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Search Results (333)

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Keywords = entropy production rate

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21 pages, 17363 KiB  
Article
Analysis of Flow Loss Characteristics of a Multistage Pump Based on Entropy Production
by Qi Meng, Guidong Li, Jieyun Mao, Danhua Zhao, Yutong Luo and Tengfei Hou
Water 2024, 16(20), 2974; https://doi.org/10.3390/w16202974 - 18 Oct 2024
Viewed by 377
Abstract
To reveal the internal flow loss characteristics of a multi-stage pump, the unsteady calculation of the internal flow field of a seven-stage centrifugal pump was carried out, and the entropy production theory and Q criterion were utilized to analyze the unsteady flow characteristics [...] Read more.
To reveal the internal flow loss characteristics of a multi-stage pump, the unsteady calculation of the internal flow field of a seven-stage centrifugal pump was carried out, and the entropy production theory and Q criterion were utilized to analyze the unsteady flow characteristics of each flow component under different flow rates. The research results show that as the flow rate increases, the entropy production value and the energy loss inside the flow components also increase accordingly. The viscous dissipation entropy production caused by fluid viscosity is very small, and the turbulent dissipation entropy production caused by turbulent fluctuations and wall dissipation entropy production are the main sources of energy loss. The impellers, diffusers, and outlet chamber are the main regions of energy loss in the multistage pump. The entropy production value of the first-stage impeller is significantly higher than that of other impellers, while the entropy production value of the first-stage diffuser is significantly lower than that of other diffusers. Through vortex structure analysis, it is found that the high entropy production regions in the impeller are concentrated in the impeller inlet area, the blade suction surface, and the impeller outlet area. Full article
(This article belongs to the Special Issue Design and Optimization of Fluid Machinery, 2nd Edition)
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21 pages, 6596 KiB  
Article
MRACNN: Multi-Path Residual Asymmetric Convolution and Enhanced Local Attention Mechanism for Industrial Image Compression
by Zikang Yan, Peishun Liu, Xuefang Wang, Haojie Gao, Xiaolong Ma and Xintong Hu
Symmetry 2024, 16(10), 1342; https://doi.org/10.3390/sym16101342 - 10 Oct 2024
Viewed by 887
Abstract
The rich information and complex background of industrial images make it a challenging task to improve the high compression rate of images. Current learning-based image compression methods mostly use customized convolutional neural networks (CNNs), which find it difficult to cope with the complex [...] Read more.
The rich information and complex background of industrial images make it a challenging task to improve the high compression rate of images. Current learning-based image compression methods mostly use customized convolutional neural networks (CNNs), which find it difficult to cope with the complex production background of industrial images. This causes useful information to be lost in the abundance of irrelevant data, making it difficult to accurately extract important features during the feature extraction stage. To address this, a Multi-path Residual Asymmetric Convolutional Compression Network (MRACNN) is proposed. Firstly, a Multi-path Residual Asymmetric Convolution Block (MRACB) is introduced, which includes the Multi-path Residual Asymmetric Convolution Down-sampling Module for down-sampling in the encoder to extract key features, and the Mult-path Residual Asymmetric Convolution Up-sampling Module for up-sampling in the decoder to recover details and reconstruct the image. This feature transfer and information flow enables the better capture of image details and important information, thereby improving the quality and efficiency of image compression and decompression. Furthermore, a two-branch enhanced local attention mechanisms, and a channel-squeezing entropy model based on the compression-based enhanced local attention module is proposed to enhance the performance of the modeled compression. Extensive experimental evaluations demonstrate that the proposed method outperforms state-of-the-art techniques, achieves superior Rate–Distortion Performance, and excels in preserving local details. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry in Neural Networks and Applications)
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19 pages, 327 KiB  
Article
Thermodynamically Consistent Evolution Equations in Continuum Mechanics
by Angelo Morro
Foundations 2024, 4(4), 494-512; https://doi.org/10.3390/foundations4040033 - 1 Oct 2024
Viewed by 481
Abstract
This paper addresses the modelling of material behaviour in terms of differential (or rate) equations. To comply with the objectivity principle, recourse is made to invariant fields in the Lagrangian description or to objective time derivatives in the Eulerian description. The thermodynamic consistency [...] Read more.
