This document summarizes a study on nitrogen dioxide (NO2) concentrations in Germany, specifically in Baden-Württemberg. It finds that while nitrogen oxide (NOx) concentrations have decreased due to lower emissions, NO2 concentrations have not decreased and frequently exceed legal limits. This is largely due to increased NO2 emissions from diesel vehicles equipped with oxidation catalysts and traps. Despite tighter emissions standards, "real world" NOx and NO2 emissions from diesel cars have increased. Selected monitoring sites in Stuttgart, Freiburg, and Karlsruhe that exceeded limits in 2008 are highlighted. The analysis notes traffic volumes and mix of vehicle types must be considered when calculating emissions levels at different locations.
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Udo Lambrecht - (Anàlisi de la contaminació de l'aire per NO2)
1. EUROPEAN CONGRESS OF CITIES AND REGIONS
FOR THE IMPROVEMENT OF AIR QUALITY
BARCELONA, 17 AND 18 JUNE 2010
Analysis of NO2 exceedances
in Germany - Baden-Württemberg
Causes and future development
www.ifeu.de
Udo Lambrecht
Udo Lambrecht
ifeu – Institut für Energie- und Umweltforschung Heidelberg GmbH
-1-
6. Development of NO2 concentrations
Sites at busy streets in Germany (selection)
Development of the NO2 concentrations (annual average)
Sites at busy urban streets in Germany
90
Stuttgart-Mitte-Straße
80
München Stachus
70
Frankfurt Friedberger Landstraße
60
50
[µg/m3]
www.ifeu.de
40
Air quality limit 2010
(annual average concentration)
30
Udo Lambrecht
20
10
Source: UBA (Federal environment agency)
and data from federal states
0
95
96
97
98
99
00
01
02
03
04
05
06
07
08
-6-
19
19
19
19
19
20
20
20
20
20
20
20
20
20
7. Udo Lambrecht www.ifeu.de
-7-
3
NO2 (µg/m )
0
20
40
60
80
100
Stuttgart Am Neckartor 120
Stuttgart Hohenheimer Straße (S)
Reutlingen Lederstraße Ost (S)
München/Landshuter Allee
Tübingen Mühlstraße (S)
München/Prinzregentenstraße
Ludwigsburg Friedrichstraße (S)
Stuttgart-Mitte-Straße
München/Stachus
Düsseldorf Corneliusstr.
Hamburg Max-Brauer-Allee II (Straße)
Hagen Graf-v.Galen-Ring
Freiburg Schwarzwaldstraße (V)
Leonberg Grabenstraße (S)
Köln Clevischer Ring 3
Darmstadt-Hügelstraße
Hamburg Stresemannstraße
Pleidelsheim Beihinger Straße (S)
München/Luise-Kiesselbach-Platz
Herrenberg Hindenburger Straße (S)
Hamburg Habichtstraße
Münster Weseler Straße
Frankfurt-Friedb.Ldstr.
B Hardenbergplatz
Wuppertal Gathe
Dortmund Brackeler Str.
Kiel-Bahnhofstr. Verk.
Hannover Verkehr
B Neukölln-Karl-Marx-Str. 76
Itzehoe Lindenstr.
Hamburg Kieler Straße
Cherbourger Straße
Nürnberg/Von-der-Tann-Straße
Osnabrück-Verkehr
Aachen Wilhelmstr.
Halle (Westfalen) Lange Str.
Wiesbaden-Ringkirche
Braunschweig-Verkehr
Heidenheim Wilhelmstraße (S)
Kassel-Fünffenster-Str.
Rostock Am Strande
Augsburg/Karlstraße
Mainz-Parcusstraße
Hürth Luxemburger Straße
Dresden-Bergstr.
Burgdorf-Verkehr
Karlsruhe-Straße
Mannheim-Straße
Chemnitz-Leipziger Str.
Marburg-Univers.Straße
Köln Turiner Straße
B Neukölln-Silbersteinstr.
Ludwigshafen-Heinigstraße
B Steglitz-Schildhornstr.
Essen Gladbecker Str.
Fulda-Petersberger Str.
Recklinghausen Bochumer Str.
Dortmund Steinstr.
