Abstract
At the nanoscale, elastic strain and crystal defects largely influence the properties and functionalities of materials. The ability to predict the structural evolution of catalytic nanocrystals during the reaction is of primary importance for catalyst design. However, to date, imaging and characterising the structure of defects inside a nanocrystal in three-dimensions and in situ during reaction has remained a challenge. We report here an unusual twin boundary migration process in a single platinum nanoparticle during CO oxidation using Bragg coherent diffraction imaging as the characterisation tool. Density functional theory calculations show that twin migration can be correlated with the relative change in the interfacial energies of the free surfaces exposed to CO. The x-ray technique also reveals particle reshaping during the reaction. In situ and non-invasive structural characterisation of defects during reaction opens new avenues for understanding defect behaviour in confined crystals and paves the way for strain and defect engineering.
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Introduction
Platinum (Pt) nanoparticles (NPs) are widely used catalysts in many important fields like the chemical industry, fuel cell technology, and automobile exhaust gas purification1,2,3. Of particular interest for catalysis is the simultaneous in situ characterization of the chemical, morphological, and structural (strain, facets, and defects) dynamical4 evolution of individual nanoparticles in (near) operational conditions. Recently, it has been observed that strain, as well as defects are key factors for catalysis, opening-up the concept of mechanochemistry, and strain-engineered catalysis5,6,7,8. Applying a strain to metal catalysts, either compression or tension, can change the way they perform6. Recently, microstrain or localized lattice strain, which is generated from structural defects, such as dislocations, grain boundaries, and twin boundaries, has been observed to enhance catalytic activity and stability9,10,11. In particular, multitwin defects, which serve as catalytically active sites, have been proven to promote electrocatalytic activity12,13,14,15,16. Twinned structures may form during crystal nucleation, growth, phase transformations, recrystallization17, or via the mechanism of deformation twinning, concurrently with the plastic deformation by slip and for metals exhibiting a low stacking-fault energy18. Crystal twinning is also sensitive to the chemical environment. The adsorption of impurity atoms may contribute to the formation of twins19. Whereas twinning mechanisms are well known, descriptions of detwinning mechanisms have been relatively sparse. They occur mostly in shape memory alloys20,21,22 or under a mechanical load23,24. To improve our understanding of physical defect mechanisms and enable defect engineering, it is crucial to develop imaging techniques capable of resolving defects and their evolution. Recently, it has been demonstrated that Bragg coherent diffraction imaging (BCDI) is particularly sensitive to defects and can resolve their three-dimensional (3D) structure nondestructively25,26,27. By illuminating an isolated object by an X-ray beam with coherence lengths larger than the object, and measuring its oversampled 3D diffraction pattern, it is possible to reconstruct the measured complex-valued object using phase retrieval iterative algorithms28,29. Its amplitude is related to the real space density or more specifically to Bragg electron density of the contributing crystal, whereas the phase is equivalent to the displacement field component projected on the Bragg diffraction vector. These two parameters can be resolved with a spatial resolution better than 10ânm30,31,32.
In this article, we demonstrate the capabilities of BCDI to reveal in 3D the local morphology (faceting), strain and defect evolution in a single Pt nanoparticle in situ during catalytic CO oxidation reaction at elevated temperatures (450â°C and 500â°C) under Ar, CO, and/or O2 atmosphere at near atmospheric pressure flow conditions.
Results
Figure 1a shows the experimental setup. The sample consists of Pt nanoparticles obtained by solid-state dewetting on a sapphire substrate (see Methods), the Pt [111] direction being normal to the substrate surface. A lithographic processing route ensured that a number of Pt particles were well-separated from their neighbors that only one crystallite is irradiated by the incoming X-ray beam, and that the irradiated particle can be easily located after the experiment (see inset of Fig. 1a). The sample was placed in a reactor33 with tunable parameters: temperature and gas conditions (see Fig. 1a and Methods). The BCDI measurements were performed by recording the intensity distribution in the vicinity of the specular 111 Pt Bragg reflection, which yields, for example, the 3D diffraction pattern displayed in Fig. 1b, the duration of the measurement being around 4 min 30 s The phase retrieval procedure used for spatial reconstruction of the measured particle, as well as experimental details are described in Methods. The reconstructed Pt crystal (morphology and phase distribution) under CO (2% in Ar) exposure and at 450â°C is shown in Fig. 1c. The particle is approximately 200âxâ320âxâ110 (height) nm3 in size and shows a complex structure, including a twin fault characterized by a {111} twin boundary (TB), in agreement with the <111> streak observed in the 3D diffraction pattern displayed in Fig. 1b. \(\Sigma\)3{111} twin boundaries (TBs) are commonly observed in face-centered cubic (f.c.c.) structures34,35. It corresponds to a boundary with a {111} composition plane (here, (\(\bar{1}\bar{1}1\)) as fixed arbitrarily) separating two domains: the twin and its parent. The crystallographic orientation of the twin domain is obtained by a rotation of 180° around the [\(\bar{1}\bar{1}1\)] direction of the parent grain. For instance, the (111) planes of the parent grain correspond to (115) planes in the twin grain36 (see Figure S1). As the twin crystal planes are rotated with respect to the parent crystal lattice, they appear as a missing Bragg electron density at the 111 Pt Bragg reflection and thus as a void in the reconstructed modulus of the particle37. This gives the peculiar shape of the reconstructed particle, which is displayed in Fig. 1c, where only the parent grain with its (\(\bar{1}\bar{1}1\)) TB is observed. Using a scanning X-ray diffraction microscopy approach38 and owing to the mask processing route employed in sample preparation, it was then possible to identify the target Pt nanoparticle, as well as the measured domain (here, named as the parent grain), as demonstrated in the scanning electron microscopy (SEM) image of the very same particle displayed in Fig. 1a.