This paper addresses the modelling of material behaviour in terms of differential (or rate) equations. To comply with the objectivity principle, recourse is made to invariant fields in the Lagrangian description or to objective time derivatives in the Eulerian description. The thermodynamic consistency is investigated in terms of the Clausius–Duhem inequality with two unusual features. Firstly, the (non-negative) entropy production is viewed as a constitutive function per se. Secondly, the inequality is viewed as a constraint on the pertinent fields and it is solved by using a representation formula, which allows for the the admissibility of a class of models. For definiteness, models of heat conduction are established, within Lagrangian descriptions, while models of the Navier–Stokes–Voigt fluid are investigated within Eulerian descriptions. In connection with thermo-viscous fluids, evolution equations are investigated within the Eulerian description. It is shown that the thermodynamic consistency is compatible with both objective and non-objective evolution equations. Full article
(This article belongs to the Section Physical Sciences)
15 pages, 2173 KiB  
Article
Crystallization Kinetics of Tacrolimus Monohydrate in an Ethanol–Water System
by Suoqing Zhang, Jixiang Zhao, Ming Kong, Jiahui Li, Mingxuan Li, Miao Ma, Li Tong, Tao Li and Mingyang Chen
Crystals 2024, 14(10), 849; https://doi.org/10.3390/cryst14100849 - 28 Sep 2024
Viewed by 447
Abstract
Nucleation and growth during the crystallization process are crucial steps that determine the crystal structure, size, morphology, and purity. A thorough understanding of these mechanisms is essential for producing crystalline products with consistent properties. This study investigates the solubility of tacrolimus (FK506) in [...] Read more.
Nucleation and growth during the crystallization process are crucial steps that determine the crystal structure, size, morphology, and purity. A thorough understanding of these mechanisms is essential for producing crystalline products with consistent properties. This study investigates the solubility of tacrolimus (FK506) in an ethanol–water system (1:1, v/v) and examines its crystallization kinetics using batch crystallization experiments. Initially, the solubility of FK506 was measured, and classical nucleation theory was employed to analyze the induction period to determine interfacial free energy (γ) and other nucleation parameters, including the critical nucleus radius (r*), critical free energy (G*), and the molecular count of the critical nucleus (i*). Crystallization kinetics under seeded conditions were also measured, and the parameters of the kinetic model were analyzed to understand the effects of process states such as temperature on the crystallization process. The results suggested that increasing temperature and supersaturation promotes nucleation. The surface entropy factor (f) indicates that the tacrolimus crystal growth mechanism is a two-dimensional nucleation growth. The growth process follows the particle size-independent growth law proposed by McCabe. The estimated kinetic parameters reveal the effects of supersaturation, temperature, and suspension density on the nucleation and growth rates. Full article
(This article belongs to the Special Issue Crystallization Process and Simulation Calculation, Third Edition)
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18 pages, 12338 KiB  
Article
Effects of Mo Addition on Microstructure and Corrosion Resistance of Cr25-xCo25Ni25Fe25Mox High-Entropy Alloys via Directed Energy Deposition
by Han-Eol Kim, Jae-Hyun Kim, Ho-In Jeong, Young-Tae Cho, Osama Salem, Dong-Won Jung and Choon-Man Lee
Micromachines 2024, 15(10), 1196; https://doi.org/10.3390/mi15101196 - 27 Sep 2024
Viewed by 555
Abstract
Highly entropy alloys (HEAs) are novel materials that have great potential for application in aerospace and marine engineering due to their superior mechanical properties and benefits over conventional materials. NiCrCoFe, also referred to as Ni-based HEA, has exceptional low-temperature strength and microstructural stability. [...] Read more.
