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Shielding or Screening
Dr. Mithil Fal Desai
Shree Mallikarjun and Shri Chetan
Manju Desai College Canacona Goa
Effective nuclear charge (Zeff)
Zeff = Z – σ
Zeff = Z – S
σ or S is shieling constant
Shielding
Screening
Shielding
The reduction of the true nuclear charge to
effective nuclear charge by other electrons is
called shielding.
Energy of electron, atomic number,
principal quantum number
Energy of electron is a
function of Z2/n2
Does this mean that energy
required to remove
electron from an atom
continuously increases
with the atomic number?
Z n Z2/n2
1 1 1
2 1 4
3 2 2.25
4 2 4
5 2 6.25
6 2 9
7 2 12.25
8 2 16
9 2 20.25
Why this is not true?
A) Average radius of 2s
orbital is greater
than 1s.
A) 2s electrons are
repelled by 1s
electrons.
Nucleus
e-
Remember!
• Shielding and screening decreases the true nuclear
charge.
• Shielding constant can be measured following the
Slater rules

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Shielding or screening effect

  • 1. Shielding or Screening Dr. Mithil Fal Desai Shree Mallikarjun and Shri Chetan Manju Desai College Canacona Goa
  • 2. Effective nuclear charge (Zeff) Zeff = Z – σ Zeff = Z – S σ or S is shieling constant
  • 5. Shielding The reduction of the true nuclear charge to effective nuclear charge by other electrons is called shielding.
  • 6. Energy of electron, atomic number, principal quantum number Energy of electron is a function of Z2/n2 Does this mean that energy required to remove electron from an atom continuously increases with the atomic number? Z n Z2/n2 1 1 1 2 1 4 3 2 2.25 4 2 4 5 2 6.25 6 2 9 7 2 12.25 8 2 16 9 2 20.25
  • 7. Why this is not true? A) Average radius of 2s orbital is greater than 1s. A) 2s electrons are repelled by 1s electrons. Nucleus e-
  • 8. Remember! • Shielding and screening decreases the true nuclear charge. • Shielding constant can be measured following the Slater rules