We collected sets of 3D coherent 111 Pt Bragg diffraction patterns at 450 and 500â°C for different gas compositions. The gas condition at near atmospheric pressure was changed in the following sequence at 450â°C: (1) pure Ar, (2) CO (2% in Ar), (3) CO (2% in Ar) + O2 (0.4% in Ar), (4) CO (2% in Ar) + O2 (1% in Ar), (5) CO (2% in Ar) + O2 (4% in Ar) (data not saved), (6) O2 (4% in Ar), (7) Ar (data not saved), and (8) CO (2% in Ar) (see Table S1 and Fig. 2). The temperature was then increased to 500â°C under (9) CO (2% in Ar). BCDI measurements were performed twice after each change of the gas composition. Diffraction patterns of the 111 Pt Bragg peak for different gas compositions at 450â°C are shown in Figure S2. The intensity distribution shows interference arising from single-particle coherent diffraction. Clear changes in the reciprocal space intensity distribution (see the evolution of the inclination of the tilted streak) indicate modifications of the strain and/or shape of the measured catalyst under different gas atmosphere conditions. The real space 3D structure of the Pt crystal was reconstructed by the same iterative phase retrieval approach (see Methods) as previously. Figure 2 shows the evolution of the reconstructed modulus (or Bragg electron density) and of the strain along the [111] direction (normal to the substrate surface), εzz, of the catalyst in real space drawn at 23% of the maximum density39 for each measured gas composition. The estimated experimental resolution ranges from 11.6 to 18.9ânm depending on the gas composition and temperature (see Figure S3 and Methods). The reconstructed real space data shows a clear evolution of the shape of the Pt crystal during CO oxidation reaction and temperature change. The black dotted contour is a guide for the eye and delimits the shape of the parent crystal measured at condition (2): Ar and CO (2%) at 450â°C (see also Fig. 1c). The estimated reconstructed crystalâs volume is displayed as a function of time and gas mixture in Figure S4. At the beginning of the experiment (see Fig. 2a), the volume of the crystal is larger and shows a {111}-type twin boundary, perpendicular to the [\(\bar{1}\bar{1}1\)] direction. After introducing CO, a significant decrease in the crystalâs volume is observed. The crystal still exhibits a [\(\bar{1}\bar{1}1\)] TB. This crystallite size decrease is caused by twin boundary migration. The twin crystal planes are rotated with respect to the parent crystal lattice and appear as a missing Bragg electron density, leading to a truncated shape of the measured crystal. By changing the gas mixture and introducing O2 in an increasing ratio (from condition (3) to condition (6)), an inverse phenomenon, i.e., the increase of the crystalliteâs volume was observed. The increase of the crystalâs volume through TB migration is the signature of the detwinning of the crystal. The parent crystal grows at the expense of the twin crystal. This was still observed when removing O2 and introducing CO (see condition (8) in Fig. 2f). Interestingly, the TB does not migrate back to the initial configuration (i.e., condition (1)); it reaches a vertical grain boundary (GB). To determine the orientation of this grain boundary, we plotted the stereographic projection40 of the 3D diffraction pattern corresponding to condition (8), as well as other most representative conditions (conditions (2) and (6)) in Fig. 3. Stereographic projection is a convenient way to determine the orientation of facets and planar defects giving rise to streaks in 3D diffraction patterns. For all projections, the central spot corresponds to the top (111) surface. A \(\bar{{{ \bf 1}}}\bar{{{\bf 1}}}{{\bf 1}}\,\)bright spot, which corresponds to the [\(\bar{1}\bar{1}1\)] TB is observed for condition (2). It evolves toward a \(\bar{{{{{{\bf{1}}}}}}}\bar{{{{{{\bf{1}}}}}}}{{{{{\bf{2}}}}}}\) spot (see Fig. 3c), i.e., a (\(\bar{1}\bar{1}2\)) interface/boundary. The GB observed in conditions (6) and (8) is then perpendicular to the [\(\bar{1}\bar{1}2\)] direction.
For the last condition (i.e., condition (9)), the temperature had been increased to 500â°C. This resulted in a decrease of the crystal volume through twin boundary migration (twinning) (see Fig. 2g). The crystal returned to the configuration observed at 450â°C under the same gas mixture (CO (2% in Ar), see condition (2)) and exhibits a [\(\bar{1}\bar{1}1\)] TB. Figure 2 also demonstrates that faceting occurs during reaction. Small facets of {111}, {210}, and {211}-types are observed for conditions (4) and (6). Note that these facets are too small (signal not intense enough) to be observed on the stereographic projections of Fig. 3.
The reconstruction results of the Bragg electron density (or modulus), the phase and the out-of-plane strain (\({\varepsilon }_{{zz}}\)) of the Pt crystal are shown in Figures S5, S6, and 4, respectively, for the different gas mixtures. Two-dimensional slices through the center of the reconstructed crystal are displayed and the reconstructed crystal has been rotated in-plane for easier visualization, so that the twin interface is parallel to one axis. The evolution of the Bragg electron density and phase (proportional to the displacement field along the [111] direction, \({u}_{z}\)) is well observed during reaction. As an example, the phase increases at the top of the crystal during detwinning: from condition (2) to (8), see Fig. S6. Local variations of the strain are also observed. After twinning (see Fig. 4b), the compressive strain was observed at the new twin boundary. During detwinning (from Figs. 4câf), compressive strain remains at the position of the TB observed in Fig. 4b.
Discussion
Interestingly, twinning is highly unfavorable in Pt, since the stacking-faults and twin boundary (322âmJ/m2) energies are high41, making the nucleation of twins difficult. Twinning is seldom observed in Pt bulk crystals; however, it has been reported in nanocrystals42,43,44, where a new twinning pathway has been identified44. It has been further observed that the formation of a twin boundary is a probable final configuration of sintered nanoparticles, even if the material shows high stacking-fault energies45,46. The latter case may explain the occurrence of a twin boundary in the Pt nanocrystal studied in this work.
Twinning/detwinning in f.c.c. crystals result from the emission of Shockley partial dislocations on successive atomic layers in {111} planes. These partial dislocations can be nucleated from grain boundaries (GBs)47, free surfaces, from defects, such as ledges on TBs48 or be multiplied by dislocation-twin boundary interaction49. Twinning/detwinning is generally dependent on: (a) sufficiently high local stress to trigger nucleation of twinning partials on successive planes, and (b) energetically favored transformation50. In our study, twinning was observed, while exposing the Pt crystal to CO gas flow, i.e., for conditions (2) and (9) (see Fig. 2 and S5). While the parent crystal is [111]-oriented normal to the substrate, the twin crystal is [115]-oriented36. When twinning occurs, the ratio of (115) to (111) exposed surface-area increases.