Oberaudorf/Inntal-Autobahn
Barbis-Verkehr
Gießen-Westanlage
Potsdam, Großbeerenstr.
Markgröningen Grabenstraße (S)
Essen-Ost Steeler Str.
2008: 89 sites > 40 µg/m3
Leipzig-Mitte
Koblenz-Hohenfelder Straße
Frankfurt-Höchst
Bremen Verkehr 1
Freiburg Zähringer Straße (S)
Augsburg/Königsplatz
Leipzig Lützner Str.
Duisburg Kardinal-Galen-Str.
B Friedrichshain-Frankfurter Allee
Würzburg/Stadtring Süd
Potsdam Zeppelinstr.
Regensburg/Rathaus
at many roadside measuring stations in Germany
Magdeburg/Damaschkeplatz
3
Magdeburg/Reuterallee
Saarbrücken-Verkehr
Heppenheim-Lehrstraße
Stuttgart-Zuffenhausen
Grenzwert 2010:
Bielefeld Stapenhorststr.59
Pinneberg Damm
Gevelsberg Hagener Str.
The NO2 limits, which came into effect in 2010, are exceeded
Quelle: UBA 2009
Mainz-Rheinallee
Reinheim
Göttingen-Verkehr
40 µg/m im Jahresmittel
Lübeck Gr. Burgstr.
Mainz-Große Langgasse
8. Causes for high NO2 Concentrations
Explications for NO2 concentrations in busy streets:
1. Increased primary NO2 emissions due to increased
NO2 /NOx ratio in the exhaust of Diesel cars equipped with
oxidation catalysts and urban buses equipped with
continuous regenerating traps
2. NO2 formed as a result of atmospheric chemical
www.ifeu.de
reactions. Nitric oxide from motor vehicle exhaust gas
reacts with ozone to form NO2.
Udo Lambrecht
NO + O3 NO2 + O2
NO2 concentration depends also on NO
- E
missions and the
availability of Ozone
-8-
9. The high NO2 concentrations are due to road traffic
in particular diesel vehicles
Contribution to NO2 concentrations:
Ozon
Primary NO2 emissions
NO2 Increasing NO2/NOx share
NO emission
from atmos- in Diesel exhaust (DOC)
(local traffic)
pheric chemical Contribution Increasing share of Diesel vehicles
reactions of Local
in Passenger Car fleet
traffic
NO2 emission NO2 (=> lower fuel consumption – CO2)
(local traffic) from primary
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emissions NO-Emissionen
NO2 Chemical Reaction with Ozone
Urban NO + O3 NO2 + O2
Udo Lambrecht
other
background
sources
(“photochemical equilibrium”)
Urban Background
(Emission other sources);
-9-
10. Despite stronger emission limits for vehicles,
„real world“ emissions of NOx and NO2 from diesel cars have increased
1,0
0,9 Emission factors for passenger cars (petrol & diesel)
Emissionsfaktoren Otto- und Diesel-Pkw
Beispielsituation
exemplary traffic situation
0,8
(Handbook Emissionfactors 3.1)
0,7
0,6 NOx
NOx (g/km)
0,5
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0,4
0,3
0,2
Udo Lambrecht
0,1 NO2
0,0
Euro-0 Euro-1 Euro-2 Euro-3 Euro-4 Euro-5 Euro-6 Euro-0 Euro-1 Euro-2 Euro-3 Euro-4 Euro-5 Euro-6
- 10 - Otto-Pkw Diesel-Pkw
PC Petrol PC Diesel
11. Despite stronger emission limits for vehicles,
„real world“ emissions of NOx and NO2 from diesel cars have increased
1,0
0,9 Emission factors for passenger cars (petrol & diesel)
Emissionsfaktoren Otto- und Diesel-Pkw
Beispielsituation
exemplary traffic situation
0,8
(Handbook Emissionfactors 3.1)
0,7
0,6 NOx
NOx (g/km)
0,5 High level – diesel cars
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0,4
0,3
0,2
Low level – petrol cars
Udo Lambrecht
0,1 NO2
0,0
Euro-0 Euro-1 Euro-2 Euro-3 Euro-4 Euro-5 Euro-6 Euro-0 Euro-1 Euro-2 Euro-3 Euro-4 Euro-5 Euro-6
- 11 - Otto-Pkw Diesel-Pkw
PC Petrol PC Diesel
12. Udo Lambrecht www.ifeu.de
- 12 -
3
NO2 (µg/m )
0
20
40
60
80
100
Stuttgart Am Neckartor 120
Stuttgart Hohenheimer Straße (S)
Reutlingen Lederstraße Ost (S)
München/Landshuter Allee
Tübingen Mühlstraße (S)
München/Prinzregentenstraße
Ludwigsburg Friedrichstraße (S)
Stuttgart-Mitte-Straße
München/Stachus
Düsseldorf Corneliusstr.