Highly entropy alloys (HEAs) are novel materials that have great potential for application in aerospace and marine engineering due to their superior mechanical properties and benefits over conventional materials. NiCrCoFe, also referred to as Ni-based HEA, has exceptional low-temperature strength and microstructural stability. However, HEAs have limited corrosion resistance in some environments, such as a 3.5 wt% sodium chloride (NaCl) solution. Adding corrosion-resistant elements such as molybdenum (Mo) to HEAs is expected to increase their corrosion resistance in a variety of corrosive environments. Metal additive manufacturing reduces production times compared to casting and eliminates shrinkage issues, making it ideal for producing homogeneous HEA. This study used directed energy deposition (DED) to create Cr25-xCo25Ni25Fe25Mox (x = 0, 5, 10%) HEAs. Tensile strength and potentiodynamic polarization tests were used to assess the materials’ mechanical properties and corrosion resistance. The mechanical tests revealed that adding 5% Mo increased yield strength (YS) by 20.1% and ultimate tensile strength (UTS) by 9.5% when compared to 0% Mo. Adding 10% Mo led to a 32.5% increase in YS and a 20.4% increase in UTS. Potentiodynamic polarization tests were used to assess corrosion resistance in a 3.5-weight percent NaCl solution. The results showed that adding Mo significantly increased initial corrosion resistance. The alloy with 5% Mo had a higher corrosion potential (Ecorr) and a lower current density (Icorr) than the alloy with 0% Mo, indicating improved initial corrosion resistance. The alloy containing 10% Mo had the highest corrosion potential and the lowest current density, indicating the slowest corrosion rate and the best initial corrosion resistance. Finally, Cr25-xCo25Ni25Fe25Mox (x = 0, 5, 10%) HEAs produced by DED exhibited excellent mechanical properties and corrosion resistance, which can be attributed to the presence of Mo. Full article
(This article belongs to the Special Issue Future Prospects of Additive Manufacturing)
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18 pages, 1333 KiB  
Article
Strain-Rate and Stress-Rate Models of Nonlinear Viscoelastic Materials
by Claudio Giorgi and Angelo Morro
Mathematics 2024, 12(19), 3011; https://doi.org/10.3390/math12193011 - 26 Sep 2024
Viewed by 446
Abstract
The paper is devoted to the modeling of nonlinear viscoelastic materials. The constitutive equations are considered in differential form via relations between strain, stress, and their derivatives in the Lagrangian description. The thermodynamic consistency is established by using the Clausius–Duhem inequality through a [...] Read more.
The paper is devoted to the modeling of nonlinear viscoelastic materials. The constitutive equations are considered in differential form via relations between strain, stress, and their derivatives in the Lagrangian description. The thermodynamic consistency is established by using the Clausius–Duhem inequality through a procedure that involves two uncommon features. Firstly, the entropy production is regarded as a positive-valued constitutive function per se. This view implies that the inequality is in fact an equation. Secondly, this statement of the second law is investigated by using an algebraic representation formula, thus arriving at quite general results for rate terms that are usually overlooked in thermodynamic analyses. Starting from strain-rate or stress-rate equations, the corresponding finite equations are derived. It then emerges that a greater generality of the constitutive equations of the classical models, such as those of Boltzmann and Maxwell, are obtained as special cases. Full article
(This article belongs to the Special Issue Computational Mechanics and Applied Mathematics)
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7 pages, 799 KiB  
Proceeding Paper
Neuro-Evolution of Augmenting Topologies for Dynamic Scheduling of Flexible Job Shop Problem
by Jian Huang, Yarong Chen, Jabir Mumtaz and Liuyan Zhong
Eng. Proc. 2024, 75(1), 19; https://doi.org/10.3390/engproc2024075019 - 24 Sep 2024
Viewed by 247
Abstract
In flexible production environments, challenges such as fluctuating customer demands and machine performance degradation significantly complicate production scheduling. This study introduces a neuro-evolution of augmenting topologies (NEAT) algorithm aimed at optimizing the scheduling efficiency in flexible job shops by minimizing both maximum completion [...] Read more.