Adsorption of CO on Pt surfaces has received continued interest ever since Irving Langmuir studied this system51 and the strong dependence of the CO adsorption energy on the surface structure is well established52,53. We have performed DFT calculations to compute the Pt/CO interface energy, \({\gamma }_{{hkl}}^{{CO}}\), (see Eqs. 1â5 of Methods) for both the {111} and {511} surfaces as a function of CO coverage. The configurations of CO molecules adsorbed on the {111} surface are taken from Ref. 53, where an extensive computational screening of many possible configurations for different coverages is reported. The reported lowest-energy configuration53 at a given coverage is adopted here to compute the \({\gamma }_{{hkl}}^{{CO}}\). Due to the lack of previous computational studies of CO adsorption on Pt{511}, we computed several possible configurations at different coverages and considered the lowest-energy case to compute the Pt{511}/CO interface energy (see Figures S6-S21). The \({\gamma }_{111}^{{CO}}\) and \({\gamma }_{511}^{{CO}}\) computed by using the revPBE functional54 are reported in Fig. 5. This functional was developed to improve the description of molecules adsorbed onto metallic surfaces and gives adsorption energies at low coverages of 137â140âkJ/mol (see Fig. S23), in good agreement with experimentally reported values55,56,57 ranging between 126 and 145âkJ/mol. While for zero and low coverage, the Pt{111}/CO interface energy is lower than the {511} case, at high coverages (>0.07âmolecule/à 2 or 0.47âML) the {511} is preferred. At intermediate coverages, between 0.04 and 0.07âmolecule/à 2, the difference in interfacial energy is negligible (see Fig. 5). Several exchange and correlations functionals were tested and found to yield slightly different numbers, as expected from previous works51,58, but the same qualitative behavior for the two surfaces is predicted (see Table S3 and Figure S8). The CO adsorption is always stronger on {511} than {111}, regardless of the coverage, and for both surfaces it decreases with increasing CO coverage (see Figures S8 and S10). In order to establish the CO coverage expected for {511} and {111} at the experimental conditions of pressure and temperature, we computed the Gibbs free energy of adsorption as a function of the CO chemical potential for the lowest-energy configurations, see Fig. 5aâb. At 700 K and at a pression of 0.02 bar of CO, a coverage of 0.062âML is predicted for the {111} facets, while 0.333âML would adsorb onto the {511} facets, yielding a difference in \({\gamma }_{{hkl}}^{{CO}}\) of 0.84âJ/m2. At 300âK and 0.02 bar, we predict a coverage of 0.56âML for {111} (see Fig. S23), in good agreement with recent computational studies by Sautet et al.59 and Gunasooriya et al.53 The larger coverage predicted for the stepped {511} surface, as compared to the flatter {111} surface, is consistent with results from electron energy loss spectroscopy experiments60.
The typical driving force associated with grain boundary migration in Pt can be estimated considering the driving force for recrystallization. It has been shown that the recrystallization in heavily cold-rolled Pt foils begins at temperatures as low as 400â°C61. The driving force of recrystallization, Erec, is mainly related to the energy of stored dislocations, and can be roughly estimated as: Erec = 0.5ÏGb2. The maximum dislocation density in heavily deformed metals with high stacking-fault energy is of the order of \(\rho\) \(\approx\) 1015âmâ2. For Pt, the magnitude of the Burgers vector is b = 0.277ânm, and the shear modulus, G, can be estimated by its isotropic value of 62 GPa. Then, Erec \(\approx\) 2.4Ã106 J/m3. On the other hand, the driving force for twin boundary migration in our working geometry is Es = Îγ/h, where Îγ = 840âmJ/m2 is the difference of the Pt/CO interface energies, and h \(\approx\) 110 nm is the particle height. The last equation can be derived by considering the infinitesimal lateral displacement of the boundary. With these data, Es \(\approx\) 7.6âÃâ106âJ/m3. The two driving forces are of the same order of magnitude. Therefore, the energy gain from CO adsorption on the {511} facets represents a viable driving force for twin boundary migration. Another example of a small difference of surface energies driving the grain boundary migration is abnormal grain growth in thin films. Indeed, Humphreys and Hatherly62 have shown that only 2% difference in surface energies of two neighboring grains can drive the abnormal growth. Note that, before the BCDI measurements presented in this manuscript, the sample was already at 450â°C in argon for 2 h 30 min as indicated in the Sample History section. Therefore, we can discard a thermal activation process for the motion of the twin boundary at 450â°C.
As a result, a chemical driving force, i.e., the difference of interface energies between {111} and {115} free surfaces exposed to CO can cause migration of the twin boundary in the direction of the interface with higher energy, i.e. Pt{111}/CO, and explain the twinning mechanism observed for conditions (2) and (9). Note that twinning is not observed for condition (8), while the particle is exposed to CO as in condition (2) (see Fig. 2). The oxidation of the Pt surface under O2 rich conditions (condition (6)) followed by reduction by CO (condition (8)) will thus unlikely reestablish the initial surface. For instance, surface roughening has been observed after oxide reduction63,64. The different surface and strain states, which depend on the history of the crystal, may explain this absence of twinning.
In addition to the anisotropy of interfacial energy between the free surfaces exposed to CO, the change of local strain/displacement at the surface of the particle during reaction may also contribute to the twin boundary migration process. The interaction of gas species with the surface results in local strain gradients. The initial crystal shows a large compressive strain at its twin boundary. The resulting stress may favor the nucleation of dislocations allowing the boundary to move. An increase of the out-of-plane displacement at the particle top surface (see Fig. S6) was observed during detwinning. Hence, deformation-induced detwinning may occur. A striking result from the strain analysis is the remnant compressive out-of-plane strain observed at the position of the twin boundary formed in condition (2) during the detwinning process. Interestingly, a surface step can be observed at the location left by the migrating TB (see Figs. 2e, f and 4e, f). The remnant compressive strain at the surface location left by the migrating TB may be explained by shear-coupled grain boundary motion65. Note that this strain increases from Fig. 4(b) to (f) and suggests that the TB leaves defects behind. However, since we do not reconstruct phase jumps typical of dislocations (see Fig. S6), we can infer that the Burgers vector (\(\vec{b}\)) of these defects does not fulfill the visibility condition66: \(\vec{g}\cdot \vec{b}\;\ne\; 0\) (where \(\vec{g}\) corresponds to the 111 diffraction vector; actually two out-of the three possible slip systems in the (\(\bar{1}\bar{1}1\)) plane fulfill the invisibility conditions) or that their induced displacement field is below the spatial resolution of the measurements as they are closely spaced or that the dislocation movement related to twin boundary migration is too fast to be detected by our technique. At the end of the detwinning process, the TB does not migrate back to the initial configuration (i.e., condition (1)); it reaches a [\(\bar{1}\bar{1}2\)] grain boundary. This GB was not present initially in the crystal at the position observed in conditions (6) and (8). It was probably in the crystal and could have migrated during twinning/detwinning due to the driving force associated with the changing strain distribution in the particle, with the anisotropy of the particle-substrate interface56 or with thermal grooving67,68. Owing to the mask processing route, it was possible to locate the Pt particle (see SEM image displayed in Fig. 1a). We performed micro-Laue diffraction at the BM32-ESRF beamline after the BCDI experiment. It has been observed that the crystal contains at least three large grains with their [111] directions aligned close to the substrate normal (see Fig. S24); this demonstrates the complex microstructure of the crystal. It should be noted that low-angle GBs are sometimes observed in the particles produced by solid state dewetting, and these may migrate during prolonged heat treatments69. Deviations from the perfect [111] orientation in the neighboring grains may provide the driving force for the GB migration due to the energy anisotropy of the particle-substrate interface70. The elevated temperatures ensure sufficiently high GB mobility (associated with diffusional movement of Pt atoms in the GB core) enabling its migration. The mobility of the Pt atoms during reaction is not only evidenced by the GB migration but also by the faceting of the particle. Knowing the 3D orientation of the particle, it is possible to determine the (hkl) Miller index of the newly grown facets (see Fig. 2). During CO oxidation (Fig. 2d), several facets are well evidenced: (\(11\bar{1}\)), {102}- and {112}-type facets. Particle refaceting has been previously observed during CO exposure71,72,73,74 or CO oxidation75,76. Surface diffusion, oxide formation, and CO adsorption may explain the surface change. As an example, Vendelbo et al.4 demonstrated that the stabilization of the facets is linked to the chemisorption of oxygen on the facet sites in a low CO concentration regime. This restructuring phenomenon may have important implications for heterogeneous catalytic reactions.
