"Thermo-acoustic investigations of polymer solutions of Hydroxyl-terminated polybutadiene (HTPB) and Chlorobenzene, in the temperature range of 303 K to 323 K, have been done using ultrasonic velocity and density data taken from...
more"Thermo-acoustic investigations of polymer solutions of Hydroxyl-terminated polybutadiene (HTPB) and Chlorobenzene, in the temperature range of 303 K to 323 K, have been done using ultrasonic velocity and density data taken from literature. Various acoustical parameters such as molar sound velocity, molar adiabatic compressibility, acoustic impedance, van der Waal’s constants, free volume, internal pressure, and cohesive energy have been determined. A large number of thermo-dynamical parameters such as available volume, geometrical volume, space filling factor, intermolecular free length, relative association, surface tension, refractive index, molar refraction, pseudo-Gruneisen parameter and Debye temperature have been evaluated.
Schaaff’s Collision Factor Theory, Nomoto’s relation, Vandeal-Vangeel relation, Impedance dependent relation and Ideal mixing relation have been used to predict the values of ultrasonic velocities in the systems under study, within the temperature range 303 K - 323 K. The obtained results have been compared with the experimental results as available in literature. Several Excess parameters e.g. Excess Adiabatic Compressibility (KSE), Excess Isothermal Compressibility (KTE), Excess Intermolecular Free Length (LfE), Excess free volume (VfE), Excess Internal Pressure (PiE), Excess Wada’s Constant (WE), Excess Rao’s Constant (RE) and Excess pseudo-Gruneisen parameter (rE), have also been evaluated at several compositions of the polymer solutions in the temperature range under investigation. The variations of thermo-acoustic parameters of the polymer solution provide a deep insight into the nature, type and strength of inter molecular interactions prevalent in it. The non-ideal behavior of the solution has been explained in terms of the composition and temperature dependence of its acoustical and thermo-dynamical parameters.
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