Hamburg Max-Brauer-Allee II (Straße)
Hagen Graf-v.Galen-Ring
Freiburg Schwarzwaldstraße (V)
Leonberg Grabenstraße (S)
Köln Clevischer Ring 3
Darmstadt-Hügelstraße
Hamburg Stresemannstraße
Pleidelsheim Beihinger Straße (S)
München/Luise-Kiesselbach-Platz
Herrenberg Hindenburger Straße (S)
Hamburg Habichtstraße
Münster Weseler Straße
Frankfurt-Friedb.Ldstr.
Stuttgart - Neckartor
B Hardenbergplatz
Wuppertal Gathe
Dortmund Brackeler Str.
Kiel-Bahnhofstr. Verk.
Hannover Verkehr
B Neukölln-Karl-Marx-Str. 76
Stuttgart –Klett Platz
Itzehoe Lindenstr.
Hamburg Kieler Straße
Cherbourger Straße
Nürnberg/Von-der-Tann-Straße
Osnabrück-Verkehr
Aachen Wilhelmstr.
Halle (Westfalen) Lange Str.
Wiesbaden-Ringkirche
Braunschweig-Verkehr
Heidenheim Wilhelmstraße (S)
Kassel-Fünffenster-Str.
Rostock Am Strande
Freiburg – Schwarzwaldstr..
Augsburg/Karlstraße
Mainz-Parcusstraße
Hürth Luxemburger Straße
Dresden-Bergstr.
Burgdorf-Verkehr
Karlsruhe-Straße
Mannheim-Straße
Chemnitz-Leipziger Str.
Marburg-Univers.Straße
Köln Turiner Straße
B Neukölln-Silbersteinstr.
Ludwigshafen-Heinigstraße
B Steglitz-Schildhornstr.
Essen Gladbecker Str.
Fulda-Petersberger Str.
Recklinghausen Bochumer Str.
Dortmund Steinstr.
Oberaudorf/Inntal-Autobahn
Barbis-Verkehr
Karlsruhe
Gießen-Westanlage
Potsdam, Großbeerenstr.
Markgröningen Grabenstraße (S)
Essen-Ost Steeler Str.
2008: 89 sites > 40 µg/m3
Leipzig-Mitte
Koblenz-Hohenfelder Straße
Frankfurt-Höchst
Bremen Verkehr 1
Freiburg Zähringer Straße (S)
Augsburg/Königsplatz
Leipzig Lützner Str.
Duisburg Kardinal-Galen-Str.
B Friedrichshain-Frankfurter Allee
Würzburg/Stadtring Süd
Potsdam Zeppelinstr.
Regensburg/Rathaus
Magdeburg/Damaschkeplatz
3
Magdeburg/Reuterallee
Saarbrücken-Verkehr
Heppenheim-Lehrstraße
Stuttgart-Zuffenhausen
Bielefeld Stapenhorststr.59
Grenzwert 2010:
Pinneberg Damm
Gevelsberg Hagener Str.
Quelle: UBA 2009
Mainz-Rheinallee
Reinheim
Göttingen-Verkehr
Lübeck Gr. Burgstr.