In summary, we observed twin boundary migration (twinning/detwinning) during reaction depending on the gas feed composition and temperature. As demonstrated by DFT calculations, twinning can be correlated with the relative change in interfacial energy between the parent and twin-free surfaces exposed to CO. Facet formation and migration of the [\(\bar{1}\bar{1}2\)] grain boundary is in line with high mobility and diffusivity of Pt atoms during reaction, either related to the gas interaction, temperature and/or strain. After twinning, a remnant compressive strain was observed at the position of the twin boundary suggesting that the twin boundary leaves trailing defects behind, and this may be explained by shear-coupled grain boundary motion. The noninvasive nature of Bragg coherent diffraction imaging is particularly well adapted to dynamically study the structure (strain, shape, faceting, defects) of nanoscale materials under external stimuli (i.e., pressure, temperature) in reactive environments at the individual particle level.
Methods
Sample preparation
A 30ânm-thin platinum film was deposited by an electron beam evaporator on a lithographically patterned α-Al2O3 sapphire (c-axis oriented) substrate. The substrate was thoroughly cleaned with a sequence of detergent water, acetone, methanol, isopropanol, followed by immersion of 10 min in Piranha solution (H2SO4:H2O2 2:1 by volume), and subsequently washed with DI water. A standard photolithography method was employed to prepare a patterned layer of photoresist on sapphire prior to the electron beam evaporation of Pt. The patterning was performed by photoresist spin coating, mask exposure, and development. After the Pt film deposition at room temperature, the lift off process in hot N-Methyl-2-pyrrolidone and acetone was performed. The thin film was subsequently dewetted at 800â°C in ambient air for 24 h in order to form single crystalline Pt particles of different sizes (100â500ânm in lateral size). The low (800â°C) annealing temperature is prone to the formation of twin and grain boundaries. The lithographic/mask processing route ensured that some of the crystallites are isolated. The obtained crystallites exhibited the same well-defined out-of-plane orientation as the original thin Pt film, with the Pt [111] direction being normal to the (0001) sapphire surface.
Gas reactor
We used a furnace compatible with nano X-ray beam and developed for in situ gas experiments33. The temperature was measured using a S-type thermocouple. The thermocouple was located in the button heater of the reactor. A gas flow of 50ml/min was delivered with a gas panel developed at TU Eindhoven. The gas composition inside the catalytic chamber was measured using a gas spectrometer (Pfeiffer vacuum ThermoStar GSD320T). The total pressure of the gas reactor was close to atmospheric pressure.
Sample history before BCDI measurements
Prior to the BCDI measurements shown in this paper, the sample has been exposed to several gas mixtures, including (1) H2 (20% in Ar), (2) pure Ar, (3) CO (2% in Ar), (4) CO (2%) and O2 (4%) in Ar, and finally (5) O2 (4% in Ar) at 300â°C. Then, O2 was replaced by pure Ar during sample re-alignment at 450â°C. The first BCDI measurement at 450â°C happened 2h30 after introducing pure Ar.
BCDI measurements
BCDI measurements were performed at the upgraded ID01 beamline of the ESRF synchrotron77. A coherent portion of the beam was selected with high precision slits by matching their horizontal and vertical gaps with the transverse coherence lengths of the beamline: 200âμm (vertically) and 60âμm (horizontally). The required beam size was obtained with a Kirkpatrick-Baez (KB) mirror, which focused the beam down to about 500 nm (horizontal) \(\times\) 680 nm (vertical) full width at half maximum, as determined by knife-edge scans. This beam size ensured the full illumination of a single nanoparticle. An order sorting aperture was placed after the KB mirror to remove any parasitic scattering. The intensity distribution around the 111 Pt reflection was measured in a vertical coplanar diffraction geometry. The sample was rotated around the Bragg condition by steps of 0.01° over a total range of 1° in order to sample the 111 Pt Bragg peak. The BCDI experiment was performed at a beam energy of 9 keV (wavelength of 1.3775 à ) using a Si (111) monochromator. The diffracted beam was recorded with a 2D Eiger2M photon-counting detector (2164 (vertical) x 1030 (horizontal) pixels, each pixel 75âxâ75âμm) positioned on the detector arm at a distance of 0.86 m. The detector distance as well as the rocking angle increment was chosen in order to ensure the oversampling of interference fringes. A typical counting time was 1 s per angle without beam attenuation. The sample was mounted on a Physik Instrumente Mars xyz piezoelectric stage with a lateral stroke of 100âμm and a resolution of 2ânm, sitting on a hexapod that was mounted on a (3â+â2 circles) goniometer.
