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Denise Kulhanek

Obtaining geochemical profiles using X-ray fluorescent (XRF) techniques has become a standard procedure in many sediment core studies. The resulting datasets are not only important tools for palaeoclimatic and palaeoceanographic... more
Obtaining geochemical profiles using X-ray fluorescent (XRF) techniques has become a standard procedure in many sediment core studies. The resulting datasets are not only important tools for palaeoclimatic and palaeoceanographic reconstructions, but also for stratigraphic correlation. The International Ocean Discovery Program (IODP) has therefore recently introduced shipboard application of a handheld XRF device, making geochemical data directly available to the science party. In all XRF scanning techniques, the physical properties of wet core halves cause substantial analytical deviations. In order to obtain estimates of element concentrations (e.g. for quantitative analyses of fluxes or mass-balance calculations), a calibration of the scanning data is required. We test whether results from the handheld XRF analysis on discrete samples are suitable for calibrating scanning data. Log-ratios with Ca as a common denominator were calculated. The comparison between the handheld device a...
We investigate the phased evolution and variation of the South Asian monsoon and resulting weathering intensity and physical erosion in the Himalaya-Karakoram Mountains since late Pliocene time (c. 3.4 Ma) using a comprehensive approach.... more
We investigate the phased evolution and variation of the South Asian monsoon and resulting weathering intensity and physical erosion in the Himalaya-Karakoram Mountains since late Pliocene time (c. 3.4 Ma) using a comprehensive approach. Neodymium and strontium isotopic compositions and single-grain zircon U-Pb age spectra reveal the sources of the deposits in the east Arabian Sea, and show a combination of sources from the Himalaya and the Karakoram-Kohistan-Ladakh Mountains, with sediments from the Indian Peninsula such as the Deccan Traps or Craton. We interpret shifts in the sediment sources to have been forced by sea-level changes that correlate with South Asian monsoon rainfall variation since late Pliocene time. We collected 908 samples from the International Ocean Discovery Program Hole U1456A, which was drilled in the east Arabian Sea. Time series of hematite content and grain size of the sediments were examined downcore. We found South Asian monsoon precipitation and weathering intensity experienced three phases from late Pliocene time. Lower monsoon precipitation, with a lower variability and strong weathering intensity, occurred during 3.4-2.4 Ma; an increased and more variable South Asian monsoon rainfall, along with strengthened but fluctuating weathering intensity, occurred at 1.8-1.1 Ma; and a reduced rainfall with lower South Asian monsoon precipitation variability and moderate weathering intensity marked the period 1.1-0.1 Ma. Maximum entropy spectral analysis and wavelet transform show that there were orbital-dominated cycles of periods c. 100 and c. 41 ka in these proxy-based time series. We propose that the monsoon, sea level, global temperature and insolation together forced the weathering and erosion in SW Asia.
Obtaining geochemical profiles using X-ray fluorescent (XRF) techniques has become a standard procedure in many sediment core studies. The resulting datasets are not only important tools for palaeoclimatic and palaeoceanographic... more
Obtaining geochemical profiles using X-ray fluorescent (XRF) techniques has become a standard procedure in many sediment core studies. The resulting datasets are not only important tools for palaeoclimatic and palaeoceanographic reconstructions, but also for stratigraphic correlation. The International Ocean Discovery Program (IODP) has therefore recently introduced shipboard application of a handheld XRF device, making geochemical data directly available to the science party. In all XRF scanning techniques, the physical properties of wet core halves cause substantial analytical deviations. In order to obtain estimates of element concentrations (e.g. for quantitative analyses of fluxes or mass-balance calculations), a calibration of the scanning data is required. We test whether results from the handheld XRF analysis on discrete samples are suitable for calibrating scanning data. Log-ratios with Ca as a common denominator were calculated. The comparison between the handheld device and conventional measurements show that the latter provide high-quality data describing Al, Si, K, Ca, Ti, Mn, Fe, Zn, Rb and Sr content (R 2 compared with conventional measurements: ln(Al/Ca)=0.99, ln(Si/Ca)=0.98, ln(K/Ca)=0.99, ln(Ti/Ca)=0.99, ln(Mn/Ca)=0.99, ln(Fe/Ca)=0.99, ln(Zn/Ca)=0.99 and ln(Sr/Ca)=0.99). Our results imply that discrete measurements using the shipboard handheld analyser are suitable for the calibration of XRF scanning data. Our test was performed on down-core sediments from IODP Expedition 355 that display a wide variety of lithologies of both terrestrial and marine origin. The implication is that our findings are valid on a general scale and that shipboard handheld XRF analysis on discrete samples should be used for calibrating XRF scanning data.
