Bio MASS 1.docx

TAKEAWAY FROMBIOMASS CO-FIRING IN THERMAL POWER PLANTS CONFERENCE
Ministry of Power on 17.11.2017 had issueda policy regarding Biomass utilizationfor power generation through co-firing in
coal-based power plants.
This was followedby an advisory dated 24.11.2017 from CEA to all the TPPs to utilize Biomass pelletsin coal -based TPPs to
the extent of 5-10%. Keepingthe above in mind, the National Mission on use of Biomass in TPPs has been constituted by
the Ministry of Power in July 2021.
What is co-firing?
Co-firing usually refers to burning several fuels together to generate heat in power plant.
Mostly the co-firing is of the biomass and fossil fuels.
Why Boimass co-firing?
Biomass is an important energy source. Biomass is any organic matter—wood, crops, seaweed, stubble, animal wastes—
that can be used as an energy source. Biomass is probably our oldest source of energy after the sun.
But this stubble is a good biomass resource that has the potential to create efficientbiomass-to-energy chains.
Torrefaction of biomass stubble,combined with densification (Pelletisationor briquetting), is a promising step towards
overcoming the logistical challenges in developinglarge-scale sustainable energy solutions, by making it easier to transport
and store. Pelletsor briquettes have higher density, contain lessmoisture, and are more stable in storage than the biomass
they are derived from.
When agro residue-based fuel,in the form of pellets,is utilizedin coal-fired power plants, it burns completely in the power
plant, and ash emitted from its combustion gets absorbed in Electro Static Precipitator (ESP) which prevents air pollution
while generating power from it.
The majority of power plants are running on coal. To reduce greenhouse gas emissionsfrom its coal-based power plants,
the Power plant intends to utilize agro residue-based pellets/torrefiedpelletsalong with coal for power generation
through biomass co-firing which is a technology recognized by UNFCCC to mitigate carbon emission.It is worth mentioning
that the equivalent amount of CO2 (carbon-di-oxide) emitted from the combustion of agro residue-based pellets/torrefied
pelletsin a power plant gets absorbed in the next crop cycle by photosynthesis. CO2 emission from agro residue-based
pelletscombustion does not increase CO2 concentration in the atmosphere and thus it is also termed as carbon neutral
fuel which is a renewable source of energy. Further, CO2 emission from diesel and electricityconsumption for agro residue
collection, processing and transportation is quite negligible as compared to saving in CO2 emissionsfrom its utilizationin
large coal-firedpower plants having higher efficiency which makes biomass co-firing a greener alternative.
In addition to reducing carbon emission from the coal-based power plant, the utilizationof agro residue-basedpellets/
torrefied pelletsin the power plant will also reduce air pollution due to the burning of stubble (i.e.paddy straw and other
agro residues) in the fieldsby farmers. Emissions of sulfur and mercury are reduced by the co-firing percentage.
The typical properties of non-torrefiedpelletsare as follows:
1. Carbon Content: 10-20 %
2. Volatile Matter: 60-66%
3. Moisture: 9-14%
4. Density: 700 kg/m3
5. Ash content: approx. 20%
6. GCV: 3400-4000 Kcal/kg

The main constraints with these pelletsare
1. Ignition temperature: 240 O Celsius
2. Moisture affinity: Very high
Operational requirement during Bio-pellets firing:
1-The mill inerting system is charged up to the mill inlet.The valve provided at mill inlet should be operable from UCR
(eithermotorized or pneumatic) along with the local pressure gauge after the valve.
2- An orifice is provided in the common header to maintain mill inerting steam pressure 02-04 ksc.
3- All individual mill outlet pipesare to be provided with RTDs and the temperature of coal pipesto be hooked up to DCS .