Phase retrieval
Phase retrieval was carried out on the raw diffracted intensity data using PyNX package, imposing at each iteration that the calculated Fourier intensity of the guessed object agrees with the measured data. The metric used to estimate the goodness of fit during phasing was the free log-likelihood78, available in PyNX. Defective pixels for experimental data and gaps in the detector were not used for imposing the reciprocal space constraint mentioned above and thus were evolving freely during phasing. The initial support, which is the constraint in real space, was estimated from the autocorrelation of the diffraction intensity. A series of 1400 Relaxed Averaged Alternating Reflections (RAAR79) plus 200 Error-Reduction steps80,81, including shrink wrap algorithm82 every 20 iterations were used. The phasing process included a partial coherence algorithm to account for the partially incoherent incoming wave front83. After removing the phase ramp and phase offset, the data was finally interpolated onto an orthogonal grid for easier visualization. To ensure the best reconstruction possible, we kept only the best 10 reconstructions (with lowest free log-likelihood) from 1000 with random phase start and performed the decomposition in modes78.
The spatial resolution has been determined by the normalized phase retrieval transfer function (PRTF)84 at a cutoff value of 1/\(e\).
The nanocrystal volume was estimated by summing all the voxels of the reconstruction having a Bragg electron density larger than 23% of the maximum of the Bragg electron density. The cutoff is chosen from the histogram of the recovered modulus39. The sum has been then multiplied by the voxel size. The error bars represent a range of ±5% of the measured volume using the 23% isosurface.
Postmortem analysis
Scanning electron microscopy (SEM) measurements have been performed ex situ after the BCDI experiment. It was possible to locate the measured nanoparticle (see Fig. 1a). Electron back-scattered diffraction (EBSD) and micro-Laue diffraction have been applied on the nanoparticle to determine the orientation of the different sub-grains composing it. The micro-Laue diffraction experiment has been performed at the BM32-ESRF beamline. The white beam has been focused down to 400âxâ400ânm using KB mirrors.
Density functional theory
The density functional theory (DFT) calculations were performed by employing the PWSCF utility of Quantum ESPRESSO85. Ultrasoft pseudopotentials with non-linear core-correction were employed86. Energy cutoffs of 55 Ry and 550 Ry were used respectively for representation of the wavefunctions and charge density.
Free-surface energies
Free-surface energies, \({\gamma }_{{hkl}}^{{vac}}\), are computed using Eq. 1:
where N is the number of Pt atoms in slab and Aslab is the area of the slab. For the bulk, a full geometrical optimization of the one-atom primitive cell of Pt (fcc) is carried out using an 8Ã8Ã8 k-point mesh to sample the integration over the Brillouin zone. The slab is built out-of 10 atomic layers with a vacuum of 18 à . Three outer layers of Pt atoms on each side of the slab are allowed to geometrically relax for the calculation of the total energy and convergence is achieved when all forces on the loose Pt atoms are lower than 0.001 Ry/Bohr. The k-points mesh for the slabs is chosen by rescaling the mesh of the primitive cell according to the relative sizes. The surface energies computed for {111} and {511} surfaces using different exchange and correlation functionals (XCF) are reported in Table S2, together with results from previous studies, for comparison. Some XCFs have been used in conjunction with Grimmeâs DFT-D3 van der Waalsâ correction without damping as implemented in PWSCF87. The unit cell employed for the {511} slab is shown in Figure S7 and is characterized by five surface atoms.
Gibbs free energy of adsorption
To study the stability of the different adsorption configurations as a function of gas pressure and temperature, we compute the Gibbs free energy of adsorption as follows:
The chemical potential of CO is determined by the thermodynamic equilibrium with the gas phase reservoir and it is computed as follows:
the first two terms are the electronic and zero-point energies and are computed using DFT. The term \({\widetilde{\mu }}_{{CO}}(T,{p}^{0})\) includes thermal effects contribution from vibrations and rotations of the molecules together with the ideal gas entropy at p0 = 1 atm. In this work, we take the experimental values from the JANAF thermochemical tables88. Specifically, we take \({\widetilde{\mu }}_{{CO}}(T,1)\) equal to â0.53âeV at 300 K and â1.40âeV at 700 K. For the free slab and the CO adsorbed configurations, we approximate G by E, i.e., the total energy (see next section).
Interfacial energy
Interfacial energy of the Pt/CO interface as a function of CO coverage is defined in Eq. 476,89; where Aslab is the unit area of the slab, n the number of CO molecules adsorbed on the Pt surface of the slab, and Eads the adsorption energy (Eq. 5).
We note that the adsorption energy, rather than the Gibbs free energy of adsorption, is employed in Eq. (4) for consistency with the calculation of \({\gamma }_{{hkl}}^{{vac}}\) which is computed using total energy differences. For the calculation of the interfacial energy, the energetically preferred configuration of the adsorbed CO molecules at each coverage is used. Adsorption energies are computed by relaxing the CO molecule and the first three Pt layers. To model adsorption of CO on Pt {111}, a 4âÃâ4 supercell of a slab of six layers of Pt atoms is considered with CO molecules adsorbing only on one side of the slab. The configurations of adsorbed CO on {111} are taken from an earlier work53. For the {511} surface, a Pt slab of seven atomic layers is used. Several low- and high-coverage configurations are computed (see Figure S7 and Figures S11-S22) and the lowest-energy configuration at a given coverage is used to compute \({\gamma }_{511}^{{CO}}\) (see Table S2). Due to the asymmetry of the slab upon CO adsorption, the CO/Pt calculations are performed by employing a dipole-correction method90 in order to cancel the unphysical dipole interactions between periodic images. The \({\gamma }_{111}^{{CO}}\) and \({\gamma }_{511}^{{CO}}\) values computed using different XCF at varying coverages are reported in Table S3. These values are then rigidly shifted by a constant for representation in Figure S9 and Fig. 5. This constant is determined by mapping the \({\gamma }_{{hkl}}^{{vac}}\) to the experimental value (see Table S2) and is applied also to shift \({\gamma }_{511}^{{CO}}\). This rigid-shift strategy allows to report non-negative values of \({\gamma }_{{hkl}}^{{CO}}\), while maintaining the DFT-predicted relative difference between the {111} and {511} curves.
Data availability
The data reported in this paper is available upon request.
Code availability
The phasing algorithm PyNX91 is available at http://ftp.esrf.fr/pub/scisoft/PyNX/. The scripts used for BCDI data post-processing, PRTF calculations and stereographic projections belong to the BCDI92 package (https://doi.org/10.5281/zenodo.3257616), that can be downloaded from PyPI (https://pypi.org/project/bcdi/) or GitHub (https://github.com/carnisj/bcdi).
References
Heck, R. M. & Farrauto, R. J. Automobile exhaust catalysts. Appl. Catal. A: Gen. 221, 443â457 (2001).
