nos. & 1000 KVA*1 Nos. (Emergency power back up)
 Fuel used & Quantity:
Sr. No. Name Of Fuel Quantity
1. Imported Coal 20 MT/Day
2. Natural Gas 230 M3/Hr
3. HSD 720 Liters/Hr
99
 Water Consumption: 570.5 KL/Day (Fresh: 300 KL/Day + Reuse: 270.5 KL/Day)
 Wastewater Generation: 5.8 KL/Day (Industrial: 348.5 KL/Day + Domestic: 11.5 KL/Day)
 Treatment facility with capacity and current operational capacity :
 Total water requirement will be 570.5 KL/Day (Fresh water: 300 KLD + Reuse: 270.5 KLD) which will be
met through GIDC water supply.
 Scrubbing Media: Effluent from Scrubber (7.5 KL/Day), in which 4.5 KL/Day will sell to end users under
Rule-9 Permission & 3 KL/Day will reuse for production of product no. 92 & 93.
 Domestic waste water (11.5 KL/Day) will treat in STP & (11.5 KL/Day) will reuse in cooling.
 Effluent from Process & R&D (141 KL/Day) & washing (20 KL/Day) Total 161 KL/Day will treat in Solvent
Stripper then treat in ETP having primary treatment then treat in MEE & MEE Condensate 131 KL/Day
will reuse in plant premises.
 Boiler & Cooling Condensate 96 KL/Day & 32 KL/Day will reuse in Boiler & Cooling.
 Mode of Discharge: Effluent from Process Low COD (96 KL/Day) & Utility (84 KL/Day) will be treat in
ETP & treated effluent (180 KL/Day) will be sent to CETP, Dahej for further Treatment & Disposal.
10
10
Hazardous Waste : 17 categories of hazardous waste There will generate 17 nos. of hazardous waste
(Discarded Containers/Bags/Liners, Used/Spent oil, Spent Solvent, Distillation Residue, Stripper Residue,
Spent Carbon, MEE Salt, Inorganic Salt, ETP Sludge/STP Sludge, Spent Catalyst, Sodium Chloride, NaSH
(30%), Dilute HBr, Dilute NH3, Sodium Bisulphite, HCl (30%), Ash from Boiler.
 Disposal of Hazardous Waste :

Sr. Source of Category Proposed
No. Name of waste Generation No. Quantity Mode of Disposal
(MT/Annum)
Storage & Collection, Storage, Transportation,
1 Discarded handling of Raw Sch-I/ 120 Decontamination & Disposal by selling to
Containers/Bags/Liners Materials 33.1 registered recycler.
Equipment & Sch-I/ Collection, Storage, Transportation and

2 Used/Spent oil Machineries 5.1 15 reused for Machine Lubrication / Given to
GPCB registered reprocessor.
3 Spent Solvent Process Sch-I/ 19696 Collection, Storage, distill & Reuse within
28.6 plant premises.
4 Distillation Residue Solvent Sch-I/ 560
Distillation 20.3
Sch-I/ Collection, Storage, Transportation and
5 Stripper Residue Solvent Stripper 35.3 1152 sell to co-processing or sent to Common
Incineration Facility.
6 Spent Carbon Process Sch-I/ 72
(Product No 6) 29.1
7 MEE Salt MEE Sch-I/ 1134
35.3
8 Inorganic Salt Process Sch-I/ 891 Collection, Storage, Transportation and
29.1 sent to common TSDF.
9 ETP Sludge In-house ETP Sch-I/ 1265.82
35.3
11
11
 Disposal of Hazardous Waste :
Sr. Source of Category Proposed
No. Name of waste Generation No. Quantity Mode of Disposal
(MT/Annum)
10 Spent Catalyst Process Sch-I/ 222 Collection, Storage, Transportation and

(Product No 12) 29.5 sent to regenerator.
Process Sch-I/
11 Sodium Chloride (Product No 24 + 938.46
Scrubber) 29.1
Process Sch-I/
12 NaSH(30%) (Product No 4) 708
29.1 Collection, Storage, Transportation &
Disposal by selling to authorized end
Sch-I/ user registered under Rule-9.
13 Dilute HBr Scrubber 547.5
28.1
Sch-I/
14 Dilute NH3 Scrubber 547.5
28.1
Process Sch-I/ Collect, Storage & will reuse in
15 Sodium Bisulphite (Product No 43 + 3034.8 production of Sodium Sulfite within
Scrubber) 28.1 the plant premises.
Process Sch-II- Collect, Storage & will reuse in

16 HCl (30%) (Product No 45) + Class 2976.30 production of Calcium Chloride Fused
Scrubber B(15) Powder / Lumps within the plant
premises.
Non-Hazardous Waste
17 Ash from Boiler -- -- 365 Collect, Storage & Sell to Brick

Manufacturer.
12
12
Location Of Project And Its Connectivity
5
K10
mKm
Sr. No. Nearest Infrastructure Feature Distance from Project Area Latitude 21°43'33.25"N
1 National Highway NH-228 27.24 Km
Longitude 72°41'13.13"E
2 State Highway – 161 23.77 Km
3 Bharuch Railway Station 32.50 Km Elevation 9 meter
4 Vadodara Airport 86.70 Km HTL 16.36 Km
5 CETP, Dahej 6.68 Km
LTL 19.65 Km
6 M/s. MRF Limited Dahej 1.10 Km
7 M/s. GACL Dahej 1.22 km 13
13
TOPOGRAPHICAL MAP
14
14
PROJECT SITE TO BE SHOWN ON GOOGLE EARTH WITH 10 KM RADIUS
15 15
ENGINEERING LAYOUT OF THE PROJECT SITE
16
16
PROJECT SITE SHOWN ON GOOGLE EARTH
DETAILS OF PUBLIC HEARING

Unit is located in PCPIR region of Notified Industrial estate of GIDC Dahej-II. Hence Public Hearing is
exempted.
17
17
BASELINE ENVIRONMENT DETAILS
Baseline Monitoring study is carried out by NABL Approved Laboratory – M/s. Aqua Air Environmental Engineers
Pvt. Ltd.
NABL Certificate:
18
18
BASELINE ENVIRONMENT DETAILS
Baseline Monitoring study is carried out by MoEFCC Approved Laboratory – M/s. Aqua Air Environmental Engineers
Pvt. Ltd.
MoEFCC Certificate:
19
19
1. AIR QUALITY
 Monitoring Period: October 1, 2020 to December 31, 2020
 Locations Of The Ambient Air, Noise, Water And Soil
 Ambient Air Quality Status: (October 1, 2020 to December 31, 2020)
SR. NAME OF VILLAGE BEARING APPROXIMATE AMBIENT NOISE WATER SOIL TYPE OF
NO. W.R.T. RADIAL DISTANCE AIR AREA
PROJECT SITE FROM PROJECT
SITE (KM)
1. Project site -- -- A1 N1 GW1 S1 Industrial

2. Suva SW 5.06 A2 N2 GW2 S2 Residential
3. Vadadla WNW 5.56 A3 N3 GW3 S3 Residential
4. Khojbal ENE 6.88 A4 N4 GW4 S4 Residential
5. Akhod NNE 3.42 A5 N5 GW5 S5 Residential
6. Galenda NW 2.21 A6 N6 GW6 S6 Residential
7. Jolva WSW 3.74 A7 N7 GW7 S7 Residential
8. Nandida NE 5.76 A8 N8 GW8 S8 Residential
9. Nadarkha NNE 6.95 A9 N9 GW9 S9 Residential
10. Jolva Pond WSW 3.74 -- -- SW1 -- Residential
11. Suva Pond SW 5.56 -- -- SW2 -- Residential
12. Nandida Pond NE 5.76 -- -- SW3 -- Residential
13. Vadadla Pond WNW 5.56 -- -- SW4 -- Residential
14. Kadodara Pond NW 6.06 -- -- SW5 -- Residential
15. Sambheti Pond NW 4.60 -- -- SW6 -- Residential
16. Akhod Pond NNE 3.26 -- -- SW7 -- Residential
17. Atali Pond E 1.72 -- -- SW8 -- Residential
20
20
WIND ROSE DIAGRAM
PROJECT SITE TO BE SHOWN ON GOOGLE EARTH

WITH 10 KM RADIUS
21
1. AIR QUALITY
Sr. Sampling SPM PM10 PM2.5 SO2 NO2 NH3 O3 VOC CO
No. Sampling Duration ppm mg/m3
Location g/m3
1. Project site (A1) 24 hours 131.5 76.10 43.25 15.04 16.67 BDL 11.09 0.6 1.19
2. Suva(A2) 24 hours 134.1 77.69 46.68 17.72 19.08 BDL 11.12 0.3 1.35
3. Vadadla(A3) 24 hours 130.9 77.23 45.84 16.73 18.06 BDL 10.12 0.6 1.22
4. Khojbal(A4) 24 hours 127.6 75.38 44.76 17.71 18.38 BDL 10.14 0.6 BDL
5. Akhod(A5) 24 hours 128.4 74.54 44.17 16.89 17.45 BDL 10.32 0.6 1.16
6. Galenda(A6) 24 hours 128.9 76.58 45.28 16.93 18.13 BDL 10.2 0.5 1.28
7. Jolva(A7) 24 hours 132.5 78.04 46.46 17.82 18.08 BDL 9.74 0.4 BDL
8. Nandida(A8) 24 hours 134.7 76.35 46.69 16.84 18.51 BDL 12.43 0.5 1.15
9. Nadarkha(A9) 24 hours 123.9 72.74 41.84 13.87 14.59 BDL 11.62 0.6 BDL
NAAQS -- 100 60 80 80 400 180 -- 4
Sr. Pb C6H6 Ni As BaP HC HBr HCl Cl2
No. Sampling ppm
Location ng/m3 g/m3
g/m3
1. Project site (A1) BDL BDL BDL BDL BDL BDL BDL BDL BDL
2. Suva(A2) BDL BDL BDL BDL BDL BDL BDL BDL BDL
3. Vadadla(A3) BDL BDL BDL BDL BDL BDL BDL BDL BDL
4. Khojbal(A4) BDL BDL BDL BDL BDL BDL BDL BDL BDL
5. Akhod(A5) BDL BDL BDL BDL BDL BDL BDL BDL BDL
6. Galenda(A6) BDL BDL BDL BDL BDL BDL BDL BDL BDL
7. Jolva(A7) BDL BDL BDL BDL BDL BDL BDL BDL BDL
8. Nandida(A8) BDL BDL BDL BDL BDL BDL BDL BDL BDL
9. Nadarkha(A9) BDL BDL BDL BDL BDL BDL BDL BDL BDL
NAAQS 1 6 20 5 01 -- -- 200 100
Note: BDL = Below Detectable Limit
22
22
1. AIR QUALITY
 Summary
 During the study SPM concentration was observed in the range of 123.9 – 134.7 µg/m3. Maximum concentration of
SPM was found at Nandida (134.7 µg/m3), which is well within the standard NAAQS limit.
 During the study PM10.0 concentration was observed in the range of 72.54 – 78.04 µg/m3. Maximum concentration of
PM10.0 was found at Jolva (78.04 µg/m3), which is well within the standard NAAQS limit.
 During the study PM2.5 concentration was observed in the range of 41.74 – 46.69 µg/m3. Maximum concentration of
PM2.5 was found at Nandida (46.69 µg/m3), which is well within the standard NAAQS limit.
 During the study SO2 concentration was observed in the range of 13.87 – 17.82 µg/m3. Maximum concentration of
SO2 was found at Jolva (17.82 µg/m3), which is well within the standard NAAQS limit.
 During the study NOx concentration was observed in the range of 14.27 – 19.08 µg/m3. Maximum concentration of
NOx was found at Suva (19.08 µg/m3), which is well within the standard NAAQS limit..
Sr. Criteria Maximum Minimum 98 Percentile Prescribed
Unit
No. Pollutant Value Value Value Standard
1 PM10.0 g/m3 78.63 71.58 78 100
2 PM2.5 g/m3 47.41 42.29 47 60
3 SO2 g/m3 14.38 9.13 14 80
4 Nox g/m3 16.96 10.25 17 80
 Conclusion: Results of all parameters are found within NAAQS limit.
23
23
1. AIR QUALITY
 Ambient Air Quality Status- Minimum, Maximum, 98th Percentile Value & Average (24 Hrs.) Unit: g/m3
Sr. Sampling Sr. Sampling

No. Location PM10 PM2.5 SO2 NO2 No. Location PM10 PM2.5 SO2 NO2
1 Project-Site 6 Galenda (A6)

(A1) Average 78.04 46.46 17.82 18.08
Average 77.10 44.25 16.04 17.67 Min – Max 75-82 44-50 13-20 16-23
Min – Max 74-79 41-47 14-18 13-20 98th Percentile 82 50 20 23
98th Percentile 79 47 18 20 7 Jolva (A7)
2 Suva (A2) Average 76.35 46.69 16.84 18.51
Average 77.69 46.68 17.72 19.08 Min – Max 72-81 44-50 14-19 16-24
Min – Max 74-80 44-50 13-20 16-26 98th Percentile 80.54 50 19 23.54
98th Percentile 79.54 50 20 25.54 8 Nandida (A8)
3 Vadadla (A3) Average 72.74 41.84 13.87 14.59
Average 75.38 44.76 17.71 18.38 Min – Max 68-75 38-44 10-16 12-16
Min – Max 71-79 41-47 13-20 16-24 98th Percentile 74.54 44 16 16
98th Percentile 79 47 20 23.54 9 Nadarkha (A9)
4 Khojbal (A4) Average 72.54 41.74 13.95 14.27
Average 74.54 44.17 16.89 17.45 Min – Max 68-75 38-44 10-16 12-16
Min – Max 70-78 41-47 14-19 13-20 98th Percentile 74.54 44 16 16
98th Percentile 78 47 19 20 Limit 100 60 80 80
5 Akhod (A5)
Average 76.58 45.28 16.93 18.13
Min – Max 72-80 40-49 14-19 16-24
98th Percentile 79.54 49 19 23.54
Limit 100 60 80 80
24
24
INPUTS FOR EMISSION MODELING * - Permissible Limit
Stack Attached To
Sr. Operating Parameters 1: BOILER 2: BOILER 3: BOILER 4: HAG 4: TFH (3 5: Lakh

HAG (1
6: D.G Set 7: D.G Set
No. Parameter [3 TPH] LAKHS Kcal/Hr - (1000
[8 TPH] [3 TPH] [3 TPH] KCAL/HR) 2 Nos.) KVA) (500 KVA)
1. Stack Height Meter 30 30 20 20 20 20 12 12

2. Diameter Meter 0.3 0.2 0.2 0.3 0.15 0.15 0.15 0.15
Flue Gas 404
3. Temperature
0
K 384 384 384 303 303 448 448
Air Pollution ESP + MCS + Adequate Adequate Adequate Adequate Adequate Adequate
stack
4. Control -- Water Bag filter stack
+ Water Height Height stack stack stack stack
Equipment scrubber Scrubber Height Height Height Height
5. Flue Gas Velocity M/S 5.5 4.5 4.5 7 4.5 4.5 7 7

