Iron Sulfide

A number of features of living systems, reversible interactions and weak bonds underlying motor-dynamics; gel-sol transitions; cellular connected fractal organization; asymmetry in interactions and organization; quantum coherent phenomena; to name some, can have a natural accounting via physical interactions, which we therefore seek to incorporate by expanding the horizons of “chemistry-only” approaches to the origins of life. It is suggested that the magnetic “face” of the minerals from the inorganic world, recognized to have played a pivotal role in initiating Life, may throw light on some of these issues. A magnetic environment in the form of rocks in the Hadean Ocean could have enabled the accretion and therefore an ordered confinement of super-paramagnetic colloids within a structured phase. A moderate H-field can help magnetic nanoparticles to not only overcome thermal fluctuations but also harness them. Such controlled dynamics brings in the possibility of accessing quantum effects, which together with frustrations in magnetic ordering and hysteresis (a natural mechanism for a primitive memory) could throw light on the birth of biological information which, as Abel argues, requires a combination of order and complexity. This scenario gains strength from observations of scale-free framboidal forms of the greigite mineral, with a magnetic basis of assembly. And greigite’s metabolic potential plays a key role in the mound scenario of Russell and coworkers-an expansion of which is suggested for including magnetism.

Fossil insects from the Lower Cretaceous (Aptian) Crato Formation of north-east Brazil are preserved as goethite replacements in laminated limestones of lacustro-lagoonal origin. They display remarkable degrees of morphological detail down to the macromolecular level in some examples. We document the fidelity of preservation and reveal an astonishing variety of morphological detail comparable in some instances with that found in amber inclusions.

We have determined the superconducting and magnetic properties of a hydrothermally synthesized powder sample of tetragonal FeS using muon spin rotation (μSR). The superconducting properties are entirely consistent with those of a recently published study, showing fully gapped behavior and giving a penetration depth of λ ab = 204(3) nm. However, our zero-field μSR data are rather different and indicate the presence of a small, nonsuperconducting magnetic phase within the sample. These results highlight that sample-to-sample variations in magnetism can arise in hydrothermally prepared phases, but interestingly the superconducting behavior is remarkably insensitive to these variations.

Iron sulfides have emerged as a fascinating class of materials in electromagnetics and catalysis areas, which however are challenging in first-principles modeling because of the strongly-correlated interactions between Fe 3d and S 3p electrons. Here, we assess the performances of 14 density functionals on the structural, electronic, and magnetic properties of five iron sulfides. The PBE + U with U eff = 2.0 eV has the overall best performance. After evaluating functionals and obtaining reliable properties, our final goal is from predicting to correlating in order to do high throughput screening for the systems since the complex structures and phases of iron sulfides, to put it in another way, to hunting a reliable descriptor for predicting their properties. In the work, we demonstrate that the crystal orbital Hamilton population (COHP) and Bader charge of Fe atoms presents a good correlation with the empirical bond valence. Our results open a new avenue to effectively investigate phases and properties for various structures of iron sulfides. Indeed, the correlations between COHP/Bader charge and bond valence can be extended to other systems.

This paper, by experimentally investigating the influence of different corrosion product layers on the corrosion resistance of 13% chromium steel in HCl solution, describes the level of the corrosion rates induced by deposited iron sulfide and elemental sulfur layers on the steel surface. In order to facilitate the experiment numbers, three analytic prediction methods, which are the optimal solution, curve fitting and artificial neural network, were applied to predict the corrosion rates of 13% chromium steel. Results showed that the fitness between measured and predicted corrosion rates by curve fitting indicates a good correlation between experiments and developed model, however, the minimum deviation from the measured data was obtained with artificial neural network model which is insignificant compared to the deviation of the two other models

ABSTRACT Fossil insects from the Lower Cretaceous (Aptian) Crato Formation of north-east Brazil are preserved as goethite replacements in laminated limestones of lacustro-lagoonal origin. They display remarkable degrees of morphological detail down to the macromolecular level in some examples. We document the fidelity of preservation and reveal an astonishing variety of morphological detail comparable in some instances with that found in amber inclusions.

The inhalation of mineral particulates and other earth materials, such as coal, can initiate or enhance disease in humans. Workers in occupations with high particulate exposure, such as mining, are particularly at risk. The ability of a material to generate an inflammatory stress response (ISR), a measure of particle toxicity, is a useful tool in evaluating said exposure risk. ISR is defined as the upregulation of cellular reactive oxygen species (ROS) normalized to cell viability. This study compares the ISR of A549 human lung epithelial cells after exposure to well-characterized common metal-sulfide ore mineral separates. The evaluation of the deleterious nature of ore minerals is based on a range of particle loadings (serial dilutions of 0.002 m2/mL stock) and exposure periods (beginning at 30 minutes and measured systematically for up to 24 hours). There is a wide range in ISR values generated by the ore minerals. The ISR values produced by the sphalerite samples are within the range of inert materials. Arsenopyrite generated a small ISR that was largely driven by cell death. Galena showed a similar, but more pronounced response. Copper-bearing ore minerals generated the greatest ISR, both by upregulating cellular ROS and generating substantial and sustained cell death. Chalcopyrite and bornite, both containing ferrous iron, generated the greatest ISR overall. Particles containing Fenton metals as major constituents produce the highest ISR, while other heavy metals mainly generate cell death. This study highlights the importance of evaluating the chemistry, oxidation states and structure of a material when assessing risk management.