TEMPERATURAS EBULLICIÓN (EC.

ANT
METANOL (1) BENCENO (2) T.eb (1) ºC
A= 8.0724 A= 6.90565 T.eb (2) ºC
B= 1574.99 B= 1211.033
C= 238.87 C= 220.79

PRESION (mmHg) 301

β x(1) TEMP. (ºC)

0 52.760973
-8.4203077 0.1 39.6509556
-3.6432512 0.2 37.5128219
-1.8631574 0.3 36.8166723
-0.8136529 0.4 36.4733278
0.00971474 0.5 36.3458921
0.83722139 0.6 36.2557348
1.90362062 0.7 36.4055885
3.74020025 0.8 36.9000641
8.83794029 0.9 38.2875175
1 42.688255

MODELO WILSON
COEFICIENTES (BIBLIOGRAFÍA)
A12 1734.42
A21 183.04

COMPARACIÓN COEFICIENTES ACTIVIDAD METANOL

6

5
f(x) = -0.4061400665 l n(x) - 1.0374068104
experimental

4 R² = 0.985466821

2
 6

5
f(x) = -0.4061400665 l n(x) - 1.0374068104

γ experimental
4 R² = 0.985466821

0
0 0.002 0.004 0.006 0.008 0.01 0.012 0.014 0.016

γ calculado

APARTADO A) CURVAS EQUILIBRIO LÍQUIDO-VAPOR PARA METANOL(1)+B

54

52

50

48
Temperatura (ºC)

46

44

42

40

38

36

34
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

x(1),y(1)
 APARTADO B)
PERATURAS EBULLICIÓN (EC. ANTOINE) F.O.
42.6882549682 301 Trocío 45.4370457
52.7609729648 301 Tburbuja 37.5128061
Tflash 42
F (kmol/h) 1000
q (=L/F) 0.3265921
L (kmol/h) 326.592097
V(kmol/h) 673.407903
z(1)= 0.2
z(2)= 0.8

x(2) γ(1) calc. γ(1) exp γ(2) calc. γ(2) exp P(vap)(1) y(1) TEMP. (ºC)
1 0 52.760973
0.9 3.28E-07 5.06 0.12086418 1.04 261.5563 0.43969264 39.6509556
0.8 3.91E-05 3.24 0.05539675 1.12 236.4932 0.50912819 37.5128219
0.7 2.23E-04 2.36 0.031447 1.24 228.7857 0.53814044 36.8166723
0.6 5.90E-04 1.86 0.01875839 1.41 225.0635 0.55630301 36.4733278
0.5 1.16E-03 1.54 0.01081454 1.64 223.6950 0.57224311 36.3458921
0.4 2.01E-03 1.33 0.00548989 1.97 222.7312 0.59049664 36.2557348
0.3 3.40E-03 1.18 0.00205413 2.45 224.3352 0.61561747 36.4055885
0.2 6.08E-03 1.08 0.00034221 3.19 229.6976 0.65933131 36.9000641
0.1 1.39E-02 1.02 2.1306E-06 4.45 245.3279 0.74820943 38.2875175
0 1 42.688255

COMPARACIÓN COEFICIENTES ACTIVIDAD BENCENO

5
4.5
f(x) = -0.3365821993 ln(x) + 0.2091787358
perimental

4 R² = 0.9807086411
3.5
3
2.5
2
1.5
1
 COMPARACIÓN COEFICIENTES ACTIVIDAD BENCENO
5
4.5
f(x) = -0.3365821993 ln(x) + 0.2091787358

γ experimental
4 R² = 0.9807086411
3.5
3
2.5
2
1.5
1
0.5
0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14

γ calculado

APOR PARA METANOL(1)+BENCENO(2) A 301 mmHg

0.5 0.6 0.7 0.8 0.9 1

x(1),y(1)
ARTADO B)
F.O P(vap 42ºC)(1)Pa P(vap 42ºC)(2)Pa
1.00000032 291.6480955163 198.2814570806
0.99999929
<--------------- NO TIENE SENTIDO

0.1928748

EXPLICACIÓN EN PDF. COMPOSICIONES GRÁFICA x(1)

OBTENIDAS GRÁFICAMENTE Y LUEGO
BALANCE DE MATERIA Z(1) 0.2 0.09

F.O. ALIMENTACIÓN 1000

LÍQUIDO 620.689655
301 VAPOR 379.310345
300.999999
301
301
301
301.000001
301
300.999999
301
y(1)
0.38

kmol/h
kmol/h
kmol/h