Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd Logo
Upload

Welcome to Scribd!

  • 33 views

    Calc

    Uploaded by

    Jobb Six-steps Matheus
    This document contains data from a process simulation of biodiesel production. It lists the stream names and flowrates of components like triolein, methanol, biodiesel, and glycerol at each step. The process involves two reactors where triolein reacts with methanol to form biodiesel and glycerol. Methanol and glycerol are separated and recycled in mixing tanks. Mass balances and chemical reactions are provided. The total amount of sodium hydroxide added is also calculated.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLSX, PDF, TXT or read online from Scribd

    Calc

    Uploaded by

    Jobb Six-steps Matheus
    33 views34 pages
    This document contains data from a process simulation of biodiesel production. It lists the stream names and flowrates of components like triolein, methanol, biodiesel, and glycerol at each step. The process involves two reactors where triolein reacts with methanol to form biodiesel and glycerol. Methanol and glycerol are separated and recycled in mixing tanks. Mass balances and chemical reactions are provided. The total amount of sodium hydroxide added is also calculated.

    Original Title

    calc

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Available Formats

    XLSX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document contains data from a process simulation of biodiesel production. It lists the stream names and flowrates of components like triolein, methanol, biodiesel, and glycerol at each step. The process involves two reactors where triolein reacts with methanol to form biodiesel and glycerol. Methanol and glycerol are separated and recycled in mixing tanks. Mass balances and chemical reactions are provided. The total amount of sodium hydroxide added is also calculated.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    33 views34 pages

    Calc

    Uploaded by

    Jobb Six-steps Matheus
    This document contains data from a process simulation of biodiesel production. It lists the stream names and flowrates of components like triolein, methanol, biodiesel, and glycerol at each step. The process involves two reactors where triolein reacts with methanol to form biodiesel and glycerol. Methanol and glycerol are separated and recycled in mixing tanks. Mass balances and chemical reactions are provided. The total amount of sodium hydroxide added is also calculated.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 34

    Stream Name

    Temperature ( C)
    Pressure (kPa)
    Mass Flowrate (Kg/h)
    Component Flowrate (Kg/h)
    Methanol
    Triolein
    Biodiesel
    Glycerol
    Sodium Methoxide
    Water
    HCl
    NaOH

    P-1

    P-14

    P-2

    P-21

    P-23

    P-24

    P-25

    P-26

    P-27

    P-28

    P-29

    P-3

    P-30

    P-31

    P-32

    P-33

    P-34

    P-35

    P-36

    P-37

    P-38

    P-39

    P-4

    P-40

    P-41

    P-42

    P-43

    P-44

    P-45

    P-46

    P-5

    P-5.1

    P-5.2

    Table of Properties
    Molecular Weight (g/mol)

    Components

    Chemical Formula

    Triolein
    Methanol
    Biodiesel

    C57H104O6

    C19H36O2

    297 0.884 g/cm3

    Glycerol
    Hydrochloric Acid
    Sodium Methoxide
    Sodium Hydroxide
    Water

    C3H8O3

    92.1 1.261 g/cm3

    HCl

    36.46

    NaOCH3

    Sodium Chloride

    NaCl

    CH4O

    NaOH
    H2O

    885.43

    Density
    0.95 g/cm3

    3
    32.04 0.7918 g cm

    54 0.868 g/cm^3
    3
    39.9971 2.13 g cm

    18 1 g/cm3
    58.44 2.165 g cm

    Boiling Point

    Critacal Temperature

    Critical Pressure

    879.9 (K)a

    954.1 (K)a
    513 K

    0.3602 (Mpa)a
    78.5 bar

    656 K

    22.1 (Mpa)

    338 K,

    563 K
    533 K
    1661 K

    273 K
    1686 K

    Material Balance
    Overall Balance:
    Biodiesel Production (kg/h):
    Chemical Reaction:
    Stoichiometric ratios (Kg):
    Ratio to Biodiesel:
    Overall Stoichiometry (Kg/h):

    2500

    Triolein
    885.43

    0.995424
    2488.561

    Overall Conversion:
    Ratio of Methanol to Oil

    0.10806071
    270.151771

    0.99
    6 :1

    NB: Amount of Catalyst is 1% of total oil


    Amount of Sodium Methoxide needed

    Moles of Triolein entering:


    Moles of Excess methanol:

    25.13698
    Water

    Triolein
    Methanol

    HCL

    NaOH
    Components
    Triolein
    Methanol
    Biodiesel
    Glycerol
    Hydrochloric Acid
    Sodium Methoxide
    Sodium Hydroxide
    Water
    Sodium Chloride