40 µg/m im Jahresmittel
Selected Sites – Study for Ministry of Environment Baden-Württemberg
Mainz-Große Langgasse
14. Traffic volumes and share of bus and HDV varies depending on locations
Calculation of emissions
has to consider fleet composition
Traffic volumes for each location and considered year:
80.000
72.000 Bus
HGV
70.000 LCV
PC Diesel
Calculation done
60.000
54.400
PC Petrol
with TREMOD
48.400
50.000
veh./d
40.000
30.000
24.900
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20.000
10.000
0
Stuttgart- Freiburg- Karlsruhe- Stuttgart-
Udo Lambrecht
Neckar- Schwarz- R.Frank- Mitte
tor waldstr. Straße
Data for 2008, Source IFEU
- 14 -
Example: fleet compostition – Light Duty vehicles
15. The contribution of single vehicle categories to NOx and NO2 emissions
varies strongly depending on location. In general Diesel Cars dominate
Traffic volumes NOx emissions NO2 emissions
8
80.000 40 Bus
72.000 Bus Bus 7,1
HGV
HGV 34 35 HGV 7
LCV 6,5 LCV
70.000 LCV 35
PC Diesel 32 PC Diesel
PC Diesel PC Petrol PC Petrol
6 5,6
60.000 PC Petrol 30
54.400
kg/km/d
48.400 5
kg/km/d
50.000 25
veh./d
4
40.000 20
3 2,5
30.000 15
24.900 12
www.ifeu.de
2
20.000 10
1
10.000 5
0
0 0 Stuttgart- Freiburg- Karlsruhe- Stuttgart-
Stuttgart- Freiburg- Karlsruhe- Stuttgart- Stuttgart- Freiburg- Karlsruhe- Stuttgart-
Udo Lambrecht
Neckar- Schwarz- R.Frank- Mitte
Neckar- Schwarz- R.Frank- Mitte Neckar- Schwarz- R.Frank- Mitte tor waldstr. Straße
tor waldstr. Straße tor waldstr. Straße
Data for 2008, Source IFEU
Diesel – Passenger Cars
- 15 -
16. At most of the measuring sites, PCs are main causes of the pollution
Contribution Contribution
Contributions to NO2 concentrations
Primary NO2 – Local atmospheric Chemistry Contributions to NO2 concentrations
Vehicle categories
120 120
local primary NO2 Bus local
110 110 HGV local
local atmospheric chemistry LCV local
100 100 13,4
urban background PC Diesel local
NO2 annual mean [µg/m³]
90 4,7 PC Petrol local
NO2 annual mean [µg/m³]
90
urban background
80 50,3 local traffic 80
1,7
70 70 11,9
46,0
25,4 16,7 4,2
60 25,8 60
1,9
50 50 3,8 1,9
18,7
23,8 16,6
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40 17,4 40 20,3
10,0 22,1 5,9
25,7 30
30 14,2
7,1 7,6
20 20
33,1 33,1 33,1 33,1
10 20,2 22,5 10 20,2 22,5
Udo Lambrecht
0 0
Stuttgart- Freiburg- Karlsruhe- Stuttgart- Stuttgart- Freiburg- Karlsruhe- Stuttgart-
Neckar- Schwar- Reinhold- Mitte Neckar- Schwar- Reinhold- Mitte
tor zwaldstr. Frank-Str. tor zwaldstr. Frank-Str.
