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Unit 11 - Problem Set 3

This document provides 11 practice problems related to chemical equilibrium. The problems cover topics such as writing equilibrium expressions, calculating equilibrium concentrations given initial concentrations and equilibrium constants, and predicting the effect of changes to a system at equilibrium on the direction of the reaction.

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107 views

Unit 11 - Problem Set 3

This document provides 11 practice problems related to chemical equilibrium. The problems cover topics such as writing equilibrium expressions, calculating equilibrium concentrations given initial concentrations and equilibrium constants, and predicting the effect of changes to a system at equilibrium on the direction of the reaction.

Uploaded by

api-182809945
Copyright
© © All Rights Reserved
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Equilibrium Practice Problems- Complete Odd #

Questions
Complete more for extra practice.
1. Write the equilibrium expression for each of the following
reactions:
N2 (g) + 3 H2 (g) 2 NH3 (g)
I2 (s) + Cl2 (g) 2 ICl
NO2 (g) NO

(g)

(g)

+ O2 (g)

2. The dissociation of acetic acid, CH3COOH, has an equilibrium


constant at
25C of 1.8 x 10-5. The reaction is
CH3COOH (aq) CH3COO- (aq) + H+ (aq)
If the equilibrium concentration of CH3COOH is 0.46 moles in
0.500 L of
water and that of CH3COO- is 8.1 x 10-3 moles in the same 0.500
L,
calculate [H+] for the reaction.

3. Given the initial partial pressures of (PPCl5) = 0.0500 atm, (PPCl3) =


0.150 atm, and (PCl2) = 0.250 atm at 250C for the following
reaction, what must each equilibrium partial pressure be?
PCl5 (g) PCl3 (g) + Cl2 (g)
Kp = 2.15

4. The reaction
2 NO (g) N2 (g) + O2 (g)
has a value
of
K= 2400 at 2000 K. If 0.61 g of NO are put in a previously empty 3.00
L
vessel, calculate the equilibrium concentrations of NO, N2, and O2.
5. Using the same reaction as in #4, calculate the equilibrium
concentrations of NO, N2, and O2 if the initial concentrations of
each species are:
[NO] = 0 M, [N2] = 0.850 M, [O2] = 0.560 M.

6. The following reaction has an equilibrium constant of 620 at a


certain temperature. Calculate the equilibrium concentrations of
all species if 4.5 mol of each component were added to a 3.0 L
flask.
H2 (g) + F2 (g) 2 HF (g)
7. Ammonia undergoes hydrolysis according to the following
reaction:
NH3 (aq) + H2O NH4+ (aq) + OH- (aq)
K = 1.8 x 10-5
Calculate [NH3], [NH4+] and [OH-] in a solution originally 0.200 M
NH3.
8. The equilibrium constant for the following reaction is 600C is
4.0. Initially, two moles of CO and one mole of H2O were mixed
in a 1.0 liter container. Determine the concentration of all
species at equilibrium.

9. If 5.0 moles of O2 and 4.0 moles of NO were entered into an


empty 1.0 liter flask, calculate the equilibrium constant if the
amount of NO2 found at equilibrium was 1.5 moles.

10.
If the equilibrium constant for the following reaction is
0.10, determine the final concentration of ICl, if 4.0 moles of I2
and Cl2 were entered initially into an empty 1.0 liter flask.
11.

The reaction of carbon disulfide with chlorine is as follows:


CS2 (g) + 3 Cl2 (g) CCl4 (g) + S2Cl2 (g)
H = -238 kJ
Predict the effect of the following changes to the system on the
direction
of equilibrium.
a. The pressure on the system is doubled by halving the volume.
b. CCl4 is removed as it is generated.
c. Heat is added to the system.

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