    Input

    Output

    2513.698 25.13698
    560.6758 275.6094
    0
    2500
    0 258.8533
    16.97212
    0
    0
    0
    18.61864
    0
    0

    3 Methanol
    96.12

    27.2038

    3 Biodiesel
    889.50
    1
    2500

    Glycerol
    92.10
    0.10354
    258.853

    2.8389573
    17.033744 Mass of Excess Methanol:

    545.7612

    Amount of Sodium Methoxide needed


    Chemical Reaction:
    Molar Mass
    Moles
    Mass

    NaOH

    25.13698

    39.9971
    0.4655
    18.61864

    MeOH

    NaOCH3

    32.04
    0.4655
    14.91461

    54
    0.4655
    25.13698

    Catalyst Mixer

    Components
    Methanol
    NaOH
    Sodium Methoxide
    Water

    Input

    Output

    560.6758 545.7612
    18.61864
    0
    0 25.13698
    0 8.378993
    Methanol

    NaOH

    H2O
    18
    0.4655
    8.378993

    Sodium Methoxide
    Methanol
    Water

    Reactor 1
    Triolein Entering

    2513.698

    Chemical Reaction:
    Stoichiometric ratios (Kg):
    Ratio to Triolein:
    Overall Stoichiometry (Kg/h):

    Triolein
    885.43

    1
    2262.328

    3 Methanol
    96.12

    3 Biodiesel
    889.50

    0.108557
    245.5925

    1.004597
    2272.727

    Reactor Conversion:
    0.9
    Triolein Reacting
    2262.328
    only 80% of Methanol and Catalyst stream entered reactor 1
    Methanol + Catalyst + water

    Triolein

    Components
    input
    Triolein
    Methanol
    Biodiesel
    Glycerol
    Catalyst
    Water

    2513.697969
    436.6089223
    0
    0
    20.10958375
    6.703194584

    Output
    251.3698
    191.0164
    2272.727
    235.3212
    20.10958
    6.703195

    Glycerol
    92.10
    0.104017
    235.3212

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    99% Recovery of components


    60% Methanol in Biodiesel (Top) Stream
    40% Methanol in Glycerol (Bottoms) Stream
    Water is assumed to go with Biodiesel stream

    Component

    Input
    Top

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    2272.727
    191.0164
    235.3212
    235.3212
    20.10958
    6.703195

    Output
    Bottoms

    2250
    114.6098
    2.353212
    232.968
    0.201096
    6.636163

    22.72727
    76.40656
    232.968
    2.353212
    19.90849
    0.067032

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    Top

    Bottoms

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    Reactor 2
    Triolein Entering

    232.968

    Chemical Reaction:
    Triolein
    Stoichiometric ratios (Kg):
    885.43
    Ratio to Triolein:
    1
    Overall Stoichiometry (Kg/h):
    209.6712

    3 Methanol
    96.12

    3 Biodiesel
    889.50

    0.108557
    22.76136

    1.004597
    210.6349

    Reactor Conversion:
    0.9
    Triolein Reacting
    209.6712
    only 20% of Methanol and Catalyst stream entered reactor 2
    Methanol + Catalyst + water

    Components
    input
    Triolein
    232.968
    Methanol 223.7621
    Biodiesel
    2250
    Glycerol
    2.353212
    Catalyst
    5.228492
    Water
    8.311961

    Triolein
    Methanol
    Biodiesel
    Glycerol
    Catalyst
    Water
    Output
    23.2968
    201.0007
    2460.635
    24.16263
    5.228492
    8.311961

    Glycerol
    92.10
    0.104017
    21.80942

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    99% Recovery of components


    60% Methanol in Biodiesel (Top) Stream
    40% Methanol in Glycerol (Bottoms) Stream
    Water is assumed to go with Biodiesel stream

    ComponentInput
    Top
    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    2460.635
    201.0007
    24.16263
    23.2968
    5.228492
    8.311961

    Output
    Bottoms

    2436.029
    120.6004
    0.241626
    23.06383
    0.052285
    8.228842

    24.60635
    80.40028
    23.921
    0.232968
    5.176207
    0.08312

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    Top

    Bottoms

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    Mixing Tank 1
    Amount of Sodium Methoxide needed
    Reaction 2: Neautralisation
    Chemical Reaction:
    NaOH
    Molar Mass
    39.9971
    Moles
    0.000968
    Mass
    0.038727
    Reaction 1: washing
    Chemical Reaction:
    Molar Mass
    Moles
    Mass

