SIB-1893

SIB-1893
识别信息
	IUPAC命名法 (E)-2-methyl-6-(2-phenylethenyl)pyridine; ;
CAS号	7370-21-0（trans） ; 6266-99-5
PubChem CID	235382;
ChemSpider	4470920 ;
UNII	4X2F5X24UK;
ChEMBL	ChEMBL88612 ;
CompTox Dashboard（英语：CompTox Chemicals Dashboard） (EPA)	DTXSID801017353 ;
化学信息
化学式	C14H13N
摩尔质量	195.27 g·mol−1
3D模型（JSmol（英语：JSmol））	交互式图像;
	SMILES c1ccccc1\C=C\c(nc2C)ccc2;
	InChI InChI=1S/C14H13N/c1-12-6-5-9-14(15-12)11-10-13-7-3-2-4-8-13/h2-11H,1H3/b11-10+ ; Key:SISOFUCTXZKSOQ-ZHACJKMWSA-N ;

SIB-1893是一种有机化合物，化学式为C₁₄H₁₃N。它可由2-甲基-6-苯乙炔基吡啶和硫化钠九水合物在二甲基甲酰胺中于140 °C反应制得。^[1]以苯甲醛和2,6-二甲基吡啶为原料在路易斯酸催化下反应，也可得到该化合物。^[2]在草酸二水合物的存在下，它可以发生光二聚反应，得到1,3-二苯基-2,4-二(6-甲基吡啶-2-基)环丁烷。^[3]

参考文献

^ Zhengwang Chen, Miaoting Luo, Yuelu Wen, Guotian Luo, Liangxian Liu. Transition-Metal-Free Semihydrogenation of Diarylalkynes: Highly Stereoselective Synthesis of trans -Alkenes Using Na 2 S·9H 2 O. Organic Letters. 2014-06-06, 16 (11): 3020–3023 [2021-09-21]. ISSN 1523-7060. doi:10.1021/ol501137x. （原始内容存档于2021-09-21）（英语）.
^ Dan Mao, Gang Hong, Shengying Wu, Xin Liu, Jianjun Yu, Limin Wang. Lewis-Acid-Catalyzed Benzylic Reactions of 2-Methylazaarenes with Aldehydes: Benzylic Reactions of 2-Methylazaarenes. European Journal of Organic Chemistry. 2014-05, 2014 (14): 3009–3019 [2021-09-21]. doi:10.1002/ejoc.201400073 （英语）.
^ Thanh Binh Nguyen, Tuan Minh Nguyen, Pascal Retailleau. [2+2] Photodimerization of Stilbazoles Promoted by Oxalic Acid in Suspension. Chemistry – A European Journal. 2020-04-09, 26 (21): 4682–4689 [2021-09-21]. ISSN 0947-6539. doi:10.1002/chem.201905597 （英语）.

[1] Zhengwang Chen, Miaoting Luo, Yuelu Wen, Guotian Luo, Liangxian Liu. Transition-Metal-Free Semihydrogenation of Diarylalkynes: Highly Stereoselective Synthesis of trans -Alkenes Using Na 2 S·9H 2 O. Organic Letters. 2014-06-06, 16 (11): 3020–3023 [2021-09-21]. ISSN 1523-7060. doi:10.1021/ol501137x. （原始内容存档于2021-09-21）（英语）.

[2] Dan Mao, Gang Hong, Shengying Wu, Xin Liu, Jianjun Yu, Limin Wang. Lewis-Acid-Catalyzed Benzylic Reactions of 2-Methylazaarenes with Aldehydes: Benzylic Reactions of 2-Methylazaarenes. European Journal of Organic Chemistry. 2014-05, 2014 (14): 3009–3019 [2021-09-21]. doi:10.1002/ejoc.201400073 （英语）.

[3] Thanh Binh Nguyen, Tuan Minh Nguyen, Pascal Retailleau. [2+2] Photodimerization of Stilbazoles Promoted by Oxalic Acid in Suspension. Chemistry – A European Journal. 2020-04-09, 26 (21): 4682–4689 [2021-09-21]. ISSN 0947-6539. doi:10.1002/chem.201905597 （英语）.

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