Emission
Concentration
SPM mg/Nm3 150* 150* 150* 150* 150* 150* 150* 150*
(g/s) (0.0452) (0.0164) (0.0164) (0.0547) (0.0117) (0.0117) (0.0123) (0.0123)
6. SO2 mg/Nm3 262* 262* 262* 262* 262* 262* 262* 262*
(g/s) (0.0790) (0.0287) (0.0287) (0.0955) (0.0204) (0.0204) (0.0215) (0.0215)
NOX mg/nm3 94* 94* 94* 94* 94* 94* 94* 94*
(g/s) (0.0283) (0.0103) (0.0103) (0.0342) (0.0073) (0.0073) (0.0077) (0.0077)
Imported Imported Natural Natural Natural Natural

7. Fuel - Coal Coal Gas Gas Gas Gas HSD HSD
25
INPUTS FOR EMISSION MODELING * - Permissible Limit
SOURCE OF PROCESS GAS EMISSION

SR. OPERATING PROPOSED
NO. PARAMETER UNIT 5
1 2 3 4
1. Stack Height Meter 12 12 12 12 12
2. Stack Diameter Meter 0.1 0.1 0.1 0.1 0.1
3. Flue Gas Velocity m/s 4.0
4.0 4.0 4.0 4.0
4. Flue Gas 305
Temperature
0
K 305 305 305 305
5. Air Pollution
Control Equipment -- Two Stage Scrubber System
6. Emission concentration
HBr mg/Nm3 5*
g/S (0.0001)
SO2 mg/Nm3 40*

g/S (0.0012)
HCl mg/Nm3 20* 20*

g/S (0.0006) (0.0006)
Cl2 mg/Nm3 9*
g/S (0.0002)
mg/Nm3 175*
NH3 (0.0053)
g/S
26
AIR QUALITY
 Equal concentration of SPM, SO2, NO2, etc. from Project Site
 Isopleths of SPM  Isopleths of NO2
 Isopleths of SO2
27
AIR QUALITY
 Equal concentration of HCl, NH3, HBr, Cl2 etc. from Project Site
 Isopleths of HCl  Isopleths of NH3
 Isopleths of HBr  Isopleths of Cl2
28
28
SUMMARY OF ISCST3 MODEL OUTPUT
SR. LOCATIONS X, Y CONCENTRATION
NO. CO-ORDINATES SPM SO2 NOx HCl NH3 HBr Cl2
(g/m3) (g/m3) (g/m )
3
(g/m )
3
(g/m3) (g/m3) (g/m3)
1. Project site (0,0) 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
2. Suva (-3226, -4000) 0.02379 0.04157 0.01425 0.00036 0.00160 0.00003 0.00006
3. Vadadala (-5548, 774) 0.00369 0.00644 0.00231 0.00006 0.00027 0.00001 0.00001
4. Khojbal (6710, 2065) 0.01286 0.02247 0.00805 0.00020 0.00088 0.00002 0.00003
5. Akhod (1677, 3097) 0.00519 0.00906 0.00325 0.00009 0.00041 0.00001 0.00002
6. Galenda (-1935, 1419) 0.00600 0.01048 0.00376 0.00012 0.00055 0.00001 0.00002
7. Jolva (-3613, -1290) 0.01203 0.02101 0.00753 0.00020 0.00089 0.00002 0.00003
8. Nandida (4645, 3742) 0.00742 0.01297 0.00465 0.00011 0.00050 0.00001 0.00002
9. Nadarkha (1548, 7226) 0.00113 0.00198 0.00071 0.00002 0.00008 0.0000 0.00000
As proposed manufacturing activities have not yet started, the predictions were made using CPCB permissible limit as
these concentrations will in no case be exceeded. Ground level concentrations calculated for proposed activities are
superimposed on existing ambient air quality monitoring results and combined values (Table-4.4) are found within
permissible National Ambient Air Quality Standards.
MAXIMUM CONCENTRATION (g/m3)

SR. X, Y
NO. CO-ORDINATES HBr Cl2
SPM SO2 NOx HCl NH3
1. (-1000,-2000) 0.20767 -- -- -- -- -- --
2. (-1000,-2000) -- 0.36287 -- -- -- -- --
3. (-1000,-2000) -- -- 0.13 -- -- -- --
4. (-1000,-2000) -- -- -- 0.00394 -- -- --
5. (-1000,-2000) -- -- -- -- 0.01742 -- --
6. (-1000,-2000) -- -- -- -- -- 0.00033 -- 29
29
1. AIR QUALITY
 Incremental Pollution load
Predicted Ambient Air Quality
SPM (g/m3) SO2 (g/m3) NOX (g/m3)
Sr. Sampling
No. Location AAQ Model Predicted AAQ Model Predicted AAQ Model Value Predicted
Value Value Value Value Value
1. Project site 131.5 0.0000 131.500 15.04 0.0000 15.040 16.67 0.0000 16.670
2. Suva 134.1 0.02379 134.124 17.72 0.04157 17.762 19.08 0.01425 19.094
3. Vadadala 130.9 0.00369 130.904 16.73 0.00644 16.736 18.06 0.00231 18.062
4. Khojbal 127.6 0.01286 127.613 17.71 0.02247 17.732 18.38 0.00805 18.388
5. Akhod 128.4 0.00519 128.405 16.89 0.00906 16.899 17.45 0.00325 17.453
6. Galenda 128.9 0.00600 128.906 16.93 0.01048 16.940 18.13 0.00376 18.134
7. Jolva 132.5 0.01203 132.512 17.82 0.02101 17.841 18.08 0.00753 18.088
8. Nandida 134.7 0.00742 134.707 16.84 0.01297 16.853 18.51 0.00465 18.515
9. Nadarkha 123.9 0.00113 123.901 13.87 0.00198 13.872 14.59 0.00071 14.591
NAAQS -- 80 80
BDL = Below Detectable Limit
Conclusion: Results of all parameters are found within NAAQS limit.
30
30
1. AIR QUALITY
 Incremental Pollution load
Predicted Ambient Air Quality
HCl (g/m3) NH3 (g/m3) HBr (g/m3) Cl2 (g/m3)

SR. SAMPLING
NO. LOCATION AAQ Model Predicted AAQ Model Predicted AAQ Model Predicted AAQ Model
Value Value Value Value Value Value Value Value Predicted
1. Project BDL 0.0000 BDL BDL 0.0000 BDL BDL 0.0000 BDL BDL 0.0000 BDL
site
2. Suva BDL 0.00036 BDL BDL 0.00160 BDL BDL 0.00003 BDL BDL 0.00006 BDL
3. Vadadala BDL 0.00006 BDL BDL 0.00027 BDL BDL 0.00001 BDL BDL 0.00001 BDL
4. Khojbal BDL 0.00020 BDL BDL 0.00088 BDL BDL 0.00002 BDL BDL 0.00003 BDL
5. Akhod BDL 0.00009 BDL BDL 0.00041 BDL BDL 0.00001 BDL BDL 0.00002 BDL
6. Galenda BDL 0.00012 BDL BDL 0.00055 BDL BDL 0.00001 BDL BDL 0.00002 BDL
7. Jolva BDL 0.00020 BDL BDL 0.00089 BDL BDL 0.00002 BDL BDL 0.00003 BDL
8. Nandida BDL 0.00011 BDL BDL 0.00050 BDL BDL 0.00001 BDL BDL 0.00002 BDL
9. Nadarkha BDL 0.00002 BDL BDL 0.00008 BDL BDL 0.0000 BDL BDL 0.00000 BDL
NAAQS 200 175 300 100
BDL = Below Detectable Limit

Conclusion: Results of all parameters are found within NAAQS limit.
31
31
2. NOISE LEVEL AT 20 LOCATIONS
NOISE LEVEL IN dB(A) CPCB LIMIT dB(A)
DAY TIME NIGHT TIME DAY NIGHT
SR. LOCATION TIME TIME
NO.
MIN. MAX. MIN. MAX. MAX. MAX.
A) RESIDENTIAL AREA
1. Suva(A2) 53.6 54.5 42.6 44.7 <55 <45
2. Vadadla(A3) 50.2 51.4 41.2 42.5 <55 <45
3. Khojbal(A4) 51.9 52.5 42.6 43.2 <55 <45
4. Akhod(A5) 52.5 53.9 41.4 43.7 <55 <45
5. Galenda(A6) 50.9 52.7 41.2 42.4 <55 <45
6. Jolva(A7) 52.5 53.8 41.4 43.7 <55 <45
7. Nandida(A8) 52.1 53.9 42.8 44.5 <55 <45
8. Nadarkha(A9) 48.7 51.8 42.4 44.9 <55 <45
B) COMMERCIAL AREA (TRANSPORTATION)
1. Nandida Bypass 61.7 62.8 53.1 54.6 <65 <55
2. Nr. Khojbal Chowkadi 59.2 60.6 50.0 51.4 <65 <55
3. Nr. Jolva Chowkadi 62.8 64.5 52.5 54.9 <65 <55
4. Nr. Vav Chowkadi 60.6 62.5 53.7 54.2 <65 <55
5. Nr. Suva Chowkadi 60.4 62.7 50.5 52.8 <65 <55
6. Nr. Vadadla Chowkadi 61.4 63.0 50.5 52.4 <65 <55
7. Nr. Nadarkha Chowkadi 60.9 62.8 52.7 54.2 <65 <55
C) INDUSTRIAL AREA
1. Project site (A1) 64.3 66.1 61.7 64.8 <75 <70
2. NR. M/s. Unnati Inorganics Pvt Ltd. 67.1 68.2 62.9 64.9 ≤75 ≤70
3. Nr. M/s. Expanded Polymer Systems 64.5 66.7 61.9 63.8 ≤75 ≤70
Private Limited
4. Nr. M/s. Aquamet India Pvt. Ltd. 67.8 69.5 65.1 67.2 ≤75 ≤70
5. Nr. M/s. Payal Polyplast Pvt. Ltd. 65.1 67.4 62.8 65.7 ≤75 ≤70
32
32
3. WATER (SURFACE + GROUND) ENVIRONMENT
 Water Quality- Physical Parameters
Sr. Temperature Turbidity T.D.S. T.S.S.
No. Sampling Location pH (0C) (NTU) (mg/L) (mg/L)
1. GIDC Water Supply (GW1) 7.70 25.0 0.33 284 <10.0
2. Suva(GW2) 7.98 24.9 0.82 1780 <10.0
3. Vadadala (GW3) 7.89 25.1 0.79 1064 <10.0
4. Khojbal (GW4) 7.94 25.0 0.61 516 <10.0
5. Akhod (GW5) 8.03 24.9 0.74 1856 <10.0
6. Galenda (GW6) 7.62 24.9 0.20 246 <10.0
7. Jolva (GW7) 7.94 25.0 1.43 248 <10.0
8. Nandida (GW8) 7.14 25.0 0.56 324 <10.0
9. Nadarkha (GW9) 8.16 25.0 0.65 636 <10.0
10. Jolva Pond (SW1) 8.79 25.0 3.0 1900 42
11. Suva Pond (SW2) 8.11 24.9 3.5 364 12
12. Nandida Pond (SW3) 8.00 25.0 2.6 486 48
13. Vadadla Pond (SW4) 8.07 25.0 2.9 502 24
14. Kadodara Pond (SW5) 8.43 25.0 3.0 1038 44
15. Sambheti Pond (SW6) 8.43 24.9 1.4 386 10
16. Akhod Pond (SW7) 7.70 25.0 1.7 352 14
17. Atali Pond (SW8) 8.34 25.0 3.7 522 92
Indian Standard
IS:10500 norms 6.5 -8.5 -- 5.0 2000 --
GW= Ground water, SW= Surface water
33
33
 Water Quality – Nutrients, Oxygen Demand and Organic Parameter
Ammonical
Nitrogen DO COD BOD327 Oil &
Sr. (as NH3-N) Grease
No. Sampling Location
(mg/L)
1. GIDC Water Supply (GW1) <0.2 6.77 1.46 <1.0 <0.4

