Problems Part 3 Complex Reactions
Problems Part 3 Complex Reactions
Problems Part 3 Complex Reactions
∞ ∞ 0.078
Calculemos ∞ :
t, h 71.8 145.5 215.8 264.3 333.3 383.5 478.3 506.0
∞ 0.199 0.137 0.096 0.074 0.052 0.043 0.028 0.022
Calculemos k1+k2:
∞
ln
∞
t, h 71.8 145.5 215.8 264.3 333.3 383.5 478.3
0.00515 0.00511 0.00509 0.00514 0.00514 0.00496 0.00487
Dejamos el ultimo valor y calculamos el promedio:
0.005126
∞ 0 0.288
3.692
∞ 0.366 0.288
0.005126
3.692
k2
CH4 + CO2
CH3COOH CH3CO + H2O.
Solución.
0.8 0.8
7.96
0.8
3.54 , 4.42 .
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Solución.
En 0.02 s se descompone:
4 3.114 0.886
1 1
ln ln
1 4
ln 75.37
0.02 0.886
Resolvemos el sistema de ecuaciones:
1
1.4
2
75.37
43.96 , 31.4
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Solución.
2
ln
1
2 1
ln 0.01
4.65
0.01 1
.
0.01 . 0.01 .
0.955
ln 100
0.0465
100 1
100 0.01 .
0.00955
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Solución.
ln 2 ln 2
0.0866
8
1 2 3
1
1
A B
t=0 5 0
t=10 min 4 1
1 0.08664 0.08664
. 0.00299
1 5 1 2.898
2
6
3
6 0.05674
1
7 3 0.05674 3 0.00810
0.00299
0.0486
0.00810