In flexible production environments, challenges such as fluctuating customer demands and machine performance degradation significantly complicate production scheduling. This study introduces a neuro-evolution of augmenting topologies (NEAT) algorithm aimed at optimizing the scheduling efficiency in flexible job shops by minimizing both maximum completion and average lag times, taking into account variables like sporadic job arrivals, variable machining durations, tool wear, preventive maintenance, and equipment failures. The NEAT algorithm harnesses the features of dynamic flexible job shop scheduling problems (DFJSPs) to devise heuristic rules for job selection and machine allocation, synthesizing these rules into coherent scheduling strategies. Employing the entropy weight method, a fitness function for multiobjective optimization is formulated, facilitating the enhancement of the neural network’s structural and nodal parameters through genetic algorithms. Comparative analysis with four conventional scheduling rules indicates that the NEAT approach consistently surpasses traditional methods, especially in managing complex disturbances. For example, in a scenario involving 50 jobs and 20 machines, NEAT dramatically reduced the average completion time to 142.14 s, markedly outperforming the 644.36 s achieved by the minimum operation completion rate/shortest processing time (MOCR/SPT) approach. These findings underscore the superiority of NEAT in dynamic scheduling contexts. Full article
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37 pages, 12671 KiB  
Article
Effect of Water and Nitrogen Coupling Regulation on the Growth, Physiology, Yield, and Quality Attributes of Isatis tinctoria L. in the Oasis Irrigation Area of the Hexi Corridor
by Yucai Wang, Xiaofan Pan, Haoliang Deng, Mao Li, Jin Zhao and Jine Yang
Agronomy 2024, 14(10), 2187; https://doi.org/10.3390/agronomy14102187 - 24 Sep 2024
Viewed by 486
Abstract
To address the prevailing problems of high water and fertilizer input and low productivity in Isatis tinctoria L. production in the Hexi Corridor in China, the effects of different irrigation amounts and nitrogen application rates on growth characteristics, photosynthetic physiology, root yield, and [...] Read more.
To address the prevailing problems of high water and fertilizer input and low productivity in Isatis tinctoria L. production in the Hexi Corridor in China, the effects of different irrigation amounts and nitrogen application rates on growth characteristics, photosynthetic physiology, root yield, and quality of I. tinctoria plants were studied with the aim of obtaining the optimal irrigation level and nitrogen application rate. From 2021 to 2023, we established a two-factor split-plot experiment in the oasis irrigation area with three irrigation amounts (sufficient water, medium water, and low water are 100%, 85%, and 70% of the typical local irrigation quota) for the main zone; three nitrogen application rates (low nitrogen, 150 kg ha−1, medium nitrogen, 200 kg ha−1, and high nitrogen, 250 kg ha−1) for the secondary zone; and three irrigation amounts without nitrogen as the control to explore the response of these different water and nitrogen management patterns for I. tinctoria in terms of growth characteristics, photosynthetic physiology, root yield, and quality. The results showed the following: (1) When the irrigation amount was increased from 75% to 100% of the local typical irrigation quota and the nitrogen application rate was increased from 150 to 250 kg ha−1, while the plant’s height, leaf area index, dry matter accumulation in the stem, leaf, and root, as well as the net photosynthetic rate (Pn), the stomatal conductance (Gs), and the transpiration rate (Tr) of I. tinctoria increased gradually, and the root–shoot ratio decreased. (2) When the irrigation amount increased from 75% to 100% of the local typical irrigation quota, the yield and net proceeds of I. tinctoria increased from 43.12% to 53.43% and 55.07% to 71.61%, respectively. However, when the irrigation quota was 100% of the local typical irrigation quota, and the nitrogen application rate increased from 150 to 200 kg ha−1, the yield of I. tinctoria increased from 21.58% to 23.69%, whereas the increase in nitrogen application rate from 200 to 250 kg ha−1 resulted in a decrease in the yield of I. tinctoria from 10.66% to 18.92%. During the 3-year experiment, the maximum yield of I. tinctoria appeared when treated with sufficient water and medium nitrogen, reaching 9054.68, 8066.79, and 8806.15 kg ha−1, respectively. (3) The effect of different water and nitrogen combination treatments on the