2. Suva(GW2) <0.2 6.86 1.75 <1.0 <0.4
3. Vadadala (GW3) <0.2 6.48 1.45 <1.0 <0.4
4. Khojbal (GW4) <0.2 6.68 1.78 <1.0 <0.4
5. Akhod (GW5) <0.2 6.96 1.62 <1.0 <0.4
6. Galenda (GW6) <0.2 6.49 1.37 <1.0 <0.4
7. Jolva (GW7) <0.2 6.58 1.48 <1.0 <0.4
8. Nandida (GW8) <0.2 6.58 1.96 <1.0 <0.4
9. Nadarkha (GW9) <0.2 6.86 1.43 <1.0 <0.4
10. Jolva Pond (SW1) BDL 6.96 17.45 2.86 BDL
11. Suva Pond (SW2) BDL 6.49 18.40 5.53 BDL
12. Nandida Pond (SW3) BDL 6.77 13.88 4.69 BDL
13. Vadadla Pond (SW4) BDL 6.96 19.76 3.68 BDL
14. Kadodara Pond (SW5) BDL 6.86 21.76 3.54 BDL
15. Sambheti Pond (SW6) BDL 6.49 15.87 3.21 BDL
16. Akhod Pond (SW7) BDL 6.68 9.25 1.81 BDL
17. Atali Pond (SW8) BDL 6.86 17.48 5.51 BDL
Indian Standard
IS:10500 norms -- 6.5 -- -- --
34
34
 Water Quality – Inorganic Parameter
Total Total Calcium Cl- SO4—2 Mg
Sr. No. Sampling Location Alkalinity Hardness Hardness
(as CaCO3)(mg/L) (mg/L)
1. GIDC Water Supply (GW1) 110.0 117.6 71.14 23.26 12.47 10.52
2. Suva(GW2) 170.0 312.3 194.3 695.3 412.5 28.64
3. Vadadala (GW3) 455.0 448.1 282.5 182.5 124.6 40.19
4. Khojbal (GW4) 195.0 214.6 144.29 55.76 40.13 17.07
5. Akhod (GW5) 430.0 622.8 412.3 588.5 379.3 51.09
6. Galenda (GW6) 115.0 116.8 74.72 21.06 15.84 10.21
7. Jolva (GW7) 110.0 116.5 82.34 26.50 18.47 8.29
8. Nandida (GW8) 120.0 120.5 74.29 15.02 12.47 11.22
9. Nadarkha (GW9) 480.0 280.5 176.3 105.1 72.56 25.29
10. Jolva Pond (SW1) 405.0 196.8 144.18 679.8 306.6 12.77
11. Suva Pond (SW2) 175.0 102.4 56.22 71.9 28.6 11.21
12. Nandida Pond (SW3) 185 94.38 40.32 84.98 33.90 13.12
13. Vadadla Pond (SW4) 205.0 160.6 84.34 56.98 49.86 18.51
14. Kadodara Pond (SW5) 255.0 160.6 100.4 314.9 148.1 14.61
15. Sambheti Pond (SW6) 190.0 140.6 90.36 31.52 24.93 12.19
16. Akhod Pond (SW7) 165.0 106.4 43.22 41.98 21.44 15.33
17. Atali Pond (SW8) 315.0 86.34 50.2 81.62 62.33 8.77
Indian Standard
IS:10500 norms 600 600 200 1000 400 --
T.H. = Total Hardness, C.H. = Calcium Hardness, BDL= Below Detectable Limit
35
35
 Water Quality – Heavy Metal
Na T-Cr+3 Cu Pb Fe Zn K Ni S-2 F-
Sr.
Sampling Location
No. (mg / L)
1. GIDC Water Supply (GW1) 18.05 <0.05 <0.05 <0.01 0.14 <0.05 2.08 <0.05 <0.2 <0.05
2. Suva(GW2) 146.65 <0.05 <0.05 <0.01 0.48 <0.05 3.17 <0.05 <0.2 <0.05
3. Vadadala (GW3) 59.96 <0.05 <0.05 <0.01 0.34 <0.05 5.85 <0.05 <0.2 <0.05
4. Khojbal (GW4) 14.45 <0.05 <0.05 <0.01 0.79 <0.05 2.06 <0.05 <0.2 <0.05
5. Akhod (GW5) 34.85 <0.05 <0.05 <0.01 0.65 <0.05 3.36 <0.05 <0.2 <0.05
6. Galenda (GW6) 11.66 <0.05 <0.05 <0.01 0.20 <0.05 2.18 <0.05 <0.2 <0.05
7. Jolva (GW7) 14.04 <0.05 <0.05 <0.01 0.31 <0.05 2.34 <0.05 <0.2 <0.05
8. Nandida (GW8) 18.85 <0.05 <0.05 <0.01 0.21 <0.05 1.24 <0.05 <0.2 <0.05
9. Nadarkha (GW9) 22.43 <0.05 <0.05 <0.01 0.14 <0.05 1.86 <0.05 <0.2 <0.05
10. Jolva Pond (SW1) 380.8 BDL <0.05 BDL 1.53 BDL 26.14 <0.05 <0.2 <0.05
11. Suva Pond (SW2) 62.47 BDL <0.05 BDL 0.19 BDL 2.74 <0.05 <0.2 <0.05
12. Nandida Pond (SW3) 168.1 BDL <0.05 BDL 3.83 BDL 45.07 <0.05 <0.2 <0.05
13. Vadadla Pond (SW4) 82.13 BDL <0.05 BDL 1.33 BDL 1.17 <0.05 <0.2 <0.05
14. Kadodara Pond (SW5) 229.2 BDL <0.05 BDL 0.64 BDL 14.42 <0.05 <0.2 <0.05
15. Sambheti Pond (SW6) 53.35 BDL <0.05 BDL 2.73 BDL 1.84 <0.05 <0.2 <0.05
16. Akhod Pond (SW7) 60.37 BDL <0.05 BDL 0.75 BDL 2.14 <0.05 <0.2 <0.05
17. Atali Pond (SW8) 109.2 BDL <0.05 BDL 12.47 BDL 4.51 <0.05 <0.2 <0.05
BDL= Below Detectable Limit
Minimum Detection Limit:
Phenol (as C6H5OH) : 0.01 mg/L Hexavalent Chromium (as Cr+6) : 0.01 mg/L Cadmium (as Cd)
**
: 0.001 mg/L
Total Iron (as Fe) : 0.01 mg/L Fluoride (as F )
-
: 0.05 mg/L Arsenic (as As)
**
: 0.00015 mg/L
Copper (as Cu) : 0.05 mg/L **
Total Chromium (as Cr+3) : 0.005 mg/L Lead (as Pb)
**
: 0.005 mg/L
Nickel (as Ni) : 0.03 mg/L **
Zinc (as Zn) : 0.022 mg/L
*
Not in our NABL Scope, **Analyzed by Sub Contractor (Not in our NABL Scope) 36
36
 Summary of Ground Water
 pH of Ground water samples varied in the range from 7.14 to 8.16. Maximum pH was found at Nadarkha (8.16),
which is well within the standard Indian Standard (IS:10500) limit.
 Total Suspended Solids was found <10.0 mg/L, which is well within the standard Indian Standard (IS:10500) limit.
 Total Hardness (as CaCO3) was varied in the range from 116.5 to 622.8 mg/L. Maximum Total Hardness (as CaCO3)
was found at Akhod (622.8 mg/L), which is well within the standard Indian Standard (IS:10500) limit.
 Total Dissolved Solids was varied in range from 246 to 1856 mg/L. Maximum Total Dissolved Solids was found at
Akhod (2086 mg/L), which is well within the standard Indian Standard (IS:10500) limit.
 Fluoride was Found <0.05 mg/L, which is well within the standard Indian Standard (IS:10500) limit.
 Chlorides was varied in the range from 15.02 to 695.3 mg/L. Maximum Chlorides was found at Suva (695.3 mg/L),
which is well within the standard Indian Standard (IS:10500) limit.
 Zinc was Found <0.05 mg/L, which is well within the standard Indian Standard (IS:10500) limit.
Maximum
Sr. Maximum Minimum Desirable Permissible
Criteria Pollutants Unit
No. Value Value Limit Limit
No Relaxation
1. pH pH Scale 8.16 7.14 6.5-8.5
2. Total Suspended Solids mg/l <10.0 <10.0 80 120
3. Total Hardness mg/l 622.8 116.5 200 600
4. Total Dissolved Solids mg/l 1856 246 500 2100
5. Fluoride mg/l <0.05 <0.05 1 1.5
6. Chlorides mg/l 695.3 15.02 250 1000
7. Zinc mg/l <0.05 <0.05 5 15
 Conclusion: Results of all parameters are found within limit.
37
37
 Summary of Surface Water
 pH of Surface water samples varied from 8.07 to 8.79. Maximum pH was found at Jolva Pond (8.79), which is well
within the standard Indian Standard (IS:10500) limit.
 DO was found 6.96 mg/L. Maximum DO was found at Jolva Pond (6.96 mg/L), which is well within the standard
Indian Standard (IS:10500) limit.
 COD was varied in range of 17.45 to 19.76 mg/L. Maximum COD was found at Vadadla (19.76 mg/L), which is well
within the standard Indian Standard (IS:10500) limit.
 BOD327 was varied in range of 2.86 to 3.68 mg/L. Maximum BOD327 was found at Vadadla Pond (3.68 mg/L), which is
well within the standard Indian Standard (IS:10500) limit.
Classification Of
Inland Water
Sr. Criteria Unit Maximum Minimum Value Body
No. Pollutants Value
A
1. pH pH Scale 8.79 8.07 6.5-8.5
2. DO mg/l 6.96 6.96 6.0
3. COD mg/l 19.76 17.45 --
4. BOD mg/l 3.68 2.86 2.0
38
38
WATER REQUIREMENT AND ITS APPROVAL STATUS
Water Consumption & Wastewater Generation:
 Water Consumption: Total : 570.5 KL/Day (Fresh: 300 KL/Day + Reuse: 270.5 KL/Day)
 Source of water: GIDC Water Supply
 Permission Letter from GIDC Industrial Area: Letter No.: GIDC/DEE/WS/BRH/1311 Dated: 11/01/2022
Table: Water Consumption & Wastewater Generation:

Sr. Category Water Consumption Waste Water Generation
No. (KL/Day) (KL/Day)
1 Domestic 15 11.5
2 Gardening 20 --
3 Industrial
Process & R&D 209 237
Washing 20 20
Boiler 200 50
Cooling 100 34
Scrubbing 6.5 7.5
Total Industrial 535.5 348.5
Grand Total 570.5 360
39
39
 Permission from GIDC Industrial Area: Wastewater Discharge Letter
Water Supply Letter
40
 Wastewater Generation: 360 KL/Day (Industrial: 348.5 KL/Day + Domestic: 11.5 KL/Day)
 Total water requirement will be 570.5 KL/Day (Fresh water: 300 KLD + Reuse: 270.5 KLD) which will be met through
GIDC water supply.
 Scrubbing Media: Effluent from Scrubber (7.5 KL/Day), in which 4.5 KL/Day will sell to end users under Rule-9
Permission & 3 KL/Day will reuse for production of product no. 92 & 93.
 Effluent from Process & R&D (141 KL/Day) & washing (20 KL/Day) Total 161 KL/Day will treat in Solvent Stripper
then treat in ETP having primary treatment then treat in MEE & MEE Condensate 131 KL/Day will reuse in plant
premises.
 Mode of Discharge: Effluent from Process Low COD (96 KL/Day) & Utility (84 KL/Day) will be treat in ETP & treated
effluent (180 KL/Day) will be sent to CETP, Dahej for further Treatment & Disposal.
41
Water Balance Diagram
DETAILED EFFLUENT TREATMENT SCHEME : ETP
M/s. Shree Ganesh Remedies Ltd (Unit-5) shall have an Effluent treatment plant consisting of primary treatment, Solvent
Stripper & MEE treatment units. The details of ETP are as follows:
Stream I (105.50KLD)
First all non-toxic and biodegradable streams of wastewater shall be collected in Collection cum Neutralization Tank-01 (CNT-01)
where caustic shall be added from CDT-01. Then, wastewater shall be pumped to Primary Settling Tank-01(PST-01). Here Alum
and Polyelectrolyte shall be dosed from Alum Dosing Tank (ADT-01) and Polyelectrolyte Dosing Tank (PEDT-1) respectively by
gravity to carry out coagulation by using Mixer. Then after, mixer will be stopped and wastewater shall be allowed to settle in
Primary Settling Tank-01 (PST-01). Clear supernatant from PST-01 shall be collected in Aeration Tank (AT-01). Here,
biodegradation of organic matter of the wastewater shall be carried out by bacteria (suspended growth) in the AT-01 and for that
oxygen shall be supplied by 2 nos. of air blowers through diffusers. Air blowers also keep MLSS in suspension.
Then after, wastewater shall go to Secondary Settling Tank (SST-01). Here, the suspended solids shall be settled. Sludge shall be
removed from bottom of SST-01 and pumped to AT-1 to maintain MLSS and excess activated sludge shall be sent to Sludge Drying
Beds (SDB-01) and Clear supernatant from SST-01 shall be collected in Holding Tank (HT-01) before pumped to strippers (ST-01).
Effluent from stripper and HPRO-01 shall be then collected in MEE Feed Tank (MFT-01). Then effluent shall be sent to Multiple
Effect Evaporator (MEE-01) for further treatment followed by Agitated Thin Film Dryer (ATFD-01) for solids dewatering.
Condensate from MEE & ATFD shall collect in Condensate Storage Tank (CST-01) before Reuse for further treatment. Solids from
ATFD-01 shall be collected and stored in HWSA for disposal in TSDF.
Sludge settled in PST-01 Shall be collected in Sludge Beds (SDBs-01-A/B) for sludge dewatering. Then, dewatered sludge shall be
stored in HWSA and then ultimate disposal to TSDF Site.
Stream II (140.0 KLD)
First all streams of wastewater shall be collected in Collection cum Equalization Tanks-(CETs-01). Mixer is provided in CET-01 to
keep all suspended solids in suspension and to provide proper mixing. Then effluent shall be pumped to Neutralization Tank -
(NT-01) where Lime shall be added from Lime Dosing tank. Then after, effluent shall have sent to Flash Mixer-1 (FM-01) where
Alum and poly shall be added from ADT and PDT-01 respectively. Then after, coagulated wastewater shall be settled in Primary
Settling Tank (PST-02). Clear supernatant from PST-02 shall be collected in Holding Tank (HT-01) before sent to CETP for Further
Treatment.
43
SIZE OF TANKS
Sr. Name of unit Size (m x m x m) No. MOC/ Remark
No.
Stream-I Flow -105.50 KLD
1 Collection cum Neutralization 55 KLD 1 RCC M30+A/A
Tank (CNT-01) Bk. Lining
2 Primary Settling Tank (PST-01) 25 KLD 1 RCC M30
3 Holding Tank (HT-01) 45 KLD 1 RCC M30
4 Aeration Tank (AT-01) 80 KLD 1 RCC M30
5 Secondary Settling Tank (SST-01) 40 KLD 1 RCC M30
6 Stripper (ST-01) 103.0 M3/D 1 SS316L
7 MEE Feed Tank (MFT-01) 50 KLD 1 RCC M30
Multi Effect Evaporator (MEE-01)
8 with Agitated Thin Film Dryer 103.0 M3/D 1 SS316L
(ATFD-01)
9 Condensate Storage Tank (CST 01) 60 KLD 1 RCC M30
10 Sludge Drying Beds 3.0 x 2.0 1 RCC M30
11 Alkali Dosing Tank 1000 Lit 1 HDPE
12 Alum Dosing Tank 1000 Lit 1 HDPE
13 Poly Dosing Tank 1000 Lit 1 HDPE
140.0 KLD Stream -2

1 Collection cum Equalization Tank 98 KL 1 RCC M30
(CET-01)
2 Neutralization Tank (CNT-01) 10 KL 1 RCC M30
3 Flash Mixer (FM-01) 10 KL 1 RCC M30
4 Primary Settling Tank (PST-02) 40 KL 1 RCC M30
5 Holding Tank (HT-02) 45 KL 1 RCC M30
RCC M25 = REINFORCED CEMENT CONCRETE (M 25 GRADE) MSEP = MILD STEEL EPOXY PAINTED
PCC = PLAIN CEMENT CONCRETE SS = STAINLESS STEEL
44
Effluent Flow Diagram:
45
EXPECTED CHARACTERISTICS OF WASTEWATER BEFORE & AFTER TREATEMENT
DILUTE STREAM
Sr. Parameter Untreated After Primary CETP Inlet
No. Stream Treatment norms
1 pH 4.0-9.0 6.5-8.5 6.5-8.5
2 COD (mg/L) 3000-3500 <3000 3500
3 BOD3 800-1000 <750 1000
(mg/L)
4 TDS (mg/L) 8000 <8000 8000
HIGH COD STREAM

Characteristics (mg/l)
Sr.
No Parameter Solvent Primary
. Untreated Stripper Treated MEE Treated
1. pH 4-6 4-6 7.0-7.5 6.5-7.5