    NaOH
    39.9971
    0.000968
    0.038727

    HCl

    NaCl

    36.46
    0.000968
    0.035302

    58.44
    0.000968
    0.056584

    MeOH

    NaOCH3

    32.04
    0.000968
    0.031022

    54
    0.000968
    0.052285

    HCl

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    Components
    Methanol
    Sodium Methoxide
    Water
    Glycerol
    Biodiesel
    Triolein
    NaCl
    HCl

    Input
    120.6004
    0.052285
    8.228842
    0.241626
    2436.029
    23.06383
    0
    0.035302

    Output
    120.6314
    0
    8.228842
    0.241626
    2436.029
    23.06383
    0.056584
    0

    H2O
    18
    0.000968
    0.017428

    H2O
    18
    0.000968
    0.017428

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    99% Recovery of components


    10% Methanol in Biodiesel (Top) Stream

    ComponentInput
    Top
    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    2436.029
    120.6314
    0.241626
    23.06383
    0.056584
    8.228842

    Output
    Bottoms

    2411.668
    12.06314
    0.002416
    22.83319
    0.000566
    8.146553

    24.36029
    108.5683
    0.23921
    0.230638
    0.056018
    0.082288

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    Top

    Bottoms

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    ComponentInput
    Top
    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    2411.668
    12.06314
    0.241626
    22.83319
    0.000566
    8.146553

    Output
    Bottoms

    0 2411.66831
    11.94251 0.120631449
    0.241626
    0
    0 22.83318971
    0.000566
    0
    8.065088 0.081465533

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    Mixing Tank 1
    Amount of Sodium Methoxide needed
    Reaction 2: Neautralisation
    Chemical Reaction:
    NaOH
    Molar Mass
    39.9971
    Moles
    0.464531
    Mass
    18.57991
    Reaction 1: washing
    Chemical Reaction:
    Molar Mass
    Moles
    Mass

    NaOH
    39.9971
    0.464531
    18.57991

    HCl

    NaCl

    36.46
    0.464531
    16.93681

    58.44
    0.464531
    27.14721

    MeOH

    NaOCH3

    32.04
    0.464531
    14.88359

    54
    0.464531
    25.08469

    HCl

    Biodiesel
    Methanol
    Glycerol
    Oil
    Catalyst
    Water

    Components
    Methanol
    Sodium Methoxide
    Water
    Glycerol
    Biodiesel
    Triolein
    NaCl
    HCl

    Input
    277.3177
    25.08469
    8.297528
    257.3698
    71.69391
    2.816818
    0.056584
    16.93681

    Output
    292.2012
    0
    8.297528
    257.3698
    71.69391
    2.816818
    27.14721
    0

    H2O
    18
    0.464531
    8.361565

    H2O
    18
    0.464531
    8.361565

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    99% Recovery of components


    100% Methanol in Glycerol (Top) Stream

    ComponentInput
    Top
    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    71.69391
    292.2012
    257.3698
    2.816818
    27.14721
    8.297528

    Output
    Bottoms

    70.97697
    292.2012
    2.573698
    2.78865
    0.271472
    8.214552

    0.716939
    0
    254.7961
    0.028168
    26.87574
    0.082975

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    Top

    Bottoms

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    ComponentInput
    Top
    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    2411.668
    12.06314
    0.241626
    22.83319
    0.000566
    8.146553

    Output
    Bottoms

    0
    11.94251
    0.241626
    0
    0.000566
    8.065088

    2411.668
    0.120631
    0
    22.83319
    0
    0.081466

    Methanol
    Glycerol

    Water

    Water + Methanol

    Glycerol

    ComponentInput
    Top
    Biodiesel
    Methanol
    Glycerol
    Oil
    NaCl
    Water

    Output
    Bottoms

    0
    0
    0
    12.06314 12.06314
    0
    0
    0
    0
    0
    0
    0
    0
    0
    0
    8.146553
    0 8.146553

    Methanol
    Water

    Water

    Methanol

    Water

    Total Amount of NaOH that entered the system


    Chemical Reaction:
    Molar Mass
    Moles
    Mass

    HCl
    36.46
    0.4655
    16.97212

    18.61864

    NaOH

    NaCl

    39.9971
    0.4655
    18.61864

    58.44
    0.4655
    27.2038

    H2O
    18
    0.4655
    8.378993

    You might also like