root quality of I. tinctoria was significant. Under the same irrigation level, increasing the nitrogen application rate from 150 to 250 kg ha−1 could increase the contents of indigo, indirubin, (R,S)–goitrin, total nucleoside, uridine, and adenosine in the root of I. tinctoria from 3.94% to 9.59%, 1.74% to 12.58%, 5.45% to 18.35%, 5.61% to 11.59%, 7.34% to 11.32%, and 14.98% to 54.40%, respectively, while the root quality of I. tinctoria showed a trend of first increasing and then decreasing under the same nitrogen application level. (4) AHP, the entropy weight method, and the TOPSIS method were used for a comprehensive evaluation of multiple indexes of water–nitrogen coupling planting patterns for I. tinctoria, which resulted in the optimal evaluation of the W3N2 combination. Therefore, the irrigation level was 100% of the local typical irrigation quota, the nitrogen application rate should be appropriately reduced, and controlling the nitrogen application rate at the level of 190.30–218.27 kg ha−1 can improve water–nitrogen productivity yields for I. tinctoria and root quality. The results of this study can provide a theoretical basis and technical support for a more reasonable water and fertilizer management model for the I. tinctoria production industry in the Hexi Corridor in China. Full article
(This article belongs to the Special Issue Water and Fertilizer Regulation Theory and Technology in Crops)
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30 pages, 3076 KiB  
Article
Constant Stress-Partially Accelerated Life Tests of Vtub-Shaped Lifetime Distribution under Progressive Type II Censoring
by Aisha Fayomi, Asmaa A. Ahmed, Neama T. AL-Sayed, Sara M. Behairy, Asmaa M. Abd AL-Fattah, Gannat R. AL-Dayian and Abeer A. EL-Helbawy
Symmetry 2024, 16(9), 1251; https://doi.org/10.3390/sym16091251 - 23 Sep 2024
Viewed by 542
Abstract
In lifetime tests, the waiting time for items to fail may be long under usual use conditions, particularly when the products have high reliability. To reduce the cost of testing without sacrificing the quality of the data obtained, the products are exposed to [...] Read more.
In lifetime tests, the waiting time for items to fail may be long under usual use conditions, particularly when the products have high reliability. To reduce the cost of testing without sacrificing the quality of the data obtained, the products are exposed to higher stress levels than normal, which quickly causes early failures. Therefore, accelerated life testing is essential since it saves costs and time. This paper considers constant stress-partially accelerated life tests under progressive Type II censored samples. This is realized under the claim that the lifetime of products under usual use conditions follows Vtub-shaped lifetime distribution, which is also known as log-log distribution. The log–log distribution is highly significant and has several real-world applications since it has distinct shapes of its probability density function and hazard rate function. A graphical description of the log–log distribution is exhibited, including plots of the probability density function and hazard rate. The log–log density has different shapes, such as decreasing, unimodal, and approximately symmetric. Several mathematical properties, such as quantiles, probability weighted moments, incomplete moments, moments of residual life, and reversed residual life functions, and entropy of the log–log distribution, are discussed. In addition, the maximum likelihood and maximum product spacing methods are used to obtain the interval and point estimators of the acceleration factor, as well as the model parameters. A simulation study is employed to assess the implementation of the estimation approaches under censoring schemes and different sample sizes. Finally, to demonstrate the viability of the various approaches, two real data sets are investigated. Full article
(This article belongs to the Section Mathematics)
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13 pages, 1765 KiB  
Article
Exergy Flow as a Unifying Physical Quantity in Applying Dissipative Lagrangian Fluid Mechanics to Integrated Energy Systems
by Ke Xu, Yan Qi, Changlong Sun, Dengxin Ai, Jiaojiao Wang, Wenxue He, Fan Yang and Hechen Ren
Entropy 2024, 26(9), 791; https://doi.org/10.3390/e26090791 - 14 Sep 2024
Viewed by 588
Abstract
Highly integrated energy systems are on the rise due to increasing global demand. To capture the underlying physics of such interdisciplinary systems, we need a modern framework that unifies all forms of energy. Here, we apply modified Lagrangian mechanics to the description of [...] Read more.