2. COD 12500 1200 950 <150
3. BOD3 4100 400 300 <50
4. TDS 18000 18000 18800 <200
46
DETAILED EFFLUENT TREATMENT SCHEME : STP
DOMESTIC WASTEWATER – 11.5 KL/DAY
Domestic Waste water Collected in collection tank- (CT-01) then effluent shall be Pass through Screen Chamber With Grit
Chamber to Remove Solid Particles Then it is reused for Gardening.
SIZE OF TANKS
Sr. Size in Meters
Name of Unit Tag No. Nos. MOC
No. (L X B X (LD+FB)
1 Collection tank (CT-01) 12 KL/Day 1 RCC M30
Screen Chamber With Grit
2 SC/GT-01 2.0 x 0.8 1 RCC M30
Chamber.
47
DETAILED EFFLUENT TREATMENT SCHEME : MEE
PROCESS DESCRIPTION:
Capacity: 100 KL/Day x 2 Nos.
Industry has installed Multi Effect Evaporator for the treatment of industrial effluent (as an additional facility) having
capacity of 100 KL/Day x 2 Nos. The condensate water generated from the MEE shall be used in process
Neutral effluent from Primary Treatment Plant is passed through 3 stages Evaporator System and the evaporated water
is collected in an Evaporated Water Collection Tank and then recycled to plant after filtering through sand filter and
carbon filter. The sludge from the evaporators is filtered through Nutsch Filter whereby solid filtered sludge is obtained
and the filtrate is recycled back to process.
Multi stage evaporator (3 - stages) is a long tube forced circulation type evaporators where in the first effect high
pressure steam of 7.0 kg/cm2 is used to evaporate waste water. The evaporated water in the form of steam at 2.0
kg/cm2g pressure is used for evaporating the effluent in the second stage at atmospheric pressure. Evaporated water
from the second stage is used for evaporating waste water in the third stage under vacuum of 650 - 720 mm Hg. Finally
evaporated water from the third stage is condensed in the steam condenser using cooling water on other side.
Condensate from all the three stages is collected in condensate receiving tanks, which is pure water and hence reused in
the process. Concentrated mass from each effect is collected in the crystallizer where, on cooling inorganic salts are
precipitated along with organic contaminants. This mass is filtered in CF / Nutsch filter and filtrate is recycled back to
process.
Design of MEE: No. of Effects : 3 (1 Falling Film + 2 Forced Circulation)
Waste Handling Capacity : 180 m3 / day

Feed Rate : 5000 kg / hour (20 working hours / day)
Feed Concentration : 10 % TDS
Feed Temperature : 35 o C
Product Rate : 1250 kg / hour
Product Concentration : 40 %
Product Temperature : 55 o C
Water Evaporation Rate : 3750 kg / hour 48
DETAILED EFFLUENT TREATMENT SCHEME : MEE
Flow Diagram of MEE:
49
4. SOIL AND BIOLOGICAL ENVIRONMENT
Sr. PROJECT SUVA VADADLA KHOJBAL AKHOD GALENDA JOLVA NANDIDA NADARKHA
Parameter Unit SITE (S1) (S2) (S3) (S4) (S5) (S6) (S7) (S8) (S9)
No.
Moisture Content % 8.45 4.42 4.75 8.45 5.24 8.59 12.68 6.94 9.39
1. *
Total Solids % 91.55 95.58 95.25 91.55 94.76 91.41 87.32 69.06 70.61
2. pH -- 7.83 7.93 7.78 8.36 8.30 8.71 7.79 7.15 8.40
3. Temperature oC 25.0 25.1 25.0 25.0 24.9 25.1 25.1 25.0 25.0
4. EC mS/cm 0.169 0.198 0.385 0.165 0.167 0.278 0.163 0.093 0.396
5. Bulk Density gm/cm3 1.18 1.17 1.18 1.18 1.35 1.14 1.11 1.18 1.20
6. Porosity % 55.58 56.29 55.58 55.58 54.35 57.13 58.07 55.58 54.67
Water Holding Capacity 71.75 65.82 65.84 71.75 59.86 70.38 70.11 58.48 69.58
7. %
(WHC)
8. *
Specific Gravity -- 2.40 2.34 2.55 2.40 2.51 2.51 2.45 2.48 2.37
9. Calcium (as Ca+2) mg/Kg 908.2 892.4 977.5 908.2 1122.4 993.8 953.04 729.6 809.2
10. Magnesium mg/Kg 185.5 171.6 165.1 185.5 189.9 160.1 145.2 179.7 111.7
11. Chlorides (as Cl-) mg/Kg 59.98 126.7 364.9 59.98 89.97 199.9 454.9 214.99 399.9
12. Total Phosphorus mg/Kg 26.91 22.47 42.58 26.91 25.93 25.30 23.73 22.40 19.55
13. Available Phosphorus mg/Kg 0.18 0.37 1.90 0.18 0.23 0.56 0.19 0.55 0.26
14. Organic Matter (OM) % 0.83 1.42 0.81 0.83 0.44 2.44 0.59 1.05 0.94
15. *
Total Alkalinity mg/Kg 275 60.0 50 275 75 150 210 35.0 110.0
16. Total Nitrogen mg/Kg 996.3 1052.7 1680.9 996.3 1297.9 934.2 1505.4 1235.1 939.6
17. Available Nitrogen mg/Kg 74.19 113.8 118.9 74.19 97.98 68.58 113.4 97.98 67.17
18. *
Nitrate Nitrogen mg/Kg 1.14 1.42 3.62 1.14 1.18 1.34 5.52 2.82 1.54
5859.7 1756. 1247.1 5859.7 5548.2 6856.8 4738. 2044.8 2101.4
19. *Sulphates (as SO4-2) mg/Kg 8 1
20. *Total Iron (as Fe) mg/Kg 163.8 35.8 26.7 163.8 21.2 34.9 21.2 136.6 123.3
50
50
Sr. PARAMETER UNIT PROJECT SUVA VADADLA KHOJBAL AKHOD GALENDA JOLVA NANDIDA NADARKHA
No. SITE (S1) (S2) (S3) (S4) (S5) (S6) (S7) (S8) (S9)
21. *Copper (as Cu) mg/Kg 1.20 BDL *
BDL *
1.20 0.60 0.85 BDL* 1.3 4.9
22. *Nickel (as Ni) mg/Kg BDL* BDL* BDL* BDL* BDL* BDL* BDL* BDL *
BDL*
23. **Lead (as Pb) mg/Kg BDL* BDL* BDL* BDL* BDL* BDL* BDL* BDL* BDL*
24. **Arsenic (as As) mg/Kg BDL* BDL* BDL* BDL* BDL* BDL* BDL* BDL* BDL*
25. **Organic Carbon % 0.48 0.82 0.47 0.48 0.26 1.42 0.34 0.61 0.55
26. **Color -- Dark Blackish Blackish Dark Blackish Dark Brown Blackish Brown
Brown Brown Brown Brown Brown Brown Brown
27. **
Sodium (as Na) mg/Kg 460.1 421.1 626.4 460.1 362.4 828.2 1760.0 305.4 2143.1
28. **
Potassium (as K) mg/Kg 51.6 121.8 30.9 51.6 61.9 134.1 31.09 175.3 264.2
29. **
Cadmium (as Cd) mg/Kg <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 BDL *
BDL*
30. **
Permeability cm/sec 9.44 x 6.46 x 2.26 x 9.44 x 6.01 x 4.82 x 6.35 x 5.89 x 10- 5.44 x 10-5
10-4 10-5 10-5 10-4 10-4 10-6 10-4 5
31. **Grain Size Analysis

Gravel % 1 2 1 1 1 0 1 2 0
Coarse Sand % 1 4 3 1 1 2 3 4 3
Medium Sand % 4 5 3 4 3 4 5 5 4
Fine Sand % 6 7 5 6 5 9 6 7 6
Silt + Clay % 88 82 88 88 90 85 85 82 87
NOTE: BDL*: Below Detectable Limit, **Analysed by Sub Contractor, *Not in our NABL Scope
Minimum Detection Limit:

*
Copper (as Cu) : 0.05 mg/Kg *
Lead (as Pb) : 0.001 mg/Kg *
Cadmium (as Cd) : 0.001 mg/Kg
*
Nickel (as Ni) : 0.03 mg/kg *
Arsenic (as As) : 0.0001 mg/kg
51
51
Summary Of Soil Quality
 pH of samples varied from 7.02 to 7.74. Maximum pH was found at Suva, which is well within the standard limit.
 Nitrogen (N) was varied in range of 934.2 to 1680.9 mg/kg. Maximum Nitrogen (N) was found at Vadadla (1680.9
mg/kg), which is well within the standard limit.
 Phosphorus (P) was varied in range of 19.55 to 42.58 mg/kg. Maximum Phosphorus (P) was found at Vadadla (42.58
 Potassium (K) was varied in range of 19.55 to 264.2 mg/kg. Maximum Potassium (K) was found at Nadarkha (264.2
 Electric Conductivity was varied in range of 0.093 to 0.396 mS/cm. Maximum Electric Conductivity was found at
Nadarkha (0.396 mS/cm), which is well within the standard limit.
Sr. Criteria Pollutants Unit Maximum Minimum

No. Value Value
1. pH pH Scale 8.94 7.15
2. Nitrogen (N) mg/kg 1680.9 934.2
3. Phosphorus (P) mg/kg 42.58 19.55
4. Potassium (K) mg/kg 264.2 30.9
5. Electric Conductivity mS/cm 0.396 0.093
52
5. SOCIO ECONOMIC ENVIRONMENT
CER Details
Company will contribute 2 % of the proposed project cost for socio economic .
Sr. Village CER Activity (2022-23) Rs. in
No. Name Lakhs
1. Suva Tree Plantation at Suva Village. 4.5
[Total Nos. of trees 150 with Protection(Cage)]
Cost = 150 Nos. of trees*3000 Rs.= 4.5 Lakhs
Company will contribute for increasing the depth of pond by 1.5 m & improving beautification 45
of surrounding pond area by providing Green wire mesh fencing and flowering plantation in
Suva Village.
Suva pond is having area of 492.75 (approx) square meters.
Providing 50 Nos. of Solar Street Light to the village of Suva as a Self-Sustaining Green 7.5
Technology
Cost = 50 Nos.* 15000 Rs.= 7.5 Lakhs
2. Akhod Company will contribute for developing of rain water harvesting (Contribution in construction 41
of tank for conservation of rain water) in Vahiyal village.
Under Ground RCC Water Tank for the Akhod Village,
Total Population of the village = 1287 Peoples as per Census 2011. As per population projection
calculation population of Akhod Village = 1500 Peoples (Approx.)
Quantity of Water Required = 1500 × 20 L/Day = 30,000 L.
Considering one-week storage = 30,000 L × 7 Days = 210 KL
Company will develop UG RCC Water Tank of 250 KL
Providing 50 Nos. of Solar Street Light to the village of Akhod as a Self-Sustaining Green 7.5
Technology
Cost = 50 Nos.* 15000 Rs.= 7.5 Lakhs
Tree Plantation at Akhod Village. 4.5
[Total Nos. of trees 150 with Protection(Cage)]
Cost = 150 Nos. of trees*3000 Rs.= 4.5 Lakhs
Total 110
Lakhs
53
53
6. RISK STUDIES & DISASTER MANAGEMENT
List of Hazardous Substances and quantity stored.
Sr. Name of the Hazardous Maximum No of Vessel Mode of Type of Hazard
No. Substance Storage Vessels Capacity Storage
1 Chlorine 19.8 MT 22 0.9 MT Tonner Toxic
2 Hydrogen 0.72 12 60 kg Cylinder Explosive
3 Ammonia Gas 9.96 MT 166 60 kg Cylinder Toxic
4 HCl Gas 4.98 MT 83 60 kg Cylinder Toxic
5 Bromine 0.9 MT 300 3 kg Bottle Toxic
6 Toluene 50 MT 2 25 MT Tank Flammable
7 Methanol 50 MT 2 25 MT Tank Flammable
8 Ethyl Acetate 20 MT 100 200 kg Drum Flammable
9 Chloroform 20 MT 100 200 kg Drum Toxic
10 Mono chlorobenzene 20 MT 100 200 kg Drum Flammable/ Toxic
11 MCB 10 MT 50 200 kg Drum Flammable/ Toxic
12 Ethylene Dichloride 10 MT 50 200 kg Drum Toxic & Flammable
13 Hexane 10 MT 50 200 kg Drum Toxic & Flammable
14 Tetrahydrofuran 10 MT 50 200 kg Drum Toxic & Flammable
15 HCl 10 MT 50 200 kg Drum Corrosive
16 Sulphuric Acid 8 MT 40 200 kg Drum Corrosive
17 Thionyl Chloride 8 MT 40 200 kg Drum Flammable
18 Acetic Acid 8 MT 40 200 kg Drum Corrosive
19 Cyclohexene 8 MT 40 200 kg Drum Flammable
20 Caustic Lye 8 MT 40 200 kg Drum Toxic/corrosive
21 Methylene Chloride 8 MT 40 200 kg Drum Toxic
22 Dimethyl Sulphate 8 MT 40 200 kg Drum Toxic
23 Sodium Methoxide 8 MT 40 200 kg Drum Flammable/ Toxic
24 Xylene 6 MT 30 200 kg Drum Flammable/ Toxic
25 Acetyl Chloride 5 MT 25 200 kg Drum Flammable/ Toxic
26 Benzyl Cyanide 5 MT 25 200 kg Drum Toxic
27 Triethyl Amine 5 MT 25 200 kg Drum Flammable
28 Liq Ammonia 2 MT 10 200 kg Drum Toxic
29 DiMethylFormamide 1 MT 5 200 kg Drum Flammable
54
54
List of Hazardous Substances and quantity stored.
Possible Accident Scenarios
Scenario MCL Scenario Quantity in