Chen, A. & Holt-Hindle, P. Platinum-based nanostructured materials: synthesis, properties, and applications. Chem. Rev. 110, 3767â3804 (2010).
Ertl, G., Knözinger, H., Schüth, F. & Weitkamp, J. Handbook of Heterogeneous Catalysis. (Wiley-VCH Verlag GmbH & Co. KGaA).
Vendelbo, S. B. et al. Visualization of oscillatory behaviour of Pt nanoparticles catalysing CO oxidation. Nat. Mater. 13, 884â890 (2014).
Sneed, B. T., Young, A. P. & Tsung, C.-K. Building up strain in colloidal metal nanoparticle catalysts. Nanoscale 7, 12248â12265 (2015).
Szuromi, P. Tuning nanoparticle strain. Science. 354, 1016â1016 (2016).
Khorshidi, A., Violet, J., Hashemi, J. & Peterson, A. A. How strain can break the scaling relations of catalysis. Nat. Catal. 1, 263â268 (2018).
Xia, Z. & Guo, S. Strain engineering of metal-based nanomaterials for energy electrocatalysis. Chem. Soc. Rev. 48, 3265â3278 (2019).
Chattot, R. et al. Beyond strain and ligand effects: microstrain-induced enhancement of the oxygen reduction reaction kinetics on various PtNi/C nanostructures. ACS Catal. 7, 398â408 (2017).
Chattot, R. et al. Surface distortion as a unifying concept and descriptor in oxygen reduction reaction electrocatalysis. Nat. Mater. 17, 827â833 (2018).
Dubau, L., Nelayah, J., Asset, T., Chattot, R. & Maillard, F. Implementing structural disorder as a promising direction for improving the stability of PtNi/C nanoparticles. ACS Catal. 7, 3072â3081 (2017).
Huang, H. et al. Understanding of strain effects in the electrochemical reduction of CO2: using Pd nanostructures as an ideal platform. Angew. Chem. Int. Ed. 56, 3594â3598 (2017).
Sun, X., Jiang, K., Zhang, N., Guo, S. & Huang, X. Crystalline control of {111} bounded Pt3Cu nanocrystals: multiply-twinned Pt3Cu icosahedra with enhanced electrocatalytic properties. ACS Nano. 9, 7634â7640 (2015).
Wu, J. et al. Icosahedral platinum alloy nanocrystals with enhanced electrocatalytic activities. J. Am. Chem. Soc. 134, 11880â11883 (2012).
Yang, J., Yang, J. & Ying, J. Y. Morphology and lateral strain control of Pt nanoparticles via coreâshell construction using alloy AgPd core toward oxygen reduction reaction. ACS Nano. 6, 9373â9382 (2012).
Jia, Y., Chen, J. & Yao, X. Defect electrocatalytic mechanism: concept, topological structure and perspective. Mater. Chem. Front. 2, 1250â1268 (2018).
Christian, J. W. & Mahajan, S. Deformation twinning. Prog. Mater. Sci. 39, 1â157 (1995).
Meyers, M. A., Vöhringer, O. & Lubarda, V. A. The onset of twinning in metals: a constitutive description. Acta Materialia. 49, 4025â4039 (2001).
Lu, S.-Z. & Hellawell, A. The mechanism of silicon modification in aluminum-silicon alloys: Impurity induced twinning. MTA. 18, 1721â1733 (1987).
Liu, Y., Xie, Z. L., Van Humbeeck, J. & Delaey, L. Effect of texture orientation on the martensite deformation of NiTi shape memory alloy sheet. Acta Materialia. 47, 645â660 (1999).
Ng, K. L. & Sun, Q. P. Stress-induced phase transformation and detwinning in NiTi polycrystalline shape memory alloy tubes. Mech. Mater. 38, 41â56 (2006).
Thamburaja, P. Constitutive equations for martensitic reorientation and detwinning in shape-memory alloys. J. Mech. Phys. Solids. 53, 825â856 (2005).
Lee, S. et al. Reversible cyclic deformation mechanism of gold nanowires by twinningâdetwinning transition evidenced from in situ TEM. Nat. Commun. 5, 1â10 (2014).
Wang, L. et al. Mechanical twinning and detwinning in pure Ti during loading and unloading â An in situ high-energy X-ray diffraction microscopy study. Scr. Materialia. 92, 35â38 (2014).
Ulvestad, A. et al. Topological defect dynamics in operando battery nanoparticles. Science. 348, 1344â1347 (2015).
Ulvestad, A. et al. Three-dimensional imaging of dislocation dynamics during the hydriding phase transformation. Nat. Mater. 16, 565â571 (2017).
Hofmann, F. et al. Nanoscale imaging of the full strain tensor of specific dislocations extracted from a bulk sample. Phys. Rev. Mater. 4, 013801 (2020).
Miao, J., Charalambous, P., Kirz, J. & Sayre, D. Extending the methodology of X-ray crystallography to allow imaging of micrometre-sized non-crystalline specimens. Nature. 400, 342â344 (1999).
Robinson, I. & Harder, R. Coherent X-ray diffraction imaging of strain at the nanoscale. Nat. Mater. 8, 291â298 (2009).
Pfeifer, M. A., Williams, G. J., Vartanyants, I. A., Harder, R. & Robinson, I. K. Three-dimensional mapping of a deformation field inside a nanocrystal. Nature. 442, 63â66 (2006).
Ulvestad, A. et al. Avalanching strain dynamics during the hydriding phase transformation in individual palladium nanoparticles. Nature Commun. 6, 10092 (2015).
Clark, J. N. et al. Three-dimensional imaging of dislocation propagation during crystal growth and dissolution. Nat. Mater. 14, 780â784 (2015).
Richard, M.-I. et al. Reactor for nano-focused x-ray diffraction and imaging under catalytic in situ conditions. Rev. Sci. Instrum. 88, 093902 (2017).
Friedel, G. (1865-1933) A. du texte. Leçons de cristallographie / par G. Friedel,... (A. Hermann et fils 1911).
Grimmer, H., Bollmann, W. & Warrington, D. H. Coincidence-site lattices and complete pattern-shift lattices in cubic crystals. Acta Cryst. 11, 197â207 (1974).
Shaw, L. L., Villegas, J., Huang, J.-Y. & Chen, S. Strengthening via deformation twinning in a nickel alloy. Mater. Sci. Eng.: A 480, 75â83 (2008).
Ulvestad, A., Clark, J. N., Harder, R., Robinson, I. K. & Shpyrko, O. G. 3D imaging of twin domain defects in gold nanoparticles. Nano Lett. 15, 4066â4070 (2015).
