Three simple semiconducting acceptor–donor–acceptor (A–D–A) small molecules based on an electron-rich (3,4-ethylenedioxythiophene) EDOT central core have been synthesised (DIN-2TE, DRH-2TE, DECA-2TE) and characterised. Organic... more
Three simple semiconducting acceptor–donor–acceptor (A–D–A) small molecules based on an electron-rich (3,4-ethylenedioxythiophene) EDOT central core have been synthesised (DIN-2TE, DRH-2TE, DECA-2TE) and characterised. Organic photovoltaic (OPV) devices incorporating these materials have been prepared and evaluated. The physical properties of the molecules were characterised by TGA, DSC, UV/vis spectroscopy and cyclic voltammetry. The optical HOMO–LUMO energy gaps of the molecules in the solid state were in the range 1.57–1.82 eV, and in solution 1.88–2.04 eV. Electrochemical HOMO–LUMO energy gaps determined by cyclic voltammetry were found to be in the range 1.97–2.31 eV. The addition of 1% 1,8-diiodooctane (DIO) to photoactive blends of the A–D–A molecules and PC71BM more than doubled the power conversion efficiency (PCE) in the case of DRH-2TE:PC71BM devices to 1.36%.
The inefficient collection of solid wastes is a global phenomenon that has received attention in recent years for the ever-increasing annual waste generation records. However, indicators to the effective application of the amassing routs... more
The inefficient collection of solid wastes is a global phenomenon that has received attention in recent years for the ever-increasing annual waste generation records. However, indicators to the effective application of the amassing routs are missing. Hence, the generally accepted source-sorting model was explored to identify the determinants that will enhance source separation of wastes at the workplace. This paper presents a foremost report on the indicators to an effective operation of solid wastes source segregation. A quantitatively examined data was collected in sixty-six working days during a monitoring and evaluation process of twenty sets of twin-dustbins that were located at the study area. The generated solid wastes were commonly sorted (65%) in comparison with the mixed collection. Most of the wastes were separated on the third month (80%) of education compared to the first (54%) and second months (61%). Wednesday displayed the working day with the utmost sorted wastes (7...
The kinetic method was applied to differentiate and quantify mixtures of regioisomeric triacylglycerols (TAGs) by generating and mass selecting alkali ion bound metal dimeric clusters with a TAG chosen as reference (ref) and examining... more
The kinetic method was applied to differentiate and quantify mixtures of regioisomeric triacylglycerols (TAGs) by generating and mass selecting alkali ion bound metal dimeric clusters with a TAG chosen as reference (ref) and examining their competitive dissociations in a quadrupole ion trap mass spectrometer. This methodology readily distinguished pairs of regioisomers (AAB/ABA) such as LLO/LOL, OOP/OPO and SSP/SPS and consequently distinguished sn-1/sn-3, sn-2 substituents on the glycerol backbone. The dimeric complex ions [ref, Li, TAG (AAB and/or ABA) ] + generated by electrospray ionization mass spectrometry were subjected to collision induced dissociation causing competitive loss of either the neutral TAG reference (ref) leading to [Li(AAB and/or ABA)] + or the neutral TAG molecule (TAG (AAB and/or ABA)) leading to [ref, Li] +. The ratio of the two competitive dissociation rates, defined by the product ion branching ratio (R iso), was related via the kinetic method to the regioisomeric composition of the investigated TAG mixture. In this work, a linear correlation was established between composition of the mixture of each TAG regioisomer and the logarithm of the branching ratio for competitive fragmentation. Depending on the availability of at least one TAG regioisomer as standard, the kinetic method and the standard additions method led to the quantitative analysis of natural TAG mixtures.
Tubers play a significant role in human diet. Samples of tubers were obtained from five different markets from Kumasi. Pulvurised samples were digested with concentrated nitric acid. Heavy metals Zn, Fe, Cu and Cd were analysed using... more
Tubers play a significant role in human diet. Samples of tubers were obtained from five different markets from Kumasi. Pulvurised samples were digested with concentrated nitric acid. Heavy metals Zn, Fe, Cu and Cd were analysed using Atomic Absorption Spectroscopy in four tubers which include yam, cassava, cocoyam and sweet potatoes. The metals were analysed using Atomc Absorption Spectrophotometer 220. The concentration ranges were 0.862 to 2.144 mg/kg for Cu, 0.476 to 0.778 mg/kg for Cd, 11.246 to 58.728 mg/kg for Zn and 27.918 to 45.872 mg/kg for Fe. Health risk assessment showed that consumers are not in danger as far as these metals are concerned.
Soil variation and its effect on the physical and chemical properties of shea butter, a product from the nut of the shea tree, were investigated in four districts of the northern region of Ghana. Thirty-six samples of freshly extracted... more
Soil variation and its effect on the physical and chemical properties of shea butter, a product from the nut of the shea tree, were investigated in four districts of the northern region of Ghana. Thirty-six samples of freshly extracted shea butter together with 36 soil samples were collected and stored at 25°C for analysis. Clinical analysis of soil properties and the clinical analysis of the physical and chemical properties of shea butter were investigated using standard methods. The results showed that the soil organic matter (1.78%), soil organic carbon (1.03%), soil nitrogen (0.10%) and sandy soil have significant positive impact on the fat content (48.69%) of the shea kernel, and the soil cation exchange capacity (6.61%) has a negative effect. Soil properties do not have an impact on the chemical properties of the shea butter. This study thus concludes that apart from other factors such as the method adopted for the extraction of shea butter, soil composition contributes significantly to the quantity of shea butter extracted from the shea kernels.