Two-dimensional flexural backstripping and thermal modelling (assuming laterally variable stretching) is applied along regional depth-converted interpreted seismic profiles from the Laxmi Basin in the Arabian Sea. Results from reverse... more
Two-dimensional flexural backstripping and thermal modelling (assuming laterally variable stretching) is applied along regional depth-converted interpreted seismic profiles from the Laxmi Basin in the Arabian Sea. Results from reverse post-rift flexural modelling reveal considerable basin-wide subsidence in response to the crustal geodynamics during and after the last extensional phase. Unloading of the stratigraphy allows us to estimate the degree of laterally varying extension, assuming thermal subsidence and pure shear. High degrees of extension in the basin centre predict considerable water depths at the time of rift cessation, consistent with deep drilling data. We suggest that regional extension prior to Paleocene time could have fuelled variable subsidence in the Laxmi Basin but that extension is less than seen in typical oceanic litho-sphere. Volcanic loading by the seamounts shortly after extension has flexed the basin and implies an effective elastic thickness (T e) at that time of ∼6 km. Reconstruction of the seamount top near sea level at the end of emplacement indicates no major transient uplift potentially linked to the Deccan mantle plume activity. Backstripping of post-rift sediments from interpreted seismic profiles supports the presence of a hyper-thinned crust underneath the Laxmi Basin, with β factors reaching >7 in the basin centre and ∼3 across much of the basin width. Computations of decom-pacted sediment accumulation rates in light of new results from IODP Expedition 355 show that basin sedimentation peaked during early-middle Miocene time, possibly coeval with uplift and erosion of the Himalayan-Tibetan Plateau driven by strong summer monsoon rains.
The Arabian Sea in the northern Indian Ocean pre-serves regional sedimentary records of rifting, tectonic subsidence, and paleoceanographic history, and also provides archives of long-term erosion of the Himalaya since the start of... more
The Arabian Sea in the northern Indian Ocean pre-serves regional sedimentary records of rifting, tectonic subsidence, and paleoceanographic history, and also provides archives of long-term erosion of the Himalaya since the start of collision between In?dia and Eurasia. Investigations reveal that drilling in this region can provide erosion records through analyses of the sediment cores, along with providing age control for the regional seismic stratigraphy. It is only by quantifying the volume of sedi?ment deposited in the fan that researchers can mass balance the volume of bedrock eroded from the mountains, constrained by thermochronology, with the volume of eroded rock deposited in the offshore and in the foreland basin.
Research Interests:
The Indian (southwest) summer monsoon is one of the most intense climatic phenomena on Earth. Its long-term development has been linked to the growth of high topography in South and Central Asia. The Indian continental margin, adjoining... more
The Indian (southwest) summer monsoon is one of the most intense climatic phenomena on Earth. Its long-term development has been linked to the growth of high topography in South and Central Asia. The Indian continental margin, adjoining the Arabian Sea, offers a unique opportunity to investigate tectonic–climatic interactions and the net impact of these processes on weathering and erosion of the western Himalaya. During International Ocean Discovery Program Expedition 355, two sites (U1456 and U1457) were drilled in Laxmi Basin in the eastern Arabian Sea to document the coevolution of mountain building, weathering, erosion, and climate over a range of timescales. In addition, recovering basement from the eastern Arabian Sea provides constraints on the early rifting history of the western continental margin of India with special emphasis on continental breakup between India and the Seychelles and its relationship to the plume-related volcanism of the Deccan Plateau.
Drilling and coring operations during Expedition 355 recovered sediment from Sites U1456 and U1457 in the Laxmi Basin, penetrating 1109.4 and 1108.6 m below seafloor (mbsf), respectively. Drilling reached sediment dated to 13.5–17.7 Ma (late early to early middle Miocene) at Site U1456, although with a large hiatus between the lowermost sediment and overlying deposits dated to <10.9 Ma. At Site U1457, a much longer hiatus occurs near the base of the cored section, spanning from 10.9 to ~62 Ma. At both sites, hiatuses span ~8.2–9.2 and ~3.6–5.6 Ma, with a possible condensed section spanning ~2.0–2.6 Ma, although the total duration for each hiatus is slightly different between the two sites.