Chahine, G. A. et al. Imaging of strain and lattice orientation by quick scanning X-ray microscopy combined with three-dimensional reciprocal space mapping. J. Appl Cryst. 47, 762â769 (2014).
Carnis, J. et al. Towards a quantitative determination of strain in Bragg Coherent X-ray Diffraction Imaging: artefacts and sign convention in reconstructions. Sci. Rep. 9, 1â13 (2019).
Richard, M.-I. et al. Crystallographic orientation of facets and planar defects in functional nanostructures elucidated by nano-focused coherent diffractive X-ray imaging. Nanoscale 10, 4833â4840 (2018).
Bernstein, N. & Tadmor, E. B. Tight-binding calculations of stacking energies and twinnability in fcc metals. Phys. Rev. B 69, 094116 (2004).
Ruan, L., Chiu, C.-Y., Li, Y. & Huang, Y. Synthesis of platinum single-twinned right bipyramid and {111}-bipyramid through targeted control over both nucleation and growth using specific peptides. Nano Lett. 11, 3040â3046 (2011).
Xie, J., Yang, X., Han, B., Shao-Horn, Y. & Wang, D. Site-selective deposition of twinned platinum nanoparticles on TiSi2 nanonets by atomic layer deposition and their oxygen reduction activities. ACS Nano 7, 6337â6345 (2013).
Wang, L. et al. New twinning route in face-centered cubic nanocrystalline metals. Nat. Commun. 8, (2017).
Harris, P. J. F. The sintering of platinum particles in an alumina-supported catalyst: Further transmission electron microscopy studies. J. Catal. 97, 527â542 (1986).
Grammatikopoulos, P., Cassidy, C., Singh, V. & Sowwan, M. Coalescence-induced crystallisation wave in Pd nanoparticles. Sci. Rep. 4, 1â9 (2014).
Capolungo, L. et al. Dislocation nucleation from bicrystal interfaces and grain boundary ledges: Relationship to nanocrystalline deformation. J. Mech. Phys. Solids 55, 2300â2327 (2007).
Zhu, T. & Gao, H. Plastic deformation mechanism in nanotwinned metals: An insight from molecular dynamics and mechanistic modeling. Scr. Materialia 66, 843â848 (2012).
Hirth, J. P. & Lothe, J. Theory of dislocations. (Krieger Publishing Company, 1992).
Wei, Y. The kinetics and energetics of dislocation mediated de-twinning in nano-twinned face-centered cubic metals. Mater. Sci. Eng.: A 528, 1558â1566 (2011).
Langmuir, I. The mechanism of the catalytic action of platinum in the reactions 2Co + O2 = 2Co2 and 2H2+ O2 = 2H2O. Trans. Faraday Soc. 17, 621â654 (1922).
Yamagishi, S., Fujimoto, T., Inada, Y. & Orita, H. Studies of CO Adsorption on Pt(100), Pt(410), and Pt(110) Surfaces Using Density Functional Theory. J. Phys. Chem. B 109, 8899â8908 (2005).
Gunasooriya, G. T. K. K. & Saeys, M. CO Adsorption on Pt(111): From Isolated Molecules to Ordered High-Coverage Structures. ACS Catal. 8, 10225â10233 (2018).
Hammer, B., Hansen, L. B. & Nørskov, J. K. Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals. Phys. Rev. B 59, 7413â7421 (1999).
Ertl, G., Neumann, M. & Streit, K. M. Chemisorption of CO on the Pt(111) surface. Surf. Sci. 64, 393â410 (1977).
Fischer-Wolfarth, J.-H. et al. An improved single crystal adsorption calorimeter for determining gas adsorption and reaction energies on complex model catalysts. Rev. Sci. Instrum. 82, 024102 (2011).
Steininger, H., Lehwald, S. & Ibach, H. On the adsorption of CO on Pt(111). Surf. Sci. 123, 264â282 (1982).
Janthon, P., Viñes, F., Sirijaraensre, J., Limtrakul, J. & Illas, F. Adding Pieces to the CO/Pt(111) Puzzle: The Role of Dispersion. J. Phys. Chem. C. 121, 3970â3977 (2017).
Sumaria, V., Nguyen, L., Tao, F. F. & Sautet, P. Optimal Packing of CO at a High Coverage on Pt(100) and Pt(111) Surfaces. ACS Catal. 12 (2020).
Hopster, H. & Ibach, H. Adsorption of CO on Pt(111) and Pt 6(111) Ã (111) studied by high resolution electron energy loss spectroscopy and thermal desorption spectroscopy. Surf. Sci. 77, 109â117 (1978).
Loginov, B., Yu., N., Yermakov, A. V., Grohovskaya, L. G. & Studenok, G. I. Annealing characteristics and Strain Resistance of 99.93 wt.% Platinum. platin met rev. 51, 178â184 (2007).
Humphreys, F. J. & Hatherly, M. Recrystallization and related annealing phenomena. (Pergamon, 1995).
van Spronsen, M. A., van Baarle, G. J. C., Herbschleb, C. T., Frenken, J. W. M. & Groot, I. M. N. High-pressure operando STM studies giving insight in CO oxidation and NO reduction over Pt(110). Catal. Today. 244, 85â95 (2015).
Spronsen, M. A., van, M., Frenken, J. W. & N. Groot, I. M. Surface science under reaction conditions: CO oxidation on Pt and Pd model catalysts. Chem. Soc. Rev. 46, 4347â4374 (2017).
Rabkin, E. & Srolovitz, D. J. Grain growth stagnation in thin films due to shear-coupled grain boundary migration. Scr. Materialia 180, 83â87 (2020).
Dingley, D. J. Dislocation invisibility in dark-field electron microscopy. Phys. Status Solidi (b) 38, 345â355 (1970).
Mullins, W. W. The effect of thermal grooving on grain boundary motion. Acta Metall. 6, 414â427 (1958).
Novick-Cohen, A., Zelekman-Smirin, O. & Vilenkin, A. The effects of grain grooves on grain boundary migration in nanofilms. Acta Materialia 58, 813â822 (2010).
Malyi, O., Klinger, L., Srolovitz, D. J. & Rabkin, E. Size and shape evolution of faceted bicrystal nanoparticles of gold on sapphire. Acta Materialia 59, 2872â2881 (2011).
Amram, D. & Rabkin, E. On the role of Fe in the growth of single crystalline heteroepitaxial Au thin films on sapphire. Acta Materialia 61, 4113â4126 (2013).