Highly integrated energy systems are on the rise due to increasing global demand. To capture the underlying physics of such interdisciplinary systems, we need a modern framework that unifies all forms of energy. Here, we apply modified Lagrangian mechanics to the description of multi-energy systems. Based on the minimum entropy production principle, we revisit fluid mechanics in the presence of both mechanical and thermal dissipations and propose using exergy flow as the unifying Lagrangian across different forms of energy. We illustrate our theoretical framework by modeling a one-dimensional system with coupled electricity and heat. We map the exergy loss rate in real space and obtain the total exergy changes. Under steady-state conditions, our theory agrees with the traditional formula but incorporates more physical considerations such as viscous dissipation. The integral form of our theory also allows us to go beyond steady-state calculations and visualize the local, time-dependent exergy flow density everywhere in the system. Expandable to a wide range of applications, our theoretical framework provides the basis for developing versatile models in integrated energy systems. Full article
(This article belongs to the Section Multidisciplinary Applications)
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12 pages, 4360 KiB  
Article
Molten Aluminum-Induced Corrosion and Wear-Resistance Properties of ZrB2-Based Cermets Improved by Sintering-Temperature Manipulation
by Huaqing Yi, Kezhu Ren, Hao Chen, Xiang Cheng, Xiaolong Xie, Mengtian Liang, Bingbing Yin and Yi Yang
Materials 2024, 17(18), 4451; https://doi.org/10.3390/ma17184451 - 10 Sep 2024
Viewed by 672
Abstract
During the hot dip aluminum plating process, components such as sinking rollers, pulling rollers, and guide plates will come into long-term contact with high-temperature liquid aluminum and be corroded by the aluminum liquid, greatly reducing their service life. Therefore, the development of a [...] Read more.
During the hot dip aluminum plating process, components such as sinking rollers, pulling rollers, and guide plates will come into long-term contact with high-temperature liquid aluminum and be corroded by the aluminum liquid, greatly reducing their service life. Therefore, the development of a material with excellent corrosion resistance to molten aluminum is used to prepare parts for the dipping and plating equipment and protect the equipment from erosion, which can effectively improve the production efficiency of the factory and strengthen the quality of aluminum-plated materials, which is of great significance for the growth of corporate profits. With AlFeNiCoCr as the binder phase and ZrB2 as the hard phase, ZrB2-based ceramic composites were prepared by spark plasma sintering (SPS). SEM, EDS and XRD were used to characterize the microstructure and properties of the sintered, corroded, and abraded material samples. The density, fracture toughness, corrosion rate and wear amount of the composite material were measured. The results show that ZrB2-AlFeNiCoCr ceramics have compact structure and excellent mechanical properties, and the density, hardness and fracture toughness of ZrB2-AlFeNiCoCr increase with the increase in sintering temperature. However, when the composite material is at 1600 °C, the relative density of the sintering at 1600 °C decreases due to the overflow of the bonding phase. Therefore, when the sintering temperature is 1500 °C, the high entropy alloy has the best performance. The average corrosion rate of ZrB2-1500 at 700 °C liquid aluminum is 1.225 × 10−3 mm/h, and the wear amount in the friction and wear test is 0.104 mm3. Full article
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22 pages, 3926 KiB  
Article
Optimization of Laser Cladding Parameters for High-Entropy Alloy-Reinforced 316L Stainless-Steel via Grey Relational Analysis
by Senao Gao, Qiang Fu, Mengzhao Li, Long Huang, Nian Liu, Chang Cui, Bing Yang and Guodong Zhang
Coatings 2024, 14(9), 1103; https://doi.org/10.3390/coatings14091103 - 1 Sep 2024
Cited by 2 | Viewed by 1073
Abstract
Laser cladding technology serves as a pivotal technique in industrial production, especially in the realms of additive manufacturing, surface enhancement, coating preparation, and the repair of part surfaces. This study investigates the influence of metal powder composition and processing parameters on laser cladding [...] Read more.