Logic Modification(C&I ):
For the operator’s ease, Biomass ON/OFF buttons must be provided on individual Mill screen. This button shall be used for
change over to Biomass mode and vice-versa.
a. Whenever Biomass firing is ON, the followingchanges should happen in the Mill logics: Mill temperature control by CAD
(cold air damper) of the mill to be shifted to Mill inlettemperature control as per the Inlet temperature set point. Mill inlet
temperature set point increase/ decrease button may be provided in the control interface
b. Mill inlettemperature set point should be controlled in such a way that operator cannot give more than 180 OC set
point.
c. Mill HAG (hot air Gate) shall close on protection if Mill inlettemperature reaches 195 O C. Alarm for Mill inlet
temperature to be provided at 185 O C.
d. Mill protection at mill outlet temperature 95O C & 110O C will also remain in service irrespective of Biomass ON/OFF
mode.
e. Alarm for mill outlet temperature >70 O C to be provided
CHP Area activity:
Storage:
1- Biomass pelletsarea for storage needs to be identifiedbythe site.This area should have firefightingfacilities.
2- The volatile matter in biomass pelletsis very high and can easilycatch fire. Hence continuous monitoring of the area
needs to be done.
3- The pelletstorage area should be different from the coal stockyard.
4- Facilitiesshould be developedto transport the biomass pelletsfrom the storage area to the blendingarea.
5-The maximum percentage of blending allowedis only 5% to 10% (blending by heat value) depending on plant operating
conditions and combustion issues.
6- The bunkers in which blendedcoal with biomass pelletsneed to be identifiedalong with the operation group and all
necessary interlocks to be ensured before dumping coal in bunkers.
7- Avoid giving Hot work permits on/near pelletsfeeding path
8- Don’t spray water / dry Fog / plain water fogging system on the pelletsand its bunker feedingpath. The biomass pellets
are hygroscopic in nature. After absorbing water or moisture, the pelletslose thier shape and converts to powdery form, so
water cannot be used. However, the system for dust suppression like dry fog/plainwater and spray water should be
available and for use in case of emergency.

9- Don’t compact the pellets.
Bunkering and Blending:
The bending ratio needsto be maintained at 5 to 10 % only (Blending by heat value).
Site-specificBunkering methodology is to be formulated by considering the followingpoints
1. Point of blending
2. Methodology of feedingpellets
3. TP or chute where blendingshall be done.
4. Control methodology for blending like using belt weigh scales etc.,
5. No of bunkers to be used for pelletsblending
Level to be maintained in bunkers in which pellets are bunkered
1- The pelletsdo not require crushing; hence blendingis to be done after crusher output.
2- Feeding to be done only along with the coal, as the biomass pelletsare highly inflammable as it has very low ignition
point and high VM content. Hence conveyor interlock is to be modifiedso that pelletsgo only when coal is in the conveyor,
and not otherwise.
3- Conveyor streams and chutes used for pelletfiring must be thoroughly emptied after feedoperations. Left-over pellet
blends in conveyors and chutes must be emptied to minimize fire hazards.
Impact of co-firing on combustion-
1.The process of biomass combustion may be associated with certain risks that do not occur during the combustion of coal.
These include fuel pre-processing (fire-explosionrisk),combustion e.g. including excessive slagging and ashing, and
chlorine corrosion. Therefore, knowledge of the physicochemical properties of plant biomass helpsto determine its
potential application in heat or electricity production. The knowledge of these parameters allows proper selectionof the
amount of combusted biomass to ensure its minimal impact on the boilersystem or the use of preventive measures
minimizingthe negative impact of biomass combustion.
2. The content of Oxygen in biomass is very high compared to coal.
3. The substantial proportion of volatile matter in the biomass fuel can be a positive factor in the improvement of ignition
and flame stability.However, volatile matter enhances the fire explosionrisk in the pre-processing system.
4. Biomass pelletsmay have a very low content of Sulphur and nitrogen compared to coal which makes them
environmentally friendlyby reduced SOX levels.