MT
1 Unconfined Pool Fire Simulations for Drum 198
Storage Area
2 Release of Chlorine 900 Kg
3 Release of HCl 60 Kg
4 Release of Hydrogen 60 Kg
5 Release of Ammonia 60 Kg
6 Release of Methanol 25
7 Release of Toluene 25
55
55
Scenario – 1: Unconfined Pool Fire Simulations for Drum Storage Area
Catastrophic Rupture
Input Data
Stored quantity - 198 MT
Wind speed – 1.44 m/s
Density (Air) – 0.867 g/cm3
Results indicate
Pool Fire Scenario
Radiation Level Distance Effect if IHR at Height of simulation
(KW/m ) 2
in meter
This level is sufficient to cause personnel if unable to reach cover
4 101.24 within 20s; however blistering of the skin (second degree burn) is
likely; 0: lethality
This level will cause extreme pain within 20 seconds and
12.5 35.26 movement to a safer place is instinctive. This level indicates
around 6% fatality for 20 seconds exposure.
This level of radiation is assumed to give 100% fatality as outlined
37.5 15.99 above.
Fire Ball Scenario
Radiation Level Distance Injury Type
(KW/m2) in meter
4 89.74 Pain after 20secs.
12.5 31.69 1st degree Burn
37.50 11.36 100% Fatal
56
56
POOL FIRE SCENARIO:
Blue – 4 KW/m2
Yellow – 12.5 KW/m2
Red – 37.5 KW/m2 57
57
FIRE BALL SCENARIO:
Blue – 4 KW/m2
Red – 37.5 KW/m2 58
58
STORAGE AND HANDLING
 Mechanical Foam type trolly (150 Ltr) mounted will be Provided in Storage area.
 Flame proof plant, pumping transfer, close process, etc.
 Double Static earthing
 Drum unloading procedure.
 SCBA sets available .
 Jumper clips on flanges
 Fire extinguishers
 Fencing and No Smoking and prohibited area.
 Tanker unloading procedure.
 Hydrant system
 Safety shower and eye wash will be provided in Drum storage area and plant area.
59
59
Scenario – 2: Release of Chlorine
Input Data
Stored quantity 900 Kgs
Rate of release 718 gram/sec
Molecular weight 70.9
Density ( Air) 2.49 kg/m3
Concentration Ground level distance
Hazard Level
(PPM) (Meter)
LC50 293 166
IDLH 10 (ACGIH) 555
STEL 15 Min 1.00 (OSHA) 1045
TWA/TLV 0.5 (OSHA) 1524
60
60
 MITIGATION MEASURES IN CASE OF CHLORINE LEAKAGE:
•Evacuate The Area in Down Wind Direction: Evacuate Area in Down Wind
•Direction Up to 300 Meter. Do Not Direct Water at Spill or Source of Leak.
•If Possible, Turn Leaking Containers So That Gas Escapes Rather Than Liquid.
•Use Chlorine Emergency Kit to Attend the Leak.
•Absorb The Fumes Through Chlorine Hood with Blower.
 PREVENTIVE MEASURES TO AVOID SUCH EMERGENCY:

•Chlorine Emergency Kit Will Be Procured and Kept Ready at Chlorine Shed.
•Chlorine Hood with Blower Will Be Provided with Scrubbing Arrangement.
•SCBA Sets Will Be Kept Ready at Chlorine Handling Area.
•Safety Shower and Eye Wash Will Be Provided in Chlorine Shed Area.
•Chlorine Absorption System Will Be Provided. In Case of Chlorine Leakage in Chlorine Shed It Will Be Suck Through
Blower and It Will Be Scrubbed in Caustic Scrubber.
•Emergency Siren and Wind Sock Will Be Provided.
•Tele Communication System and Mobile Phone Will Be Used in Case of Emergency Situations for Communication.
•First Aid Boxes and Occupational Health Centre Will Be Made at Site.
•Emergency Organization and Team Will Be Prepared as Per On Site-off Site Emergency Planning.
•Full Body Protection Suite and Other PPEs Will Be Kept Ready in ECC at Site.
•Emergency Team Will Be Prepared and Trained for Scenario Base Emergency. Like Toxic Control Team, Fire Control
Team, First Aid Team, Communication And General Administration Team, Medical Team Etc.
61
61
CHLORINE STORAGE AND HANDLING
 Chlorine will be stored in 900 kgs. tonners at site.
 Chlorine tonner storage area will be away from the process plant.
 Chlorine KIT, HOOD, PIT, SCBA sets will be kept ready and maintained in tiptop working condition.
 Chlorine Hood with blower will be provided with scrubbing arrangement.
 Safety Shower and eye wash will be provided in Chlorine shed area.
 Tonner handling EOT crane will be installed in Chlorine shed area for safe tonner handling.
 Safety Valve will be provided on chlorine header line and it will be connected to caustic scrubber.
 Barometric lag height will be maintained up to maximum height of the process building.
 SCBA sets will be kept ready at chlorine handling area.
 Safety valve will be provided on vaporizer header and outlet of safety valve connected to scrubber.
 Flow and temperature controllers will be provided on process line.
 SOP will be prepared for safe handling of Chlorine tonners. 14. Caution note and emergency handling procedure
will be dwell be played and trained all employees.
 Neutralizing chemicals will be kept ready in tonner storage area.
 Regular Mock-drill conducted for chlorine emergency.
PROCESS SAFETY OF CHLORINE
 DCS System will be provided for control the process
 FLP type area will be provided.
 Total enclosed process system.
 Instrument & Plant Air System.
 Nitrogen blanketing in Chlorination reactor.
 Safety valve and Rupture disc provided on reactor.
 Cooling Chilling and power alternative arrangement have been made on reactor.
 Chlorine Cylinder bank away from the auto clave reactor.
 PRV station with shut off valve, safety valve provision will be made for chlorination reaction safety.
 Flame arrestor will be provided on vent line of reactor and it will be extended up to roof level.
 Open well ventilated and fragile roofs will be provided to on reactor.
 Safe Catalyst charging method will be adopted. 62
62
Scenario - 3. Release of HCl Gas
Input Data
Stored quantity 60 Kgs
Rate of release 41.57 bar
Molecular weight 34.46 g/mol
Density ( Air) 1.49 kg/m3
Hazard Level Concentration Ground level distance (Meter)
(PPM)
LC50 3124 166
IDLH 50 555
STEL 15 Min 1.00 1045
TWA/TLV 0.5 1524
63
63
Graph
64
SAFETY PRECAUTION:
 Preventive maintenance of FLT. Train and license driver will be employed to drive FLT.
 Limit switch, interlock will be provided, Apron, Hand gloves, gumboot, helmet, goggles will be provided.
 Apron, Hand gloves, gumboot, helmet, goggles will be provided.

 Separate store will be made in cool and dry place.
 Eyewash fountains should be located in areas where bromine is handled, used or stored.
 When in danger of contact with liquid bromine, wear an approved chemical resistant suit.
 Leather or other non-woven ANSI approved steel-toed shoes or Gum boot
 Protective rubber boots should be worn over shoes for extra protection.
 Have NIOSH approved respirators and self-contained breathing apparatus available.
 Gloves: 100% Nitrile rubber gloves or Neoprene gloves
 Safe handling procedure for bromine will be prepared, displayed and trained to employees.
 Emergency handling procedure will be prepared and train for the same.
 PPEs will be procured and made it compulsory for bromine handling.
 Hazard identification and emergency action plan will be prepared and train all plant people for the same.
 SOP will be prepared for safe handling and storage of Bromine
65
65
PROCESS SAFETY
 DCS System will be provided for control the process
 Glasses, Acid-Alkali Proof Gloves etc. will be provided to the employees.
 Safety measures will be adopted from the design stage.
 Safety Valve and pressure gauge will be provided on reactor and its jacket (if jacket is provided).
 Utility like Chilling, cooling, vacuum, steaming and its alternative will be provided to control reaction parameters in a
safe manner.
 Free Fall of any flammable material in the vessel will be avoided.
 Static earthing provision will be made at design stage to all solvent handling equipments, reactors, vessels & powder
handling equipments.
 Any reaction upsets will be confined to the reaction vessel itself.
 All emergency valves and switches and emergency handling facilities will be easily assessable.
 Further all the vessels will be examined periodically by a recognized competent person under the Gujarat Factory Rules.
 All the vessels and equipments will be earthed appropriately and protected against Static Electricity. Also for draining in
drums proper earthing facilities will be provided.
 Materials will be transferred by pumping through pipeline or by vacuum from drums.
 Caution note, safety posters, stickers, periodic training & Updation in safety and emergency preparedness plan will be
displayed and conducted.
 Flame proof light fittings will be installed in the plant.
 All the Plant Personnel will be provided with Personal Protection
 Equipments to protect against any adverse health effect during operations, leakage, spillages or splash. PPE like
Helmets, Safety Shoes, Safety
 All employees will be given and updated in Safety aspects through periodic training in safety.
 Material Safety Data Sheets of Raw Materials & Products will be readily available that the shop floor
66
66
Scenario 4: Release of Hydrogen:
SCENARIO : UNCONFINED JET FIRE
Input Data
Stored quantity 60 Kg
Wind speed 2.14 m/s
Gas Density 67 kg/m3
Incident IHR- Effect if IHR at Height of Simulation
Intensity of Isopleths
Heat Radiation Distance
(IHR) at ground ( Meters )
level KW /m 2
Damage to process equipment. 100 % Fatal in

37.5 8.5 1 Min. 1 % fatal in 10 sec.
Min. to ignite wood (without flame contact).
25.0 10.6 100 % fatal in 1 Min. Significant injury in 10
sec.
Min. to ignite wood (with flame contact). 1 %
12.5 14.8 fatal in 1 min. 1 st deg. burn in 10 sec.
4.0 29.0 Pain after 20 secs. Blistering unlikely.
Results:
In the 8.5-meter radius area is considered as 100% fatality in 1 min.
In the 14.8-meter radius first degree burns in 10 sec.
In the 29-meter radius area will give pain after 20 seconds. Blistering unlikely.
67
67
JET FIRE SCENARIO:
Blue – 4 KW/m2
Red – 37.5 KW/m2 68
68
Scenario 5: Release of Ammonia
This scenario considers release of Ammonia from Cylinder:
Input Data
Stored quantity - 60 Kg
Molecular weight - 17.031 g/mol
Density (Air) – 0.86 kg/m
Results indicate
Fireball Scenario
Radiation Level (KW/m2) Distance in meter Injury Type
4 20.5 Pain after
20secs.
37.5 -- 100% Fatal
69
Fireball Scenario
Blue – 4 KW/m2
70
Scenario 6: Release of Methanol
This scenario considers release of Methanol from Storage Tank:
Input Data
Molecular weight -33.05
Density (Air) –0. 791 g/cm3
Results indicate
Pool Fire Scenario
Radiation Level Distance in meter Effect if IHR at Height of simulation
(KW/m ) 2
4 54.09 This level is sufficient to cause personnel if unable to reach cover

within 20s; however blistering of the skin (second degree burn) is
12.5 26.12 This level will cause extreme pain within 20 seconds and movement
to a safer place is instinctive. This level indicates around 6% fatality
for 20 seconds exposure.
37.5 13.2 This level of radiation is assumed to give 100% fatality as outlined
above.
Flash Fire Scenario
Radiation Level Distance in meter Injury Type
(KW/m2)
4 58.66 This level is sufficient to cause personnel if unable to reach cover
within 20s; however blistering of the skin (second degree burn) is
12.5 34.66 This level will cause extreme pain within 20 seconds and movement
to a safer place is instinctive. This level indicates around 6% fatality
for 20 seconds exposure.
37.5 9.66 This level of radiation is assumed to give 100% fatality as outlined
above. 71
71
Fireball Scenario
(KW/m2)
4 38 Pain after 20secs.
37.5 11 100% Fatal
POOL FIRE SCENARIO:
Blue – 4 KW/m2
Red – 37.5 KW/m2
72
FLASH FIRE SCENARIO:
Blue – 4 KW/m2
Red – 37.5 KW/m2
73
73
FIRE BALL SCENARIO:
Blue – 4 KW/m2
Red – 37.5 KW/m2
74
GRAPH:
75
75
 Mechanical Foam type trolley (150 Ltr * 5 Nos.) mounted will be provided in Tank Storage area.
 Flame arrestor provided on vent line of the tank
 Double Static earthing
 Dyke wall
 SCBA sets available .
 Jumper clips on flanges
 Fire extinguishers
 Fencing and No Smoking and prohibited area.
 Hydrant system
 Safety shower and eye wash will be provided in Tank storage area and plant area.
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Scenario – 7: Release of Toluene:
This scenario considers release of Methanol from Storage Tank:
Input Data
Molecular weight -92.14
Wind speed - 2.3 m/s
Density ( Air) – 860 kg/m3
Results indicate
Pool Fire Scenario
Radiation Level Distance in Effect if IHR at Height of simulation
(KW/m2) meter
4 93.70 This level is sufficient to cause personnel if unable to reach cover within
20s; however blistering of the skin (second degree burn) is likely; 0: lethality
12.5 40.61 This level will cause extreme pain within 20 seconds and movement to a
safer place is instinctive. This level indicates around 6% fatality for 20
seconds exposure.
37.5 -- This level of radiation is assumed to give 100% fatality as outlined above.
Vapor Cloud Explosion
Radial Distance (m) Over Fatality lung Eardrum Structure Glass Rupture (%)
Pressure Rupture (%) Rupture (%) Damage (%)
(psi)
5.2 36.2 100.0 100.0 100.0 100.0
5.9 8.9 0.0 77.0 100.0 100.0
8.9 2.0 0.0 3.1 14.5 100.0
In case of Unconfined Vapor Cloud Explosion up to 5.2 meter is considered as 100% fatality and 100% ear drum
rupture radius.
In case of Unconfined Vapor Cloud Explosion up to 5.9 meter is considered as 100% structure damage and up to
8.9 meter 100% glass rupture area.
77
77
Fireball Scenario
Fireball Radius: 8.336 m
Fireball intensity of Heat Radiation (KW/m2) – 149.074
Fireball rate of Energy release (KJ/Sec)- 107389
Fireball total energy released (KJ)- 185056
Fireball duration (Sec) – 1.72334
(KW/m2)
37.50 9.33 100% Fatal
22.04 12.66 Significant Injury
12.5 16.66 1st Degree burn
1.6 50 No Injury
Flash Fire
(KW/m ) 2
50.79 8.66 100% Fatal

37.5 10.73 100% Fatal
28.24 12.66 Significant Injury
17.95 14.66 1st Degree burn
12.5 18 Pain after 20secs.
1.6 46.66 No Injury
78
POOL FIRE SCENARIO:
Blue – 4 KW/m2
Red – 37.5 KW/m2 79
79
FLASH FIRE SCENARIO:
Blue – 4 KW/m2
Red – 37.5 KW/m2
80
Measures to be taken to prevent such accident:
 Priority will be given to Tanker to immediately enter the storage premises at site and will not be kept waiting near the
gate or the main road.
 Security person will check License, TREM CARD, Fire extinguisher condition, Antidote Kit, required PPEs as per SOP
laid down.
 Store officer will take sample as per sampling SOP from sampling point.
 After approval of QC department unloading procedure will be allowed be started.
Following precautions will be adopted during unloading
 Wheel stopper will be provided to TL at unloading platform.
 Static earthing will be provided to road tanker.
 Tanker unloading procedure will be followed according to check list and implemented.
 Flexible SS hose connection will be done at TL outlet line.
 The quantity remaining in the hose pipeline will be drained to a small underground storage tank, which will be
subsequently transferred by nitrogen pressure to the main storage tank thus ensuring complete closed conditions for
transfer from road tanker.
 All TL valves will be closed in TL.
 Finally earthing connection and wheel stopper will be removed.
 Only day time unloading will be permitted.
Following precautions will be adopted Storage of such chemicals
 Storage tank will be stored away from the process plant.
 Tanker unloading procedure will be prepared and implemented. Caution note and emergency handling procedure
will be displayed at unloading area and trained all operators. NFPA label will be provided. Required PPEs like full body
protection PVC apron, Hand gloves, gumboot, Respiratory mask etc.
 It will be provided to operator. Neutralizing agent will be kept ready for tackle any emergency spillage. Safety shower,
eye wash with quenching unit will be provided in acid storage area. Material will be handled in close condition in
pipe line.
 Dyke wall will be provided to all storage tanks, collection pit with valve provision. Double drain valve will be provided.
Level gauge will be provided on all storage tanks. Safety permit for loading unloading of hazardous material will be
prepared and implemented. TREM CARD will be provided to all transporters and will be trained for transportation
Emergency of Hazardous chemicals. 81
Risk Assessment Summary
 From the Risk Assessment studies conducted, it would be observed that by and large, the risks are confined within
the factory boundary walls. Based on these studies company has been proposed to plan its facility sitting as well as
location of operator cabin, open area, etc.
 Company has to increase awareness programme in the surrounding vicinity and educate people for safe evacuation
at the time of toxic release. A HAZOP study to be carried out for all product plant and storage facilities.
 Induction safety course to be prepared and trained all new employees before starting duties in plant.
 Safety Precautions Of Various Chemicals:

Safety Precautions for Acid
 Dyke wall- filled with sufficient size is provided.
 Tank, valve, pipeline are checked and maintain, in good condition.
 All Gaskets are checked periodically & if new one replaces found defective.
 Joints are checked regularly to found any Leakage.
 ADEQUATE PPE is kept to handle the Hazard.
 ISI Portable fire extinguisher & Hydrant line is provided as per TAC norms.
 Sufficient amount of sand/soil are kept to control any spillage.
 Flame proof fitting provided.
 Eye washer cum shower is provided near tank-farm area.
 Level indicator provided.
 Spark arrester are installed on all vehicles in side the premises.
 SBA set, Canister mask and airline mask is provided.
 Earthing & bonding on tanks is provided.
 Vent line provided at sufficient height.
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 Sufficient amount of sand/soil are kept to control any spillage.
 Flame proof fitting provided.
 Eye washer cum shower is provided near tank-farm area.
 Level indicator provided.
 Spark arrester are installed on all vehicles in side the premises.
Methanol
 Tank, valve, pipeline are checked and maintain, in good condition through preventive maintenance.
 Joints are checked regularly to detect any Leakage.
 ISI Portable fire extinguisher & Fire Hydrant line is provided as per TAC norms.
 Flame proof electrical fittings / installation provided.
 Proper Earthing, Bonding & flange-to-flange jump ring is provided.
 Flame arrester provided on vent line.
 CCE approved Separate Storage area with door having locking arrangement.
 Auto & manual sprinkler provided.
 Spark arrester are installed on all vehicles inside the premises.
 Apron, Hand gloves, gumboot, goggles and helmet provided.
 Train operator employed.
 Eye washer & shower provided.
 Tank’s thickness measured on regular interval.
 Good ventilation in the area.
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83
6. Risk Studies & Disaster Management a) Explosion of high magnitude affecting the adjacent area
 Onsite mitigation measures/ DMP b) Heavy / Profuse leakage of toxic / flammable gases for a
Disaster Management Plan long duration.
M/s. Shree Ganesh Remedies Ltd (Unit-5) shall develop Objectives Of Emergency Management System
the emergency management system to tackle the The objectives of the emergency management system are
emergency situation, apart from its emergency summarized as under.
management system. The detail of disaster management •To identify and assess types of emergencies due to
system is discussed in the following section. different types of hazards.
Defining The Nature Of Emergency •To work out plan with all provisions to handle emergencies
Level Of Emergency Can Be Classified In Three Categories and safeguard employees and people in the vicinity of the
Level - 1: factory.
The leakage or emergency, which is confinable within the •To provide for emergency preparedness and the periodical
plant, premises. It may be due to - rehearsal of the plan.
a) Small fire in the plant •To plan mode of proper communication and actions to be
b) Low toxic gas release for short duration. followed in the event of emergency.
c) Collapsing of equipment that do not affect out side •To keep all necessary information with respect to
premises. hazard/accident control and emergency contacts in one
Level - 2: document for easy and speedy reference.
The emergency, which is confinable within the factory •To inform employees, general public and the authorities
premises. It may arise due to - about the hazards/risk if any and the role to be played by
a) Major fire inside the factory premises. them in the event of emergency.
b) Medium scale explosion confined to the factory •To control and contain the accident.
premises. •To effect rescue and treatment of casualties.
c)Heavy toxic / flammable gas leakage for short duration. •To inform and help relatives of casualties.
Level - 3: •To secure rehabilitation of affected area and restore
The emergency, which is not confinable within the factory normalcy.
premises and general public in the vicinity likely to be •To provide information to media and government
affected. It may arise due to - agencies.
•To preserve record, equipment etc. for investigating cause
of emergency.
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84
•To be ready for “mutual aid” if need arises to help ·Training on good housekeeping
neighboring units. Training on use of PPE
The records of the training programs shall be maintained
Onsite Mitigation Measures/ DMP
by the Safety Committee. New topics will be included in the
Structure Of Emergency Management System
safety training programs year by year to upgrade safety
The management structure at M/s. Shree Ganesh
Remedies Ltd (Unit-5) includes the following personnel’s; knowledge among the workers.
Chief Emergency Controller Frequency: Once in a year
•Incident Controllers and Deputy Incident Controllers Personal Protective Equipment
•Site Main Controllers To procure adequate number of personal protective
•Key Personnel’s equipment (aprons, hand gloves, safety goggles, helmets,
•Essential Workers nose masks, safety belts, gas cartridges, self-breathing
•Assembly points apparatus, safety shoes etc.) suitable for plant operations
•Emergency control center and maintain records of use.
•Fire control arrangements
To have proper system for issuing the PPE and disposal of
•Medical arrangements
used PPE
•Other arrangements
•Individual Responsibility During On Site Emergency Plan To train the workers about proper use of PPE.
Safety Training To check the fresh air blowers provided at confined spaces
To organize regular training for the employees for for fresh air to workers.
handling of safety equipment, use of personal protective
equipment, first-aid, etc. by internal/external faculty, as
well as by sending persons outside to attend safety
programs etc. The topics covered in safety training will be
·Training on fire fighting
·Training on spill control.
·Training on toxic release control
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85
Individual Responsibility During On Site Emergency Plan
1 Every Individuals Primary responsibilities for all are to ensure that the fire is extinguished by
using suitable fire extinguishers. As soon as fire / leak observed start shouting
FIRE. FIRE and LEAK..LEAK and immediately intimate to incident controller (HOD
/ Plant incharges / shift incharges )
2 S.M.C. Immediately to be aware of the emergency control centre he will go to the
Site Main Controller incident place. He will relieve the incident controller of his responsibility for
(Director – Works) overall main control. He will give information to district authority and decide
the nature of help required such as evacuation, traffic control, warming to the
public vehicle requirement etc. He will inform to head office. He will guide to
incident controller.
3 Dy. S.M.C. In absent of S.M.C. Dy.S.M.C. will act as a S.M.C. and if S.M.C. is present then he
Dy. Site Main Controller will help to I.C. to control emergency.
(Sr.G.M.-Works)
4 Fire & Safety He will rush to the incident place and guide to I.C. for the actions to be taken to
Ehs Department tackle the incident. He will organize for Mutual Aid from the neighbor and
(Manager / Officer) D.P.M.C. He will also help to S.M.C.
5 Transportation Team He will control safe assembly point. He will shift injured person to hospital. He
P & A Department will organize the additional vehicles if required. If evacuation require,
(G.M. / Executive / officer) mobilization of person have to done.
6 Incident Controller Shall be incident controller and also act as S.M.C. till S.M.C.’s availability. His
Production Department duties will be to assess the situation and take necessary actions deem fit,
(Manager / Executive / officer) looking to the gravity of situation.
7 Plant Operators If fire takes place in plant, he shall inform to the incident controller (shift
officer / supervisor) immediately and follow his instruction. He is responsible
for process isolation and fire fighting.
8 Utility Incharge / Operator He will follow the instruction of incident controller / maintenance engineer. He
is responsible to operate fire hydrant pumps.
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86
Individual Responsibility During On Site Emergency Plan
9 Electrical Maintenance He should contact the incident controller and follow his instruction. If fire takes
(Manager / Officer / Electrician) place in plant where electrical cables are lying, immediately cut off power
supply to necessary places. If there is a fire in MCC immediately cut off power
supply and starts extinguishing activities.
10 Mechanical Department He should report to incident place and follow the incident controller’s
(Manager / Exec./Officer/ Fitter) instructions. Help incident controller for process isolation.
11 QAD Department They should be ready with the first aid box and shift injured person to safe
(Manager / Exe. / officer) assembly point / vehicle and follow the instruction of incident controller.
12 Security Department He should be attending the telephone. Also ensuring emergency vehicle is kept
(Manager / ASO / Supervisor in the running in the ideal condition at the gate area.
12 Guards) He should be ready for gate operation when fire tenders arrives. Restrict
outside person at gate. He should inform key persons of the company. Security
guards will help in fire fighting. Do head count.
13 Evacuation Team Reach near incident place and cordon area. Remove material from incident
Store Department places.
(Manager / Officer/ Helper)
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DETAILS OF SCHEDULE-I SPECIES
Study Area: Company Located in Dahej
The Schedule- I species as per Wildlife Protection Act -1972 are:
Scientific Name
Sr. No. Animal Type Local Name WPA Status IUCN Status
(Zoological Name)
Oriental honey
1 Pernis ptilorhynchus Madhiyo baj I LC
buzzard
2 Black kite Milvus migrans Samadi I LC
3 Shikra Accipiter badius Shakro I LC
4 Indian peafowl Pavo cristatus Mor I LC
Black-shouldered
5 Elanus axillaris Kapasi I LC
kite
Conservation Plan for Schedule – I species documented from project site

Introduction
A detailed biological survey of the core zone (Project site) and buffer zone (10 km radius from periphery of the project
site) was carried out giving details of flora and fauna. However, peacock which belongs to Schedule I of the Wildlife
(Protection) Act 1972 are the only species of fauna found in the study area.
A detailed field survey was carried out for complete documentation of floral as well as faunal biodiversity for the core
zone which is at Project site and the buffer zone which is 10 km aerial circular area from the project site. The Indian
Peafowl (Pavocristatus) among the birds was recorded from the study area and these faunal species belongs to
Schedule – I of the Wildlife Protection Act – 1972. Following are species wise conservation plans and also generalized
measures for their conservation.
88
88
ACKNOWLEDGEMENT COPY OF CONSERVATION PLAN
89
PROCESS FLOW CHART
Manufacturing Process, Chemical Reaction and Mass Balance of each products
1) Deltamethrin:
Manufacturing Process:
Take Deltametric Acid, Benzene and Catalyst in the rector, Add C3PB Alcohol slowly at 20 Degree temperature. This
reaction mass is taken into another vessel to separate aq. Layer. Organic layer is separated in distillation unit to get
product.
Chemical Reaction:
90
PROCESS FLOW CHART
Manufacturing Process, Chemical Reaction and Mass Balance of each products
Mass Balance:
Sr Input Kgs Output Kgs
No.
1 DCA 550 Prpduct 1000
2 CPBA 500 Rec. Catalyst 180
3 Benzene 600 Rec. Benzene 588
4 Catalyst 180 Loss 12
5 Caustic 100 Effluent 500
6 Water 350
Total 2280 Total 2280
91
DETAILS OF GREEN BELT DEVELOPMENT PLAN
BREAK UP OF DIFFERENT LAND USE OF FACTORY
Total 40554.30 sq. meter land area is available at site; out of this area about 13382.92 sq. meter (33 %) area is
covered as greenbelt and other forms of greenery.
Trees will be planted with spacing of 2m x 2m and Approx. 3345 number of trees have to be developed
accordingly. Good greenery shall be maintained in and around the site by planting various types of tress and
maintaining lawns. A green belt shall be developed within the site boundary and across the premises inside roads.
Trees like Neem, Gulmohar, Champa, Gauva, Palm Trees, Nariyal, Ghaneri, Shevga, Jangli badam, Sag, Jamun,
Mango, Rain tree etc. shall be planted in and around the site.
GREEN BELT DEVELOPMENT PROGRAMME
Year No. of Trees

2022-2025 3345
BUDGET FOR DEVELOPMENT OF GREENBELT
Year Cost in Rupees Recurring Cost

2022-2025 16,72,500 2,00,000 Rs./Year
92
Green-Belt 02
6566.69 SQ.M.
Green-Belt 03
4754.94 SQ.M.
Green-Belt 01
2061.29 SQ.M.
93
TREE DISTRIBUTION OF GREENBELT
No. of Trees
Sr. (Approx.)
Types Of Tree
No.
Green Belt
1 Neem 460
2 Gulmohar 265
3 Champa 260
4 Gauva 260
5 Palm 260
6 Nariyal 260
7 Ghaneri 260
8 Shevga 260
9 Jangli Badam 265
10 Sag 265
11 Jamun 265
12 Mango 265
Total 3345
94
ENVIRONMENT MANAGEMENT PLAN
ENVIRONMENTAL
SOURCES OF IMPACT MITIGATIVE MEASURE
COMPONENTS
Water Environment Construction activity & abstraction of water Proper management of surface water runoff shall
for construction requirement and sanitation be made. Company will provide the sanitation
in housing for workers. facility for workers and domestic wastewater will
be treated into STP.
Generation of process effluents, Washing Wastewater (Low COD stream of process