Laser cladding technology serves as a pivotal technique in industrial production, especially in the realms of additive manufacturing, surface enhancement, coating preparation, and the repair of part surfaces. This study investigates the influence of metal powder composition and processing parameters on laser cladding coatings utilizing the Taguchi orthogonal experimental design method. To optimize the laser cladding parameters, multi-response grey relational analysis (GRA) was employed, aiming to improve both the microhardness and the overall quality of the coatings. The optimal parameter combinations identified through GRA were subsequently validated through experimental tests. The results reveal that the microhardness and quality of the coatings are substantially influenced by several critical factors, including the powder feed rate, laser power, high-entropy alloy (HEA) addition rate, scanning speed, and substrate tilt angle. Specifically, the powder feed rate exerts the most significant effect on the microhardness, dilution rate, and average contact angle. In contrast, laser power primarily impacts the mean contact angle difference. The HEA addition rate notably affects the mean contact angle difference, while the scanning speed affects the microhardness and the substrate tilt angle influences the average contact angle. The results of the validation experiment showed a deviation of only 0.95% from the predicted values, underscoring the efficacy of the grey relational analysis (GRA) in optimizing the laser cladding process parameters. The methodology presented in this paper can be applied to determine the ideal processing parameters for multi-response laser cladding processes, encompassing applications such as surface peening and surface repair. Full article
(This article belongs to the Special Issue Research and Application of High Entropy Alloys)
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20 pages, 19570 KiB  
Article
Effect of Combined Application of Wood Vinegar Solution and Biochar on Saline Soil Properties and Cotton Stress Tolerance
by Liu Yang, Guangmu Tang, Wanli Xu, Yunshu Zhang, Songrui Ning, Pujia Yu, Jie Zhu, Qingsong Wu and Peng Yu
Plants 2024, 13(17), 2427; https://doi.org/10.3390/plants13172427 - 30 Aug 2024
Viewed by 673
Abstract
Biomass pyrolysis by-products, such as biochar (BC) and wood vinegar (WV), are widely used as soil conditioners and efficiency enhancers in agriculture. A pot experiment was conducted to examine the effects of WV, both alone and in combination with BC, on soil properties [...] Read more.
Biomass pyrolysis by-products, such as biochar (BC) and wood vinegar (WV), are widely used as soil conditioners and efficiency enhancers in agriculture. A pot experiment was conducted to examine the effects of WV, both alone and in combination with BC, on soil properties in mildly saline soil and on cotton stress tolerance. The results demonstrated that BC and WV application, either individually or together, increased soil nutrient content. The combined application was more effective than the individual applications, resulting in a 5.18–20.12% increase in organic matter, a 2.65–15.04% increase in hydrolysable nitrogen, a 2.23–58.05% increase in effective phosphorus, and a 2.71–29.38% increase in quick-acting potassium. Additionally, the combined application of WV and BC led to greater improvements in cotton plant height, net photosynthetic rate (Pn), leaf nitrate reductase (NR), superoxide dismutase (SOD), and catalase (CAT) activities compared to the application of BC or WV alone. The enhancements in this study varied across different parameters. Plant height showed an increase of 14.32–21.90%. Net photosynthetic rate improved by 13.56–17.60%. Leaf nitrate reductase increased by 5.47–37.79%. Superoxide dismutase and catalase showed improvements of 5.82–64.95% and 10.36–71.40%, respectively (p < 0.05). Moreover, the combined treatment outperformed the individual applications of WV and BC, resulting in a significant decrease in MDA levels by 2.47–51.72% over the experimental period. This combined treatment ultimately enhanced cotton stress tolerance. Using the entropy weight method to analyze the results, it was concluded that the combined application of WV and BC could enhance soil properties in mildly saline soils, increase cotton resistance, and hold significant potential for widespread application. Full article
(This article belongs to the Special Issue Soil Carbon Management for Crop Production)
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11 pages, 2613 KiB  
Article
Manufacturing of Ni-Co-Fe-Cr-Al-Ti High-Entropy Alloy Using Directed Energy Deposition and Evaluation of Its Microstructure, Tensile Strength, and Microhardness
by Ho-In Jeong, Jae-Hyun Kim and Choon-Man Lee
Materials 2024, 17(17), 4297; https://doi.org/10.3390/ma17174297 - 30 Aug 2024
Cited by 1 | Viewed by 633
Abstract
High-entropy alloys (HEAs) have drawn significant attention due to their unique design and superior mechanical properties. Comprising 5–35 at% of five or more elements with similar atomic radii, HEAs exhibit high configurational entropy, resulting in single-phase solid solutions rather than intermetallic compounds. Additive [...] Read more.