5. Burning biomass fuelsor biomass-coal mixtures containing low Sulphur content is valuable for major reduction of
SOx/SO2 emissions but might negatively influence the ash deposition behavior, in particular Chloride’s deposition.It has
been generally accepted that the occurrence of Sulphur can alleviate corrosion problems associated with chloride deposits
via the followingsulphation mechanism
6. In biomass, elementssuch as chlorine and potassium are mostly present as water-soluble inorganic salts, and primarily
as chloride, nitrates, and oxides,etc. which can be easily volatilizedduring the combustion, resultingin high mobilityfor
alkali materials and, consequently, high pollution tendency.
7. An important elementin the use of biofuelsin the power industry, in particular in the combustion process, istheir
adverse effect on the slagging and foulingprocesses. The chemical composition of biomass ash is significantlydifferent
from that of coal. The mineral material from biomass does not contain aluminosilicates but does contain quartz and simple
inorganic salts of potassium, calcium, magnesium, and sodium in the form of phosphates, sulphates, and chlorides.

8. One area of particular concern is the ash composition of biomass fuels.Most of these ashes are high in alkali and alkaline
earth elementswhich are known to promote deposition in the boiler. Even though the ash quantity in the biomass is small,
high alkali and alkaline earth materials tend to act as fluxingagents and reduce the melting temperature of the coal ash.
This should be evaluated. One characteristic feature of the ashes yieldedby biomass combustion is the considerable
content of phosphorus, potassium and their compounds, calcium, magnesium,etc. Biomass ash is thus characterized by a
low melting temperature and a high tendency to slagging and fouling.Ca and Mg compounds usuallyincrease the ash
melting temperature, while K and Na reduce it. In combination with potassium, silicon can induce the formation of low-
melting silicatesin volatile ash particles. These processes are highly important, given the risk of fouling and ash slagging on
the walls of furnaces or heated surfaces.
9. The main effect of biomass co-firing with coal is the emissionof vapours of potassium compounds and subsequent
condensation on the surface of ash particles and boilerpipes.
10. The two most abundant alkali metals contained in the fuel are usually potassium and sodium. They existin the original
fuel in different forms. These alkali species are mostly volatilizedwith organic species or maybe released as metallic
elements,although they then rapidly react. If fuel contains chlorine, alkalis probably appear as the salts KCl or NaCl. Some
of the sodium and potassium are readily volatile evenat relativelylow temperatures. However, on the particle surface,
where combustion takes place, temperatures may be considerably higher than the overall bulk gas temperature; this
would suggest that most alkalis are vaporized during combustion and are available for reaction with other compounds. For
example,sodium and potassium may react with SO2 or SO3 in the gas to form the alkali sulphates, K2SO4 and Na2SO4,which
can condense and deposit. In this manner, the surface initiallyacquires a characteristic thin, dense, and reflective deposit
layer observed in nearly all cases. The vaporization and subsequent chemical reactions are responsible for much of the
fouling,corrosion, and silicate formation found in boilers.The addition of these alkalis tends to lower the fusion
temperatures of the solids,making them more liquidsand able to stick to water wall surfaces.
11. One method of estimating the amount of alkalis readily volatilizedis to determine the “water-soluble alkalis.” This test
is intended to measure the quantity of alkali present in the form of compounds that may be readily volatilizedduring
combustion. Most sodium and potassium compounds are water-soluble;the assumption is that those that are not water-
soluble are present in the form of large complex moleculessuch as clays and would not readily decompose on heating. The
greater the fraction of water-soluble alkalis, the greater will be the potential for deposition.
12. Role of Calcium: Calcium and other alkaline earth materials are found in coal. Calcium in fuel is more refractory and less
readily volatilized,although some may be released by similar mechanisms and in similar forms as the alkalis. In general,
alkaline earth species form more stable compounds that are lessvolatile than materials formed from alkali materials. In
addition, calcium may react with gaseous sulphur species and remove them from contributing to the formation of low -
melting compounds.
Increased levelsof potassium compounds in biomass are a highly unfavorable phenomenon due to the process of slagging
and ashing. These components are characterized by the formation of low-meltingeutectics, which contribute to a faster
rate of ash melting and depositionon superheater tubes and heating surfaces.