effluent and waste streams to be generated wastewater) & Dilute Stream will be treated in to
from boiler, cooling tower etc. ETP & finally disposed to CETP, Saykha Industrial
Estate.
Industrial wastewater High COD & TDS stream will
be sent to ETP then treated into In-house MEE then
MEE condensate will be reused and MEE Salt will
send to TSDF site. Solvent residue will be send to
Incineration site.
Air Environment During Construction activities, Emission of Emission of fugitive dust due to movement of
fugitive dust heavy vehicles etc. shall be controlled by spraying
water in the affected zone for which an operational
water truck shall be made available at site at all
times.
There will be three-process gas emission Company will use the Imported Coal Natural gas as
source like Boiler, TFH and D.G. Set. fuel in Boiler & TFH.
Increase the level of PM concentrations in Company will provide ESP + water scrubber &
ambient air. adequate stack height to control Process gas
emission & adequate scrubber to control Flue gas
emission.
95
ENVIRONMENT MANAGEMENT PLAN
ENVIRONMENTAL
SOURCES OF IMPACT MITIGATIVE MEASURE
COMPONENTS
Land Environment There will be generation of 23 Nos. of category Company will collect storage, transportation
of hazardous waste from Process, ETP, Utilities and disposal/sell/reuse the hazardous waste as
and scrubber. per characteristics of hazardous waste.
Noise Increase noise level due to Operation of Manufacturers / suppliers of major noise
Environment equipment and machineries generating equipment / machines like
compressors, turbines, generators should be
asked to take required measures for
minimizing the noise levels generated by
machines by using noise absorbing material for
various enclosures or using appropriate
design / technology for fabricating /
assembling the machines.
Noise emissions will be kept to a minimum by
regular maintenance of machineries.
Regular oiling, lubrication and maintenance of
the equipment shall be carried out to minimize
noise generation.
Infrastructure & Improved communication, transport, housing, Development has been gradual.
Services educational & medical facilities
Environmental Hazards Risk to environment & neighboring population Disaster management plan Safe practices.
(Handling and storage of chemicals, solvents
& fuels)
96
DETAILS OF ENVIRONMENT PERSONNEL (Environment Engineers and Environment Scientist)
posted in Environment Management Cell.
97
DETAILS OF ENVIRONMENT PERSONNEL (Environment Engineers and Environment Scientist)
posted in Environment Management Cell.
Company has a system of reporting of non-compliances / violations of environmental norms to the Board of Directors of
the company and / or shareholders or stakeholders at large.
 Operators will be responsible for Operation of EHS system. If any problem will be observed in operation, then the
operator will report the same to the Shift In-Charge.
 Shift In-Charge will be responsible for implementing HSE Management Programs. If any non-compliances/ violations of
environmental norms will be observed, then the executives will report the same to the Assistant Manager.
 Assistant Manager will be responsible to define and monitor the key characteristics for measure of performance in
production, maintenance and EHS. Assistant Manager is responsible to report the non-compliances received to Partner.
 General Manager will have overall responsibility for effective implementation of Occupational Health, Safety &
Environment Management System (OHS & EMS) and the partner will conduct management review every three months
to assess the effectiveness of HSE Management System. If necessary, resources will be allocated for taking Corrective
and Preventive action on Non-Conformance within time period.
 General Manager will advise and monitor the establishment and implementation of HS & EMS.
 Verification activities, including internal HSE Audits shall be carried out at the direction of General Manager.
98
SPECIFIC TORs
SPECIFIC TERMS OF REFERENCE FOR EIASTUDIES FOR PESTICIDES INDUSTRY AND PESTICIDE SPECIFIC INTERMEDIATES
(EXCLUDING FORMULATIONS)
TOR-1 : Commitment that no banned pesticides will be manufactured
Undertaking for no banned pesticide will be manufactured
99
TOR-2 : Details on solvents to be used, measures for solvent recovery and for emissions control.
Solvent Management Plan
 A highly efficient and full fledge solvent recovery system will be installed to recover maximum possible solvent and
will be reused back in process. Detailed process is as described below.
 All the solvents shall be directly distilled from product mixes and; if required shall be purified in packed column with
the help of reflux and therefore there is no generation of any distillation residue from the solvent distillation.
 The solvent distillation system shall be designed so as to achieve maximum 95 - 99 % recovery of solvent.
 Pure solvent, crude solvent and distilled (recovered) solvent shall be stored only in storage tanks and company shall
not use drums at any stage in the Solvent Management System.
 Wherever required, the solvents shall be directly pumped into day tanks from the storage tanks and shall be charged
into the reactors without involving any manual handling.
 All the pumps shall be mechanical seal type to avoid any leakage of solvent.
 All necessary firefighting systems shall be provided with alarm system. Flame proof wiring and flame proof electrical
accessories shall be provided to avoid any mishap.
 All the storage tank and day tank shall be connected to a vent system through cooling water and chilled brine
condensers to prevent loss of solvents in the atmosphere.
 All the distillation column vents are also connected to cooling water/ chilled brine condensers for maximum possible
recovery of the solvents.
 All the vents will be connected to a common carbon Adsorber for removing traces of solvent from vent gases.
 Residue generated from the distillation will be incinerated in-house or sent to BEIL incinerator site.
100
FLOW DIAGRAM OF SPENT SOLVENT MANAGEMENT SYSTEM
101
SOLVENT BALANCE
Input Recovery %
Solvent B.P °C V.P.
(MT/Month) (MT/Month) Recovery
Methanol 64.7 96 mm of Hg (@ 20°C) 551 540.80 98.15
Toluene 110.6 30.89 hPa (@21.1 °C) 1025 1007.06 98.25
Ethylene 83 87 hPa (@ 20°C) 252 246.86 97.96
Dichloride
Hexane 69 17.3 kPa (@ 20°C) 185 181.67 98.20
Xylene 139 882 Pa (@ 25 °C) 150 147.17 98.11
Chloroform 61.2 882 Pa (@ 25 °C) 515 505.73 98.20
Mono 132 12 mm Hg (@ 25 °C) 550 539.88 98.16
chlorobenzene
Cyclohexane 80.75 104 mbar (@ 20°C) 210 206.26 98.22
102
Leak Detection and Repair Immediate Repair of devices in case of Leakages:
Monitoring of Solvent Losses: A regular preventive maintenance schedule will be in place
In warding, storage and consumption of solvents in various to replace or rectify all gaskets and joints to ensure no
products shall be measured through Level Transmitters and fugitive emissions shall take place.
Load cells weighing systems resp. The quantity at each stage Plant shall also maintain adequate number of spares and
shall be reconciled periodically to arrive at Losses. consumables required to repair the leaking device
Periodic monitoring of work area will be carried out to check Plant shall also have competent contractor team to handle
the fugitive emission. Leakages and can repair the same immediately
VOC detectors will be installed at various places to detect Standby equipments like Pumps, valves etc shall be kept
leak. basis the criticality and usage
Plant shall also have access equipments like Boom lift to
Leak Detection and Repair (LDAR) handle leakages at height immediately
To prevent losses of these solvents in atmosphere, following
infrastructure shall be used in addition to LDAR program Preventive Maintenance to prevent Leakages
Leak Free Pumps & Valve for transfer of solvents In order to prevent leakage from Pump, Seals, Valves etc,
MSW Gaskets in solvent pipelines to prevent leakage from preventive maintenance shall be carried out periodically as
flanges per plan. Regular maintenance of valves, pumps, flanges,
Minimum number of flanges, joints and valves in pipelines. joints and other equipment will be done to prevent leakages
To eliminate chances of leakages from glands of pumps, and thus minimizing the fugitive emissions of VOCs.
double mechanical seal will be provided at all solvent
Preventive
pumps. Sr.
Component Maintenance
All the rotating equipments like pumps will be installed with No.
schedule
double Mechanical Seals to arrest any sort of emissions. 1 Pump seals with visible liquid Daily
Condenser post Reactor with cooling arrangement and dripping
chilling Arrangement. 2 Valves/flanges Quarterly
Flanges will be sealed so less losses will be there.
3 Compressor seals Quarterly
Down the Temperature of Chilling tower to -15°C. Closed
loop system. 4 Pressure relief devices Yearly
5 Pipeline Thickness Testing Yearly
103
TOR-3 : Details of process emissions from the proposed unit and its arrangement to control.
Process gas emissions is refer as Slide No. 8
TOR-4: Ambient air quality data should include VOC, other process-specific pollutants* like NH3*, chlorine*, HCl*,
HBr*, H2S*, HF*,etc.,(*-as applicable)
Ambient air quality data is Refer as Slide No. 21-22
TOR-5: Work zone monitoring arrangements for hazardous chemicals.
Environmental
Parameters Standards Frequency
Component
Air Environment
As prescribed by GPCB including PM2.5, PM10, SO2, Once in a month
AAQM at plant site Prescribed by CPCB
Nox, HCl, Br2, Cl2, HBr & VOCs through NABL Lab.
Stack emission Parameters prescribed by GPCB of Flue Gas Once in a month by
Prescribed by GPCB
monitoring emission and Process Gas Emission NABL Lab.
Fugitive emissions/
Once in a month by
work place monitoring PM10 & PM2.5, VOC Prescribed by GPCB
NABL Lab.
within the plant side
Water Environment
Water quality Once in a Season by
Surface water quality Parameters prescribed by GPCB
Standards NABL Lab
Water quality Once in a Season by
Ground water quality Parameters prescribed by GPCB
Standards NABL Lab
Noise Environment
Ambient Noise at plant As per National Once in a Month by
Noise level in dB(A)
site Noise Standards NABL Lab
Soil Environment
Analysis of pH, conductivity, Sulphates, calcium,
Once in a Season by
At plant site magnesium, Chloride, Potassium, Phosphorus --
NABL Lab
and nitrogen, WHC, Porosity
104
TOR-6: Detailed effluent treatment scheme including segregation of effluent streams for units adopting 'Zero' liquid
discharge.
 Total water requirement will be 570.5 KL/Day (Fresh water: 300 KLD + Reuse: 270.5 KLD) which will be met through
GIDC water supply.
 Scrubbing Media: Effluent from Scrubber (7.5 KL/Day), in which 4.5 KL/Day will sell to end users under Rule-9
Permission & 3 KL/Day will reuse for production of product no. 92 & 93.
 Effluent from Process & R&D (141 KL/Day) & washing (20 KL/Day) Total 161 KL/Day will treat in Solvent Stripper
then treat in ETP having primary treatment then treat in MEE & MEE Condensate 131 KL/Day will reuse in plant
premises.
 Mode of Discharge: Effluent from Process Low COD (96 KL/Day) & Utility (84 KL/Day) will be treat in ETP & treated
effluent (180 KL/Day) will be sent to CETP, Dahej for further Treatment & Disposal.
Details of Effluent treatment is referred as Slide No. 43-49
105
TOR-7: Action plan for odour control to be submitted.
Action Plan for Odour Control

• All liquid raw materials shall be charged into Reactors with pumps or under gravity through closed pipes.
• Suction Hoods shall be placed near the Man-holes & Charging funnels of Reactors & Filters so that chemical vapors and
dust do not escape into the Plant & surroundings, when the man-hole covers are opened for inspection or charging of
RM.
• All storage tanks of low boiling chemicals shall be provided with Conservation Vents.
• Vent lines of Dosing vessels shall be connected back to the vents of storage tanks to prevent contaminated air release
during material transfer.
• All pumps handling hazardous chemicals shall be provided with mechanical seals to prevent fugitive emission. Wherever
possible magnetic coupled pumps will be used.
• Any spillage from drums etc. will be absorbed with saw dust / soda ash and moped clean. The contaminated absorbent
will be safely disposed off along with hazardous waste.
• Measuring Instruments with sound alarm and having strategically placed sensing elements will be provided for alerting
the personnel in case of any escape of gases like Chlorine vapors.
Procedure for unloading chemicals from tankers

When a liquid is transferred from one container to another the air from the receiving container is displaced to
atmosphere and the air from atmosphere is sucked into the container from which the material is transferred.
The air released from receiving container is contaminated with vapors of the liquid being transferred. To avoid this
release of vapors into atmosphere, the contaminated air from receiving tank is let into the tanker from where the
material is transferred with help of a designated pipe line called as pressure equalization line or vent equalization line.
The system has been depicted in the following drawing.
106
Procedure for transferring chemicals from one tank to another tank or reactor.
The same technique of pressure equalization is used for transfer of liquid from one tank to another tank or reactor to
reduce the release of vapors to atmosphere.
The system has been depicted in the following drawing.
107
TOR-8: A copy of the Memorandum of Understanding signed with cement manufacturers indicating clearly that they
co-process organic solid/hazardous waste generated.
Unit has obtained Membership from M/s. BEIL Infrastructure, Dahej for TSDF Disposal & M/s. BEIL Infrastructure for
Incineration Disposal of hazardous waste.
Membership letter of TSDF & Incineration site:
108
TOR-9: Authorization/Membership for the disposal of liquid effluent in CETP and solid/hazardous waste in TSDF, if
any. TSDF & Incineration Site
Membership Certificate of CETP, Dahej:
109
TOR-10: Material Safety Data Sheet for all the Chemicals are being used/will be used.
MSDS of Hazardous Chemical
Name of LEL UEL SP.GR. NFPA TLV/
Hazard F.P (0C) BP (0C) VD IDLH LC50 / LD50 Antidote
Chemical % % 20 0C H F R TWA
Chlorine gas T - -34 - - 1.40 2.45 4 0 0 0.5 10 <5000 mg/kg (Rat) No specific antidote
Liquid 0.66
T NA 58.78 NA NA 3.11 7.1 300 3 ppm 2,600 mg/kg [Rat] No specific antidote
Bromine ppm
49000 mg/m 4
Toluene F 4.444 110.6 1.1 7.1 0.8636 3.1 2 3 0 300 ppm 500 ppm Oxygen, Novasine Eye drops.
hours [Rat]
Hexane T (-) 23.2 68.9 1.2 7.5 0.659 2.97 3-0-0-X 260 1100 NA NA
Trimethyl 101 –
F&T 13 1.40 44.60 0.970 3.67 230 - - 412 mg/L/48h No specific antidote
orthoformate 102
Acetic 1000 ppm/4H
Anhydride C 54 140 2.9 10.3 1.0820 3.5 321 5 ppm 200 ppm [Rat] No specific antidote
Oxygen, Baking Soda in a glass

Methanol F 12 64.5 6 36.5 0.7915 1.11 1 3 0 250 ppm 6000 ppm 64000 ppm 4 of water, ethanol, Novasine
hours [Rat]
Eye drops.
39.75°C
Methylene T&F NA (103.5°F 12% 19% 1.3266 2.93 2 1 0 NA NA 1600 mg/kg NA
chloride )
Ethylene 0.06 2646 ppm 1 hours
T&F 13 82 - 84
2 0.162 1.25
1.24 330 1 ppm 50 ppm No specific antidote
Dichloride [Rat]
143 to
Xylene F&T 31 0.9 6.7 0.865 3.7 230 N.A 724 ppm 3608 mg/kg No specific antidote
145
Hydrochlori 1.1- 1.26 4701 ppm 0.5 Milk of Magnesia, Drink
C NA 108.58 NA NA 3 0 1 5 ppm 50 ppm
c Acid 1.19 7 hours [Rat] Large Quantity of Water
Sodium 2 10
T 1390 NA NA NA NA 1.38 NA NA No specific antidote
Hydroxide mg/m3 mg/m3
Cyclohexan 100 1300 13.9 mg/L 4 h
F -18.0 80.7 1 9 0.770 2.90 230 No specific antidote
e ppm ppm [Rat]
-
Hydrogen F 252.8 NA 4.0 75 0.089 0.07 0 4 0 NA NA NA Fresh air
Gas 8
7 °C
Sulphuric 1 15 510 mg/m3 for 2H Sodium Hydro-Carbonate (4%

C NA 340 NA NA 1.84 NA 3 0 2 mg/m3 mg/m3 Rat Conc.), Milk, Lime Juice, Milk of
Acid Megnesia
T NA 36 NA NA yes 3.38 300 NA NA NA NA

Ammonia 110
TOR-11: Authorization/Membership for the disposal of solid/hazardous waste in TSDF.
Membership for the disposal of solid/hazardous waste in TSDF is refer as Slide No. 108
TOR-12: Details of incinerator if to be installed.