- 16 -
17. Future developments
of vehicle emissions
and NO2 air quality
www.ifeu.de
Udo Lambrecht
- 17 -
18. Techniques to decrease the NOx emissions are available.
Large reductions for Diesel Passenger Cars will first appear with Euro 6
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Udo Lambrecht
- 18 -
Source: Volkswagen
19. Techniques to decrease the NOx emissions are available.
Large reductions for Diesel Passenger Cars will first appear with Euro 6
1,0
0,9 Emission factors for passenger cars (petrol & diesel)
Emissionsfaktoren Otto- und Diesel-Pkw
Beispielsituation
exemplary traffic situation
0,8
(Handbook Emissionfactors 3.1)
0,7
0,6
NOx (g/km)
0,5
0,4
www.ifeu.de
0,3
0,2
0,1
Udo Lambrecht
0,0
Euro-0 Euro-1 Euro-2 Euro-3 Euro-4 Euro-5 Euro-6 Euro-0 Euro-1 Euro-2 Euro-3 Euro-4 Euro-5 Euro-6
Otto-Pkw Diesel-Pkw
- 19 -
Source: Schindler 2010
20. Model projections show, that with an introduction of Euro 5- and Euro 6-
vehicles NOx- and NO2-emission levels will further strongly decrease
NOx emissions of local traffic
40
-55% -62% -49% -54%
35
kg/km/d
30 Bus
HGV
25 LCV
20 PC Diesel
PC Petrol
15
10
5
0
2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020
Stuttgart- Freiburg- Karlsruhe- Stuttgart-
Neckartor Schwarzwaldstraße Reinhold-Frank-Straße Mitte
NO2 emissions of local traffic
www.ifeu.de
9
8 -36% -37% -31% -47%
7 Bus
kg/km/d
HGV
6 LCV
5 PC Diesel
4 PC Petrol
Udo Lambrecht
3
2
1
0
2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020
Stuttgart- Freiburg- Karlsruhe- Stuttgart-
Neckartor Schwarzwaldstraße Reinhold-Frank-Straße Mitte
- 20 -
21. Using a Chemical Box Model to calculate future NO2 concentrations
Ozon
NO emission NO2
(local traffic) from atmospheric
chemical reactions Contribution
of Local
NO2 emission NO2 traffic
(local traffic) from primary
emissions
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NO2 Chemical box model
- windspeed and temperature
Urban
other - Emission of NO, NO2,
background
sources - RADM2: 59 substances, 161 reactions
Udo Lambrecht
(21 photolytic, 140 therm.)
- 21 -
22. Appr. half of the stations which today are > 40 µg/m3
can meet the NO2 air quality limit in the year 2015 in the trend scenario
NO2 concentrations 2008-2020
160
-37% -45% -37% -42%
140
NO2 annual mean [µg/m³]
local street increment
120 urban background
109 109
100 93 NO2 limit value 2010
77 74
80 73
69 69
www.ifeu.de
59
60 55
52 50
42 45
40
33
40
Udo Lambrecht
20
0
2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020
- 22 - Stuttgart- Freiburg- Karlsruhe Stuttgart-
Neckartor Schwarzwaldstraße Reinhold-Frank-Straße Mitte
23. Appr. half of the German stations which today are > 40 µg/m3
can meet the NO2 air quality limit in the year 2015 in the trend scenario
NO2 concentrations 2008-2020
160
-37% -45% -37% -42%
140
NO2 annual mean [µg/m³]
local street increment
120 urban background
109 109
100 93 NO2 limit value 2010
? 77 74
80 73
69 69
www.ifeu.de
59
60 55
52 50
42 45
40
33
40
Udo Lambrecht
20
0
2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020
Stuttgart- Freiburg- Karlsruhe Stuttgart-
- 23 - Neckartor Schwarzwaldstraße Reinhold-Frank-Straße Mitte
24. Also with the legal introduction of Euro 5/6 vehicles,
at very high polluted sites the air quality limit will not be met in 2020
NO2 concentrations 2008-2020
160
-37% -45% -37% -42%
140
NO2 annual mean [µg/m³]
local street increment
120 urban background
109 109
100 93 NO2 limit value 2010
77 74
80 73
69 69
www.ifeu.de
59
60 55
52 50
42 45
40
33
40
Udo Lambrecht
20
0
2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020
- 24 - Stuttgart- Freiburg- Karlsruhe Stuttgart-
Neckartor Schwarzwaldstraße Reinhold-Frank-Straße Mitte
25. In the future passenger cars will still be
the highest contributor for NO2 pollution
120
Bus local
HGV local
13 12 LCV local
100 PC Diesel local
NO2 annual mean [µg/m³]
5 5 PC Petrol local
8 urban background
5
NO2 limit value 2010
80
Achtung: Nächste Folie noch einmal,
2
47 53 4 mit Otto D - Aufteilung. Nicht benötigte 13
2 - iesel 12
3 16 Folie wieder rauslöschen. 4