High-entropy alloys (HEAs) have drawn significant attention due to their unique design and superior mechanical properties. Comprising 5–35 at% of five or more elements with similar atomic radii, HEAs exhibit high configurational entropy, resulting in single-phase solid solutions rather than intermetallic compounds. Additive manufacturing (AM), particularly direct energy deposition (DED), is effective for producing HEAs due to its rapid cooling rates, which ensure uniform microstructures and minimize defects. These alloys typically form face-centered cubic (FCC) or body-centered cubic (BCC) structures, contributing to their exceptional strength, hardness, and mechanical performance across various temperatures. However, FCC-structured HEAs often have low yield strengths, posing a challenge for structural applications. In this study, a Ni-Co-Fe-Cr-Al-Ti HEA was manufactured using the DED method. This study proposes that the addition of aluminum and titanium creates a γ + γ′ phase structure within a multicomponent FCC-HEA matrix, enhancing the thermal stability and coarsening the resistance and strength. The γ′ phase with an ordered FCC structure significantly improves the mechanical properties. Analysis confirmed the presence of the γ + γ′ structure and demonstrated the alloy’s high tensile strength and microhardness. This approach underscores the potential of AM techniques in advancing HEA production for high-performance applications. Full article
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18 pages, 3765 KiB  
Article
Optimizing Fertilization Strategies to Promote Leaf-Use Ginkgo Productivity and Ecosystem Economic Benefits: An Integrated Evaluation of a Field Trial in Southern China
by Mengrui Xiao, Shuangshuang Chu, Fenglin Zheng, Lihua Xian, Jie Lu, Dandan Liao, Jianhui Ouyang, Mandi Long, Douglass F. Jacobs, Dongnan Hu and Shucai Zeng
Agronomy 2024, 14(9), 1956; https://doi.org/10.3390/agronomy14091956 - 29 Aug 2024
Viewed by 423
Abstract
Field experiments were conducted on a four-year-old leaf-use ginkgo plantation in southern China to assess the impact of nine different fertilization strategies with varying N-P2O5-K2O rates at three growth phases (FBD: March for bud development; FLG: May [...] Read more.
Field experiments were conducted on a four-year-old leaf-use ginkgo plantation in southern China to assess the impact of nine different fertilization strategies with varying N-P2O5-K2O rates at three growth phases (FBD: March for bud development; FLG: May for leaf growth; FLS: July for leaf strengthening) on leaf-use ginkgo (Ginkgo biloba L.) leaf productivity and ecological economic benefits (EEBs). The results indicated that regardless of timing and rate, fertilizer application led to an increase in leaf area and thickness, resulting in higher ginkgo leaf yield. The highest fresh (215.14 g tree−1) and dry (78.83 g tree−1) yields were observed with 3 g N + 2.5 g P2O5 + 1.5 g K2O tree−1 in FLG. FLS was found to mitigate the decline in SPAD values of leaves during late summer. Furthermore, fertilized ginkgo trees exhibited higher flavonoid concentrations in leaves, enhancing profitability. However, higher fertilizer rates were associated with elevated greenhouse gas emissions, nitrogen losses and ecological costs. Despite these drawbacks, all fertilization treatments resulted in increased net economic income. Specifically, compared to no fertilization, FBD, FLG and FLS treatments boosted net income by 3.5~26.6%, 11.6~60.5% and 5.8~35.4%, respectively. Using the entropy weight TOPSIS method, it was concluded that optimizing the N, P and K fertilization rate and timing (applying 3–2.5–1.5 g tree−1 of N-P2O5-K2O in May) is a beneficial approach to maximize EEBs and industrial benefits in leaf-use ginkgo plantations in southern China. This study provides valuable insights into suitable fertilization patterns and management for leaf-use ginkgo plantations in southern China. Full article
(This article belongs to the Section Horticultural and Floricultural Crops)
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