The kinetic method was applied to differentiate and quantify mixtures of regioisomeric triacylglycerols (TAGs) by generating and mass selecting alkali ion bound metal dimeric clusters with a TAG chosen as reference (ref) and examining... more
The kinetic method was applied to differentiate and quantify mixtures of regioisomeric triacylglycerols (TAGs) by generating and mass selecting alkali ion bound metal dimeric clusters with a TAG chosen as reference (ref) and examining their competitive dissociations in a quadrupole ion trap mass spectrometer. This methodology readily distinguished pairs of regioisomers (AAB/ABA) such as LLO/LOL, OOP/OPO and SSP/SPS and consequently distinguished sn-1/sn-3, sn-2 substituents on the glycerol backbone. The dimeric complex ions [ref, Li, TAG (AAB and/or ABA) ] + generated by electrospray ionization mass spectrometry were subjected to collision induced dissociation causing competitive loss of either the neutral TAG reference (ref) leading to [Li(AAB and/or ABA)] + or the neutral TAG molecule (TAG (AAB and/or ABA)) leading to [ref, Li] +. The ratio of the two competitive dissociation rates, defined by the product ion branching ratio (R iso), was related via the kinetic method to the regioisomeric composition of the investigated TAG mixture. In this work, a linear correlation was established between composition of the mixture of each TAG regioisomer and the logarithm of the branching ratio for competitive fragmentation. Depending on the availability of at least one TAG regioisomer as standard, the kinetic method and the standard additions method led to the quantitative analysis of natural TAG mixtures.
As a measure to prevent cardiovascular diseases and enhance in-utero development of the foetus, adequate omega-3 intake has been recommended. This has led to the manufacture of omega-3 supplements by various pharmaceutical companies and... more
As a measure to prevent cardiovascular diseases and enhance in-utero development of the foetus, adequate omega-3 intake has been recommended. This has led to the manufacture of omega-3 supplements by various pharmaceutical companies and these products have flooded the market. Coldwater fishes are the primary sources of the omega-3 food supplements but these fishes are known to have high levels of mercury in them. There is therefore the potential of mercury poisoning in the course of people taking the omega-3 food supplements. Mercury levels in ten products of Omega-3 food supplements have been determined in order to ascertain their safety for human consumption. The mean mercury levels determined for the ten brands were 0.0170.003 µg/g, 0.093 0.002 µg/g, 0.0210.003 µg/g, 0.2730.005 µg/g, 0.1230.004 µg/g, 0.06580.001 µg/g, 0.0180.005 µg/g, 0.0260.008 µg/g, 0.4280.002 µg/g, 0.4280.002 µg/g, 0.0290.004 µg/g. All the levels of mercury determined were within the acceptable limits stipulated by Food and Agriculture Organization and World Health Organization, and therefore do not pose any health threat to consumers.
Background. Anthropogenic activities such as artisanal mining pose a major environmental health concern due to the potential for discharge of toxic metals into the environment. Objectives. To determine the distribution and pollution... more
Background. Anthropogenic activities such as artisanal mining pose a major environmental health concern due to the potential for discharge of toxic metals into the environment. Objectives. To determine the distribution and pollution patterns of arsenic (As), iron (Fe), nickel (Ni), cobalt (Co), chromium (Cr), manganese (Mn), copper (Cu) and zinc (Zn) in the topsoil of a mining community in Ghana, along with potential human health risks and in vitro bioaccessibility. Methods. Concentrations of metals were determined using X-ray fluorescence techniques and validated using inductively coupled plasma-mass spectrometry. Results. Concentrations of the metals in topsoil were in the order of magnitude of Cu (31.38 mg/kg) < Ni (45.39 mg/kg) < As (59.66 mg/kg) < Cr (92.87 mg/kg) < Zn (106.98 mg/kg) < Mn (1195.49 mg/kg) < Fe (30061.02 mg/kg). Geo-statistical and multivariate analyses based on hazard indices including contamination, ecological risks, geo-accumulation, and poll...
Basil (Ocimum basilicum Linn.) is a plant that has found use in traditional medicine and household remedy against human ailments. The present study aimed at investigating hexane and ethanol fruit extracts of Ocimum basilicum Linn. for... more
Basil (Ocimum basilicum Linn.) is a plant that has found use in traditional medicine and household remedy against human ailments. The present study aimed at investigating hexane and ethanol fruit extracts of Ocimum basilicum Linn. for their phytoconstituents and anti-inflammatory, antioxidant, and anthelmintic activities. Phytochemical screenings were performed using standard protocols. Anti-inflammatory activities were assessed using the egg albumin denaturation method, while the antioxidant activities of the extracts were determined using DPPH scavenging, total antioxidant capacity (TAC), and hydrogen peroxide (H2O2) assays. In vitro anthelmintic activity of both extracts was investigated against Eudrilus eugeniae (Earthworms). Column chromatography was employed to separate the least polar fraction A, using hexane as the mobile phase, which was analyzed using FTIR analysis. The preliminary phytochemical screening revealed the presence of alkaloids, phenols, saponins, glycosides, s...