Podda, N. et al. Experimental and Theoretical Investigation of the Restructuring Process Induced by CO at Near Ambient Pressure: Pt Nanoclusters on Graphene/Ir(111). ACS Nano 11, 1041â1053 (2017).
Avanesian, T. et al. Quantitative and atomic-scale view of CO-induced Pt nanoparticle surface reconstruction at saturation coverage via DFT calculations coupled with in situ TEM and IR. J. Am. Chem. Soc. 139, 4551â4558 (2017).
Abuin, M. et al. Coherent X-ray Imaging of CO-Adsorption-Induced Structural Changes in Pt Nanoparticles: Implications for Catalysis. ACS Appl. Nano Mater. 2, 4818â4824 (2019).
Tao, F. et al. Break-up of stepped platinum catalyst surfaces by high CO coverage. Science 327, 850â853 (2010).
Flytzanistephanopoulos, M. Surface morphology of platinum catalysts. J. Catal. 49, 51â82 (1977).
Shipilin, M., Gustafson, J., Zhang, C., Merte, L. R. & Lundgren, E. Step dynamics and oxide formation during CO oxidation over a vicinal Pd surface. Phys. Chem. Chem. Phys. 18, 20312â20320 (2016).
Leake, S. J. et al. The Nanodiffraction beamline ID01/ESRF: a microscope for imaging strain and structure. J. Synchrotron Rad. 26, 571â584 (2019).
Favre-Nicolin, V., Leake, S. & Chushkin, Y. Free log-likelihood as an unbiased metric for coherent diffraction imaging. Sci. Rep. 10, 2664 (2020).
Luke, D. R. Relaxed averaged alternating reflections for diffraction imaging. Inverse Probl. 21, 37â50 (2004).
Gerchberg, R. & Saxton, O. A practical algorithm for the determination of the phase from image and diffraction plane pictures. Optik 35, 237â246 (1972).
Fienup, J. R. & Wackerman, C. C. Phase-retrieval stagnation problems and solutions. J. Opt. Soc. Am. A, JOSAA 3, 1897â1907 (1986).
Marchesini, S. et al. X-ray image reconstruction from a diffraction pattern alone. Phys. Rev. B 68, 140101 (2003).
Yang, W. et al. Coherent diffraction imaging of nanoscale strain evolution in a single crystal under high pressure. Nat. Commun. 4, (2013).
Chapman, H. N. et al. High-resolution ab initio three-dimensional x-ray diffraction microscopy. J. Opt. Soc. Am. A, JOSAA 23, 1179â1200 (2006).
Giannozzi, P. et al. QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials. J. Phys.: Condens. Matter 21, 395502 (2009).
Vanderbilt, D. Soft self-consistent pseudopotentials in a generalized eigenvalue formalism. Phys. Rev. B 41, 7892â7895 (1990).
Grimme, S., Antony, J., Ehrlich, S. & Krieg, H. A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu. J. Chem. Phys. 132, 154104 (2010).
Stull, D. R., Prophet, H., United States, & National Bureau of Standards. JANAF thermochemical tables. (U.S. Dept. of Commerce, National Bureau of Standards, 1971).
Barmparis, G. D. & Remediakis, I. N. Dependence on CO adsorption of the shapes of multifaceted gold nanoparticles: A density functional theory. Phys. Rev. B 86, 085457 (2012).
Bengtsson, L. Dipole correction for surface supercell calculations. Phys. Rev. B 59, 12301â12304 (1999).
Favre-Nicolin, V. et al. PyNX: high-performance computing toolkit for coherent X-ray imaging based on operators. J. Appl Cryst. 53, 1404â1413 (2020).
J. Carnis, S. J. Leake, The BCDI Python package can be downloaded from PyPi, (https://pypi.org/project/bcdi/) or GitHub (https://github.com/carnisj/bcdi), https://doi.org/10.5281/zenodo.3257616 (2021).
Acknowledgements
The authors are grateful to the European Synchrotron Radiation Facility for allocating beamtime. BCDI measurements were performed at beamline ID01. We thank Hamid Djazouli for his excellent support during the preparation of the experiment. Laue microdiffraction measurements were measured at beamline BM32. The authors would like to thank Vincent Favre-Nicolin for his continuous improvement of the PyNX package used here for phase retrieval. E.J.M.H. acknowledges financial support of NWO TOP and KNAW CEP grants. M.-I.R. acknowledges financial support from ANR Charline (ANR-16-CE07-0028-01) and ANR Tremplin ERC (ANR-18-ERC1-0010-01). This project has received funding from the European Research Council (ERC) under the European Unionâs Horizon 2020 research and innovation programme (grant agreement No. 818823). N.G., E.A. and E.R. wish to thank the support by a grant from the Ministry of Science & Technology, Israel & Franceâs âCentre National de la Recherche Scientifique (CNRS)â. The thin film processing was performed at the Micro-Nano Fabrication and Printing Unit (MNF&PU), Technion. The calculations presented in this paper were performed using the Froggy platform of the CIMENT infrastructure (https://ciment.ujf-grenoble.fr), which is supported by the Rhône-Alpes region (GRANT CPER07_13 CIRA) and the Equip@Meso project (ANR-10-EQPX-29-01) of the âProgramme Investissements dâAvenirâ supervised by the âAgence Nationale pour la Rechercheâ. This work was supported by the Netherlands Center for Multiscale Catalytic Energy Conversion (MCEC), an NWO Gravitation programme funded by the Ministry of Education, Culture and Science of the government of the Netherlands.
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J.C., L.G., F.O., J.P.H., S. Labat, J.-S.M. and M.-I.R. carried out the experiment. M.I.-R directed the project. J.C., M.-I.R., S. Labat analysed the data. J.C., M.-I.R, S. Labat, L.F., M.T., L.W., M.D., S.J.L., E.H., T.S. and O.T. interpreted the data. A.C. and L.F. performed electron microscopy measurements. A.K. and R.P. carried out DFT simulations. N.G., E.A. and E.R. prepared the samples. J.C. and M.-I.R. wrote the manuscript. All authors reviewed, discussed the manuscript and have given approval to its final version. The authors declare no competing interests.
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Carnis, J., Kshirsagar, A.R., Wu, L. et al. Twin boundary migration in an individual platinum nanocrystal during catalytic CO oxidation. Nat Commun 12, 5385 (2021). https://doi.org/10.1038/s41467-021-25625-0
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DOI: https://doi.org/10.1038/s41467-021-25625-0
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