A major submarine fan draining the western Himalaya and Karakoram must have been supplying sediment to the eastern Arabian Sea since at least ~17 Ma. Sand mineral assemblages indicate that the Greater Himalayan Crystalline Sequence was fully exposed to the surface by this time. Most of the recovered sediment appears to be derived from the Indus River and includes minerals that are unique to the Indus Suture Zone, in particular glaucophane and hypersthene, most likely originating from the structural base of the Kohistan arc. Pliocene sandy intervals at Site U1456 were deposited in lower fan “sheet lobe” settings, with intervals of basin plain turbidites separated by hemipelagic muddy sections deposited during the Miocene. Site U1457 is more distal in facies, reflecting its more marginal setting. No major active lobe appears to have affected the Laxmi Basin since the Middle Pleistocene (~1.2 Ma).
We succeeded in recovering sections spanning the 8 Ma climatic transition, when monsoon intensity is believed to have changed strongly, although the nature of this change awaits postcruise analysis. We also recovered sediment from a large mass transport deposit measuring ~330 and ~190 m thick at Sites U1456 and U1457, respectively. This section includes an upper sequence of slump-folded muddy and silty rocks, as well as underlying calcarenites and limestone breccias, together with smaller amounts of volcanic clasts, all of which are likely derived from the western Indian continental shelf. Identification of similar facies on the regional seismic lines in Laxmi Basin suggests that these deposits form parts of one of the world’s largest mass transport deposits.
Coring of igneous basement was successful at Site U1457. Recovery of massive basalt and associated volcaniclastic sediment at this site should address the key questions related to rifting and volcanism associated with formation of Laxmi Basin. Geochemical analysis is required to understand the petrogenesis and thus the tectonic setting of volcanism that will reveal whether it is oceanic basalt or volcanic rock contaminated by underlying continental crust or continental flood basalt. However, the fact that the lavas are massive and have few vesicles implies water depths of eruption likely deeper than 2000 m. This precludes opening of the basin in the presence of a major mantle thermal anomaly, such as that associated with the Deccan Large Igneous Province. Other observations made at the two sites during Expedition 355 provide vital constraints on the rift history of this margin. Heat flow measurements at the two drill sites were calculated to be ~57 and ~60 mW/m2. Such heat flow values are compatible with those observed in average oceanic crust of 63–84 Ma age, as well as with the presence of highly extended continental crust. Postcruise analyses of the more than ~1722 m of core will provide further information about the nature of tectonic–climatic interactions in this global type area for such studies.
Research Interests:
The late Miocene is a time of strong environmental change in SW Asia. Himalayan foreland stable isotope data show a shift in the dominant vegetation of the flood plains away from trees and shrubs towards more C4 grasslands at a time when... more
The late Miocene is a time of strong environmental change in SW Asia. Himalayan foreland stable isotope data show a shift in the dominant vegetation of the flood plains away from trees and shrubs towards more C4 grasslands at a time when oceanic upwelling increased along the Oman margin. We present integrated geochemical and colour spectral records from International Ocean Discovery Program Site U1456 in the eastern Arabian Sea to reconstruct changing chemical weathering and erosion, as well as relative humidity during this climatic transition. Increasing hematite/goethite ratios derived from spectral data are consistent with long-term drying after c. 7.7 Ma. Times of dry conditions are largely associated with weaker chemical alteration measured by K/Rb and reduced coarse clastic flux, constrained by Si/Al and Zr/Al. A temporary phase of increased humidity from 6.3 to 5.95 Ma shows a reversal to stronger weathering and erosion. Wetter conditions can result in both more and less alteration due to the nonlinear relationship between weathering rates, precipitation and sediment transport times. Trends in relative aridity do not follow existing palaeoceanographic records and are not apparently linked to changes in Tibetan or Himalayan elevation, but more closely correlate with global cooling. An apparent opposing trend in the humidity evolution in the Indus compared to southern China, as tracked by spectrally estimated hematite/goethite, likely reflects differences in the topography in the Indus compared to the Pearl River drainage basins, as well as the generally wetter climate in southern China.