13. Chlorine is an undesirable element in the process of fuel combustion due to the increased risk of high-temperature
chlorine corrosion. The enhanced risk of corrosion is associated with the chemistry of ash deposits accumulated on boiler
surfaces. The surfaces of superheaters are mostly at risk due to the high temperature of the operating factor, which results
in an increased tendency of surface deposits to melt and react with the surface of superheated tubes. Changes in the ash
composition and quality occurring during the co-firing process may also influence the use and storability of ashes. The
methods appliedin the energy industry for purifying solid-derivedexhausts in electrostatic precipitators or wet
desulphurization lead to the formation of by-products, which are used in other sectors, i.e.construction and cement
industries. An increase in the amounts of undesirable substances may result in difficultiesinmanagement thereof and a
necessity to store them, which significantly reduces the efficiencyof power plants.
14. If fly ash and bottom ash are currently sold in the concrete market, an evaluation must be made since current
standards are for coal ash only.
All the stations should get the biomass pelletsultimate analysis done before the start of the biomass pelletsco-firingand
understand the impact on the combustion based on the ultimate analysis. Ash elemental analysis is also to be done during

the initial days of firing in the boilerand furnace temperature measurement is to be done frequently during the initial days
of biomass co-firing. The Boiler isto be monitored for the ash build-upand slagging during the biomass co-firing.
Combustion has to be monitored closely while biomass co-firing takes place.
My understanding and Questions-
1-Co-firing can be done but our PA-inletdesign temperature is 270 degc.Now whether I mix bio-pelletsor other additives
inlettemperature with existingsystem can not be maintained 180 degc as mentioned .It needssome modification of the
system at APH itself.Sohow Power ministry going to address this in various power plants?
2-What is the impact of this co-firing on Fly ash quality?Does it change Blaine number that is used for Cement industry?
3-Clinkering and slagging tendency will increase or decrease no straight forward discussion was there.So how can we be
sure of this for our Boiler life?
4-Co-firing case ash resistivityincrease and it may affect ESP performance.How to address this?
5-It does not change merit order despatch in that prespective it is ok.
6-Just like FGD project Power ministry should give time line for this as large power plants require some system
modification.
7-Once becomes commercial pelletsQC to be very strict or else inferiorquality may hamper boilerlife.
8-I understand Boiler efficiencywill reduce as DFG will increase.It will affect Unit Heat rate.
9-In technical minimum load condition it may affect Boilerflame stability.
10-Any issue with Mill reject handling or not needs clarification .
11-Bottom ash removal any issue or not needs clarification.Ash meltingpoint if changes issue may arise.
12-Feeder view glass one extra purge line is required.It can be done.
NOTE-My questions are already mailed to the concerned person.
.
. ABSTRACT
Seven out of 12 pieces of hangers for superheater pipe were failed after one year in service.
Failure analysis has been conducted to find out the root cause of failure. Hanger material is
ASTM A182 Grade F22 Class 1. Fractography examinations revealed that the fracture mode is
due to mechanical fatigue. Tensile test results show a tensile strength of 1015 MPa which is far
beyond the minimum standard requirement of 415 MPa. The hardness of the failed hanger is
between 270 to 325 HB, and un-failed hanger is around 245 HB, which are higher than the
maximum standard requirement of 170 HB. The Charpy impact energy is 3 J, far below the
standard requirement of 54 J. The microstructure in the bend area and the straight section
contained tempered martensite and ferrite. Further examinations were conducted by heat
treatment simulations to explore properties after heat treatment. Materials are subjected to full
annealing treatment at 900°C, and normalizing at 955°C followed by tempering at 675°C. The
average hardness is 154 HB after annealing, and 235 HB after normalizing and tempering.
According to heat treatment simulation results, hanger material was supposed to be supplied
under annealing condition where the hardness fulfils the standard requirement. Failure of
superheater pipe hanger is due to improper heat treatment which promote brittleness and initiate

premature crack during start-up. Crack initiation might also occur during post forging
quenching. Fatigue crack propagation occur during service by small amplitude vibration.
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