60 14 2 4
2 8
51 4 1
4 8 2
1 3
2
1 19 2
4 20
37 4
www.ifeu.de
40 23 1 19 1
1 2
10 25 5 21 20 1
8 6
3 1 5
26 21 15
5 7 3
4 7 19 5 15
20 6 2
33 3 33
31 4 2 31
24 3 24
Udo Lambrecht
21 20 19 23 21 21
13 16 14
10
0
2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020 2008 2010 2015 2020
Stuttgart- Freiburg- Karlsruhe Stuttgart-
Neckartor Schwarzwaldstraße Reinhold-Frank-Straße Mitte
- 25 -
27. Approaches to reduce NOx + NO2 emissions from road transport
Introduction of vehicles with lower NOx & NO2 emissions (Euro 5/6/VI)
Introduction of vehicles that meet Euro 6/VI on the market before the
mandatory deadline (early introduction)
Limiting/Reducing direct NO2 emissions (Pt/Pd)
Ensure that NOx and NO2 emissions from Euro 5/6 cars
are reduced in real urban driving situations
Petrol cars still have lower NO2- + NOx Emissions
compared to Diesel cars
Retrofit buses with NOx reduction technology
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Measures to optimise traffic flow in towns and cities (traffic management)
Udo Lambrecht
Better Public Transport – Non motorized traffic
- 27 -
28. Even with a „Euro 6/VI fleet“, concentrations at „Stuttgart Neckartor“
would still exceed the NO2 limit (40 µg/m3)
NOx emissions Stuttgart Neckartor NO2-Konzentrationen Stuttgart-Neckartor
40
35 -55% -41%
120
kg/km/d
30 µg/m³ NO2 HGV local
25 LCV local
20 PC local
13 12
15 100 urban background
5 5
10
8
5
5
0 80
2008 2010 2015 2020 Euro
6/VI NO2 limit value
PC LCV HGV Bus 58 4
61 3
www.ifeu.de
60
NO2 emissions Stuttgart Neckartor 56
9 2
2
-45% 41
8 -36
40
7
kg/km/d
6 25
Udo Lambrecht
5
4 20
3 33 31
2 24 21 21
1
0 0
2008 2010 2015 2020 Euro 2008 2010 2015 2020 Euro 6/VI
- 28 -
6/VI
PC LCV HGV Bus
29. Early introduction of Euro 6 vehicles
First Euro 6 cars are on the market
With introduction of Euro 6 vehicles a reduction of NOx and NO2 emissions
from automobiles is expected.
⇒ Higher costs (1000 € (?) – need of benefits, tax reduction, subsidies..)
Remark
Reduction of emissions should not be only met in the homologation cycle
but also in reality. This is essential to achieve the air quality limits.
www.ifeu.de
Udo Lambrecht
- 29 -
30. Retrofitting of buses and LCV could help to reduce air pollution (NO2)
Technology is in principle available
- Costs
- Reduction efficiency at low temperature
- Considering local conditions
- Packaging
- Homologation procedure – EU..
www.ifeu.de
Udo Lambrecht
- 30 -
Source: Kleinebrahm 2010
31. What can be done on the part of communities and regions?
Measures introduced:
- HDV ban
- Retrofitting of buses (SCR systems)
- Environmental Zones
- Improving public transport, non motorized traffic..
- Parking fees...
But: Communities with high NO2 concentrations are feeling to be left
alone, because they are not able to introduce strong emission limits
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before legally binding.
NO2 problems will not be solved with current environmental zone
arrangements. The zones schemes focus too closely on PM
Udo Lambrecht
(not on NO2)
PM – NO2 conflict: Retrofitting with Particle traps eventually will
increase NO2 emissions
- 31 -
32. Summary
Exceedances of NO2 limits at many sites in Germany
Traffic – esp. Diesel cars – are the main cause of NO2 pollution
Share of different vehicle categories on pollution varies
(to consider - measures)
Possibility of a postponement of the attainment date is essential
The legally binding introduction of Euro 6 passenger cars
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comes too late. Early introduction of Euro 6 could help
National, regional and local measures are necessary!
Udo Lambrecht
=> Realistic and affordable measures to reduce NO2 concentrations?
- 32 -
33. Thank you for your attention!
And thanks to
Udo Lambrecht udo.lambrecht@ifeu.de
www.ifeu.de
Frank Dünnebeil frank.duennebeil@ifeu.de
Alexander Schacht alexander.schacht@ifeu.de
Christoph Kessler christoph.kessler@avisogmbh.de
Udo Lambrecht
Further information:
www.no2-tagung2010.de
www.no2-
- 33 - www.ifeu.de/no2