Incinerable Waste will be disposed to M/s. BEIL Infrastructure Ltd.
TOR-13: Risk assessment for storage and handling of hazardous chemicals/solvents. Action plan for handling & safety
system to be incorporated.
Risk assessment for storage and handling of hazardous chemicals/solvents are Refer as Slide No. 54-84
111
TOR-14: Arrangements for ensuring health and safety of workers engaged in handling of toxic materials.
Occupational health impact on employees, control measures, action plan if accident occur
Sr. Chemical Occupational health impact Control measures provided Action plan if accident occurs
No. on employees
Methylene Carcinogenic Effects: Provide exhaust ventilation or Absorb with an inert material and put the
Chloride Classified + (Proven.) by other engineering controls to spilled material in an appropriate waste
CAS #75-09-2 OSHA. The substance is toxic keep the airborne concentrations disposal. Be careful that the product is not
1. to lungs, the nervous system, of vapors below their respective present at a concentration level above TLV.
liver, mucous membranes, threshold limit value. Ensure that
central nervous system (CNS). eyewash stations and safety
2. Sulfuric Acid Prolonged or repeated skin Facilities storing or utilizing this Clean up spills immediately, observing
CAS # 7664-93-9 contact may cause dermatitis. material should be equipped with precautions in the Protective Equipment
Prolonged or repeated an eyewash facility and a safety section. Carefully scoop up and place into
inhalation may cause shower. Use adequate general or appropriate disposal container.
nosebleeds, nasal congestion, local exhaust ventilation to keep Provide ventilation. Do not get water
erosion of the teeth, airborne concentrations below inside containers. Cover with dry earth,
perforation of the nasal the permissible exposure limits. dry sand, or other non-combustible
septum, chest pain and Use a corrosion-resistant material followed with plastic sheet to
bronchitis. Prolonged or ventilation system. minimize spreading and contact with
repeated eye contact may water.
cause conjunctivitis. Effects
may be delayed. Workers
chronically exposed to
sulfuric acid mists may show
various lesions of the skin,
tracheobronchitis, stomatitis,
conjunctivitis, or gastritis.
Occupational exposure to
strong inorganic acid mists
containing sulfuric acid is
carcinogenic to humans.
112
Sr. No. Chemical Occupational health Control measures provided Action plan if accident occurs
impact on employees
3. EDC Carcinogenic Effects: Provide exhaust ventilation or Absorb with an inert material and put the
CAS # Classified + (Proven.) by other engineering controls to spilled material in an appropriate waste
107-06-2 OSHA. The substance is keep the airborne concentrations disposal. Be careful that the product is not
toxic to lungs, the nervous of vapors below their respective present at a concentration level above TLV.
system, liver, mucous threshold limit value. Ensure that
membranes, central eyewash stations and safety
nervous system (CNS).
4. Bromine The substance may be Provide exhaust ventilation or Keep locked up. Keep container dry. Do
CAS # toxic to kidneys, liver, other engineering controls to not ingest. Do not breathe gas/fumes/
7726-95-6 cardiovascular system, keep the airborne concentrations vapor/spray. Never add water to this
central nervous system of vapors below their respective product. In case of insufficient ventilation,
(CNS), thyroid. Repeated threshold limit value. Ensure that wear suitable respiratory equipment. If
or prolonged exposure to eyewash stations and safety ingested, seek medical advice
the substance can produce showers are proximal to the immediately and show the container or
target organs damage. work-station location. the label. Avoid contact with skin and
eyes. Keep away from incompatibles such
as reducing agents, combustible
materials, organic materials.
5. Xylene The substance is toxic to Provide close process Flammable liquid. Keep away from heat.
CAS # blood, the reproductive Keep away from sources of ignition. Stop
141-78-6 system, liver, upper leak if without risk. Absorb with DRY
respiratory tract, skin, earth, sand or other non-combustible
central nervous material. Do not touch spilled material.
Prevent entry into sewers, basements or
confined areas; dike if needed.
113
impact on employees
6. Cyclohexane The substance is toxic to Provide close process Flammable liquid. Keep away from heat.
110-82-7 system, liver, upper leak if without risk. Absorb with DRY earth,
respiratory tract, skin, sand or other non-combustible material.
central nervous Do not touch spilled material. Prevent
entry into sewers, basements or confined
areas; dike if needed.
7. Hydrochloric Acid Very hazardous in case of Provide close process and Corrosive liquid. Poisonous liquid. Stop
CAS # skin contact (corrosive, scrubber on process vent and leak if without risk. Absorb with DRY earth,
7647-01-0 irritant, permeator), of eye storage vent sand or other non-combustible material.
contact (irritant, corrosive), Do not get water inside container. Do not
of ingestion. Slightly touch spilled material. Use water spray
hazardous in case of curtain to divert vapor drift.
inhalation (lung sensitizer).
Non- corrosive for lungs.
Liquid or spray mist may
produce tissue damage
particularly on mucous
8. Toluene The substance is toxic to Provide close process Flammable liquid. Keep away from heat.
114
Sr. No. Chemical Occupational health impact Control measures provided Action plan if accident occurs
on employees
9. Hydrochloric Acid Very hazardous in case of Provide close process and Corrosive liquid. Poisonous liquid. Stop
CAS # skin contact (corrosive, scrubber on process vent and leak if without risk. Absorb with DRY earth,
7647-01-0 irritant, permeator), of eye storage vent sand or other non-combustible material.
contact (irritant, corrosive), Do not get water inside container. Do not
of ingestion. Slightly touch spilled material. Use water spray
hazardous in case of curtain to divert vapor drift.
inhalation (lung sensitizer).
Non- corrosive for lungs.
Liquid or spray mist may
produce tissue damage
particularly on mucous
10. Toluene The substance is toxic to Provide close process Flammable liquid. Keep away from heat.
11. Methanol The substance is toxic to Provide close process Flammable liquid. Keep away from heat.
CAS# blood, the reproductive Keep away from sources of ignition. Stop
115
impact on employees
12. Chlorine Toxic by inhalation. Use only with adequate Immediately contact emergency personnel.
Irritating to eyes, ventilation. Use process Keep unnecessary personnel away. Use
respiratory system and enclosures, local exhaust suitable protective equipment. Eliminate all
skin. ventilation or other ignition sources if safe to do so.
Very toxic to aquatic engineering controls to keep Do not touch or walk through spilled
organisms. worker exposure to airborne material. Shut off gas supply if this can be
contaminants below any done safely. Isolate area until gas has
recommended or statutory dispersed.
limits.
116
OCCUPATIONAL HEALTH AND SAFETY PROGRAM:
•Medical checkup of each employee and workers carry out six monthly basis.
•Total Nos. of employees & worker= 100 Nos.
•Periodic Medical Checkup of employees and workers = 100 Nos.
•There was not found any abnormality of any employees and workers. All employees and workers was found fit.
Tests carried out:
1) Physical test
2) General Examination like Temp., Pulse, Pressure, Pallor/Icterous/Cyanosis/Clubbing/Edema/others
3) Systemic Examination like CVS, R/S, A/S, CNS, ENT, Skin, Musculoskeletal, Genitourinary
4) Vision Testing
5) ECG
6) LFT
7) Audiometry
8) Haemogram Profile
9) Blood Group
10) ESR
11) Biochemistry
12) Urine Examination
13) Spirometry (FVC)
The client ensures that…
(1) Workers employed are medically examined by a qualified medical practitioner/ Factory Medical Officer, in the
following manner:
(2) (a) Once in a period of 1 year, to ascertain physical fitness of the person to do the particular job;
(3) (b) Once in a period of 1 year, to ascertain the health status of all the workers in respect of occupational health
hazards to which they are exposed and in cases where in the opinion of the Factory Medical Officer it is necessary to
do so at a shorter interval in respect of any workers; © In periodic and pre-medical examinations, various
parameters are checked. Viz., LIVER FUNCRION TESTS, Chest X-rays, Audiometry, Spirometry, Vision testing (Far &
Near vision, color vision and any other ocular defect) ECG and other parameters as will be found necessary as per
the opinion of Factory Medical officer.
117
(2) No person is employed for the first time without a certificate of granted by the Factory Medical Officer.
EMP For The Occupational Safety & Health Hazards So That Such Exposure Can Be Kept Within Permissible Exposure
Level (PEL) So As To Protect Health Of Workers
It is proposed to formulate and implement an EMP for Occupational Safety and Health with following aims…
To keep air-borne concentration of toxic and hazardous chemicals below PEL.
Protect general health of workers likely to be exposed to such chemicals
Providing training, guidelines, resources and facilities to concerned department for occupational health hazards.
Permanent changes to workplace procedures or work location to be done if it is found necessary on the basis of findings
from workplace Monitoring Plan.
It is proposed that this EMP be formulated on the guidelines issued by Bureau of Indian Standards on OH&S
Management Systems: IS 18001:2000 Occupational Health and Safety Management Systems Proposed EMP will be
incorporated in Standard Operating Procedure also.
The proposed EMP will also include measure to keep air-born concentration of toxic and hazardous chemicals below
its PEL, like…
Leak Surveys, Separate storage for toxic chemicals, Exhaust Ventilation, Proper illumination, Close processes to avoid
spills and exposures, Atomization of process operations to hazards of manual handling of chemicals
Supply of proper PPEs like Air mask, Berating canisters, SCBA sets, On-line breathing apparatus at the places where there
is possibility of presence of toxic chemicals, Decontamination procedure for empty drums and carboys. Regular
maintenance program for pumps, equipment, instruments handling toxic and corrosive chemicals,Display of warning
boards
Training to persons handling toxic and corrosive chemicals
Workplace Monitoring Plan
It is proposed that a Workplace Monitoring Plan to be prepared & implemented in consultation with FMO and industrial
hygienists.
Each workplace must be evaluated to identify potential hazards from toxic substances or harmful physical agents. Air-
borne concentration of toxic chemicals will be measured and record will be kept.
The current state-of-the-art exposure measurement model is as follows: For purposes of measuring worker exposure
across a single shift it is sufficient t o place a reasonably accurate exposure measuring device on the worker , within t he
worker ’s breathing zone, and have it operate for nearly the full shift. Client has been proposed to study the exposure
data when the plant is operative.
118
Health Evaluation of Workers
It is proposed that management will device a plan to check and evaluate the exposure specific health status evaluation of
workers
Workers will be checked for physical fitness with special reference to the possible health hazards likely to be present
where he/she is being expected to work before being employed for that purpose. Basic examinations.
like Liver Function tests, chest x ray, Audiometry, Spirometry Vision testing (Far & Near vision, color vision and any other
ocular defect) ECG, etc. will be carried out. However, the parameters and frequency of such examination will be decided in
consultation with Factory Medical Officer and Industrial Hygienists. While in work, all the workers will be periodically
examined for the health with specific reference to the hazards which they are likely to be exposed to during work. Health
evaluation will be carried out considering the bodily functions likely to be affected during work. The parameters and
frequency of such examination will be decided in consultation with Factory Medical Officer and Industrial Hygienists. Plan
of monthly and yearly report of the health status of workers with special reference to Occupational Health and Safety.
Medical Surveillance Program
Pre-employment Medical Check Up
•Chest X-ray
•Cardiogram
•Audiometry
•Hematological Examination:- CBC, SGOT, SGPT, Cholesterol, Blood Sugar etc.
•Urine Examination
•Vision test & Colour blindness test
•Lung function test- Spirometry
Periodical Medical Check up
•Lung Function test
•Cardiogram
•Audiometry
•Hematological Examination
•Urine examination
•Vision test
•Colour blindness test.
•Biomarker in Blood & Urine
119

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Presentation for Environmental Clearance before EAC (Industry-3), MoEFCC, New

Delhi on, 2022 and Agenda No.

Proposal No.: IA/GJ/IND3/241900/2021

 Name of EIA Co-ordinator: Mr. Jayesh S. Patel

 Total Plot Area: 40554.30 m2

 Process gas emission:

 Treatment facility with capacity and current operational capacity :

 Disposal of Hazardous Waste :

Equipment & Sch-I/ Collection, Storage, Transportation and

10 Spent Catalyst Process Sch-I/ 222 Collection, Storage, Transportation and

Process Sch-II- Collect, Storage & will reuse in

17 Ash from Boiler -- -- 365 Collect, Storage & Sell to Brick

DETAILS OF PUBLIC HEARING

1. Project site -- -- A1 N1 GW1 S1 Industrial

PROJECT SITE TO BE SHOWN ON GOOGLE EARTH

Sr. Sampling Sr. Sampling

1 Project-Site 6 Galenda (A6)

Sr. Operating Parameters 1: BOILER 2: BOILER 3: BOILER 4: HAG 4: TFH (3 5: Lakh

1. Stack Height Meter 30 30 20 20 20 20 12 12

5. Flue Gas Velocity M/S 5.5 4.5 4.5 7 4.5 4.5 7 7

Imported Imported Natural Natural Natural Natural

SOURCE OF PROCESS GAS EMISSION

SO2 mg/Nm3 40*

HCl mg/Nm3 20* 20*

 Isopleths of HBr  Isopleths of Cl2

MAXIMUM CONCENTRATION (g/m3)

HCl (g/m3) NH3 (g/m3) HBr (g/m3) Cl2 (g/m3)

BDL = Below Detectable Limit

GW= Ground water, SW= Surface water

1. GIDC Water Supply (GW1) <0.2 6.77 1.46 <1.0 <0.4

Table: Water Consumption & Wastewater Generation:

140.0 KLD Stream -2

HIGH COD STREAM

1. pH 4-6 4-6 7.0-7.5 6.5-7.5

Waste Handling Capacity : 180 m3 / day

31. **Grain Size Analysis

Minimum Detection Limit:

Sr. Criteria Pollutants Unit Maximum Minimum

2. Nitrogen (N) mg/kg 1680.9 934.2

3. Phosphorus (P) mg/kg 42.58 19.55

4. Potassium (K) mg/kg 264.2 30.9

5. Electric Conductivity mS/cm 0.396 0.093

 Conclusion: Results of all parameters are found within limit.

Possible Accident Scenarios

Scenario MCL Scenario Quantity in

 PREVENTIVE MEASURES TO AVOID SUCH EMERGENCY:

STORAGE AND HANDLING

Damage to process equipment. 100 % Fatal in

4 54.09 This level is sufficient to cause personnel if unable to reach cover

POOL FIRE SCENARIO:

50.79 8.66 100% Fatal

 Safety Precautions Of Various Chemicals:

Conservation Plan for Schedule – I species documented from project site

Total 2280 Total 2280

GREEN BELT DEVELOPMENT PROGRAMME

Year No. of Trees

BUDGET FOR DEVELOPMENT OF GREENBELT

Year Cost in Rupees Recurring Cost

Generation of process effluents, Washing Wastewater (Low COD stream of process